Technical Commentary/ Flux Flummoxed: A Proposal for Consistent Usage by Philip H. Stauffer I would like to bring to the attention of the hydrogeology community an ongoing inconsistency in the published literature concerning the use of the term flux. The definition of flux that is most pertinent to Ground Water readers comes from the field of transport phenomena, where the flux of some quantity (e.g., mass, energy, momentum, entropy) is defined as the flow rate of that quantity per unit area. For example, a mass flow rate, which has SI units of kg/s, when referenced to a unit area, results in mass flux having SI units of kg/(m2 s). Because this definition includes a direction (i.e., the surface normal of the unit area), flux is a vector. I would like to propose that the community agrees to consistently use this definition in technical presentations, published literature, and, most importantly, classrooms. To support this proposal, I first present details on the two primary definitions of flux currently used in physics, describe the fluxes most commonly found in hydrogeology, continue with a brief history of the usage of the term flux, and then give some examples of uses that are either incorrect or confusing. 1983). Continuum mechanics and vector analysis are the primary tools used to construct and solve the governing equations of ground water flow and solute transport (Bear 1972; de Marsily 1986; Anderson and Woessner 1992; Fetter 1999). For example, because it is a vector, mass flux ( fm) can be used in transport equations such as the statement of mass continuity as r( fm) 2 (mass accumulation rate) ¼ 0, where r is the divergence operator and bold type is used to denote a vector quantity (Boas 1983). Conversely, the EM definition leads to magnetic or electric flux being a scalar quantity that has no time component. These two distinct definitions have been used for more than 100 years. Recently, however, there has been a trend to mix these two definitions without being clear as to which usage is intended. One possible explanation for this trend is that some EM textbooks use the flow of water as an analogy for magnetic flux, apparently unaware that the transport definition of flux is quite different (Lorrain and Corson 1962). Additional confusion comes from sources such as Chen (1995), who mistakenly applies an EM style integral definition of flux to the transport of mass through a finite surface. Flux Defined In the various subfields of physics, there exist two common usages of the term flux with rigorous mathematical frameworks. First, from the field of unified transport phenomena (momentum, heat, and mass transport), the flux of some quantity is defined as the flow rate of that quantity per unit area (Bird et al. 2002). Second, the field of electromagnetism (EM) defines flux as the surface integral of a vector field (Lorrain and Corson 1962). Because transport flux is defined with respect to the outward normal of the reference area, flux is a vector at each point in space (Carslaw and Jaeger 1959; Bird et al. 2002). Vectors have special properties and implied meaning in both mathematics and continuum mechanics (Boas Mail Stop T003, Earth and Environmental Sciences Division, Los Alamos National Laboratory, Los Alamos, NM 87545; (505) 665 4638; stauffer@lanl.gov Received October 2005, accepted November 2005. Journal compilation ª 2006 National Ground Water Association. No claim to original US government works. doi: 10.1111/j.1745-6584.2006.00197.x Fluxes in Hydrogeology The most common flux used in the field of hydrogeology is the volumetric flux (q), expressed by the generalized form of Darcy’s law as follows: q ¼ 2Kr(h), with SI units of m3/(m2 s) where K is the hydraulic conductivity tensor as a function of water content and h is the hydraulic head (Evans et al. 2001). Although the correct English term is volumetric flux, I would like to suggest that for consistency with mass flux, energy flux, solute flux, and heat flux, we use the term volume flux to describe q in Darcy’s law. An added benefit of this consistent usage is that students will have a much easier time making transitions between discussions of Darcy’s law, Fourier’s law, and Fick’s law. In these three cases, the volume flux (q), thermal energy flux (qt), and diffusive chemical flux (j) are related to the spatial gradients of scalar fields multiplied by a function of material properties (e.g., qt ¼ 2Ktr (temperature) and j ¼ 2Dr (concentration) where Kt and D are the thermal conductivity tensor and chemical diffusion tensor, respectively) (Bejan Vol. 44, No. 2—GROUND WATER—March–April 2006 (pages 125–128) 125 1995). Although one might be tempted to define flux based on the notion of the spatial gradient of a scalar field, many fluxes, including mass flux with a high Reynolds number and neutron flux, are not related to a scalar field. History of Flux in Transport Phenomena One of the first instances of the use of the term flux to describe transport was by Maxwell (1891):‘‘the flux of heat at any point of a solid body may be defined as the quantity of heat which crosses a small area drawn perpendicular to that direction divided by that area and by the time. Here the flux is referenced to an area.’’ Maxwell (1891) also states that ‘‘In the case of fluxes, we have to take the integral, over a surface, of the flux through every element of the surface. The result of this operation is called the Surface integral of the flux. It represents the quantity which passes through the surface.’’ Thus, the integral of the flux of some quantity is defined as the flow rate of that quantity through the surface of integration. Carslaw and Jaeger (1959) state that ‘‘The rate at which heat is transferred across any surface S at a point P, per unit area per unit time, is called the flux of heat.’’ The authors note that the units of heat flux are energy per unit area per unit time. Additionally, after presenting the onedimensional Fourier equation for heat flux, they develop the general form of the equation in three dimensions and arrive at the heat flux vector (qt) that is, for the rest of the book, referred to as simply ‘‘heat flux.’’ In one of the most cited transport textbooks, Bird et al. (1960) state that ‘‘By 126 P.H. Stauffer GROUND WATER 44, no. 2: 125–128 flux is meant ‘rate of flow per unit area.’ Momentum flux then has units of momentum per unit area per unit time.’’ Also discussed in Bird et al. (1960) is Fickian mass flux, defined as mass flow rate per unit area, with SI units of kg/(m2 s). A well-written summary of flux as related to the laws of conservation in heat and mass transfer can be found in Potter (1967). In this engineering sciences handbook, heat flux, work flux, and mass flux are defined as vectors. Furthermore, the author notes that the difficult concept of fluid velocity (nonporous) can be more easily understood as the mass flux divided by the fluid density (qf). Interestingly, the nonporous fluid velocity, fm/qf, reduces to the volume flux of the fluid, acknowledging that the true velocity (dx/dt) of a fluid molecule is not so clearly defined (e.g., turbulent flow). Bear (1972), in his development of the equations of ground water flow, makes a careful distinction between the specific discharge and the specific discharge vector. However, after the introductory material, he refers to the specific discharge vector as simply ‘‘specific discharge.’’ Turcott and Shubert (1982) are very clear that heat flux is a vector with SI units of W/m2. The authors also differentiate heat flux from heat flow, which has units of W or energy per time. Anderson and Woessner (1992) clearly state that q in Darcy’s law is a vector. Fetter (1999) distinguishes between the vector q and a one-dimensional q, and note that in the general form of the transport equations, specific discharge is a vector. I would argue that q is a vector in either case, because if the one-dimensional Darcy equation were really just giving the magnitude of the flux vector (a scalar), there would be no need for the negative sign that indicates the direction of flow. In all these examples, the flux of a quantity (e.g., energy, mass, moles) is defined as a vector. The historical record shows that although usage of the term flux began in a fairly loose manner, referring to both the magnitude of a vector and the vector itself, usage quickly evolved to define flux as a vector. Flux Flummoxed In the subsurface flow literature, volume flux is described using many very different terms such as water flux (Jury et al. 1992), volumetric flux vector (Evans et al. 2001), specific flux vector (Bear 1972), volumetric flow rate per unit area (Turcott and Shubert 1982), Darcy velocity (Domenico and Schwartz 1990), fictitious velocity (Davis and DeWiest 1966), superficial velocity (Lake 1989), specific discharge (Fetter 1980), specific discharge vector (Bear 1972), discharge rate (Anderson and Woessner 1992), flux density (Hillel 1982), filtration velocity (de Marsily 1986), or Darcy flux (Fetter 1999). These terms are all used to refer to the same quantity and lead to much confusion not just among students but also among researchers in the field. Of all these terms, the most commonly used is specific discharge, which is generally defined as follows: Q/A, where Q is the volumetric flow rate (m3/s) and A is the area over which that volume is flowing. Although this term is often used synonymously with volume flux, specific discharge is not necessarily a vector, unless the normal to the area of integration is given. Use of the term specific flux is redundant as it is implicit in the transport definition of flux that the flow is per unit area. Additionally, in the field of thermodynamics, use of the term specific as a modifier has a long association with meaning ‘‘per mass,’’ as in specific volume (m3/kg), specific surface area (m2/kg), specific enthalpy (J/kg), and specific heat (J/(kg C)). The expression volumetric flux vector is also redundant because when using the transport definition, flux is a vector. The use of Darcy flux is vague to readers outside the hydrogeology field, suggesting that this term be carefully defined in publications as a volume flux. The term Darcy velocity should not be used as this confuses the actual average water velocity (also called seepage velocity) and the volume flux; although both have units of length per time, each has a very distinct meaning. The terms fictitious velocity, filtration velocity, and superficial velocity are also poor choices for describing volume flux as they imply a velocity that is not real. The term flux density apparently is a combination of the EM and transport definitions. The EM literature discusses the flux density of a magnetic field as the magnetic field strength per area. Flux density has no meaning with respect to the transport definition of flux. Another common misuse is the term flux rate, which is redundant because all transport fluxes are rates (i.e. per unit time). This is akin to saying velocity rate. Another confusing usage, although somewhat infrequent, is to call the volumetric flow rate the flux of water (de Marsily 1986) or volumetric flux (Freeze and P.H. Stauffer GROUND WATER 44, no. 2: 125–128 127 Cherry 1979). Finally, confusion is introduced in books such as Turcott and Shubert (1982). Although the authors make careful definitions of heat flux (J/(m2 s)) and heat flow (J/s) in equations 4-1 and 4-5, throughout the text they mix these terms in a loose and imprecise manner. Summary This technical commentary shows that the most appropriate definition of flux, as related to ground water, is that used in the field of transport phenomena. With respect to transport phenomena, the flux of some quantity is defined as the flow rate of that quantity per unit area. Because flux is defined with respect to a direction, flux is a vector at each point in space. Vectors have special properties and implied meaning in both mathematics and continuum mechanics. I propose that the transport definition of flux be used consistently in technical presentations, published papers, books, and earth science classrooms. Consistent usage will help in teaching the next generation of hydrogeologists that flux has a definite meaning in science. Acknowledgments Reprinted (heavily revised) with permission from the October 2005 issue of The Hydrogeologist, Newsletter of the Geological Society of America Hydrogeology Division. Special thanks to Eleanor Dixon, Don Neeper, Carl Gable, Ioannis Tsimpanogiannis, Kay Birdsell, Bruce Robinson, George Zyvoloski, Dan Levitt, Josh Stein, Andy Fisher, Chris Neuzil, David Deming, and Mary Anderson for their very helpful and interactive reviews of this commentary. References Anderson, M.P., and W.W. Woessner. 1992. Applied Groundwater Modeling, Simulation of Flow and Advective Transport. San Diego, California: Academic Press. 128 P.H. Stauffer GROUND WATER 44, no. 2: 125–128 Bear, J. 1972. Dynamics of Fluids in Porous Media. New York: Dover Publications. Bejan, A. 1995. Convective Heat Transfer, 2nd ed. New York: J. Wiley and Sons. Bird, R.B., W.E. Stewart, and E.N. 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