I. ASCRC General Education Form (revised 2/8/13) Use to propose new general education courses (except writing courses), to change or renew existing gen ed courses and to remove designations for existing gen ed courses. Note: One-time-only general education designation may be requested for experimental courses (X91-previously X95), granted only for the semester taught. A NEW request must be submitted for the course to receive subsequent general education status. Group II. Mathematics VII: Social Sciences (submit III. Language VIII: Ethics & Human Values separate forms III Exception: Symbolic Systems * IX: American & European if requesting IV: Expressive Arts X: Indigenous & Global more than one V: Literary & Artistic Studies XI: Natural Sciences general w/ lab w/out lab X education VI: Historical & Cultural Studies group *Courses proposed for this designation must be standing requirements of designation) majors that qualify for exceptions to the modern and classical language requirement Dept/Program Chemistry and Biochemistry Course # CHMY121N Course Title Prerequisite Introduction to General Chemistry None Credits II. Endorsement/Approvals Complete the form and obtain signatures before submitting to Faculty Senate Office Please type / print name Signature Instructor Phone / Email 3 Date Garon Smith (406) 243-5606 garon.smith@umontana.edu Program Chair Mark Cracolice Dean Christopher Comer III. Type of request New One-time Only Renew X Change Remove Reason for Gen Ed inclusion, change or deletion Description of change IV. Description and purpose of the general education course: General Education courses must be introductory and foundational within the offering department or within the General Education Group. They must emphasize breadth, context, and connectedness; and relate course content to students’ future lives: See Preamble: http://umt.edu/facultysenate/archives/minutes/gened/GE_preamble.aspx CHMY121N is aimed at students who require a working knowledge of chemistry for careers in fields such as forestry, resource management, wildlife biology, botany, zoology, nursing, medical technology, physical therapy, athletic training, exercise physiology and environmental studies. It provides a foundation of chemical principles illustrated through their application to "real world" examples, especially those with environmental or medical implications. Real world examples include an examination of the former Smurfit-Stone Pulp Mill and its impacts on the community, air pollution in the Missoula Valley and its primary sources, cyanide heap leaching, diesel contamination of the Missoula aquifer, and conditioning honey bees to find buried landmines and hidden explosives. V. Criteria: Briefly explain how this course meets the criteria for the group. See: http://umt.edu/facultysenate/documents/forms/GE_Criteria5-1-08.aspx The course systematically develops Courses explore a discipline in the skills in fundamental chemistry - atomic natural sciences and demonstrate how and molecular theory, nuclear chemistry, the scientific method is used within the chemical bonding, chemical reactions discipline to draw scientific conclusions. (precipitation, acid/base and redox), states of matter, and aqueous solution chemistry. In many instances, students are presented with historical data that led to “Aha-Insight!” moments in the field. They’re then challenged to “see the Eureka!” themselves. One example of this is uncovering number patterns in the quantum nature of electron energy levels. Courses address the concept of analytic uncertainty and the rigorous process required to take an idea to a hypothesis and then to a validated scientific theory. Lab courses engage students in inquirybased learning activities where they formulate a hypothesis, design an experiment to test the hypothesis, and collect, interpret, and present the data to support their conclusions. Instead of simply relating what scientists discovered in the past, the class is regularly invited to look at real data and find the patterns in it for themselves. (See an example of this in the Student Learning Goals section below.) Not a lab course although I run many demos as a simulation of the scientific method, i.e., challenge them to debunk my “magical prowess” with a testable hypothesis. I often refuse to explain how my “tricks” work until they systematically divine its underlying principle through observations and testing. VI. Student Learning Goals: Briefly explain how this course will meet the applicable learning goals. See: http://umt.edu/facultysenate/documents/forms/GE_Criteria5-1-08.aspx understand the general principles associated with the discipline(s) studied; I have systematically developed and refined a wealth of very detailed course materials that seem effective in reaching virtually the entire spectrum of my course audience. Among my most valuable tools are embedded remedial mathematics tutorials to help those who are quantitatively challenged. These are captured through Camtasia which blends all PowerPoints, projected items (website visits, video clips) and the miced audio lecture into an MP3 file that is available on ITunesU immediately after class. I also archive them as part of the Mansfield Library’s electronic reserve. I regularly teach workshops on their design and construction at a summer National Science Foundation institute. understand the methodology and I provide detailed accounts of activities scientists use to gather, validate instrumental methods and laboratory and interpret data related to natural protocols used to acquire data. Many processes; are historical accounts of how discoveries were made. This is done primarily in environmental applications with air and water quality issues or with public health, areas in which I am actively engaged in as funded research or professional activities. detect patterns, draw conclusions, develop conjectures and hypotheses, and test them by appropriate means and experiments understand how scientific laws and theories are verified by quantitative measurement, scientific observation, and logical/critical reasoning; and understand the means by which analytic uncertainty is quantified and expressed in the natural sciences. As an example of this, I present 10 years worth of hydrogen sulfide data from the Frenchtown pulp mill in graphical form and ask the students to tell me what they see. Most find both a seasonal trend and a diurnal trend once “noise” has been suppressed with an averaging strategy. I subsequently present meteorological data that are completely consistent with the hypothesis to which they are inevitably drawn and relate how the Montana DEQ eventually ruled on this question. As Chair of the Missoula City-County Health, Air and Water Boards, I share with them current health and environmental issues that are under debate in the local community. I present them with the data and arguments on both sides of the question. I later disclose how the question played out during the public hearings, which data and explanations held merit and how the Board ultimately voted. VII. Justification: Normally, general education courses will not carry pre-requisites, will carry at least 3 credits, and will be numbered at the 100-200 level. If the course has more than one pre-requisite, carries fewer than three credits, or is upper division (numbered above the 200 level), provide rationale for exception(s). VIII. Syllabus: Paste syllabus below or attach and send digital copy with form. The syllabus should clearly describe how the above criteria are satisfied. For assistance on syllabus preparation see: http://teaching.berkeley.edu/bgd/syllabus.html CHMY 121N – SPRING 2013 INTRODUCTION TO GENERAL CHEMISTRY INSTRUCTOR: Dr. Garon C. Smith garon.smith@umontana.edu Office: Chemistry 002 e-mail: Phone: 243-5606 (voice mail) Laboratories: Chemistry 008 OFFICE HRS: M & T 11:10; W & Th 10:10; F 12:10 other times by appointment. Office hours will be met in Chemistry 002. Periodically I have meetings or off-campus duties that conflict with class or office hours. When possible, I will notify you in advance about these times. MATERIALS: Chemistry 121: Introduction to General Chemistry, Volume 1 (Introduction to General, Organic, and Biochemistry. 10th Edition by Frederick A. Bettelheim, William H. Brown, Mary K. Campbell and Shawn O. Farrell), 2012, Brooks Cole Cengage Learning, 321 p. plus appendices. With the purchase of a new text you also get the Solutions Manual for Introduction to General, Organic, and Biochemistry. 10th Edition and access to the OWL online practice problem software. OBJECTIVE: CHMY 121N is aimed at students who require a working knowledge of chemistry for careers in fields such as forestry, resource management, wildlife biology, botany, zoology, nursing, medical technology, physical therapy, athletic training, exercise science, forensic anthropology and environmental studies. It provides a foundation of chemical principles illustrated through their application to "real world" examples, especially those with environmental, physiological or medical implications. The course systematically develops skills in fundamental chemistry atomic and molecular theory, nuclear chemistry, chemical bonding, chemical reactions (precipitation, acid/base and redox), states of matter, and aqueous solution chemistry. In addition, you will gain experience with analytical thinking and quantitative problem solving. Organic chemistry – the study of carbon-containing compounds – is integrated into lecture throughout the semester GRADING: CHMY 121 can ONLY be taken for traditional grades (A, B, C, D, F). Pluses and minuses are awarded as appropriate. The Credit/No Credit option IS NOT available. Grades for CHMY 121 will be determined through a combination of weekly quizzes, online homework assignments, hour exams and a comprehensive final exam. Representative questions and practice problems will be assigned from each chapter in the text. You should thoroughly understand these exercises since good performance on the quizzes, homework and tests relies on being able to complete similar tasks on the exams/quizzes in a timely manner. Attendance is not taken. Persons who miss an exam or quiz due to illness or other extenuating circumstances should contact me in person, leave a voice mail message at (406) 243-5606 or send me an e-mail no later than 48 hours after the test time. I will then make appropriate arrangements. Arrangements after the 48-hour notification period has expired are at the instructor’s discretion. All lecture materials are available on ITunesU and electronic reserve at http://eres.lib.umt.edu Password: CHMY121. If you find errors in grading or wish to have exam/quiz questions regraded, write your comments on your exam/quiz and return it to me within two working days of the date on which graded exams were first available for pick up. Grades adjusted beyond this time period are at the instructor’s discretion. Averages for the course will be computed according to the following weighting scheme: 9 quizzes (drop one) 25% 4 hour exams (drop one) 50% Final exam 25% Total 100% This course is accessible to and usable by otherwise qualified students with disabilities. To request reasonable program modifications, please consult with the instructor. Disability Services for Students will assist the instructor and student in the modification process. For more information, visit the Disability Services website at http://www.umt.edu/disability. All students must practice academic honesty. Academic misconduct is subject to an academic penalty by the course instructor and/or a disciplinary sanction by the University. All students need to be familiar with the Student conduct Code. The Code is available for review online at http://life.umt.edu/vpsa/student_conduct.php. OTHER DATES: Last day to pay or finalize your registration bill before a $40 late fee is Wednesday, January 30th. Last day to drop/add classes without consent is Tuesday, February 5th. Last day to add/drop by paper or CyberBear overrides, receive a partial refund or choose an audit option is Friday, February 15th. Drops with advisor and instructor signatures, “W” on transcript and $10 fee per drop until Monday, April 8th. Drops by petition to dean until Friday, May 10th. COURTESY: This is a large class and can get noisy at times. Please respect those who want to hear by not participating in disruptive conversation, by not allowing cell phones to ring or by making derogatory remarks to others. On exam days, there will probably be a seating overflow. Please be as accommodating as possible. Spring 2013 Tentative Lecture Schedule 1/29-2/8 Chapter 1 - Matter, Energy and Measurement pp. 1-30 2/12-2/21 2/22-3/1 3/5-3/14 3/15-3/27 3/28-4/16 4/17-4/24 4/25-5/3 5/7-5/10 Chapter 2 - Atoms Chapter 9 - Nuclear Chemistry Chapter 3 - Chemical Bonds Chapter 4 - Chemical Reactions Chapter 5 - Gases, Liquids and Solids Chapter 6 - Solutions and Colloids Chapter 7 - Reaction Rates and Chemical Equilibrium Chapter 8 - Acids and Bases pp. 31-67 pp. 276-306 pp. 68-107 pp. 108-140 pp. 141-177 pp. 178-209 pp. 210-239 pp. 240-275 Tentative Recitation/Quiz/Exam Schedule Mon, Feb 4 Mon, Feb 11 Mon, Feb 18 Tues, Feb 19 Mon, Feb 25 Mon, Mar 4 Mon, Mar 11 Tue, Mar 12 Mon, Mar 18 Mon, Mar 25 Apr 1 – Apr 5 Mon, Apr 8 Tues, Apr 9 Mon, Apr 15 Mon, Apr 22 Mon, Apr 29 Tues, Apr 30 Mon, May 6 Fri, May 17 Quiz #1 Quiz #2 President’s Day – no class Exam #1 Quiz #3 Quiz #4 Review for Exam #2 Exam #2 Quiz #5 Quiz #6 Spring break – no class Review for Exam #3 Exam #3 Quiz #7 Quiz #8 Review for Exam #4 Exam #4 Quiz #9 Final exam(10:10 am – 12:10 pm) Ch 1(start) Ch 1(end) Ch 1 – 2(start) Ch 2(end) Ch 9 Ch 2(End), 9, Ch 3(start) Ch 2(End), 9, Ch 3(start) Ch 3(end) Ch 4(start) Ch 3(end) – Ch 5(start) Ch 4(end) – Ch 5(start) Ch 5(middle) Ch 5(end) – Ch 6(start) Ch 5(end) – Ch 7(start) Ch 5(end) – Ch 7(start) Ch 7(end) Ch 1 – Ch 9 Chemistry 121N – Spring 2013 Learning Goals Chapter 1: Matter, Energy and Measurement 1. Distinguish between physical and chemical changes, especially with fire 2. Use scientific notation in calculations 3. Understand significant figure limitations 4. Perform conversions from one unit to another including temperatures among Fahrenheit, Celsius and kelvin 5. Use metric units and prefixes for mass, length, volume, etc. 6. Apply the factor-label method 7. Describe the four states of matter - solid, liquid, gas and plasma 8. Perform calculations with density (d = m/V) 9. Describe different kinds of energy (potential vs. kinetic) 10. Perform calculations with specific heats (q = SH x m x T) Chapter 2: Atoms 1. Recognize the contributions of Zeno, Democritus, Dalton, Urey, Mendeleev and Pauli to our knowledge of atomic structure 2. Distinguish between elements and compounds; pure substances and mixtures; heterogeneous and homogeneous mixtures 3. Name and give symbols of common elements 4. Know fundamental forces - strong nuclear, electrostatic, gravitational 5. Explain the composition of different atoms according to the number of protons, neutrons and electrons they contain 6. Know what cations and anions are. Use charge to predict electron numbers and vice versa 7. Understand what isotopes are, how to write isotope notation, and how to use their natural abundances to compute average atomic masses 8. Describe how elements are arranged in the periodic table, name the subdivisions of the periodic table, and relate the position of an element in the periodic table to its electron structure Metals vs. metalloids vs nonmetals Main group elements vs (outer) transition metals and inner transition metals the alkali metals, alkaline earth metals, halogens, noble gases s-block elements, p-block elements, d-block elements, f-block elements 9. Explain how the electrons are distributed in shells and subshells around the nucleus of an atom 10. Know how many electrons can be found in each shell (2n2), subshell and orbital 11. Know the shapes, occurrence, number of lobes and orientations possible for each subshell type 12. Draw a simple picture of lobe arrangements within a subshell. 13. Write the electron configuration for simple elements and monatomic ions 14. Construct dash-arrow diagrams to show the electron configurations of elements or ions 15. Use Noble Gas core notation in electron configurations 16. Draw Lewis structures of main group elements 17. Predict periodic trends from an element’s position in the periodic table Chapter 3: Chemical Bonds 1. Identify the operational difference between ionic (e- transfer), covalent (e- pair sharing) and metallic bonds (wandering e- or e- sea) 2. Predict the most stable ion for a Group A element based on its position in the periodic table. 3. Given ion charges, write the formula for an ionic compound 4. Be familiar with and use monatomic ions in Tables 3.1-3.3 and polyatomic ions in Table 3.4. Also additional ions on handout. 5. Given a formula, name simple ionic compounds (ionic compounds start with metal or NH4 – no prefixes like di-, tri-, etc.) 6. Understand the nature of ionic solids as crystal networks 7. Construct Lewis structures for simple organic molecules and ions by using the normal bond orders listed in the top section of the handout 8. Recognize the occurrence of single, double and triple bonds as well as lone pairs 9. Describe the 3-D structure of sigma and pi bonds in covalent molecules 10. Construct Lewis structures for inorganic compounds or polyatomic ions using the general procedures in the bottom half of the handout 11. Recognize coordinate covalent bonds (not in text – see notes) – both e-‘s in a bond from same atom 12. Name binary covalent compounds given a formula and vice versa (covalent compounds start with nonmetal or metalloid – use multiplying prefixes e.g., di-, tri-, etc., end with “-ide”) 13. Use the VSEPR approach to predict the geometry and bond angles around central atoms 14. Draw structures of molecules showing 3-D shape and proper angles 15. Draw simple resonance structures for molecules or ions 16. Use electronegativity differences, e.n., to evaluate bond types 17. Use bond polarity and molecular geometry to predict overall molecular polarity Chapter 4 - Chemical Reactions 1. Know and use the mole concept to convert between grams and moles 2. Compute formula weights 3. Convert between moles and atoms/molecules using Avogadro’s number 4. 5. 6. 7. 8. Balance simple chemical equations with smallest whole-number coefficients Work stoichiometric problems (g A mol A mol B g B) Identify limiting reagents Calculate percent yield Identify type of reactions between ions: precipitation – ionic solid product appears in solution gas formation – gaseous product bubbles out of solution neutralization – HX + YOH make (ionic salt + H2O) redox – oxidation numbers change between reactants and products 9. Write formula equations, total ion equations or net ionic equations 10. Use solubility rules to identify the formula of a precipitate when two solutions are mixed. 11. Know the definitions and terms of oxidation and reduction processes 12. 13. 14. Oil rig: Oxidation is loss (of electrons); Reduction is gain (of electrons) Identify the relative oxidation states of classes of organic molecules Most reduced hydrocarbons alcohols and ethers aldehydes and ketones carboxylic acids Most oxidized CO2 and carbonates Determine the oxidation number of atoms in elements, ions and compounds Understand heat of reaction, Hrxn, exothermic vs endothermic 15. Perform simple energy calculations based on Hrxn Chapter 5 – Gases, Liquids and Solids 1. Be familiar with phase change possibilities – melting, boiling, sublimation, pyrolysis, combustion, condensation, freezing 2. Know the properties of ideal gases (kinetic molecular theory) 3. Inter-convert among pressure units 4. Use the Ideal Gas Law to work problems 1-state – 3 variables given 2-state – two values of same kind mass/formula weight – problem has grams in it 5. 6. 7. 8. 9. 10. 11. 12. 13. 14. 15. Use Dalton’s Law to compute of partial pressures of mixture components, Ptotal = sum of partial pressures Understand the relative magnitudes of chemical bonds and intermolecular forces (IMFs) Describe the origin of the three types of IMFs – hydrogen bonds, dipole-dipole interactions, London dispersion forces; given a formula, identify which IMF is most important Define vapor pressure and know how it changes with temperature Be familiar with using honeybees to find explosives Bees find food by smell first, then by color/shape TNT most common explosive, but DNT is more volatile Proboscis extension response reveals bees smell it Able to smell at parts per quadrillion Takes hours to train, 25 seconds to find Can track bees by eye or by lidar Can find bodies through sulfur compounds Assess relative boiling point orders based on IMFs - #1 interaction type, #2 molecular weight, #3 molecular geometry Categorize the solid phases of substances by interaction type – ionic network, covalent network, metallic network, molecular solid (by IMFs) Know what an allotrope is Interpret heating/cooling curves with phase changes and Hfus and Hvap Calculate heat associated with temperature changes on heating and cooling curves (i.e., one term for each line segment encountered) Label and Interpret phase diagrams; predict phase changes encountered for specified pressure or temperature shifts Chapter 6: Solutions and Colloids 1. Distinguish properties among solutions, colloids and suspensions 2. Know terminology associated with solutions Dilute vs. concentrated solute vs. solvent miscible vs. immiscible unsaturated vs. saturated vs. supersaturated 2. 3. Predict solubility trends for temperature and pressure changes Apply the rule “like dissolves like” polar solvents dissolve polar and ionic solutes nonpolar solvents dissolve nonpolar solutes 4. Perform calculations involving concentration units Percent composition, molarity, dilution, ppm, ppt, ppb, ppq 5. Understand what makes a good electrolyte, distinguish strong vs. weak 6. Be familiar with typical examples of colloidal systems 7. Know Rayleigh scattering (molecular) and Tyndall scattering (colloidal) cause sunrise/sunset colors 8. Know the colligative properties bp elevation, fp depression, vp reduction, osmotic pressure 9. Work colligative property problems given a fp constant, etc. 10. Characterize classes of membranes impermeable, permeable, semipermeable; osmotic vs. dialytic 11. Calculate osmolarities and decide if solution is isotonic(~0.30±0.02), hypertonic (>0.30) or hypotonic (<0.30). 12. Predict direction of water flow across a membrane given osmolarities on both sides. Chapter 7: Reaction Rates and Chemical Equilibrium 1. Be able to interpret slopes as rate information on conc. vs. time curves; calculate rate given (time, conc) data pairs 2. Understand the sequence of events accompanying reactions. 3. Know the collision parameters that affect rates – frequency, energy and orientation. 4. Understand energy diagrams and be able to label their parts reactants, collision zone, products, activation energy, Hrxn, transition state (or activated complex) 5. Know how temperature and concentration affect reaction rates; use understanding to make simple predictions (e.g., change in temp of 10oC changes reaction rate by factor of 2. 6. Understand Boltzmann energy distribution diagrams 7. Know what catalysts are and how they work homogeneous vs. heterogeneous, enzymes 8. Know the characteristics that define equilibrium concentration constant over time rate of forward and reverse reactions are equal 9. Write the equilibrium constant expression for a reaction (or vice versa) 10. Interpret the direction and completeness of a reaction from a K value. 11. Given all equilibrium concentrations, calculate the value of K 12. Use Le Chatelier’s Principle to predict how an upset equilibrium will respond to disturbances – addition/removal of reactant or products, temperature, pressure, catalysts Chapter 8: Acids and Bases 1. Use Ka and Kb to determine acid-base strength. 2. 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. Determine/identify conjugate acid/base pairs Know acid/base terminology: monoprotic, diprotic, triprotic, amphiprotic Name acids based on their anion type - -ide, -ate, ide Complete common reactions of acids with active metals, metal hydroxides, oxides, and amines Predict the acid/base character of dissolved salts Be familiar with the pH scale Calculate pH, pOH or pK. Perform back calculations from pH, pOH or pK to [H3O+], [OH-] and K Understand what a buffer is and how it works Use the Henderson-Hasselbalch equation to compute buffer pH or ratio of base form to acid form Know what acidosis and alkalosis are Chapter 9: Nuclear Chemistry 1. 2. Know historical figures in the discovery of radioactivity Roentgen (X-rays), Becquerel (radioactivity), Curie (isolated radium as cause of radioactivity), Rutherford (alpha, beta, gamma), Curie/Joliot (artificial isotopes) Be familiar with regions of the electromagnetic spectrum and their interactions with matter: Gamma rays (nuclear transitions), X-rays (inner electron transitions), UV (outer electron removal), visible (outer electron excitation), IR (bond vibrations and rotations), microwaves (bond rotations, electron flips), radio waves (nuclear flips) 3. 4. 5. 6. 7. 8. 9. 10. 11. 12. 13. Interconvert between wavelength and frequency ( = c/ ) Write/complete reactions for alpha, beta, gamma and positron emissions Understand half-lives Use half-lives to calculate amount left or radio-dates Characterize the penetrating power of radiation types Learn the risks imposed to living systems by radiation Know relative magnitude of sources of common radiation exposures Describe the difference between diagnostic and therapeutic radiation Enumerate characteristics of good diagnostic isotopes Compare/contrast nature of imaging techniques PET scans (positrons lead to gamma pairs), CT scans (X-ray slices), MRI (radio waves cause H-atom flips), ultrasound (compression waves reflect) Differentiate between fission and fusion; be able to complete nuclear reactions involving either process Chapter 10 – Organic Chemistry 1. Know how to distinguish between organic and inorganic compounds 2. Understand the difference between natural and synthetic compounds 3. Write structures using the normal bonding patterns for H, C, N, O, S, P and halogens 4. Recognize functional groups for alcohols, amines, aldehydes, ketones, carboxylic acids and esters 5. Categorize alcohols and amines as primary, secondary or tertiary Please note: Approved general education changes will take effect next fall. General education instructors will be expected to provide sample assessment items and corresponding responses to the Assessment Advisory Committee.