TESTING EMISSIONS FROM HEM-FIR LUMBER Don Hejna Potlatch Bemidji, Minnesota Lumber Kiln Emissions Testing • • • • W hy test? Test program Results Sum m ary W hy Test? • • • • • • • MACT Rules: Hazardous air pollutants plywood and com posite wood products boilers Thresholds >10 tons/year of single HAP >25 tons/year of all HAPs 189 HAPs- prim arily six in wood products MACT Rules: Low risk subcategory look up tables site specific testing and m odeling If low risk is dem onstrated without control equipm ent, facility is in com pliance with the rule W hat capacity m ill needs to consider HAPs? 150-200 m m bf/year depending upon species co-located operations including boilers critical single HAP - m ethanol up to 90% of total W hy Not Use Emission Factors? • • • Em ission factors should be used first May provide a large data base However, May not be appropriate to your facility species product - e.g., bark from trees kept in saltwater; contam inated wood from dem olition May not be accurate for your facility W estern Dry Kiln Association 35 May, 2006 Test Program Team - See addendum for contact inform ation 1. EPA -OAQPS-Gary McAlister 2. Geom atrix - Ken Richm ond 3. Interpoll Laboratories - Dan Despen 4. NCASI - Dr. David W ord 5. Oregon State University - Dr. Mike Milota 6. Potlatch Forest Products Corporation--Berne W ilm arth/Don Hejna Alternatives • Full scale kiln testing Vents m ake it difficult, but possible Stacks are easier Kilns inherently leak - how m uch? • Photographs • Screen for presence of HAPs Sam ple concentration inside kiln • Sm all scale kiln test • Based on PCW P MACT low risk dem onstration Regulatory agencies m ay require different procedures for other purposes W estern Dry Kiln Association 36 May, 2006 W estern Dry Kiln Association 37 May, 2006 OSU Sm all-Scale Kiln W estern Dry Kiln Association 38 May, 2006 Test Program • • • Purpose Estim ate HAPS from drying hem /fir Lum ber Drying Test Plan based on App C to Subpart DDDD of Part 63 – Considerations for a sm all-scale kiln em ission testing program Test Plan reviewed by NCASI - Dr. David W ord EPA-OAQPS - Gary McAlister - no form al approval App C to Subpart DDDD of Part 63 Considerations for a Sm all-Scale Kiln Em ission Testing Program • • • • • • Representative sam ples of lum ber Kiln operating param eters, sim ilar to full scale kilns (air flow, tem perature, tim e) Em issions sam pling Sam ple intervals (3 hrs) and runs (2) Reporting - graphs, num erical data, water balance, MDL, em issions rates Guidance - NCASI TB-845 Test Program - Review s • • EPA issues addressed in Test Plan Review Use of GC/MSD v. GC/FID in NCASI 99.02 Detection lim its < 1 ppm QA/QC spike trains - lab and field Tim ber location/harvest date/tim e in log yard Post Test Review Use of silica gel One-hour sam pling to avoid errors Test Program - Stack Tester • Criteria for selecting stack tester Confidence 30 year history with wood products pioneer work with HAPs, ethanol industry QA/QC and detection capability Truck m ounted lab for im m ediate results W estern Dry Kiln Association 39 May, 2006 Test Program - Results, lb/mbf Test Results - Caveats • • • • Be careful of one test result Adjust to KD target m oisture 17-19% As a m inim um , correct with statistics, or add 50-100% safety factor Exam ple Acrolein test result - 0.002 lb/m bf Acrolein - EPA table - 0.009 lb/m bf Stack tester m ore com fortable with 0.009 Summary • • • • Sm all-scale kiln testing Accepted by EPA for low risk determ ination Test plan Follow guidance in App C to Subpart DDDD of Part 63 -Considerations for a sm all-scale kiln em ission testing program EPA Review - Resolve issues - No written approval Be wary of single test results Add safety factor, at least statistical factor Stack testing program Confidence in stack tester Detection lim it capability for HAPs QA/QC On-site analysis v. Lab W estern Dry Kiln Association 40 May, 2006 Test Program Team 1. EPA - QAQPS - Gary McAlister 919-541-1062 m calister.gary@ epam ail.epa.gov 2. Geom atrix - Ken Richm ond 425-921-4014 krichm ond@geom atrix.com 3. Interpoll Laboratories - Dan Despen 763-786-6020 x46 dan.despen@ interpoll-labs.com 4. NCASI - Dr. David W ord 352-331-1745 x 241 d_word@ src-ncasi.org 5. Oregon State University - Dr. Mike Milota 541-737-4210 m ike.m ilota@ oregonstate.edu 6. Potlatch Corporation - Bernie W ilm arth 208-245-7517 bernie.wilm arth@ potlatchcorp.com Em ission Factor References 1. EPA Em issions Factors, PCW P MACT (FR Vol. 71, No. 32/Thursday, February 16, 2006). 2. June 9, 2000 letter to Mary Tom Kissle (EPA) from Katie Hanks, MRI (Docket), Subject” Em issions Estim ates (OAR-2003-0048-0189) 3. Milota, M.R. “Sm all-Scale Kiln Study Utilizing Ponderosa Pine, Lodgepole Pine, W hite Fir, and Douglas Fir” report to Interm ountain Forest Association 4. Milota, M.R., VOC Em issions from Douglas-fir: Com paring a com m ercial and a laboratory kiln, Forest Products Journal, vol. 50, No. 7/8. 5. A com parative study of VOC em issions from sm all-scale and full scale lum ber kiln drying southern pine, NCASI TB-845, May 2002. 6. A sm all-scale kiln study on Method 25A m easurem ents of volatile organic com pound em issions from lum ber drying, NCASI TB-718, July 1996. W estern Dry Kiln Association 41 May, 2006