Supercond. Sci. Technol. 13 (2000) 202–208. Printed in the UK PII: S0953-2048(00)08900-4 Current–voltage characteristics and flux creep in melt-textured YBa2Cu3O7−δ H Yamasaki and Y Mawatari Electrotechnical Laboratory, 1-1-4 Umezono, Tsukuba, Ibaraki 305-8568, Japan E-mail: hyamasak@etl.go.jp Received 21 October 1999 Abstract. We investigated the current–voltage (E–J ) characteristics in melt-textured YBa2 Cu3 O7−δ strips by measuring the magnetic-field sweep rate dependence of magnetization. We took account of the current density J distribution in the specimen using a previously developed method (Mawatari Y et al 1997 Appl. Phys. Lett. 70 2300). For a wide temperature and magnetic-field range (60–80 K, 0.2–5.0 T), the E–J curves in the electric-field window E = 10−10 –10−5 V m−1 exhibited power-law behaviour E ∝ J n , and the power index n generally became smaller at higher magnetic fields and temperatures. In low magnetic fields (µ0 Ha 6 0.5 T) the n values were large (>20), and thus the Bean model becomes a good approximation. The E–J characteristics in the lower E window were also derived from the relaxation of magnetization, the flux creep, and we found that the wide-range E–J characteristics exhibit near-power-law behaviour but that there exist slight downward curvatures in the log E versus log J plots. This downward curvature reveals that the dissipation approaches zero when the current is substantially reduced. The drastic decrease of the flux creep, which was observed when the sample temperature was decreased in a fixed magnetic field, is consistent with the observed E–J characteristics. 1. Introduction The current–voltage (E–J ) characteristics of superconductors reveal how dissipation occurs as a result of current, and thus it is an important parameter for power applications. For melt-textured YBa2 Cu3 O7−δ (YBCO), however, the transport measurement, which can obtain the E–J characteristics in relatively high-electric-field E regions (E > 1 µV m−1 ), is difficult owing to its large critical current. The E–J characteristics can also be obtained from the magnetic-field sweep rate β dependence of magnetization M or from the relaxation of M [1–7]. However, when using magnetization measurements to extract the E–J characteristics, several previous studies disregarded the effect of the current density J distribution inside the sample [1–3]. Superconducting rings were used for precise measurement, because, in these rings, the J and E distributions are negligible [5–7]. Recently, Mawatari et al proposed a new method to obtain the E–J characteristics from the magnetic-field sweep rate dependence of M, taking account of the J and E distributions in the specimen [8, 9]. Using this method we can precisely measure the E–J characteristics of superconducting disks or strips, which can be prepared with much less difficulty than rings [10]. In this study, we investigated the E–J characteristics of melt-textured YBCO strips. We found that, for a wide temperature and magnetic-field range (60–80 K, 0.2–5.0 T), the E–J 0953-2048/00/020202+07$30.00 © 2000 IOP Publishing Ltd curves in the electric-field window E = 10−10 –10−5 V m−1 exhibited power-law behaviour like that which has often been observed in high-Tc superconductors [1, 2, 4, 11–14]. Using the same specimen, we also investigated the relaxation of magnetization, the flux creep, and extracted the E–J characteristics data in the still lower E region. Combining both measurements, we found that the wide-range E–J characteristics exhibit near-power-law behaviour but that there exist slight downward curvatures in the log E versus log J plots. This downward curvature reveals that the dissipation approaches zero when the current is substantially reduced and is consistent with the vortex-glass theory [15, 16] and the collective flux-creep theory [17]. We observed a drastic decrease in the flux creep by slightly decreasing the sample temperature in a fixed magnetic field. 2. Experimental procedure Superconducting strips used for the E–J characteristic measurements were cut from a melt-textured, single-domain bulk sample with a diameter of 44 mm and a height of 18 mm (Dowa Mining Co.). Most of the measurements were performed on a strip with a thickness d of 0.5 mm, a width w of 0.8 mm and a length l of 7.8 mm (sample A). Sample B (d = 0.4 mm, w = 0.8 mm and l = 3.8 mm) and sample C (d = 0.3 mm, w = 1.0 mm and l = 6.3 mm) were also used. X-ray diffraction measurement showed that the YBCO Current–voltage characteristics and flux creep in melt-textured YBCO (a) 3. E–J characteristics obtained from the β dependence of M (b) Magnetization (kA/m) phase was well oriented with the c-axis perpendicular to the strip plane and that sample C includes a large amount of the oxygen-deficient YBCO phase. All three samples contained a small amount of the 211 phase (Y2 BaCuO5 ). Magnetization M was measured using an Oxford vibrating sample magnetometer with magnetic fields applied parallel to the c-axis of the YBCO phase, perpendicular to the strip plane. We measured M with a magnetic-field sweep rate β from 0.6 T min−1 to 0.0001 T min−1 with a field width that was sufficiently large for the sample to be in the fullpenetration condition, in which the shielding current flows in a simple circular direction. For the flux-creep measurements the applied magnetic field was increased with a constant sweep rate (β = 0.5 T min−1 ), the field sweep was terminated at a specific magnetic field and the relaxation of M was measured. 80 40 T = 77.3 K, H II c-axis 0 β = µ0d Ha/dt = 0.0001–0.6 T/min -40 -80 0.1 0.15 0.2 0.25 0.3 Applied field (T) 5 Let us consider a superconducting strip that is in an applied magnetic field Ha perpendicular to the strip plane (parallel to the z-axis) and in the full-penetration condition. When Ha is swept with a constant sweep rate β = µ0 dHa /dt, the electric field E induced in the superconductor in the steady state (see the next paragraph) has a simple distribution and is proportional to β, where µ0 is the magnetic permeability for vacuum. The magnetization M of the sample is nearly proportional to the shielding current density J inside the sample. Therefore, the β dependence of M reflects the E–J characteristics of the superconducting specimen. Here, we assume a steady state where β is much larger than the time derivative of the magnetic flux density due to the shielding current: |β| |∂Bz /∂t −β| ∼ (1−D)µ0 |∂M/∂t|, where Bz is the z component of the magnetic flux density and D is the demagnetization factor [8, 9]. It should be noted that this condition is not satisfied immediately after the change of the magnetic-field sweep direction, where |∂M/∂Ha | ∼ 1/(1 − D) and (1 − D)µ0 |∂M/∂t| ∼ |β| [9]. We also assume that the E–J characteristics (and the critical current density Jc defined by a certain criterion) only weakly depend on the magnetic field and that the effect of the self-field (shielding currents) and the local field variation in the sample can be ignored. This assumption is well justified in higher magnetic fields (µ0 Ha > 1 T), where the self-field is much smaller than Ha . As for the influence of the self-field in lower magnetic fields (µ0 Ha 6 0.5 T), see [10]. When the magnetic field is perpendicular to a strip of length l, width w and thickness d (l w > d), E and J at the edge of the superconducting strip in the steady state are expressed as [8, 9] E = −βw/2 (1) J = (2 + α)2M/w α= β ∂M ∂(ln |M|) = . ∂(ln |β|) M ∂β (2) We can extract the precise E–J characteristics using equations (1) and (2). In this method, the E and J distributions in the superconducting specimen are considered Magnetization (kA/m) 4 3.1. Correction for the E and J distribution 3 2 1 0 T = 77.3 K β = 0.0001– 0.6 T/min H II c-axis -1 -2 -3 4.8 4.9 5 5.1 5.2 Applied field (T) Figure 1. Effect of the magnetic-field sweep rate β on magnetization M, measured in sample A at 77.3 K and around (a) µ0 Ha = 0.2 T and (b) µ0 Ha = 5 T. β values were 0.0001, 0.0003, 0.0006, 0.0012, 0.003, 0.006, 0.012, 0.03, 0.06, 0.12, 0.3 and 0.6 T min−1 . M depends strongly on β at µ0 Ha = 5 T, reflecting the broad E–J characteristics in such a high magnetic field. [8, 9]. If α → 0 in equation (2), then the average current density hJ i = 4M/w, and equation (2) results in the wellknown Bean model equation as Jc = 4M/w. (3) The parameter α in equation (2) reflects the inhomogeneous J distribution in the specimen. In the case of the powerlaw E–J characteristics with a power index n (E ∝ J n ), we obtain α = 1/n [8, 9]. This result indicates that the deviation from the simple Bean model (neglecting the J distribution inside the specimen) becomes large with small n values which indicate broad E–J characteristics. 3.2. Power-law E –J characteristics observed for E = 10−10 –10−5 V m−1 Figure 1 shows the effect of the magnetic-field sweep rate β on magnetization M at 77.3 K in sample A. |M| is larger 203 1 05 (a) 1 0-5 0.2 T, α = 0.033 1 04 ↓ 3 T, α = 0.083 2 T, α = 0.098 5 T, α = 0.188 H II c-axis 77.3 K & 80 K 3 10 1 0-6 1 0-5 1 0-4 1 0-3 10 -7 Figure 2. Magnetic-field sweep rate β dependence of magnetization hysteresis width 1M, measured at T = 77.3 K and 80 K. Open symbols represent the data at 77.3 K and at µ0 Ha = 0.2, 0.3, 0.5, 1, 2, 3 and 5 T. Full symbols represent the data at 80 K and at µ0 Ha = 0.2, 0.3, 0.5 and 2 T. with larger sweep rate β, because larger β leads to larger E (see equation (1)), which in turn leads to larger J (M). The M dependence on β was pronounced at µ0 Ha = 5 T (figure 1(b)) owing to the broad E–J characteristics in such high magnetic fields. Then, the hysteresis widths 1M = M− − M+ at µ0 Ha = 0.2–5.0 T and at T = 77.3 K and 80 K are plotted against β in figure 2, where M− (M+ ) is the magnetization in the magnetic-field decreasing (increasing) branch. The β dependence of 1M exhibits clear power-law behaviour. The power index directly gives the parameter α in equation (2), which is constant and does not depend on β. Next, we calculated E and J at the edge of the superconducting strip using equations (1) and (2), replacing 2M with 1M. Figure 3 shows the E–J curves at various fields at 65, 70, 77.3 and 80 K in sample A. In this electricfield window E = 10−10 –10−5 V m−1 , power-law behaviour E ∝ J n is observed over the entire magnetic-field range covered (µ0 Ha = 0.2–5.0 T). In lower magnetic fields (µ0 Ha 6 1 T) the power index n was large (>25), which indicates that the E–J curves are steep. In this case, the parameter α = 1/n is small compared with 2 in equation (2), and the correction for the J distribution is quite small (<2%). Therefore, the Bean model equation (equation (3)) is a good approximation for the calculation of J . In high magnetic fields, however, n is not as large and the correction from equation (3) becomes substantial, e.g. ∼10% at 77.3 K and 5 T (figure 3(a)). For the power-law E–J characteristics, the correction for the J distribution consists of a simple multiplication by a constant (2 + α)/2. Thus, the n values derived from the experimental results do not depend on whether or not the data were corrected. Equations (1) and (2) can be used for long superconducting strips whose length l is much larger than width w. If l is not sufficiently long compared with w, a correction is necessary. If anisotropy in the critical T = 77.3 K and 80 K No correction (Bean model) 5T 1 0-8 2T n= 10.2 1 0-9 0.2 T 5T n = 5.3 1 0-10 6 10 n= 30.8 3T 2T n = 12.3 n = 20.3 1 07 1 08 1 09 Current density (A/m2) 1 0-2 Magnetic-field-sweep rate, β (T/sec) 204 Electric field (V/m) 1 0-6 (b) 1 0-5 T = 70 K and 65 K 1 0-6 Electric field (V/m) Hysteresis width, ∆M (A/m) H Yamasaki and Y Mawatari 1 0-7 5T 1 0-8 n = 17.4 1 0-9 3T 1 0-10 1 T 0.5 T 0.2 T n = 25.5 n = 29.2 n = 28.4 n = 40.4 1 08 1 09 2 Current density (A/m ) Figure 3. Current–voltage characteristics of sample A in applied fields of µ0 Ha = 0.2–5.0 T at (a) T = 77.3 K and 80 K and (b) T = 65 K and 70 K, calculated using equations (1) and (2). Data calculated by the Bean model equation (3) are also shown (crosses in (a)). Open symbols represent the data at µ0 Ha = 0.2, 0.3, 0.5, 1.0, 2.0, 3.0 and 5.0 T at T = (a) 77.3 K and (b) 70 K. Full symbols represent the data at (a) µ0 Ha = 0.2, 0.3, 0.5 and 2.0 T at 80 K and (b) µ0 Ha = 0.2, 0.3 and 0.5 T at 65 K. current density within the a–b-plane is neglected, then the magnetization hysteresis width is calculated based on the Bean model: 1M = (wJc /2)(1 − w/3l) [18]. Therefore, the correction factor is 1/(1 − w/3l), and it is found that the current density J of figure 3 in sample A (l = 7.8 mm and w = 0.8 mm) is underestimated by ∼3.4%. We measured the E–J characteristics for 0.2 T 6 µ0 Ha 6 5.0 T and for temperatures 60 K 6 T 6 80 K in sample A and for 0.2 T 6 µ0 Ha 6 0.5 T and 70 K 6 T 6 80 K in samples B and C. In almost all cases, powerlaw behaviour was observed in the electric-field window E = 10−10 –10−5 V m−1 . The downward curvature in the log E versus log J plots, which is regarded as a characteristic of the vortex-glass state [15, 16] or the collective flux creep [17], was only slightly exhibited (figure 3). The observed values of n for samples A, B and C are summarized in table 1. In general, n was smaller at higher magnetic fields Current–voltage characteristics and flux creep in melt-textured YBCO Table 1. The n values of E–J curves in melt-textured YBCO samples measured by magnetic-field sweep rate dependence of magnetization. (1) Sample A: Jc ∼ 2.5 × 108 A m−2 at 77.3 K, 0.3 T (E = 1 µV m−1 criterion). n for the following T (K) B (T) 60 65 70 75 77.3 77.3 (second) 80 0.2 0.3 0.5 1 2 3 5 44 40.4 33.5 30.3 29.9 32.7 36.6 40.4 37.4 32.6 — — — — 37.1 35 28.4 29.2 26.2 25.5 17.4 31.9 31 25.8 — — — — 30.2 27.9 25.1 24.9 21.8 12 5.31 30.8 25.5 27.2 25.3 20.3 12 — 27.2 25.8 27.5 — 10.2 — — (2) Sample B: Jc ∼ 1.7 × 108 A m−2 at 77.3 K, 0.3 T (E = 1 µV m−1 criterion). n for the following T (K) B (T) 70 75 77.3 80 0.2 0.3 0.5 38.3 34.4 30.1 34.4 31.0 29.3 33.3 29.6 26.1 30.3 26.6 25.5 (3) Sample C (containing oxygen-deficient YBCO): Jc ∼ 5.8 × 106 A m−2 at 77.3 K, 0.3 T (E = 1 µV m−1 criterion). n for the following T (K) B (T) 70 77.3 80 0.2 0.3 0.5 25.7 23.7 21.6 25.4 21.7 20.0 23.2 22.0 19.2 The power-law E–J characteristics indicate that the activation energy U for the flux motion depends logarithmically on J [11, 12], U = U0 ln(J0 /J ), where U0 is a J -independent activation energy. Then, the induced electric field E and the n value are expressed as E = E0 exp[(U0 /kT ) ln(J /J0 )] = E0 (J /J0 )n n = U0 /kT . (4) This indicates that the n value is directly related to the pinning strength through U0 . Since U0 generally becomes smaller in higher magnetic fields and temperatures, the observed field and temperature dependence of n can be qualitatively explained by equation (4). 3.3. Calculation of hysteresis loss for the power-law E –J characteristics Figure 4. Relaxation of M at T = 60 K and 77.3 K measured in sample A. and temperatures, with the exception of high magnetic fields (µ0 Ha > 2 T) at 60 K in sample A, in which n increased. This may be related to the broad peak effects in the M–H curves that were observed in high magnetic fields and low temperatures (µ0 Ha > 5 T at 60 K and µ0 Ha > 4 T at 50 K). Superconducting magnetic-levitation applications, such as superconducting magnetic bearings in flywheel energy storage systems, are regarded as one of the most important applications of melt-textured YBCO. In these systems, the magnetic field is generated by permanent magnets and is usually limited to less than 0.7 T [19–21]. It is evident from table 1 that, in such low magnetic fields, the n values are quite large (>25) in good-quality samples (samples A and B), and that even a poor-quality sample with very low Jc (sample C) has rather large n values (>19). In this case, the effect of the J dependence of E becomes small, and the simple Bean model becomes a good approximation. 205 H Yamasaki and Y Mawatari 1 0-5 Electric field (V/m) 1 0-6 n = 21.8 (β depend.) n= 24.9 n= 27.2 n= 30.8 n= 25.5 ⇒ 1 0-8 1 0-9 1 0-11 10 -12 1 0-13 n= 44.0 T = 60K 1 0-7 1 0-10 n= 33.5 77.3K n = 26.9 (flux creep) 2 T n= 34.4 n= 34.1 1 T 0.5 T 1 08 ⇐ n= 32.5 n= 36.2 n= 34.5 0.2 T 0.3 T 0.5 T Current density (A/m2) n = 57.2 (flux creep) 0.2 T 1 09 Figure 5. Wide-range E–J characteristics of sample A measured by both the β dependence of M and the flux creep. Rhyner calculated the ac losses of superconductors with the power-law E–J characteristics of equation (4) and derived an analytic equation for a semi-infinite superconductor exposed to an oscillating external field (B0 sin(ωt)) parallel to its surface [22]. The losses per cycle per unit surface area A are B03 Qc E0 µ0 J0 1/(1+n) = (1.33 + 3.11n−0.55 ). (5) A 2µ20 J0 ωB02 We note that the hysteresis loss of the superconductor, which results from the nonuniform distribution of the magnetic field and can be estimated by equation (5), causes the rotation loss of the rotor in the superconducting magnetic bearing [19, 21]. Typical values of the parameters for the rotationloss calculation are E0 = 10−6 V m−1 , J0 = 2 × 108 A m−2 , ω/2π = 100 Hz and B0 = 0.02 T. The induced electric field is estimated to be ωB02 E0 µ0 J0 1/(1+n) ≈ 7.2 × 10−4 V m−1 ωB0 z∗ = µ0 J0 ωB02 where z∗ is the ac penetration length [22] and n = 20 is used. If we assume that the observed power-law behaviour continues to occur in the E range two orders of magnitude higher than that of figure 3, then equation (5) can be used for the calculation. Then, the correction factor from the Bean critical state (n → ∞) is 0.720 × 1.93/1.33 = 1.04 for n = 20 and 1.09 for n = 30. 4. E–J characteristics obtained from the flux-creep data Next, we measured the time dependence of magnetization, the flux creep. The log |M+ | versus log t plots measured at various fields at 60 K and 77.3 K in sample A reveal that the |M|–t relation also exhibits power-law behaviour, except for small-t regions (figure 4). If the E–J characteristics are expressed by a power law with n 1, then the J distribution inside the sample can be neglected and the electric field can 206 be expressed as E = E0 (M/M0 )n . Combining this equation with Faraday’s law E = −(µ0 w/2) dM/ dt (6) we can calculate the relaxation of magnetization as t0 = µ0 wM0 /2(n − 1)E0 . (7) For our experimental conditions for sample A, w = 0.8 mm, β = 0.5 T min−1 , E0 = 4 × 10−6 V m−1 , M0 ≈ 4 × 104 A m−1 and n ≈ 30, we obtain t0 ≈ 0.17 s. Then, t/t0 1 for most of the measured time period, and the t dependence of M (i.e. equation (7)) can be expressed by a power law with the index of 1/(1 − n). The straight lines in figure 4 illustrate that the time dependence predicted by equation (7) is actually observed, and the n values can be obtained from the slopes of these lines. Note that the normalized flux-creep rate S = −∂ log |M|/∂ log t = 1/(n − 1), and S is nearly inversely proportional to n. An interesting phenomenon is that the values of n obtained from the relaxation of M (figure 4) were larger than those obtained from the β dependence of M (table 1). This is due to the difference in the related electric-field windows. It is also possible to extract the E–J characteristics from the flux-creep data, using equation (6). The E–J curves obtained by both the β dependence of M and the flux creep are depicted in figures 5 and 6 for samples A and B, respectively. It can be seen that the electric-field window of the E–J curves from the flux-creep data is about two orders of magnitude lower than that obtained from the β dependence of M. Combining both measurements, we found that there is a slight downward curvature in the wide-range log E versus log J plots. This downward curvature is expected according to the vortex-glass theory [15, 16] and the collective flux-creep theory [17], in which the J -dependent potential barrier diverges at J → 0, as U (J ) ∼ J −µ . Several researchers have reported the observation of this J dependence of the activation energy by measuring the β dependence of magnetization and flux creep in melt-textured YBCO samples [23, 24]. M = M0 (t/t0 + 1)1/(1−n) Current–voltage characteristics and flux creep in melt-textured YBCO Electric field (V/m) 1 0-6 1 0-7 1 0-8 1 05 n= 29.6 n= 31.0 n = 34.4 (β depend.) 70 K n = 40.2 80 K 75 K µ 0H a = 0.3 T 1 0-9 1 0-10 1 0-11 1 0-12 10 n= 38.0 µ 0 H a = 0.3 T 6 104 n= 26.6 |M+| (A/m) 1 0-5 n= 37.5 n = 40.2 (flux creep) 77.3 K 75 K 70 K n = 37.5 77.3 → 70, 75 K 77.3 K 80 → 77.3 K 2 104 1 10 100 1 03 1 04 n = 38.0 1 05 1 06 -13 1 08 Current density (A/m2) Time (sec) 1 09 Figure 6. Wide-range E–J characteristics of sample B measured Figure 7. Retarding the flux creep by decreasing the temperature in a fixed magnetic field (sample B). at µ0 Ha = 0.3 T and at T = 70–80 K. −9 −7 −1 In the electric-field window range of 10 –10 V m , the E–J curves obtained from the flux creep do not completely match those obtained from the β dependence of M. One reason for this disagreement is that the former were extracted from the M+ data only whereas that the latter were obtained from the 1M = M− − M+ data. Because of the contribution from the reversible magnetization, |M+ | is larger than |M− |, and this results in the overestimation of J in the former case, which can be observed in figures 5 and 6. However, both curves did not coincide even when the above effect was corrected. This is due to experimental error. 5. Retarding the flux creep by decreasing the temperature in a fixed magnetic field It is found that the wide-range E–J characteristics exhibit near-power-law behaviour but that there are slight downward curvatures in the log E versus log J plots. This downward curvature reveals that the dissipation approaches zero when the current is substantially reduced. Thus, it is expected that the flux creep can be eliminated if we can substantially reduce the shielding current density from the critical state. Figure 6 shows that the diamagnetic shielding current density J immediately after the magnetic field of µ0 Ha = 0.3 T is applied at T = 77.3 K is about 1.6 × 108 A m−2 and that the induced electric field E with this J is very small at 75 K. Therefore, we predict that the flux creep will be greatly retarded if we apply the magnetic field of 0.3 T at 77.3 K and then decrease the sample temperature to 75 K. A drastic decrease in the flux creep was observed when the sample temperature was decreased from 77.3 K to 75 K (or 70 K) in a fixed magnetic field of 0.3 T (figure 7). The same phenomenon was observed when the sample temperature was reduced from 80 K to 77.3 K, and this can be understood in the same way on the basis of the E–J characteristic data of figure 6. Several researchers previously observed the reduction of the flux creep by temperature change [25–28], but none of them explained the phenomenon in terms of the E–J characteristics. 6. Summary We investigated the E–J characteristics in melt-textured YBCO superconducting strips by measuring the magneticfield sweep rate β dependence of magnetization M. We took account of the current density distribution in the specimen using a novel method. For a wide temperature and magnetic-field range (60–80 K, 0.2–5.0 T), the E–J curves in the electric-field window E = 10−10 –10−5 V m−1 exhibited power-law behaviour E ∝ J n . The observed n values are generally high (>25) in low magnetic fields (60.5 T) with which most superconducting magneticlevitation applications are concerned. This suggests that the Bean critical-state model is a good approximation. The E–J characteristics in the lower E window were also derived from the flux-creep data. Although the wide-range E–J characteristics exhibit near-power-law behaviour, there are slight downward curvatures in the log E versus log J plots, which reveal that the dissipation approaches zero when the current is substantially reduced. 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