Marine and Petroleum Geology 06 "1999# 090Ð007 Paleogene tu}aceous intervals\ Grane Field "Block 14:00#\ Norwegian North Sea] their depositional\ petrographical\ geochemical character and regional implications Helge Jarle Haaland a\ \ Harald Furnesb\ Ole J[ Martinsenc a Phillips Petroleum Company\ P[B[ 119\ 3945\ Tananger\ Norway b Geological Institute\ Allegt[ 30\ N!4996\ Bergen\ Norway c Norsk Hydro Research Centre\ N!4919\ Bergen\ Norway Received 06 March 0887^ received in revised form 14 February 0888^ accepted 0 March 0888 Abstract Paleogene volcaniclastic rocks from four wells from the Grane Field "Block 14:00#\ Southern Viking Graben on the western ~ank of the Utsira High "North Sea#\ have been studied[ The tu}aceous intervals consist of the volcanic phase 0 "47Ð46 Ma# in the Vale and Lista Formations\ and the volcanic phase 1 "44Ð41 Ma# in the Sele and Balder Formations[ Tu} beds of phase 0 are interpreted as having been redeposited by turbidity currents\ whereas those of phase 1 re~ect normal settling of fall!out pyroclastics in water[ Two types of fragments occur\ the most abundant being vesicular pyroclasts with irregular shape and dark\ microlithic\ partly vesicular granules\ representing shallow submarine\ Surtseyan!type eruptions[ The other type of pyroclastic fragments are vitric shards\ which originate by quenching granulation during subaqueous eruptions[ The tu}aceous intervals have been subdivided into "0# identi_ed pyroclastics based on textural interpretations\ and "1# assumed pyroclastics based on geochemical interpretations[ The majority of the samples are sub!alkaline basalts and basaltic andesites[ The phase 0 tu}s evolved from basalts to rhyolites upwards in the Lista Formation\ and phase 1 tu}s consist of sub!alkaline basalts and basaltic andesites of within!plate origin\ similar to the contemporaneous Lower Basalts in East Greenland\ the Rockall Trough and the Middle Series on Faroes\ all linked to the opening of the North Atlantic Ocean[ Þ 1999 Elsevier Science Ltd[ All rights reserved[ Keywords] North Sea^ Grane Field^ Volcanism^ Volcaniclastics^ Geochemistry 0[ Introduction During the Palaeogene onset of sea ~oor spreading began north of the Charlie Gibbs Fracture Zone in the North Atlantic "Ziegler\ 0870#[ Continental rifting in the proximity of an Icelandic plume resulted in massive amounts of igneous rocks in the East Greenland and along the margins of the North Atlantic Basin "White + McKenzie\ 0878#[ This igneous activity in the North Atlantic Igneous Province took part in two stages\ at 51 and 42Ð45 Ma "Saunders\ Fitton\ Kerr\ Norry + Kent\ 0885#[ The latter one is contemporaneous with the tu}aceous intervals in the North Sea Basin[ The area of study is Norwegian Block 14:00\ the Grane:Balder area[ It is located on the north!western ~ank of the Utsira High\ a basement high forming the eastern margin of the Southern Viking Graben "Fig[ 0#[ Corresponding author[ Tel[] ¦36 41 91 08 13^ fax] ¦34 41 91 06 75[ E!mail address] hjhaalaÝppco[com "H[ J[ Haaland# Cores from wells 14:00!04\ 14:00!05\ 14:00!06 and 14:7! 3 from the Grane Field are described in order to make a macroscopic and microscopic identi_cation of the pyro! clastic components also determining their chemical characteristics[ By isolating the end!members "sandstone\ mudstone and tu}s# on the basis of the core description\ possible volcanogenic levels were macroscopically ident! i_ed[ These have been studied petrographically in thin sections and geochemically by XRF "X!ray ~uorescence#[ The results of this study have implications for the overall understanding of Paleogene successions in the North Sea\ both locally and regionally[ It also gives a better under! standing of the volcanism development\ associated with the initiation of the PaleoceneÐEocene opening of the North Atlantic[ 1[ Stratigraphy The lithostratigraphy in the Grane area is summarised in Fig[ 1[ The thicknesses of the cored sections are 094 m 9153!7061:99: ! see front matter Þ 1999 Elsevier Science Ltd[ All rights reserved[ PII] S 9 1 5 3 ! 7 0 6 1 " 8 8 # 9 9 9 9 8 ! 3 091 H[J[ Haaland et al[ : Marine and Petroleum Geolo`y 06 "1999# 090Ð007 Fig[ 0[ The Grane Field is situated on the north!western ~ank of the Utsira High\ Southern Viking Graben[ The location of the Grane Field is shown with respect to the Norwegian mainland "redrawn from Hanslien\ 0876#[ The map in the lower right corner shows the localization of the wells 14:00! 04\ 14:00!05\ 14:00!06 and 14:7!3 "redrawn from Norsk Hydro#[ in well 14:00!04\ 032 m in well 14:00!05\ 69 m in well 14:00!06 and 004 m in well 14:7!3[ The Paleogene succession in the Grane area consists of calcareous and purely siliciclastic shale formations\ interbedded with sandstone members and tu}aceous intervals "Fig[ 1#[ The Lista Formation rests conformably on the Vale Formation[ The Lista shales are non!lami! nated "massive# with randomly distributed tu} layers[ The Heimdal Member "not present in the cored interval of well 14:00!06# consists of medium!grained sandstone with few internal sedimentary structures\ and has a blocky gamma ray!sonic log pattern[ The sandstone units occur within the grey and black shales in the lower part of the Lista Formation[ The Sele Formation is present only in the cored inter! vals of the wells 14:00!05 "4 m# and 14:00!06 "4 m#[ The age of the Sele Formation is Paleocene to earliest Eocene[ The rocks of the Sele Formation consist of tu}aceous\ montmorillonite!rich shales and carbonaceous\ grey or greenish!grey\ _nely laminated siltstones[ Cores from the Balder Formation were recovered from the wells 14:00!05 "20 m#\ 14:00!06 "12 m# and 14:7!3 "15 m#[ The Balder Formation is of early Eocene age\ and the rocks are laminated\ varicoloured\ _ssile shales with interbedded grey\ green or brownish yellow sandy tu}s[ Balder sands are only present in well 14:00!06[ The upper boundary is placed at the transition to the overlying non! laminated sediments of the Hordaland Group[ The lower boundary is de_ned by the change in gamma log signature from higher to lower response[ 2[ The tuffaceous intervals in the North Sea Lower Tertiary tu}s are recognised throughout most of the North Sea "Jacque + Thouvenin\ 0864^ Knox + Morton\ 0872#[ They are found northwards along the Norwegian shelf as far as the Haltenbanken and Tr%na! banken areas "Malm et al[\ 0873#\ and southwards to Denmark and in the northern part of Germany "Morton + Knox\ 0889#[ Early Tertiary volcanic activity is divided into two H[J[ Haaland et al[ : Marine and Petroleum Geolo`y 06 "1999# 090Ð007 092 Fig[ 1[ The stratigraphy "based on nannoplankton zonation# of the Grane area "redrawn after Norsk Hydro\ Mangerud et al[ "in press#\ with additional geomagnetic data from Cande and Kent\ 0884 and the volcanic phases of Knox + Morton\ 0872#[ The lithostratigraphic nomenclature is from Deegan and Scull "0866#[ main phases of pyroclastic deposition during the time interval 47Ð41 Ma[ These have been further strati! graphically subdivided by the means of dino~agellate cyst correlation "Knox + Morton\ 0872#[ Phase 0 "47Ð46 Ma# consists of ash layers interbedded with mudstones[ The ash layers are normally graded and vary in thickness from 9[4Ð4 cm[ Phase 1 "44Ð41 Ma# is divided into four subphases[ They all have di}erent characteristics prob! ably related to depositional mode[ Subphase 1a is rep! resented by sporadically thin\ graded ash layers[ Subphase 1b "the main tu} zone# has more than 074 amalgamated graded layers which vary in thickness from a few millimetres up to 17 cm[ The two last subphases\ 1c and 1 d\ are represented by thin\ generally widely!spaced graded layers interbedded with red and varicoloured shales[ The geochemical compositions of the Tertiary volcanic ash beds show a wide range "Jacque + Thouvenin\ 0864^ Knox + Morton\ 0872^ Malm et al[\ 0873^ Knox + Morton\ 0877^ Morton + Knox\ 0889#[ Phase 0 is reported to be of basaltic composition\ including di}er! entiated FeÐTi tholeiites\ and its distribution would indi! cate a Hebridean origin\ connected to the Scottish central intrusions "Knox + Morton\ 0872#[ In some samples\ aegirine\ indicative of a peralkaline composition\ is present[ Since aegirine appears in both the British Ter! 093 H[J[ Haaland et al[ : Marine and Petroleum Geolo`y 06 "1999# 090Ð007 tiary Volcanic Province "Bell + Emelius\ 0877^ Hawkes\ Merriman\ Harding + Darbyshire\ 0864# and in East Greenland "Nielsen\ 0868#\ it is possible that both con! tributed to the phase 0 deposits[ Phase 1 shows a much wider compositional range than phase 0[ Subphase 1a encompasses ashes of tholeiitic to rhyolitic "partly peralkaline# compositions "Pedersen\ Engell + Ro nsbo 0864#\ whereas the tu}s of subphase 1b are basalts only\ and those of subphases 1c and 1 d are basaltic with some minor occurrences of intermediate rocks "Knox + Morton\ 0877#[ The tu}aceous sediments in the North Sea are completely altered to smectitic clay "Knox + Morton\ 0877#[ Whole!rock XRF analyses of some fresh samples from Denmark have been performed by Pedersen et al[ "0864#[ On altered samples\ the primary composition has been deduced from analyses of fresh feldspars and amphiboles "Knox + Morton\ 0877#[ A limited geochemical study by Malm et al[ "0873# of the main tu} zone\ subphase 1b\ showed that the tu}s are best comparable with {within!plate| basalts[ Morton and Knox "0889# studied {immobile| trace elements of the tu}s from the Balder and Sele formations in four wells in the northern and southwestern North Sea[ Their study con_rms the geochemical results done on the tephra layers onshore in Denmark "Morton + Evans\ 0877#[ Subphases 1a and 1b are compositionally similar both in the North Sea and in Denmark[ In spite of the di}erent geochemical characteristics\ Morton and Knox "0889# deduced them to be of the same origin indicating a rift! related setting\ and their stratigraphic development sug! gests an evolving volcanic centre[ The geochemical data indicate an evolution from variably silica under!saturated to silica!saturated magmas\ interpreted to re~ect both an increase in the degree of partial melting and decreasing crustal involvement "Pedersen + Jo rgensen\ 0870#[ The proto!Icelandic plume generating the early Paleogene basalts of East Greenland and the Faroes was believed to be the source of the basaltic tephras "Morton + Knox\ 0889#[ During the late Paleocene this plume became established and generated a great volume of basaltic lava in the area between the East Greenland Blosseville Kyst and the Faroes "Bott\ 0877^ White\ 0877#[ 2[0[ The Grane Field tuffs 2[0[0[ Description The tu}aceous layers are divided into lithofacies based on bed thickness\ lithology\ texture and sedimentary structures[ Normally graded tu} beds appear in wells 14:00!05\ 14:00!06 and 14:7!3 within the Balder and Sele Formations[ They are most distinctly developed in well 14:00!06 "Fig[ 2#\ within which two successions of amal! gamated tu}!beds "2[8 and 0[5 m#\ separated by a 5 m thick massive Balder sandstone\ occur[ In well 14:00!05 the normally graded tu} layers sum up to 4[64 m[ In well Fig[ 2[ Normal graded tu}!beds interbedded with laminated silt[ From well 14:00!06\ Balder Formation[ 14:7!3\ 2[79 m of the normally graded tu} beds show alternations between hemipelagic silt and tu}\ and a 0[59 m thick succession of amalgamated tu}s[ The layers vary in grain size from medium!grained at the base to silt! or clay size on top[ A total of 007 beds have been recorded in well 14:00!06\ 62 in well 14:00!05 and 73 in well 14:7!3[ The individual beds vary in thickness from 9[4Ð08 cm[ The base of the beds are well de_ned and show two di}erent characteristics] "i# erosion into the underlying laminae\ or "ii# conformable character[ Macroscopically the di}erence may be subtle[ The top of the beds are often mudstone!dominated or capped by dark brown laminated shale[ The beds are dominantly amalgamated[ The tu}s vary in colour[ Most of them are yellow to light green at the base\ and darkening towards the top[ The yellow appearance at the base of some of the beds is due to calcite cementation[ In well 14:7!3 the normally graded tu} beds contain several vertical cracks which are _lled with calcite[ The Balder sandstones con! tain fragments of undistorted tu}!beds\ implying that H[J[ Haaland et al[ : Marine and Petroleum Geolo`y 06 "1999# 090Ð007 the total of 007 tu}!beds do not necessarily record the complete thickness of the pyroclastic beds[ The isolated tu}s are present in all four wells and are restricted to the Lista! and Vale Formations[ The number of beds varies from 19Ð27 in each well\ each bed varying in thickness from 9[4Ð01[4 cm[ There is no consistent variation in the distance between the layers[ Commonly they appear as single occurrences "Fig[ 3#\ but in the lower part of the Lista Formation they are more frequent[ The recognition of this facies is based on a distinctive colour change from the mudstones and siltstones\ in addition to grain size changes[ A majority of the beds are normally graded with a grain size variation from medium!\ _ne! or very!_ne sandstone to silt and mud[ The basal contact is either distinguished by a marked colour change in the _ne grained varieties or a sharp contact in the coarser beds[ The sharp contacts may be erosive or non!erosive[ The upper contacts have also a variety of features\ such as a marked colour change or a grain size change[ The layers are always capped by mud[ Laminated shale is not recognised[ The upper contact 094 may be either abrupt or gradational[ The colour of the layers varies from di}erent shades of green to red[ The thickest layers are dark green at the base and lighter towards the top[ 2[0[1[ Interpretation Normally graded tu} beds may be emplaced by two di}erent mechanisms of transport and deposition[ One possibility is that they represent wind transported tephra deposits by fallout into water settling hemipelagically through the water column[ The other possibility is depo! sition or redeposition by low!density turbidity currents[ After deposition the tephra beds may be further reworked and redistributed by bottom currents "Cas + Wright\ 0877#[ Of those investigated for this study\ only a few beds have been reworked[ The isolated occurrences re~ect more episodic depo! sition "Jacque + Thouvenin\ 0864^ Knox + Morton\ 0872#[ The majority of the isolated layers are reworked[ They are deposited _rst by fallout into water and there! after reworked by low!density turbidity currents[ Only very few of the isolated layers seem to be una}ected by secondary processes[ Norin "0847# classi_ed tu}s according to sharp or di}use upper contact\ presence of vertical grading\ amount and kind of pumice and non!volcanic grains\ type of internal lamination and grain morphology[ Evidence indicating a turbiditic origin includes erosional bases and partial Bouma sequences with graded beds "Watkins et al[\ 0867#[ If the tephra contains other grains than those of pyroclastic origin\ this is attributed to turbiditic pro! cesses[ These characteristics apply to the majority of the phase 0 layers\ which are of single occurrence[ The process of wind!blow\ water settled tephra is tho! roughly described by Ledbetter and Sparks "0868#[ The size distribution of the particles and size of a graded layer is a function of duration of eruption\ rate of release\ residence time in the atmosphere\ settling velocity and water depth at the site of deposition[ Tephra is ejected into the prevailing wind system from the eruption clouds[ After wind transport\ the grains fall onto the water sur! face and sink to the bottom\ by a process of size sorting through the water column[ As the process continues\ larger grains will settle before earlier!erupted\ _ner!grai! ned particles[ During one eruption there will be a thin zone of the largest particles at the base of the tu} layer[ This process re~ects the sedimentary mechanism for the phase 1 tu}s\ where only a small number have been resedi! mented[ 3[ Petrography 3[0[ Introduction Fig[ 3[ Example of isolated tu} in the Lista Formation " from well 14:00!06#[ Tertiary volcaniclastic sediments in the areas sur! rounding the North Sea were _rst described by Bo ggild 095 H[J[ Haaland et al[ : Marine and Petroleum Geolo`y 06 "1999# 090Ð007 "0807# from onshore sediments in northern Denmark and were later found in northern Germany "Andersen\ 0826# and in south!east England "Elliott\ 0860#[ Jacque and Thouvenin "0864# presented the _rst paper on the equi! valent o}shore sediments\ in which textures of two types of volcanogenic fragments were described[ Later work by Malm et al[ "0873# discussed the textures of the volcanogenic fragments from well 29:1!0 in the north Viking Graben\ in relation to a speci_c volcanic setting[ The morphology of the grains were found to be comparable to those produced by Surtseyan!type erup! tion\ i[e[ explosive activity caused by water gaining access to the top of a vent "Kokelaar\ 0875#[ The vesicular tu} particles of these eruptions are described as dominantly green with subordinate dark brown and yellow grains[ In addition to the predominantly vitric particles some grains contain microscopic quench crystals of plagioclase[ These two types of pyroclastic grains are identical to those described by Jacque and Thouvenin "0864# "Fig[ 4"a# and "b##[ Based on the main constituents of the tu}!layers\ they have been subdivided into two types] "0# Tu}s consisting of Surtseyan!type shards "Walker + Croasdale\ 0861^ Heiken\ 0863#\ containing "i# vesicular pyroclasts with irregular shape and "ii# dark microlithic\ partly vesicular granules[ These clasts are typically of shallow submarine basaltic eruptions\ during which water\ having free access to the vent\ either becomes trapped near the magma\ or engulfed in it[ The magma moves through a wet slurry of clastic material\ a process referred to as {bulk interaction steam explosivity| "Kokelaar\ 0875#\ taking place at the magmaÐwater interface[ The water thus becomes super! heated resulting in an explosive expansion of steam that disrupts the magma[ Deposits consisting of these shards are named hyalotu} "Honnorez + Kirst\ 0864#[ "1# Tu}s consisting of aphyric\ vitric shards[ A vitric shard\ formed subaqueously by granulation during quenching\ is com! monly irregular with planar\ concave and convex surfaces\ containing abundant vesicles[ Two di}erent processes may account for the shard production "Bergh + Sigvaldason\ 0880#[ When the hydrostatic pressure is high\ the resulting slow eruption rate suppresses ves! iculation and results in pillow lavas[ Shards with low vesicularity may be fragmented from the outer rim of the pillows[ With a low hydrostatic pressure and initial high content of volatiles\ the resulting eruption rate is high[ The fragments formed are more vesiculated[ The related deposits are termed hyaloclastite "Rittman\ 0859#[ 3[1[ Microscopic facies description Based on detailed thin section studies of 27 samples and depositional interpretations\ the tu}aceous layers have been divided into di}erent microscopic facies[ Those facies containing grains of volcanic origin have been classi_ed as "0# primary volcaniclastic layers\ "1# sec! ondary volcaniclastic layers\ "2# volcaniclastic shale and "3# volcaniclastic mud[ The relative abundance of the di}erent grain types is estimated at the base of the layers[ The grain size is measured across the widest part of a grain[ 3[1[0[ Primary volcaniclastic layers A deposit characterised by a sharp non!erosive base\ normal grading\ consisting of dominantly volcaniclastic grains\ has been classi_ed as a water!lain primary vol! caniclastic layer[ The abundance of volcanic shards varies from 69Ð84)\ the rest representing calcite cement and a minor fraction of hemipelagic clay[ Two types of Surtseyan!type shards\ having partly similar characteristics\ are present[ The size of the shards ranges from 9[4Ð0[9 mm at the base to 9[94 mm in the upper part of the layers[ Their original shape is identical and both have microlithic plagioclase needles[ Apart from the microlites\ some have plagioclase crystals larger than 9[0 mm[ One shard type is de_ned as dark microlithic vesicular\ irregularly shaped granules "Fig[ 4"c##\ with scattered microlithic plagioclase needles[ Some of the vesicles are _lled with clay minerals and calcite[ The other shard type de_ne vesicular\ transparent pyroclasts with irregular shapes that vary from subrounded to suban! gular[ The vesicularity ranges from few to abundant\ irregular to spherical vesicles\ _lled with clay minerals and to a lesser extent calcite[ Microlithic plagioclase nee! dles are only present in some of the grains[ 3[1[1[ Secondary volcaniclastic layers These rocks represent resedimented volcaniclastic deposits[ The criteria used to distinguish between epicl! astic and pyroclastic layers is the presence of erosive bases and ~oating mudclasts of the former\ as well as the grain composition[ The epiclastic layers are normally graded and massive\ without any sign of lamination[ The bases of the secondary volcaniclastic layers are markedly di}erent from the primary pyroclastic deposits as their contacts to underlying mud layers are erosive[ In contrast to the knife!sharp base of the primary vol! caniclastic layers\ the secondary volcaniclastics have an irregular base[ There is no sign of load features like lam! inae forced into the underlying sediments[ In two of the thin sections mudclasts {~oating| in the layers have been observed[ The di}erent grains in the layers range from purely pyroclastics to mixed pyroclastic and lithics\ with pyroclastic fragments consisting of Surtseyan!type shards and vitric\ non!vesicular shards[ The lithic fragments con! sist of plagioclase\ biotite\ muscovite and mud clasts[ The epiclastics can be further subdivided into two types[ Those of pure pyroclastic origin are found in the Balder and Sele Formations whereas those with mixed pyroclastic and lithic grains only are found in the Lista! and Sele Formations[ "i# Epiclastics of pure pyroclastic origin consist of the same fragments as those described H[J[ Haaland et al[ : Marine and Petroleum Geolo`y 06 "1999# 090Ð007 096 Fig[ 4[ "a# Weathered aphyric vitreous\ vesicular shard[ "b# Strongly weathered dark ash granule with small microlithic plagioclases "white#[ "c# Dark microlithic vesicular granule\ well 14:00!06\ depth 0520[79 m[ "d# Platy vitric shards\ well 14:00!06\ depth 0520[61 m[ 097 H[J[ Haaland et al[ : Marine and Petroleum Geolo`y 06 "1999# 090Ð007 in the primary volcaniclastic deposits\ consisting of ves! icular pyroclasts or dark microlithic granules[ "ii# Epicla! stics with mixed pyroclastics and lithics consist of vitric chards\ biotite and mud clasts in a clayey matrix in addition to Surtseyan!type shards[ Vitric shards] These shards are brown to transparent and have a grain size distribution from 9[91Ð9[1 mm[ Their shapes are either platy concave or vesicular "Fig[ 4"d##[ The platy fragments are more angular and de_ne inward curving walls re~ecting the breakage of vesicle walls[ Plagioclase] Plagioclase grains have only been found in dark microlithic\ vesicular granules of which plagioclase crystals are the only fresh remnants[ The size of the plagioclase needles vary from 9[92Ð9[1 mm[ Biotite] Biotite has only been found within one of the epiclastic layers[ The platy crystals\ varying in size from 9[0Ð9[1 mm\ are brown and pleochroic[ Mud clasts] The mud clasts vary in size from 9[1Ð 0[9 mm and are situated immediately above the base of the layers aligned in the direction of ~ow[ These clasts consist of resedimented\ consolidated mud or fragments of consolidated epiclastic layers[ 3[1[2[ Volcaniclastic shale The volcaniclastic shale is con_ned to the laminated intervals immediately above the normally graded tu} lay! ers in the Balder and Sele Formations[ These layers con! sist of shaly mud with undulating\ allochtonous\ coaly laminae[ The coaly laminae are discontinuous and consist of fragments with a length from 9[94Ð9[1 mm and a width of ca 9[91 mm[ Small concretions\ 9[0Ð9[1 mm\ are ran! domly scattered within the layers[ Semiquantitative SEM analyses show that these concretions predominantly con! sist of iron\ manganese and magnesium[ The depositional origin of the volcaniclastic shales is similar to that of the primary volcaniclastic layers[ There is no indication of transportation other than passive set! tling from water[ Occasionally 9[94Ð9[1 mm sized pyro! clastic fragments are present[ 3[1[3[ Volcaniclastic mud The muddy microfacies consists of a matrix of clay minerals in addition to fragments of plagioclase\ coal and biogenic material[ The minerals are dominantly chloriteÐ smectite mixed layer clays with subordinate illite and smectite "N[ Gjelsvik\ pers[ comm[#[ Plagioclase\ ranging in size from 9[90Ð9[94 mm\ is present as microliths ident! ical to those described in the Surtseyan!type shards[ The coal fragments\ constituting 0Ð09) of the rock\ are of the same size as the plagioclase microliths[ Neither of these seem to be con_ned to speci_c levels\ they are both randomly distributed[ Minor occurrences of fora! minifers are found[ Macroscopically the rock has a massive appearance\ but the plagioclase grains coal fragments are aligned\ de_ning thin laminae in the majority of the samples[ 4[ Geochemistry Geochemical analysis have been performed on rocks from all four wells investigated[ Special emphasis is\ how! ever\ put on well 14:00!06\ which was petrographically studied in detail[ A total of 041 samples of the identi_ed tu} layers\ rocks supposed to represent tu}s\ mudstones and sandstones throughout the cores\ have been exam! ined "05 from well 14:00!04\ 16 from well 14:00!05\ 55 from well 14:00!06 and 32 from well 14:7!3#[ Due to the pervasive alteration of the pyroclastic layers\ the appli! cation of major elements\ was not considered useful for this study[ The geochemical study is therefore based on immobile trace elements of bulk!rock analyses[ 4[0[ Analytical methods The trace element analyses were carried out in the Geological Institute\ University of Bergen[ The analyses were performed on a Philips PW 0393 X!ray ~uorescence "XRF#\ using pressed powder!pellets[ The method is described by Norrish and Hutton "0858#\ and inter! national standards with recommended values after Gov! indaraju "0873# were used for calibration[ 4[1[ Element mobility All the tu}aceous sediments have su}ered severe alter! ation as evidenced by thin section and SEM studies[ The initial vitric material is entirely altered to smectite "Mor! ton + Knox\ 0889#[ The trace elements Zr\ Nb\ Y and Ti are recognised to be stable during alteration and weath! ering "Pearce\ 0864^ Winchester + Floyd\ 0866^ Pearce + Norry\ 0868^ Malm et al[\ 0873#[ Cr is also found to be fairly stable during alteration "Hu}\ 0872#\ and in the absence of major elements\ it may be used to indicate the degree of di}erentiation of the rock[ During weathering\ pyroclastic material will undergo di}erent chemical changes depending on whether it con! sists of basaltic or silicic glass "Fisher + Schmincke\ 0873#[ Such di}erences are most pronounced when alter! ation occurs at low temperature[ Basaltic glass changes its nature from palagonite\ commonly a non!crystalline or poorly crystalline material\ and further to smectite "Thorseth\ Furnes + Tumyr\ 0880#[ Ti is the only above! mentioned element which may be a}ected by this alter! ation "Cas + Wright\ 0877#\ but is found to be stable by most authors "e[g[ Pearce\ 0864^ Winchester + Floyd\ 0866^ Pearce + Norry\ 0868#[ Silicic glass is not so easily altered as basaltic glass due to the rigid framework of Si and Al[ Y and Zr tend to increase and Cr decreases during alteration "Fisher + H[J[ Haaland et al[ : Marine and Petroleum Geolo`y 06 "1999# 090Ð007 Schmincke\ 0873#[ Zr\ however\ has to be used with care as zircon may be present locally and thus bias the chemi! cal data "Schmincke\ Viereck\ Gri.n + Pritchard\ 0871#[ 4[2[ Classi_cation of the samples During core!investigation\ the samples were grouped into sandstone\ mudstone and layers of probable pyro! clastic origin[ For petrographic evaluation the samples were investigated microscopically[ These studies made it possible to isolate the end members\ i[e[ sandstone\ clean mudstone and clean tu}[ The end members were plotted in all possible combinations of the elements Cr\ Nb\ Zr\ Ti and Y[ The YÐNb and ZrÐTiO1 diagrams "Fig[ 5"a# and "c## were found most suitable to separate the pyro! clastics from mudstones and sandstones\ thus de_ning a pyroclastic origin[ The YÐNb and ZrÐTiO1 diagrams were subsequently used to identify the nature of the {unknown| "not micro! scopically investigated# samples further down in the Lis! ta! and Vale Formations[ The samples which plot in the _eld de_ned by pure pyroclastic material "Fig[ 5"b# and "d## are on this basis {de_ned| to represent pyroclastic rocks[ 4[3[ Bulk rock chemistry Of all the analysed samples\ approximately 0:2 have been identi_ed as tu}s based on macroscopic textures and the YÐNb and ZrÐTiO1 relationships "Fig[ 5"a#Ð"d##[ The selected elements show a wide range of values[ Cr varies from 7Ð547 ppm\ Nb from 02Ð192 ppm\ Zr from 028Ð1744 ppm\ Y from 14Ð506 ppm\ and TiO1 from 9[38Ð 4[47 wt)[ These values re~ect the highly variable com! position of the di}erent tu}s[ 4[3[0[ Classi_cation of the individual rock!types The tu}s can be classi_ed into di}erent rock series by using the Zr:TiO1ÐNb:Y diagram Winchester and Floyd "0866#[ Based on the Nb:Y ratio\ the volcanic rocks may be divided into subalkaline and alkaline suites[ Pearce and Cann "0862# and Floyd and Winchester "0864# found the Y:Nb ratios suitable for separating tholeiitic and alkaline rocks\ for which purpose Winchester and Floyd "0866# suggested a value of 9[56[ This applies to all rocks except the most siliceous ones\ as the Nb:Y ratio increases slightly with increased di}erentiation[ The Zr:TiO1 ratio may be used as an index of frac! tionation and since these elements are stable during alter! ation\ they can be applied to classify altered rocks\ plotted against Nb:Y[ With di}erentiation from basic to acid rocks\ the Zr:TiO1 ratio increases[ In the four wells\ 46 tu} layers have been recognised "Table 0#[ Fig[ 6"a# classi_es the identi_ed pyroclastics "based on textural interpretation#\ and Fig[ 6"b# classi_es 098 the assumed pyroclastics "based on a geochemical interpretation#[ The majority of the identi_ed pyroclastic samples plot in the sub!alkaline suite of basalts and the transition andesites:basalts[ Only one is a rhyolite[ One sample is an alkali basalt and two are trachyandesites[ The majority of the assumed pyroclastics "29 samples# plot as sub!alkaline basalts and andesite:basalts[ Four samples plot as andesites\ one rhyolite and one is a per! alkaline comendite:pantellerite[ Only a minority of the samples plots in the alkaline _eld\ with two alkali basalts and two trachyandesites[ Thus\ the majority of assumed and identi_ed tu}s are sub!alkaline basalts\ transitional andesites:basalts and andesites "Fig[ 6"a# and "b##[ 4[4[ Geochemical variations with depth In Fig[ 7 the geochemical data from well 14:00!06 are shown in relation to stratigraphic depth[ In the Balder Formation the tu}s are dominantly sub!alkaline basalts and minor andesites:basalts characterised by low Nb:Y! and Zr:TiO1!ratios "Figs[ 7\ 6"a# and "b##[ Samples 2[510 and 2[520 have anomalously high Cr values\ and are correspondingly low in the incompatible elements\ especially Y and Nb "Table 0#\ indicative of a {primitive| composition of the magma[ The andesitic:basaltic rocks have slightly lower Nb:Y!ratios[ Their Y values have a profoundly higher average value "195 ppm# than that of the average the sub!alkaline basalts "56 ppm#\ consistent with a more di}erentiated magma[ Only two sub!alkaline basalt samples are represented from the Sele Formation "Fig[ 7#[ The Nb:Y!ratios are similar to those of the tu}s in the Balder Formation\ but their Y and Nb values are slightly higher[ The Lista Formation shows a much wider range in the composition of the tu}s compared to those of the Balder and Sele Formations "Fig[ 7#[ The majority of the tu}s range from sub!alkaline basalts\ andesite:basalts\ andes! ite to rhyolites[ There are minor occurrences of alkali basalts and trachyandesites[ In general\ the Cr content of the tu}s decreases upwards\ indicating that the magmas become more fractionated with time[ Of the tu} layers sampled in the Vale Formation\ three are sub!alkaline basalts\ one is an alkaline basalt and two are samples of andesitic:basaltic composition "Fig[ 7#[ 4[5[ Geochemical character and tectonic setting For the purpose of viewing the geochemistry of the tu}s in relation to the tectonic setting\ two discriminant diagrams have been applied[ The TiÐZrÐY diagram of Pearce and Cann "0862# separates within!plate basalts\ volcanic!arc basalts\ and mid!ocean ridge basalts\ and the NbÐZrÐY diagram of Meschede "0875# which dis! tinguishes between di}erent types of mid!ocean!ridge 009 H[J[ Haaland et al[ : Marine and Petroleum Geolo`y 06 "1999# 090Ð007 Fig[ 5[ NbÐY and ZrÐTiO1 diagrams showing the range of values for pure sandstone\ mudstone and tu}aceous layers of the Balder!\ Sele!\ Lista! and Vale Formations in well 14:00!06[ "a# Shows the de_ned areas in which the sandstones and the microscopically identi_ed mudstones and pyroclastics plot[ "b# De_nes the assumed pyroclastics by the Nb and Y range found in "a#[ "c and d# Zr vs TiO1 data of sandstone\ mudstone and tu}aceous layers[ "c# Shows the de_ned areas in which the sandstones and the microscopically identi_ed mudstones and pyroclastics plot[ "d# De_nes the assumed pyroclastics by the Zr:TiO1!range found in "c#[ basalts\ within!plate tholeiites and within!plate alkali basalts[ Of the samples classi_ed as tu}s "based on thin section studies#\ only those of primary origin " _ve samples# have been considered[ In the TiÐZrÐY diagram "Fig 8"a##\ four of the analyses plot in the area between volcanic!arc and ocean!~oor basalts\ close to _eld of within!plate basalt[ In the NbÐZrÐY diagram\ the analyses plot in _elds of N! and E!type MORB\ volcanic!arc basalts "Fig[ 8"b##[ In the TiÐZr diagram of Pearce "0871# which distinguishes between within!plate lavas\ and volcanic!arc lavas and MORB\ all analyses plot in the _eld of within!plate basalts "Fig[ 8"c##[ In Fig[ 09"a# and "b#\ the assumed tu}s are plotted in the TiÐZrÐY and NbÐZrÐY diagrams[ A large number of the samples show high Y\ and some have high Zr concentrations[ This is probably an e}ect of the sec! ondary reworking and sorting resulting in enrichment of zircon and apatite\ resulting in abnormally high contents of Zr and Y\ respectively[ The majority of the samples\ however\ cluster in the area between volcanic!arc and ocean!~oor basalts\ close to _eld of within!plate basalt[ Mobility of Y of the North Sea tu}s is a feature also noted by Morton and Evans "0877# and Morton and Knox "0889#\ and Winchester and Floyd "0866# found the Y values of the altered North Sea samples to be H[J[ Haaland et al[ : Marine and Petroleum Geolo`y 06 "1999# 090Ð007 Table 0 Selected major "TiO1# and trace elements "Cr\ Zr\ Y\ Nb# of the various tu} layers[ Sample pre_xes 0\ 1\ 2\ 3 refer to wells 14:00!04\ 14:00!05\ 14:00!06 and 14:7!3\ respectively Sample Depth "m# Cr TiO1 Zr Y Nb Subalkaline basalt 0[009 0607[649 0[049 0617[369 1[249 0764[449 1[259 0765[179 1[289 0771[019 2[911 0529[054 2[913 0529[109 5[439 0529[689 4[659 0521[299 4[239 0522[979 2[939 0522[069 2[930 0522[079 2[950 0539[704 2[980 0536[719 2[989 0536[729 2[199 0692[719 2[129 0609[789 2[510 0612[799 2[520 0612[704 3[930 0583[249 3[949 0586[904 3[969 0690[024 3[961 0690[089 3[963 0690[129 3[089 0650[739 192 132 087 024 087 005 093 007 74 028 76 64 88 74 71 88 129 301 547 15 063 65 64 006 121 1[96 2[04 4[96 1[26 1[20 3[44 3[78 3[53 4[45 2[56 2[09 1[21 2[49 3[97 1[80 4[47 4[23 0[25 1[72 2[42 2[09 2[97 2[07 2[12 1[82 107 146 213 136 172 274 276 271 214 277 240 108 259 263 297 310 244 078 138 028 144 290 165 184 118 28 22 60 41 39 85 78 51 75 78 52 56 70 82 091 095 69 23 39 38 64 40 50 44 32 07 05 16 19 08 22 20 20 17 18 29 10 23 49 33 25 14 04 08 08 10 10 08 11 03 Andesite:Basalt 0[969 0602[509 0[099 0605[239 1[034 0627[239 1[204 0748[729 5[929 0520[839 7[059 0520[799 6[969 0532[054 2[079 0587[009 2[074 0699[599 2[169 0629[539 2[179 0622[069 3[951 0587[659 3[109 0664[059 60 012 230 050 77 84 63 126 115 13 66 37 35 1[56 0[57 3[15 3[08 1[63 1[97 2[60 1[31 0[74 2[80 3[08 1[41 1[68 060 006 164 321 192 052 279 066 198 152 215 165 177 506 393 010 68 60 65 026 350 056 024 217 86 096 28 12 15 10 03 02 17 29 05 13 33 14 10 Andesite 0[019 0[039 1[209 3[909 0608[639 0615[789 0748[659 0551[074 073 050 049 62 0[58 0[18 1[49 1[18 107 118 210 335 70 26 42 52 03 04 04 11 Rhyolitt 2[039 3[069 0559[269 0645[769 05 7 9[59 9[35 801 611 69 63 29 07 Comendite:Pantellerite 0[959 0698[389 01 9[38 1744 256 192 Alkali!basalt 1[039 0627[179 1[109 0674[439 2[159 0612[499 171 029 143 2[70 1[20 2[81 134 123 213 16 26 14 10 39 13 000 Table 0 "continued# Trachyandesite 1[239 0762[819 1[279 0768[689 2[019 0545[879 2[130 0604[089 32 79 16 59 0[24 0[48 9[84 0[42 0106 623 178 894 037 004 17 024 079 007 31 052 Fig[ 6[ "a# Samples petrographically identi_ed as pyroclastic by the use of thin sections\ plotted in the Zr:TiO1ÐNb:Y diagram of Winchester and Floyd "0866#[ "b# The rocks de_ned as pyroclastic material based on the YÐNb and ZrÐTiO1 diagrams "Fig[ 5"a#Ð"d##\ plotted in the Zr:TiO1ÐNb:Y diagram of Winchester and Floyd "0866#[ 001 H[J[ Haaland et al[ : Marine and Petroleum Geolo`y 06 "1999# 090Ð007 Fig[ 7[ Cr\ Nb\ Zr\ TiO1\ Y and Nb:Y plotted against the core log in well 14:00!06[ The tu}s are marked with symbols showing the rock types[ Open square subalkaline basalt^ open diamonds] andesite:basalt^ open triangle] rhyolite^ _lled circle] trachyandesite[ The arrows indicate levels from which thin sections of the tu}s have been studied[ slightly higher than the contemporaneous\ fresh Danish tephra[ On this basis\ it is thus reasonable to suggest that the samples re~ect within!plate character[ 5[ Discussion and conclusions 5[0[ Magmatic setting The theory of an Icelandic hot spot has prevailed in the literature since Holmes "0807# described the Thulean Volcanic Province[ The _rst indications of volcanism related to plume activity are from 53 Ma in the British Tertiary Province and from 51Ð50 Ma in East Greenland "White + McKenzie\ 0878#[ The timing suggests that the volcanism in these two areas were linked to the same plume activity "White 0878^ Ritchie + Hitchen\ 0885#[ The plume was supposedly generated by rising jets of buoyant mantle which created vertical and horizontal ~ow within the mantle\ thus causing uplift of the litho! sphere above "Nadin\ Kusznir + Cheadle\ 0886#[ The plume a}ected an area of ×1999 km in diameter "White\ 0878#[ After the plume impinged on the lithosphere\ the North Atlantic rift responded isostatically by uplift and subsequent spreading "White + McKenzie\ 0878#[ The magmatic activity increased in magnitude until its maximum at around 51Ð47 Ma "Ritchie + Hitchen\ 0885#[ The volcanism was active from 50Ð44 Ma "Dewey + Windley\ 0877# and terminated at the time of the initiation of the North Atlantic Ocean "Ritchie + Hitchen\ 0885#[ 5[1[ The deposition and origin of the tuff layers The tu} layers are related to the opening of the North Atlantic Ocean\ an interpretation based on geochemical correlations "as discussed below#[ The tu}s were trans! ported by prevailing winds from the northwest into the North Sea Basin "Knox + Morton\ 0877#[ Based on sedi! H[J[ Haaland et al[ : Marine and Petroleum Geolo`y 06 "1999# 090Ð007 002 mentary facies interpretation and petrography\ the tu}s are classi_ed as "0# normally graded tu} beds or "1# isolated tu}s[ This division is evident in the stratigraphic distribution of the layers[ There is an upward increase in the occurrence of the tu} beds throughout the Vale Formation and the lower part of the Lista Formation[ The majority of these single tu} beds are reworked or resedimented[ There is a period of quiescence in the upper part of the Lista Formation\ before amalgamated tu} beds are deposited in the upper Sele Formation and the lower part of the Balder Formation[ These amalgamated tu}s probably re~ect more continuous\ explosive volcan! ism[ In the Sele and Balder Formations the amalgamation e}ectively protected the ones previously deposited[ This is due to repeated rapid sedimentation as primary water! lain tu}s as opposed to single events[ From thin section studies it seems that the Balder and Sele were rarely exposed long enough to be a}ected by resedimentation or reworking by bottom currents[ Therefore the amal! gamated tu}s are better preserved than the single layers in the Lista and Vale Formations[ 5[2[ Regional correlation of the volcanic activity Fig[ 8[ "a# The petrographically determined primary tu}s plotted in the TiÐZrÐY diagram of Pearce and Cann "0862#[ The samples plot in _elds B and C\ denoting calc!alkali basalts "B and C# and ocean!~oor basalts "B#[ Field A and B represents low!potassium tholeiites and D within! plate basalt[ "b# The same samples plotted in the NbÐZrÐY diagram of Meschede "0875#[ The samples plot in _eld B and C in addition to one in _eld D[ The representative setting for Ai\ Aii and C are within!plate basalt\ E!type MORB in B\ N!type MORB in D and volcanic!arc basalts in C and D[ "c# The samples plotted in the TiÐZr diagram of Pearce "0871#[ The reworked tu}s of the Vale and Lista Formations are not suitable for geochemical correlation\ leaving their stratigraphic position as the only useful tool for corre! lation[ Knox and Morton "0877# attribute these layers to the volcaniclastic phase 0\ the timing of which is con! sistent with the doming related to the Icelandic hot!spot "½47Ð64 Ma#[ The proposed source areas\ the FaroeÐ Greenland Province and the British Province "Knox + Morton\ 0877#\ are also comparable by being time!equi! valents[ Geochemical data from di}erent areas of the North Atlantic Igneous Province "NAIP# are compared with the contemporaneous phase 1 tu}s[ The areas of extrusive activity in the North Atlantic Igneous Province at the given time are East Greenland\ the Vo ring Plateau "Upper Series#\ Hatton Bank\ Faroe Plateau "the Middle and Upper Series of Faroe Lava Group# and the North Rockall Trough!Hebrides "the North Rockall Trough! Hebrides Lava Group# "Fig[ 00#[ In the TiÐZrÐY diagram\ the Flado dykes and basalts from the Lower Lavas from East Greenland plot in the _eld of within!plate basalts "WPB# extending into the _eld of mid!ocean ridge basalts "MORB# "Fig[ 01"a##[ In the NbÐZrÐY diagram "Fig[ 01"b## and the Flado dykes straddle the boundaries between WPA "within!plate alk! ali basalt#\ WPB:VAB and P!type MORB "plume in~u! enced mid!ocean ridge basalt#\ whereas the Lower Lavas plot between WPB and VAB "volcanic!arc basalts#[ The Upper Series on the Vo ring Plateau show WPB to MORB:VAB a.nity by applying the TiÐZrÐY diagram "Fig[ 01"a## and N!type MORB "normal mid!ocean basalt#:VAB to WPB:VAB in the NbÐZrÐY diagram 003 H[J[ Haaland et al[ : Marine and Petroleum Geolo`y 06 "1999# 090Ð007 Fig[ 09[ "a# The assumed tu}s plotted in the TiÐZrÐY diagram of Pearce and Cann "0862#\ and "b# the NbÐZrÐY diagram of Meschede "0875#[ Explanation to diagrams as in Fig[ 8[ "Fig[ 01"b##[ This series is partly time!equivalent with the Middle Series on Faroes "Hitchen + Ritchie\ 0885#[ Data from the Middle Series "Gariepy\ Ludden + Brooks\ 0872# are only plotted in the NbÐZrÐY diagram in Fig[ 01"b#\ due to the lack of TiO1 data[ Here they plot entirely in the joint _eld of WPB:VAB[ Data from well 052:5!0A from the Rockall Trough "Morton et al[\ 0877# show a WPB origin "Fig[ 01"b# and "b##[ A majority of the sam! ples tend to plot in the _eld of within!plate basalts[ The TiÐZrÐY diagram does not\ however\ separate con! tinental tholeiites "WPB# from mid!ocean ridge or con! tinental!arc basalts "Meschede\ 0875#[ The NbÐZrÐY H[J[ Haaland et al[ : Marine and Petroleum Geolo`y 06 "1999# 090Ð007 004 Fig[ 00[ Correlation diagram of early Tertiary volcanic events in the North Atlantic Igneous Province[ The correlation is based on the data of the authors mentioned in the _gure\ in addition to data of Eldholm et al[ "0878#^ Hitchen and Ritchie "0882# and Ritchie and Hitchen "0885#[ The geomagnetic polarity time scale is that of Cande and Kent "0884#[ The phase 1 tu}s in the Grane Field comprise phase 1b and 1c of Knox "0873#[ diagram separates these di}erent types "Fig[ 01"b##[ By applying the TiÐZr!diagram of Pearce "0871# the above! mentioned basalt provinces plot in the _elds of within! plate basalts MORB "Fig[ 01"c##[ The basalts from the Vo ring Plateau "Vierick et al[\ 0877# are most comparable to N!type MORB\ whereas the Flado dykes from East Greenland "Gill\ Nielsen\ Brooks + Ingram\ 0877# range from WPA:WPB to P! type MORB[ The Lower Basalts in East Greenland\ the Rockall Trough and the Middle Series on Faroes "Gill et al[\ 0877^ Morton et al[\ 0877^ Gariepy et al[\ 0872# all plot in the within!plate basaltic _eld[ It is apparent that the phase 1 data from the Grane Field are compatible with all the samples that plot in the P!type MORB and the WPB _elds " _lled circles in Fig[ 01"b##[ They are time! equivalent\ have a similar geochemistry and hence most probably can be linked to the same source area[ 5[2[0[ Textural and paleogeographic considerations The volcaniclastic fragments in the Sele and Balder Formations are de_ned as Surtseyan!type shards[ Their formation requires eruption in a shallow!marine setting\ thus providing a criterion to be used to limit possible source areas in the NAIP[ Due to the lack of pillow structures in the Lower Basalts of the Rockall Trough\ they are considered to have erupted subaerially "Morton et al[\ 0877^ Upton\ 0877#[ Also the basalts on the Faroes are of subaerial origin "Gariepy et al[\ 0872#[ The basalts of the Vo ring Upper Series have reddened tops due to subaerial erup! tion and weathering "Vierick et al[\ 0877#[ The Lower Basalts in East Greenland\ however\ may have erupted in a submarine setting due to the presence of interbedded hyaloclastites and pyroclastics\ indicating explosive vol! canism in an aqueous environment "Gill et al[\ 0877#[ On the Faroes\ basaltic tu}s are deposited subaerially on top of the Upper Series[ Based on the occurrence of palagonitized sideromelane fragments\ variable ves! icularity and the abundance of small blocky and vitric clasts\ Waagstein and Heilmann!Clausen "0884# inter! preted these basaltic tu}s as having originated from a phreatomagmatic eruption[ On the Vo ring Plateau sec! ondary tu} beds are interlayered in the Upper Series[ These have characteristics of submarine origin and may on this basis\ in addition to their chemical composition\ be correlated with the Balder Formation "Vierick et al[\ 0877#[ The data above indicate an aerially extensive carpet of tu}s of similar origin as the phase 1 tephras of the Grane Field[ Regarding possible source areas\ the basalts having erupted subaerially are unlikely candidates[ That leaves a source near East Greenland as the most plausible\ a connection which is also geochemically consistent[ 5[2[1[ Other suggested volcanics to be equal to phase 1 A temporal correlation "based on biostratigraphy# between the Balder Formation and the coal!bearing tu}! agglomerate zone of the Faroe Islands "between the Lower Series and the Middle Series# has been proposed "Smythe\ Chalmers\ Skuce\ Dobinson + Mould\ 0872#[ This correlation was later regarded as speculative due to the local distribution of the tu}s and their di}erent chemistry and hence dismissed "Waagstein\ 0877#[ Morton and Knox "0889# indicated a relationship 005 H[J[ Haaland et al[ : Marine and Petroleum Geolo`y 06 "1999# 090Ð007 between the only known volcanic centre in the North Atlantic Igneous Province\ the Erlend Volcano "Ridd\ 0872# as a possible source for the Balder Formation tephras[ However\ seismic!re~ection mapping show that the Balder Formation "phase 1b of Knox and Morton "0877## onlaps the volcanic succession of the Erlend Vol! cano and thus postdates these deposits "Hitchen + Ritchie\ 0882#[ 5[3[ Concluding remarks A thorough investigation of the stratigraphic occur! rence\ the texture and geochemistry of tu}aceous layers in the wells 14600!04\ 14:00!05\ 14:00!06 and 14:7!3 on the Grane Field allow the following conclusions to be drawn] The tu} layers consist of two types of deposits\ primary water!lain tu}s and tu} layers redeposited as thin bedded turbidites[ Two types of pyroclastic fragments can be recognized] "0# Surtseyan!type fragments which originated from shal! low submarine explosive eruptions and "1# vitric shards which originated by quenching granulation during suba! queous eruptions[ The tu}s in the Lista and Vale Formations "phase 0# become more fractionated with time\ from basic to acid composition[ The Balder and Sele Formations "phase 1# consist of tu}s of the sub!alkaline group exclusively\ indicating a rather uniform magmatic composition[ The majority of the samples are of a within!plate origin inferred from the TiÐZrÐY and NbÐZrÐY diagrams[ Phase 1 tu}s have a similar geochemistry as the Lower basalts in East Greenland\ the Rockall Trough and the Middle Series on Faroes\ all of which are extruded at an incipient stage of the North Atlantic spreading ridge[ Acknowledgements Fig[ 01[ "a\ b\ c#[ The phase 1 petrographically identi_ed tu}s " _lled circles# compared with various basalt lavas\ pyroclastics and dykes of the North Atlantic Igneous Province plotted in ZrÐYÐTi\ ZrÐYÐNb and ZrÐTi diagrams[ Explanation to diagrams in Fig[ 8[ Explanation to letters in diagram "a#] a# Flado dykes "Gill et al[\ 0877#\ b# Lower Basalts on East Greenland "Gill et al[\ 0877^ Holm 0877#\ c# Vo ring Upper Series "ODP site 531E\ Vierick et al[\ 0877#\ d# Rockall Middle Series "well 052:5!0A\ Morton et al[\ 0877# and e# the Faroe tu} "Waagstein + Heilmann!Clausen\ 0884#[ Explanation to letters in diag! ram "b#] a# Flado dykes "Gill et al[\ 0877#\ b# Lower Basalts on East Greenland "shaded area\ Gill et al[\ 0877#\ c# Lower Basalts on East Greenland "Holm\ 0877#\ d# Vo ring Upper Series "ODP site 531E\ Vierick et al[\ 0877#\ e# Rockall Middle Series "well 052:5!0A\ Morton et al[\ 0877# and f# the Faroe tu} "Waagstein + Heilmann!Clausen\ 0884#[ "c# Basalt dykes\ lavas and tu}s of the North Atlantic Igneous Province plotted in a ZrÐTi diagram[ References to sources are given in the text[ This work represents the main parts of the lead author|s Cand[ Scient[ thesis at the University of Bergen\ Norway[ Prof[ R[ J[ Steel is acknowledged for his e}orts in the initial planning of the study\ and the formal organ! ising with Norsk Hydro for sample collection[ We further thank Dr J[ P[ Nystuen for useful discussions\ and Dr J[ Tveranger for critical comments on an early version of the manuscript[ The thin sections and illustrations were kindly prepared by G[ Torkildsen and J[ Ellingsen\ respectively[ We thank Norsk Hydro for _nancial support\ and for making the cores available for this study[ References Andersen\ S[ A[ "0826#[ De vulkanske Askelag i Vejgennemsk%ringen ved š Ols og deres Udbredelse i Danmark[ Danmarks Geologiske Underso gelse\ R%kke 1\ 48\ 49[ H[J[ Haaland et al[ : Marine and Petroleum Geolo`y 06 "1999# 090Ð007 Bell\ B[ R[\ + Emelius\ C[ H[ "0877#[ Pyroclastic rocks of the British Tertiary Volcanic Province[ In A[ C[ Morton\ + L[ M[ Parson\ Early Tertiary Volcanism and the Opening of the NE Atlantic\ Vol[ 28 "pp[ 254Ð268#[ London] Geological Society Special Publication[ Bergh\ S[ G[\ + Sigvaldason\ G[ E[ "0880#[ Pleistocene mass!~ow deposits of basaltic hyaloclastite on a shallow submarine shelf\ South Iceland[ Bulletin of Volcanology\ 42\ 486Ð500[ Bott\ H[ M[ P[ "0877#[ A new look at the causes and consequences of the Icelandic hot!spot[ In A[ C[ Morton\ + L[ M[ Parson\ Early Tertiary Volcanism and the Opening of the NE Atlantic\ Vol[ 28 "pp[ 04Ð12#[ London] Geological Society Special Publication[ Bo ggild\ O[ B[ "0807#[ Den vulkanske Aske i Moleret[ Danmarks Geo! 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