Chabot E45 Class Tour Slides Ron Horn Chief Consulting Engineer Materials Technology Key Topics • Overview of Key BWR Components and their metals and materials • Which materials are used • How are they made and checked • What are the possible problems • What different engineering disciplines are needed to select, manufacture and fabricate power plant components • What key topics in E45 apply 2 Ron Horn: Chabot College Feb. 13, 2012 • Considerations for Selection Strength at Temperature General Corrosion Resistance Cost Stress Corrosion Resistance Experience base/laboratory data in operating (BWR) environments Recognized standards used in Codes (ASTM, ASME, JIS, DIN) Radiation resistance Other mechanical and physical properties • Weldability, Modulus, Coefficient of thermal expansion, • Fatigue resistance, toughness • Effects of irradiation 3 Ron Horn: Chabot College Feb. 13, 2012 Overview of BWR HEAD COOLING SPRAY NOZZLE SPARE TOP HEAD NOZZLE RPV TOP HEAD DRYER HOLD DOWN BRACKET RPV CLOSURE FLANGE STUD, NUT AND WASHER GUIDE ROD/BRACKET RPV FLANGE AND LEAK DETECTION NOZZLE STEAM DRYER MAIN STEAM NOZZLE INSTRUMENTATION NOZZLE INSTRUMENTATION NOZZLE STEAM SEPARATOR SHELL WELDS INSTRUMENTATION NOZZLE FEEDWATER SPARGER CORE SPRAY FEEDWATER NOZZLE CORE SPRAY NOZZLE CRD NOZZLE RHR/LPCI NOZZLE TOP GUIDE RPV HORIZONTAL AND VERTICAL SHELL WELDS LPCI COUPLING INSTALLATION WELDS TOP GUIDE GRID INSTRUMENTATION NOZZLE SHROUD SURVEILLANCE SPECIMEN CONTROL ROD CORE PLATE JET PUMP ASSEMBLY RECIRCULATION INLET NOZZLE RECIRCULATION OUTLET NOZZLE JET PUMP INSTRUMENTATION NOZZLE CONTROL ROD GUIDE TUBE AND FUEL SUPPORT CASTING BOTTOM HEAD WELDS SHROUD SUPPORT ACCESS HOLE INCORE HOUSING SLC PIPE RPV HOLD DOWN BOLT INCORE HOUSING TO BOTTOM HEAD DRAIN NOZZLE CRD HOUSING CRD HOUSING TO BOTTOM HEAD 4 Ron Horn: Chabot College Feb. 13, 2012 Reactor Materials Usage SS OVERLAY RPV SHELL COURSE LOW ALLOY STEEL SA-533 GrB CL 1 RPV WALL CLADDING - ER 308L/309L INLAY - ALLOY 182 NOZZLE TO VESSEL WELD SAW-LOW ALLOY WELD WIRE BRACKET - 304 SS NOZZLE TO VESSEL WELD WELD - ALLOY 182 INCONEL BUTTER SAFE END TO NOZZLE WELD SA-508 CL 2 PAD INCONEL BUTTER SA-508 CL 1 SA 376 TYPE 304 Recirculation Inlet Nozzle RPV Attachment Bracket 5 Ron Horn: Chabot College Feb. 13, 2012 Metal Alloys Used in BWRs •Stainless Steel (Type 304L): •18 Cr-8 Ni and low Carbon •Yield strength 30-40 ksi (lots of ductility) – Solid solution strengthening •Low alloy steel: cheaper • Small amounts of Cr, Ni, Mn • Yield strength ~ 50 ksi and UTS of 80 ksi) – Requires heat treatment to achieve strength • Weld Metals – Compatible with the “wrought” material – Similar composition 6 Ron Horn: Chabot College Feb. 13, 2012 Alloy Strengthening •Type 304 SS – yield strength 30-40 ksi – Solid solution strengthening •XM-19 – yield strength ~ 50 ksi – Interstitial and solid solution •Low alloy steel – yield strength ~ 50 ksi – (Ultimate tensile strength ~80 ksi) – Heat treatment 7 Ron Horn: Chabot College Feb. 13, 2012 Processing-Composition-Properties Why it isn’t enough to specify a material type Three “levers” to pull to tailor materials, but they don’t act independently Processing Composition Properties Transformation Strengthening Stress-strain Curve Untempered Martensite 400 350 Stress, ksi 300 Pearlite 250 200 150 100 50 0 0 Tempered Martensite 10 20 30 40 50 Elongation, % 9 Ron Horn: Chabot College Feb. 13, 2012 Steel Manufacturing Process Hydrostatic test and Final NDE 10 Ron Horn: Chabot College Feb. 13, 2012 Steel Forgings for Pressure Vessels 11 Ron Horn: Chabot College Feb. 13, 2012 Examples: ABWR Steel Forgings 12 Ron Horn: Chabot College Feb. 13, 2012 Welding Processes F W H S ( P v W I L Submerged Arc Welding FineLineTM Welding 13 Ron Horn: Chabot College Feb. 13, 2012 Possible Materials Degradation in BWRs •Fatigue: due to stresses and strains from startup and shutdown • Also, flowing coolant or steam within reactor system can lead to many loading cycles • >1E11 cycles over the life of a plant (40-60 years) • Stress corrosion cracking: material in contact with the coolant • Regions near welds are possible locations •Many welds in a plant: the vessel and internal structures are very large •Aging and changes in the materials with operation •Temperature is 288oC (550oF) 14 Ron Horn: Chabot College Feb. 13, 2012 Example: Stress Corrosion Cracking “Three Circles” represent required conditions for SCC 15 Ron Horn: Chabot College Feb. 13, 2012 Stress Corrosion Cracking: Material Susceptibility Sensitization in Stainless Steel Cold Work in Stainless Steel Pipe Weld Susceptibility Cr depletion in grain boundaries (C level >0.03%) 16 Ron Horn: Chabot College Feb. 13, 2012 Examples: Material Degradation Beltline Shroud Cracking Ex. Cold Work Induced Cracking Ex. Stress Corrosion Cracking 17 Ron Horn: Chabot College Feb. 13, 2012 Different Engineering Skills • Materials Engineer • Designer (Mechanical Engineer) • Welding Engineer • Non-Destructive Testing Engineer • Testing and Quality Engineer • Materials Researcher • Chemical Engineer 18 Ron Horn: Chabot College Feb. 13, 2012 Related E45 Topics Phase diagrams • iron-carbon phase diagram – iron-carbon alloy microstructure development; alloying elements and phases Solid phase transformations • phase transformation kinetics: nucleation and growth • multiphase transformation • isothermal /continuous cooling phase transformation diagrams • Mechanical behavior of alloys – strength vs. microstructure – Testing for YS and UTS, fracture mechanics Applications and processing of metal alloys • ferrous and nonferrous alloys, stainless steels • forming and casting, post process heat treatment, precipitation hardening Ceramics: Applications and processing of ceramics 19 Ron Horn: Chabot College Feb. 13, 2012 Questions? 20 Ron Horn: Chabot College Feb. 13, 2012