Earth and Planetary Science Letters 401 (2014) 381–383 Contents lists available at ScienceDirect Earth and Planetary Science Letters www.elsevier.com/locate/epsl Debating the petrogenesis of Proterozoic anorthosites – Reply to comments by Vander Auwera et al. on “Pyroxene megacrysts in Proterozoic anorthosites: Implications for tectonic setting, magma source and magmatic processes at the Moho” G.M. Bybee a,b,∗ , L.D. Ashwal a , S.B. Shirey b , M. Horan b , T. Mock b , T.B. Andersen c a b c School of Geosciences, University of the Witwatersrand, Private Bag 3, Wits, 2050, South Africa Department of Terrestrial Magnetism, Carnegie Institute for Science, 5142 Broad Branch Road NW, Washington, D.C., 20015, USA Center of Earth Evolution and Dynamics (CEED), University of Oslo, P.O. Box 1047, Blindern, 0316, Oslo, Norway a r t i c l e i n f o Article history: Received 2 May 2014 Accepted 4 June 2014 Editor: T.M. Harrison We welcome the opportunity for discussion on the petrogenesis of Proterozoic anorthosites stimulated by a recent comment by Vander Auwera et al. (2014). In their comment Vander Auwera et al. accept our new geochronologic and isotopic data on comagmatic, high-aluminum orthopyroxene megacrysts (HAOMs) and anorthosites (Bybee et al., 2014), but provide an alternate interpretation of the data, in line with their model of magma genesis through melting of a mafic lower crust. In short, they suggest that the similarity of the ages of the HAOMs and a potential lower crustal source for the Rogaland Anorthosite Province (RAP) is evidence that the HAOMs crystallized at 1.05 Ga at the base of a thickened crust from the parent magma of the gabbronoritic Feda suite. They suggest that this hypothesis is supported by overlapping Nd and Pb isotopic compositions of the HAOMs and Feda suite. Vander Auwera et al.’s argument centers on their suggestion that the HAOMs, observed in most Proterozoic anorthosites, are restitic source material entrained in the melts from their proposed gabbronoritic source. This model relies on a two-stage petrogenesis, wherein an underplating event forms lower crustal gabbronoritic cumulates, followed approximately 100 million years later by a lower crustal melting event that entrains HAOMs and then crystallizes vast amounts of plagioclase to form Proterozoic anorthosites. We strongly disagree with this interpretation of our geochronologic DOI of original article: http://dx.doi.org/10.1016/j.epsl.2013.12.015. DOI of comment: http://dx.doi.org/10.1016/j.epsl.2014.06.031. Corresponding author at: School of Geosciences, University of the Witwatersrand, Private Bag 3, Wits, 2050, South Africa. Tel.: +27 11 717 6633. E-mail address: grant.bybee@wits.ac.za (G.M. Bybee). * http://dx.doi.org/10.1016/j.epsl.2014.06.032 0012-821X/© 2014 Elsevier B.V. All rights reserved. and geochemical data for the reasons that are outlined in this reply. The alternative that we proposed in Bybee et al. (2014) is that comagmatic HAOMs crystallize from a depleted, mantle-derived magma, which ponded at the Moho, allowing sufficient time for accumulation of plagioclase. Crucial HAOM geochronology (combined with published anorthosite geochronology) indicates that megacryst crystallization, lower crustal assimilation, polybaric ascent of plagioclase mushes through the crust and final emplacement at 5–10 km depths took between 100–130 million years, thereby restricting the tectonic setting to long-lived environments such as continental arcs (Bybee et al., 2014). In the subsequent discussion we (1) establish points of agreement, and (2) evaluate criteria that would support one or the other hypothesis, including textural evidence preserved in the HOAMs, geochemical relationship of the high-Al HOAMs to other HOAMs, and the temperatures, time frames and heat sources required by each model. In some general principles, the two interpretations of these anorthosite suites are not very different: both call on processes at the Moho, both call on a convergent margin setting, both agree that the HAOMs crystallized from magmas significantly older than the anorthosites, both propose that the anorthosites rose diapirically at a much later stage than the crystallization of the HOAMs, and both models operate in concert with extensive lower crust melting. The chief disagreement centers on the petrogenesis of the HAOMs and its interpretation for the anorthosites. In the Vander Auwera et al. model, the HAOMs are related directly to the Feda suite parental magmas based on isotopic compositions, but then become restites of partial melting to produce high-alumina basaltic parental magmas of the anorthosites some 120 Ma later. The issue 382 G.M. Bybee et al. / Earth and Planetary Science Letters 401 (2014) 381–383 Fig. 1. a. Al2 O3 vs. calculated pressure (using the Al-in-orthopyroxene geobarometer) in suites of samples from the Rogaland Anorthosite Province, the Mealy Mountains Intrusive Suite and the Nain Plutonic Suite. b. Mg# vs. calculated pressure (kbar) in the Rogaland Anorthosite Province (Norway). c. Al2 O3 content and Eu anomaly illustrating that megacrysts formed at the same pressure (similar Al content) have variable Eu/Eu∗ . reduces to whether these HAOMs represent preserved fragments of a lower crustal source or are comagmatic cumulates. A problematic aspect of the Vander Auwera et al. model is how the HAOMs, with their relatively evolved compositions could be restites and especially how the HAOMs could retain such pristine, older ages if they were. Furthermore, the Vander Auwera et al. model does not take into account a source for the heat for these processes and the importance of mass transfer across the Moho – two important contributions of the Bybee et al. model. A significant aspect of Vander Auwera et al.’s argument against mantle-derived models is the observation that the HAOMs have similar isotopic compositions to calc-alkaline magmas, manifest at surface as the mafic Feda Suite (Vander Auwera et al., 2011) and hypothetical lower crustal gabbronoritic equivalents. Although they use this similarity in isotopic composition to propose that the megacrysts are fragments of a lower crustal cumulate (complementary to the Feda Suite), these same observations could support our model in which the megacrysts crystallized from a mantle derived, calc-alkaline magma formed in a subduction zone setting at approximately the age we determined for HAOM crystallization (1.041 Ga). Vander Auwera et al.’s argument hinges on a suggestion that HAOMs might represent restitic minerals of a lower crustal source. One would predict, that these phases would display textures indicative of a melt-depleting event. To the best of our knowledge, no descriptions or discussions dealing with HAOMs in Proterozoic anorthosites (Dymek and Gromet, 1984; Emslie, 1975; Morse, 1975; Wiebe, 1986; Xue and Morse, 1994) have documented any textural evidence for these minerals (and/or their surrounding pegmatitic plagioclase) being restitic phases and displaying typical textural features of restites (as documented, for example, by Vernon, 2004). All the aforementioned researchers reach the same conclusion – all evidence is consistent with the megacrysts crystallizing from magmas that were parental to the anorthosites. In contrast to Vander Auwera et al.’s restitic model, we provide geochemical evidence, supporting several previous studies (Charlier et al., 2010; Emslie, 1975; Fram and Longhi, 1992), showing that the all HAOMs are comagmatic with Proterozoic anorthosites and therefore part of polybaric fractionation series. Well-constrained Al-in-orthopyroxene geobarometry for HAOMs from Proterozoic anorthosites indicates that Al2 O3 content is a reliable predictor of crystallization pressure of these HAOMs (Fig. 1a). HAOMs crystallized at the highest pressure are the most primitive members of each suite (as indicated by their higher Mg#) and as crystallization pressure decreases, the HAOMs become more G.M. Bybee et al. / Earth and Planetary Science Letters 401 (2014) 381–383 evolved (Fig. 1b). An argument could be made that this covariation in Al2 O3 (vis. crystallization pressure) and MgO is indicative of differentiation of source cumulates in a lower crustal chamber. However, HAOMs with Al content greater than >8 wt% (i.e. those that would have crystallized at approximately the same pressure), show significant variation in Eu anomaly, with Eu/Eu∗ < 1 to > 1 (Fig. 1c), indicating that plagioclase joined the crystallizing assemblage during crystallization of these megacrysts. These variations in Eu anomaly, at constant Al concentration, would not be plausible if the HAOM suite was simply a differentiated lower crustal cumulate, not comagmatic with the anorthosites. This evidence strengthens our assertions that HAOMs are comagmatic with the Proterozoic anorthosites and crystallized from a magma ponded at the Moho, undergoing fractional crystallization, and in which plagioclase joins the crystallizing assemblage after some HAOM crystallization has occurred. In particular, very clear geochemical trends and correlations in major and trace element geochemistry between higher and lower pressure high-Al megacrysts in the RAP (Charlier et al., 2010), in combination with geochemical modeling, show that the highalumina megacrysts are comagmatic and form part of a polybaric fractionation sequence (Charlier et al., 2010). This result directly supports our arguments. One of the most problematic aspects of the lower crustal source hypothesis are the thermal and geodynamic problems involved in extensive melting of a gabbronoritic lower crust to yield highvolume, broadly basaltic magmas that could be parental to the anorthosites. To contend with this, the commentators speculate that lowermost crustal temperatures of 1390 ◦ C might be achieved if a “conservative” geothermal gradient of 20 ◦ C/km can be linearly extrapolated downward from the conditions of 1000 ◦ C at 0.75 GPa (∼20–25 km) recorded in 1.01 Ga sapphirine granulites that outcrop near the Rogaland anorthosites (Drüppel et al., 2013). However, crustal geotherms are characteristically parabolic in shape, and steepen dramatically as they approach the adiabatic gradients in the sub-lithospheric mantle. Therefore, lowermost crustal temperatures should rarely exceed ∼1050 ◦ C, even if conditions sufficient to produce sapphirine granulites are achieved at shallower depths. Timing is also an issue in this model, as the required high temperatures are constrained at 1.01 Ga, after which the terrane must decompress isothermally. However, in the Vander Auwera et al. model, melting to form parent magmas of anorthosite occurs at approximately 930 Ma, after the terrane has isothermally decompressed to 0.5 GPa. It may not be appropriate to extrapolate geothermal conditions at 1.01 Ga to lower crustal depths, as melting, in their model, occurs at a later time (as well as after terrane decompression). An ancillary, but important question, for the lower crustal model is the lack of an adequate energy source to melt large volumes of the lower crust in order to generate the required voluminous magmas which ultimately crystallize Proterozoic anorthosite massifs. The on- and off-shore surface area of the Rogaland Anorthosite Province is ∼3500 km2 (Sigmond, 1992; Norges Geologiske Undersøkelse website, 2014), and assuming a conservative thickness of 4 km, this massif would have a volume of 6712 km3 . Given the notion that parental magmas of Proterozoic anorthosites were broadly basaltic (Ashwal, 1993; Morse, 1982), approximately 40–50% of the mafic phases are missing. Consequently, one can infer that a complete melt would consist of ∼28 000 km3 of liquid. Assuming 40% partial melting, the total volume of lower crust involved would be 70 000 km3 . To melt this significant volume of crust, heat must be imported. The only reasonable mechanism to induce the required volume of melting would be upwelling mantle. If this were the case, we would expect to see equally, if not more voluminous, coeval mafic melts (formed by decompression melting 383 of the upwelling mantle) together with the anorthosites – a feature which is simply not observed around Proterozoic anorthosite massifs. The volume of melting required is a conservative estimate given that the largest massifs have a surface area of ∼18 000 km3 and should be formed by the same processes (Ashwal, 2010). Furthermore, if the source material is not a cotectic composition, the supporters of the lower crustal model would require near total melting of a significant volume of the mafic lower crust to produce a broadly basaltic melt capable of forming anorthosites. In any case, we conclude that extensive, dry, lower crustal melting of mafic protoliths is unlikely to account for the generation of the magmas parental to massif-type anorthosite, either in Norway or elsewhere on Earth. Acknowledgement We thank Vander Auwera et al. for their interest in our new data on Proterozoic anorthosites and the debate that their commentary has stimulated. Editorial Acknowledgement The Editor thanks the reviewer, Carol Frost, for her thoughtful and balanced reviews of both Commentary and Reply. References Ashwal, L., 1993. Anorthosites. Springer-Verlag. Ashwal, L.D., 2010. The temporality of anorthosites. Can. Mineral. 48, 711–728. Bybee, G.M., Ashwal, L.D., Shirey, S.B., Horan, M., 2014. Pyroxene megacrysts in Proterozoic anorthosites: implications for tectonic setting, magma source and magmatic processes at the Moho. Earth Planet. Sci. Lett. 389, 74–85. Charlier, B., Duchesne, J.C., Vander Auwera, J., Storme, J.Y., Maquil, R., Longhi, J., 2010. Polybaric fractional crystallization of high-alumina basalt parental magmas in the Egersund-Ogna massif-type Anorthosite (Rogaland, SW Norway) constrained by plagioclase and high-alumina orthopyroxene megacrysts. J. Petrol. 51, 2515–2546. Drüppel, K., Elsäber, L., Brandt, S., Gerdes, A., 2013. Sveconorwegian mid-crustal ultrahigh-temperature metamorphism in Rogaland, Norway: U–Pb LA-ICP-MS geochronology and pseudosections of Sapphirine granulites and associated paragneisses. J. Petrol. 54, 305–350. Dymek, R., Gromet, L., 1984. Nature and origin of orthopyroxene megacrysts from the St-Urbain anorthosite massif, Quebec. Can. Mineral. 22, 297–326. Emslie, R.F., 1975. Pyroxene megacrysts from anorthositic rocks: new clues to the sources and evolution of the parent magmas. Can. Mineral. 13, 138–145. Fram, M., Longhi, J., 1992. Phase-equilibria of dikes associated with Proterozoic Anorthosite complexes. Am. Mineral. 77, 605–616. Morse, S., 1975. Plagioclase Lamellae in Hypersthene, Tikkoatokhakh Bay, Labrador. Earth Planet. Sci. Lett. 26, 331–336. Morse, S.A., 1982. A partisan review of Proterozoic anorthosites. Am. Mineral. 67, 1087–1100. Geologiske Undersøkelse, 2014. www.ngu.no/mineralforekomster/ Norges bjerkreim-sokndal/English/the_rogaland_anorthosite_province.php. Date accessed – 1 July 2014. Sigmond, E.M.O., 1992. Berggrunnskart, Norge med havområder – Målestokk 1:3 millioner (Bedrock map, Norway with Marine Areas – Scale 1:3 Million). Norges Geologiske Undersøkelse. Vander Auwera, J., Bolle, O., Bingen, B., Liégeois, J.P., Bogaerts, M., Duchesne, J.C., De Waele, B., Longhi, J., 2011. Sveconorwegian massif-type anorthosites and related granitoids result from post-collisional melting of a continental arc root. Earth-Sci. Rev. 107, 375–397. Vander Auwera, J., Charlier, B., Duchesne, J.C., Bingen, B., Longhi, J., Bolle, O., 2014. Comment on Bybee et al. (2014): Pyroxene megacrysts in Proterozoic anorthosites: implications for tectonic setting, magma source and magmatic processes at the Moho. Earth Planet. Sci. Lett. 401, 378–380. http://dx.doi.org/10.1016/j.epsl.2014.06.031. Vernon, R.H., 2004. A Practical Guide to Rock Microstructure. Cambridge University Press. Wiebe, R.A., 1986. Lower crustal cumulate nodules in Proterozoic dikes of the Nain Complex: evidence for the origin of Proterozoic anorthosites. J. Petrol. 27, 1253–1275. Xue, S., Morse, S., 1994. Chemical characteristics of Plagioclase and Pyroxene Megacrysts and their significance to the Petrogenesis of the Nain Anorthosites. Geochim. Cosmochim. Acta 58, 4317–4331.