Sample DRS_3_9_4 DRS_3_9_4 DRS_3_9_4 DRS_3_9_4 DRS_3_9_4 DRS_3_9_4 Analysis # 1 4 5 6 8 9 Trace element concentrations (Pg/g) Li 23.4 10.5 29.0 25.2 18.9 19.3 Si 275927 275148 278957 266350 258608 284604 Ca 60717 61693 56856 72271 80894 49399 Ti 78 239 97 165 127 53 V 0.8 1.0 0.4 Rb 1.2 1.1 1.2 1.1 1.2 Sr 1051 529 925 906 1069 851 Sr 1081 535 958 937 1104 878 Y 0.3 Zr Nb Cs Ba 78 172 112 56 45 122 La 2.3 4.4 2.4 1.3 1.6 4.3 Ce 4.0 8.7 3.5 2.7 2.8 7.1 Pr 0.4 0.8 0.3 0.2 0.3 0.7 Nd 0.9 2.6 0.7 0.7 0.7 1.6 Sm Eu 0.7 1.3 0.8 0.5 0.5 1.2 Pb 2.8 4.8 2.7 1.7 1.4 5.6 Th U Table C3: Continued 391 Sample DRS_3_9_4 DRS_3_9_4 DRS_3_9_4 DRS_3_9_4 DRS_3_9_4 DRS_3_9_4 DRS_3_9_4 Analysis # 10 11 12 13 16 19 21 Trace element concentrations (Pg/g) Li 26.7 28.0 24.2 26.4 20.3 17.2 22.6 Si 276647 284348 264573 283353 265713 275973 271513 Ca 59808 49745 74307 51081 73005 60659 66165 Ti 91 64 112 186 101 181 214 V 0.8 0.9 Rb 1.3 52.1 1.0 6.2 Sr 931 796 996 585 1130 822 734 Sr 965 822 1029 600 1160 853 760 Y 0.2 0.2 0.9 0.3 0.4 Zr 12.5 5.7 Nb 0.5 0.3 Cs Ba 118 121 44 135 66 130 86 La 4.3 4.3 1.3 4.6 2.0 2.9 2.1 Ce 7.3 6.8 2.2 8.2 3.3 4.6 3.8 Pr 0.7 0.5 0.2 0.7 0.3 0.4 0.4 Nd 2.0 1.7 0.9 2.4 1.0 1.3 1.3 Sm 0.2 0.3 Eu 1.0 1.0 0.5 1.0 0.5 0.9 0.6 Pb 3.5 4.7 2.6 5.9 2.0 2.7 2.6 Th 0.3 0.2 U 0.2 0.1 Table C3: Continued 392 Sample DRS_3_9_4 DRS_3_9_4 DRS_3_9_4 DRS_3_9_4 DRS_3_9_4 DRS_3_9_4 DRS_3_9_4 Analysis # 22 24 27 31 32 33 34 Trace element concentrations (Pg/g) Li 28.0 26.1 16.2 24.1 20.9 25.1 18.0 Si 278046 280238 267135 280211 280863 271158 271078 Ca 58028 55195 71362 55231 54377 66594 66690 Ti 77 56 131 182 116 105 107 V 0.6 Rb 1.5 1.1 1.2 1.1 Sr 987 1015 937 780 826 1085 991 Sr 1015 1064 967 805 854 1127 1019 Y 0.3 0.3 Zr 0.7 Nb Cs Ba 79 111 59 135 120 67 51 La 2.6 4.0 1.6 3.1 3.3 1.9 1.6 Ce 4.5 6.3 2.9 5.3 5.4 3.2 3.1 Pr 0.4 0.5 0.3 0.5 0.4 0.3 0.3 Nd 1.4 1.5 0.8 1.5 1.4 0.9 1.0 Sm Eu 0.7 0.9 0.6 1.0 0.8 0.6 0.5 Pb 3.3 3.9 2.2 2.6 3.1 2.0 1.6 Th U Table C3: Continued 393 Sample SH303-1g SH303-1g SH303-1g SH303-1g SH303-1g SH303-1g SH303-1g SH303-1g Analysis # 2 4 5 6 7 8 10 11 Trace element concentrations (Pg/g) Li 18.5 22.8 23.4 20.2 17.3 22.8 22.9 24.0 Si 257524 233958 236560 233282 208572 236717 239183 233110 Ca 82050 104071 101933 104615 121138 101801 99703 104753 Ti 198 527 530 629 224 669 566 730 V 2.0 2.4 1.9 3.7 1.0 5.4 3.6 6.5 Rb 4.5 2.6 Sr 1307 1249 1211 1231 1370 1265 1238 1205 Sr 1368 1297 1256 1305 1427 1345 1302 1244 Y 0.9 Zr 5.5 4.0 6.4 Nb 0.6 Cs 1.8 Ba 209 126 132 120 63 144 147 123 La 6.8 3.4 3.2 3.0 2.1 2.9 2.9 2.8 Ce 9.4 5.0 4.9 5.0 3.1 5.5 6.5 5.8 Pr 0.9 0.7 0.8 0.3 0.8 0.7 0.5 Nd 2.9 1.5 1.8 0.9 1.0 2.1 2.9 2.0 Sm Eu 1.6 0.9 0.8 1.2 1.1 0.9 Pb 3.8 2.3 1.5 1.2 0.9 1.5 2.6 1.9 Th U Table C3: Continued 394 Sample SH303-1g SH303-1g SH303-1g SH303-1g SH303-1g SH303-1g SH303-1g SH303-1g Analysis # 18 19 20 21 22 23 24 25 Trace element concentrations (Pg/g) Li 23.1 20.6 19.2 16.9 11.9 23.3 22.3 20.1 Si 232378 237847 234482 236539 232877 235162 237599 235882 Ca 105336 100847 103647 101950 104939 103091 101058 102497 Ti 174 595 544 623 632 530 544 651 V 1.3 3.3 2.2 5.9 4.0 2.3 1.9 7.7 Rb 4.4 3.0 3.3 3.0 Sr 4024 1287 1255 1311 1218 1326 1235 1345 Sr 6742 1341 1292 1358 1279 1392 1302 1408 Y 0.9 0.8 Zr 3.3 4.8 Nb 0.4 Cs 2.4 1.9 1.7 1.5 Ba 174 154 121 160 129 150 138 153 La 5.9 4.0 2.3 3.7 3.4 3.0 2.8 3.9 Ce 11.1 6.4 4.8 5.4 6.3 5.8 6.1 6.1 Pr 1.0 0.7 0.6 0.7 0.6 0.7 0.6 0.7 Nd 3.8 1.8 1.3 2.6 1.9 1.9 2.0 Sm Eu 0.8 1.4 1.4 1.3 0.9 1.2 1.3 1.3 Pb 1.4 2.0 1.7 2.8 1.2 1.7 1.7 2.3 Th U Table C3: Continued 395 Table C3: Continued Sample SH303-1g SH303-1g SH303-1g SH303-1g SH303-1g SH303-1g SH303-1g Analysis # 26 27 28 30 32 33 34 Trace element concentrations (Pg/g) Li 23.3 21.5 19.1 16.8 17.1 22.6 25.1 Si 238416 238155 236905 235381 203691 233535 235677 Ca 100362 100585 101643 102911 123628 104413 102667 Ti 572 547 553 536 203 593 516 V 1.7 2.1 1.7 2.0 3.6 1.4 Rb 2.3 2.7 2.8 2.4 Sr 1376 1230 1310 1297 1420 1353 1269 Sr 1435 1290 1373 1373 1482 1395 1317 Y 1.1 Zr Nb Cs 1.9 2.3 1.8 Ba 166 143 161 138 50 143 148 La 3.7 3.4 3.3 3.6 2.0 3.7 3.8 Ce 6.7 5.5 6.0 5.6 3.5 5.5 6.1 Pr 0.6 0.7 0.8 0.6 0.5 0.6 0.7 Nd 2.2 2.3 2.4 2.0 1.5 2.0 1.6 Sm Eu 1.2 1.2 1.2 0.8 0.5 1.1 1.6 Pb 1.9 1.7 1.8 2.1 0.6 1.4 2.2 Th U 396 Table C3: Continued Sample SH307-1g SH307-1g SH307-1g SH307-1g SH307-1g SH307-1g SH307-1g SH307-1g Analysis # 1 2 5 6 7 8 9 12 Trace element concentrations (Pg/g) Li 33.3 29.7 21.8 24.4 27.9 22.6 28.1 15.1 Si 234004 261859 265878 268459 246658 245772 233877 228314 Ca 104034 77352 72816 69812 92944 93775 104137 108463 Ti 219 129 317 317 119 387 183 288 V 1.0 1.2 2.0 0.8 2.6 Rb 4.0 2.6 7.6 19.4 3.3 2.6 8.0 Sr 669 1131 848 896 1277 1103 1243 1500 Sr 690 1159 905 939 1349 1193 1339 1599 Y 1.2 1.3 Zr 6.7 11.3 4.6 Nb 1.0 Cs 1.4 2.7 Ba 133 174 323 255 91 157 59 98 La 7.2 6.2 8.0 6.7 3.9 4.6 2.1 2.8 Ce 9.1 7.9 12.0 11.9 5.5 6.6 2.9 4.2 Pr 1.1 0.9 1.2 2.0 0.7 0.4 0.3 0.5 Nd 4.6 2.5 4.0 3.6 1.9 2.3 1.4 Sm Eu 1.1 1.7 2.2 1.1 1.4 1.9 1.2 Pb 3.1 4.3 6.1 6.7 2.8 2.5 1.9 2.4 Th U 397 Table C3: Continued Sample SH307-1g SH307-1g SH307-1g SH307-1g SH307-1g SH307-1g SH307-1g SH307-1g Analysis # 19 21 22 23 24 26 27 31 Trace element concentrations (Pg/g) Li 23.6 29.9 19.8 21.8 22.9 14.1 22.0 22.7 Si 269610 254096 238555 242625 254061 217905 228489 263074 Ca 68449 85624 100243 96664 85659 115666 108332 75999 Ti 173 106 151 128 310 168 189 257 V 1.5 Rb 4.9 3.0 13.1 13.8 Sr 805 1406 1272 1459 1219 1286 1271 931 Sr 846 1490 1385 1577 1335 1364 1342 978 Y 1.2 1.1 Zr 2.5 8.9 5.3 Nb 0.5 0.4 Cs 1.5 2.4 1.8 2.3 Ba 327 174 68 109 225 70 95 276 La 6.9 6.7 2.1 4.5 5.3 3.0 2.6 6.3 Ce 11.0 8.1 3.4 6.0 8.2 4.4 4.3 9.6 Pr 0.7 0.9 0.6 1.0 0.7 1.0 Nd 3.0 2.2 1.0 1.7 3.0 2.0 3.2 Sm Eu 1.5 1.6 0.8 0.8 1.8 1.6 2.2 Pb 6.4 4.0 2.4 3.3 4.9 1.8 2.2 5.2 Th U 398 Table C3: Continued Sample SH307-1g SH307-1g SH307-1g SH307-1g SH307-1g JP1020-fine JP1020-fine Analysis # 32 34 35 36 37 1 3 Trace element concentrations (Pg/g) Li 22.1 22.6 31.6 24.4 25.9 17.4 17.4 Si 236771 243549 232625 228753 253147 Ca 101756 95827 105140 108134 86590 212382 176295 Ti 185 151 160 144 232 66 91 V 1.5 1.0 0.1 0.2 Rb 3.0 2.6 2.9 0.2 0.0 Sr 1438 1518 1269 1254 1055 Sr 1545 1621 1361 1381 1126 1224 1062 Y 0.1 0.2 Zr Nb 0.5 Cs Ba 131 121 61 55 206 47 106 La 3.4 3.1 2.6 2.5 4.8 2.1 3.3 Ce 4.7 5.4 4.4 3.7 6.5 3.3 5.0 Pr 0.7 0.5 0.5 0.6 0.3 0.5 Nd 2.4 1.7 2.5 1.0 1.5 Sm 0.2 0.2 Eu 1.0 1.3 1.1 Pb 2.3 2.9 1.6 1.6 3.7 1.7 2.4 Th U 399 Table C3: Continued Sample JP1020-fine JP1020-fine JP1020-fine JP1020-fine JP1020-fine JP1020-fine JP1020-fine Analysis # 4 5 7 8 11 12 13 Trace element concentrations (Pg/g) Li 18.7 20.1 24.1 21.7 17.4 36.2 36.4 Si Ca 222959 193358 170130 178630 165926 107402 161275 Ti 92 78 166 236 32 39 72 V 0.3 0.2 0.7 1.9 0.1 0.3 0.4 Rb 0.3 0.3 0.4 0.5 0.4 1.8 0.5 Sr Sr 1196 1216 1062 981 1149 881 1256 Y 0.1 0.1 0.2 0.3 0.2 0.1 0.2 Zr 0.1 0.4 0.3 0.2 0.7 Nb 0.0 0.0 Cs Ba 38 88 132 126 57 178 60 La 1.7 3.2 3.2 2.8 2.7 5.4 2.0 Ce 2.7 5.0 5.0 4.9 4.7 7.8 3.9 Pr 0.3 0.4 0.5 0.5 0.5 0.6 0.4 Nd 1.0 1.5 1.5 1.5 1.6 1.9 1.2 Sm 0.1 0.2 0.2 0.2 0.2 0.1 0.2 Eu Pb 1.2 2.6 2.7 2.2 3.5 6.0 2.5 Th U 400 Table C3: Continued Sample JP1020-fine JP10/20-1fine JP10/20-1fine JP10/20-1fine JP10/20-1fine JP10/20-1fine Analysis # 14 1 2 3 4 5 Trace element concentrations (Pg/g) Li 38.5 27.9 37.8 23.8 31.1 22.7 Si 279889 294410 281083 284424 280191 Ca 102786 55649 35639 54089 49643 55257 Ti 33 81 38 61 103 119 V 0.8 Rb 1.1 1.3 Sr 874 676 884 822 729 Sr 833 919 706 914 856 769 Y 0.2 0.3 Zr 0.3 Nb 0.0 Cs Ba 173 47 139 69 126 89 La 5.8 1.8 4.0 2.9 2.7 2.2 Ce 8.9 4.0 7.1 5.2 4.8 4.2 Pr 0.8 0.4 0.6 0.4 0.4 0.4 Nd 2.2 1.5 1.3 1.4 1.2 1.0 Sm 0.1 0.3 0.2 Eu 0.5 1.1 0.7 0.8 0.7 Pb 5.9 2.5 6.2 3.5 3.0 2.5 Th U 401 Table C3: Continued Sample JP10/20-1fine JP10/20-1fine JP10/20-1fine JP10/20-1fine JP10/20-1fine JP10/20-1fine Analysis # 6 7 8 9 10 11 Trace element concentrations (Pg/g) Li 23.7 23.2 22.6 19.7 22.3 27.7 Si 279849 281915 275741 279325 270996 276381 Ca 55702 52994 60951 56381 66788 60145 Ti 108 107 58 70 136 75 V 0.5 Rb 1.3 Sr 830 785 887 874 849 855 Sr 870 820 940 930 890 906 Y 0.2 Zr Nb Cs Ba 86 89 39 55 60 64 La 2.4 2.4 1.3 2.3 1.6 2.5 Ce 4.3 4.3 2.8 3.7 2.9 4.4 Pr 0.4 0.4 0.3 0.2 0.2 0.4 Nd 1.2 1.3 0.9 0.8 0.7 1.2 Sm Eu 0.8 0.7 0.5 0.7 0.5 0.8 Pb 2.6 2.7 2.0 2.6 2.0 2.8 Th U 402 Table C3: Continued Sample JP10/20-1fine JP10/20-1fine Analysis # 12 15 Trace element concentrations (Pg/g) Li 15.5 25.4 Si 284051 284736 Ca 50146 49221 Ti 127 45 V Rb Sr 735 900 Sr 762 948 Y 0.4 Zr Nb Cs Ba 143 107 La 3.3 3.4 Ce 5.8 5.6 Pr 0.5 0.5 Nd 1.5 1.1 Sm Eu 1.0 1.0 Pb 3.0 4.8 Th U 403 404 APPENDIX D SULFUR PEAK SHIFT DATA Tables D1 and D2 report peak positions determined by fitting a gaussian curve to the electron microprobe wavescan data. Peaks are determined using the computer program Igor Pro. Sulfur wavescans made at the University of Oregon were conducted on a Cameca SX 50 microprobe with 3 PET crystals. Results are presented in Table D1. Peak positions are reported in angstroms (Å). Peak positions calculated from wavescans on the SX 100 at Oregon State University are reported in Table D2. Spectrometers 4 and 5 are fitted with PET crystals while spectrometer 3 has a LPET crystal with higher sensitivity. Units are reported in sin T units *105 which can be converted to angstroms following equation 4 in Appendix A. The error reported for calculated peak fits is reported to 1 V. Melt inclusion sample numbers correspond to peak shift analysis numbers. Mineral standards pyrrhotite (po) and troilite (tr) are analyzed before and after every unknown while anhydrite (anhy), barite (bar), and pyrite (py) are typically analyzed one to two times over the course of each analytical session. Appendix D data is available upon request. 405 Table D1: Sulfur KD peak position determined from microprobe analysis (U of O). Sample Pyrrhotite anhydrite pyrite 03-061-3 Pyrrhotite Pyrrhotite 03-058-10 Pyrrhotite 03-058-15 Pyrrhotite 03-063-5 Pyrrhotite anhydrite pyrite anhy.std pyrite.std po.1 03-014b-1 po.2 03-014b-16 po.3 04-036-1 po.4 po.5 04-036-9 po.6 03-041-8 po.7 03-041-9 po.8 03-041-13 po.9 troilite po.10 anhydrite po.11 pyrite po.12 14-3glass po.13 11-49glass po.14 qvscoria po.15 JDF D2 po.16 10-34glass po.17 anhy.std Analysis Date 10/28/2003 10/28/2003 10/28/2003 10/28/2003 10/28/2003 10/28/2003 10/28/2003 10/28/2003 10/28/2003 10/28/2003 10/28/2003 10/28/2003 10/28/2003 10/28/2003 7/2/2004 7/2/2004 7/2/2004 7/2/2004 7/2/2004 7/2/2004 7/2/2004 7/2/2004 7/2/2004 7/2/2004 7/2/2004 7/2/2004 7/2/2004 7/2/2004 7/2/2004 7/2/2004 7/2/2004 7/2/2004 7/2/2004 7/2/2004 7/2/2004 7/2/2004 7/2/2004 7/2/2004 7/2/2004 7/2/2004 7/2/2004 7/2/2004 7/2/2004 7/2/2004 7/2/2004 7/2/2004 7/2/2004 7/2/2004 7/2/2004 spec 4 5.3738 5.3708 5.3735 5.3721 5.3739 5.374 5.3726 5.3741 5.3727 5.3742 5.3725 5.3742 5.3712 5.3738 5.3704 5.3731 5.3736 5.3733 5.3736 5.373 5.3738 5.3717 5.3738 5.3738 5.3711 5.3737 5.3736 5.3738 5.3735 5.3737 5.3728 5.3736 5.3737 5.3736 5.3706 5.3735 5.3733 5.3734 5.3733 5.3733 5.3733 5.3732 5.3711 5.3732 5.3732 5.3732 5.3731 5.3732 5.3702 (+/-) 2.07E-05 2.32E-05 2.45E-05 3.07E-05 2.57E-05 2.26E-05 4.57E-05 2.19E-05 4.86E-05 2.47E-05 5.63E-05 2.27E-05 2.56E-05 2.33E-05 2.29E-05 2.04E-05 2.24E-05 9.83E-05 2.21E-05 6.14E-05 2.05E-05 6.40E-05 2.06E-05 2.21E-05 4.18E-05 2.23E-05 1.27E-04 2.25E-05 1.35E-04 2.23E-05 1.35E-04 2.19E-05 1.89E-05 2.11E-05 1.98E-05 2.13E-05 2.23E-05 2.05E-05 7.13E-05 2.00E-05 1.06E-04 2.18E-05 5.07E-05 2.21E-05 6.09E-05 2.31E-05 8.91E-05 2.08E-05 2.18E-05 Angstroms spec 2 (+/-) 5.374 1.52E-05 5.3704 1.50E-05 5.3731 1.24E-05 5.3717 2.54E-05 5.3736 1.39E-05 5.3736 1.36E-05 5.3722 3.59E-05 5.3737 1.53E-05 5.3724 3.17E-05 5.3738 1.44E-05 5.3723 4.88E-05 5.3739 1.47E-05 5.3709 1.49E-05 5.3735 1.42E-05 5.3709 1.34E-05 5.3736 1.41E-05 5.3741 1.39E-05 5.3741 6.56E-05 5.3742 1.45E-05 5.3736 4.99E-05 5.3744 1.51E-05 5.3724 4.72E-05 5.3745 1.46E-05 5.3745 1.51E-05 5.3718 3.64E-05 5.3745 1.47E-05 5.3746 8.39E-05 5.3746 1.45E-05 5.3743 1.07E-04 5.3744 1.35E-05 5.3737 8.58E-05 5.3741 1.38E-05 5.3741 1.40E-05 5.3739 1.20E-05 5.3709 1.45E-05 5.3737 1.29E-05 5.3736 1.43E-05 5.3737 1.41E-05 5.3734 4.20E-05 5.3734 1.54E-05 5.3734 6.37E-05 5.3732 1.50E-05 5.3711 3.26E-05 5.3732 1.38E-05 5.3732 5.41E-05 5.3732 1.43E-05 5.3732 5.87E-05 5.3732 1.43E-05 5.3702 1.34E-05 spec 3 5.3739 5.3709 5.3736 5.3722 5.3741 5.3741 5.3727 5.3743 5.3729 5.3743 5.3729 5.3744 5.3714 5.374 5.3708 5.3735 5.3739 5.3738 5.374 5.3733 5.374 5.372 5.374 5.374 5.3714 5.374 5.3738 5.3741 5.3737 5.374 5.3731 5.374 5.3741 5.3739 5.371 5.3739 5.3737 5.3739 5.3737 5.3737 5.3738 5.3736 5.3714 5.3737 5.3737 5.3736 5.3737 5.3736 5.3704 (+/-) 1.90E-05 1.90E-05 1.94E-05 2.20E-05 1.95E-05 1.72E-05 3.16E-05 1.87E-05 2.81E-05 1.29E-05 4.65E-05 1.92E-05 2.03E-05 1.93E-05 1.91E-05 1.95E-05 1.93E-05 7.56E-05 1.92E-05 4.95E-05 1.88E-05 5.21E-05 1.80E-05 1.91E-05 3.04E-05 1.92E-05 7.22E-05 1.87E-05 9.19E-05 1.84E-05 7.76E-05 1.96E-05 1.90E-05 1.95E-05 1.91E-05 1.85E-05 1.94E-05 1.89E-05 5.32E-05 1.87E-05 7.98E-05 1.93E-05 3.26E-05 1.89E-05 4.92E-05 1.95E-05 6.73E-05 1.84E-05 2.05E-05 406 Table D1: Continued Sample pyrite.std po.1 py.1 any.1 po.2 03-072-8.1 po.3 03-072-19.1 po.4 03.072-7.1 po.5 po.6 04-028-7.1 po.7 04-028-14.2 po.8 04-050-17.1 po.9 po.10 04-028-17.1 po.11 03-015-26.1 po.12 03-015-47.1 po.13 03-015-77.1 po.14 04-050-20.1 po.15 py.2 any.2 Analysis Date 7/2/2004 12/1/2004 12/1/2004 12/1/2004 12/1/2004 12/1/2004 12/1/2004 12/1/2004 12/1/2004 12/1/2004 12/1/2004 12/1/2004 12/1/2004 12/1/2004 12/1/2004 12/1/2004 12/1/2004 12/1/2004 12/1/2004 12/1/2004 12/1/2004 12/1/2004 12/1/2004 12/1/2004 12/1/2004 12/1/2004 12/1/2004 12/1/2004 12/1/2004 12/1/2004 12/1/2004 spec 4 5.373 5.3744 5.3743 5.3714 5.3746 5.3743 5.3746 5.3746 5.3745 5.3744 5.3745 5.3746 5.3745 5.3747 5.3736 5.3747 5.3725 5.3748 5.3749 5.3733 5.3749 5.3739 5.3749 5.3738 5.3749 5.3734 5.3749 5.3722 5.3749 5.3747 5.3718 (+/-) 2.15E-05 2.04E-05 1.98E-05 2.07E-05 1.89E-05 8.21E-05 2.15E-05 8.48E-05 2.08E-05 1.03E-04 2.02E-05 2.02E-05 7.51E-05 2.20E-05 1.57E-04 2.15E-05 5.08E-05 2.19E-05 2.14E-05 2.02E-04 2.06E-05 9.77E-05 2.10E-05 9.95E-05 2.04E-05 1.06E-04 2.04E-05 3.53E-05 2.17E-05 2.03E-05 2.51E-05 Angstroms spec 2 (+/-) 5.3729 1.40E-05 5.3745 1.57E-05 5.3743 1.50E-05 5.3715 1.24E-05 5.3747 1.46E-05 5.3747 5.76E-05 5.3747 1.52E-05 5.3748 6.32E-05 5.3747 1.37E-05 5.3745 8.08E-05 5.3746 1.53E-05 5.3746 1.41E-05 5.3746 7.08E-05 5.3747 1.30E-05 5.3737 1.06E-04 5.3747 1.58E-05 5.3724 3.06E-05 5.3748 1.43E-05 5.3749 1.45E-05 5.3731 1.93E-04 5.3749 1.41E-05 5.3739 8.83E-05 5.3748 1.42E-05 5.3738 7.61E-05 5.3747 1.56E-05 5.3733 8.19E-05 5.3748 1.47E-05 5.372 2.49E-05 5.3747 1.36E-05 5.3745 1.40E-05 5.3717 1.26E-05 spec 3 5.3734 5.3747 5.3745 5.3717 5.3749 5.3748 5.3749 5.3748 5.3748 5.3747 5.3747 5.3747 5.3748 5.3748 5.3741 5.3749 5.3725 5.375 5.375 5.374 5.3752 5.3743 5.3753 5.3744 5.3752 5.3737 5.3752 5.3726 5.3752 5.375 5.3722 (+/-) 1.91E-05 1.84E-05 1.88E-05 1.87E-05 1.94E-05 5.85E-05 1.85E-05 6.47E-05 1.92E-05 7.87E-05 1.84E-05 1.87E-05 5.64E-05 1.87E-05 1.13E-04 1.82E-05 3.24E-05 1.84E-05 1.83E-05 1.10E-04 1.92E-05 7.28E-05 1.87E-05 7.09E-05 1.99E-05 7.56E-05 1.84E-05 2.85E-05 1.88E-05 1.88E-05 2.14E-05 407 Table D2: Sulfur Ka peak position determined from microprobe analysis (OSU). Sample tr8-30.1 tr-8-30incremental QV-50-30incremental tr-8-30.1 QV-9-30 tr-8-30.2 QV-12-30 tr-8-30.3 QV-15-30 tr-8-30.4 QV-18-30 tr-8-30.5 QV-21-30 tr-8-30.6 QV-30-30 tr-8-30.7 QV-50-30 tr-8-30.8 anhy-9-30 tr-8-30.9 anhy-12-30 tr-8-30.10 anhy-15-30 tr-8-30.11 anhy-18-30 tr-8-30.12 anhy-21-30 tr-8-30.13 anhy-30-30 tr-8-30.14 tr-9-30 tr-8-30.15 tr-12-30 tr-8-30.16 tr-15-30 tr-8-30.17 tr-18-30 tr-8-30.18 tr-21-30 tr-8-30.19 tr-30-30 tr-8-30.20 QV-50-50 tr-8-30.21 anhy-30-50 tr-8-30.22 tr-30-50 tr-8-30.23 tr-8-50 tr-8-30.24 tr-8-30.1 14-3-5-30 tr-8-30.2 Analysis Date 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/26/2005 2/28/2005 2/28/2005 2/28/2005 spec 3 61450 61450 61422 61448 61422 61449 61421 61449 61421 61449 61421 61450 61421 61450 61423 61451 61421 61451 61416 61451 61415 61452 61415 61450 61415 61451 61414 61451 61415 61452 61451 61451 61451 61452 61452 61450 61451 61451 61452 61451 61451 61452 61421 61451 61416 61452 61452 61452 61451 61452 61451 61451 61452 (+/-) 0.325 0.308 0.79 0.32 0.522 0.316 0.518 0.32 0.521 0.326 0.498 0.314 0.516 0.321 0.444 0.315 0.393 0.319 0.328 0.328 0.323 0.326 0.334 0.321 0.312 0.317 0.301 0.328 0.347 0.33 0.312 0.325 0.322 0.317 0.318 0.331 0.321 0.327 0.328 0.33 0.318 0.325 0.4 0.315 0.321 0.329 0.327 0.328 0.321 0.324 0.318 1.06 0.312 SinT spec 4 61459 61459 61430 61456 61428 61457 61428 61457 61429 61457 61429 61459 61430 61458 61428 61459 61429 61459 61424 61459 61423 61459 61423 61458 61423 61459 61423 61459 61423 61460 61460 61459 61460 61460 61460 61458 61460 61459 61460 61459 61459 61460 61428 61459 61424 61460 61460 61460 61459 61460 61461 61460 61462 (+/-) 0.214 0.218 0.788 0.207 0.778 0.215 0.852 0.205 0.7 0.214 0.619 0.187 0.662 0.227 0.539 0.22 0.424 0.203 0.2 0.239 0.175 0.201 0.185 0.217 0.195 0.214 0.191 0.197 0.196 0.216 0.21 0.224 0.201 0.215 0.207 0.217 0.199 0.218 0.207 0.218 0.205 0.209 0.332 0.208 0.2 0.194 0.209 0.222 0.212 0.223 0.215 1.67 0.205 spec 5 61456 61456 61426 61455 61426 61455 61427 61455 61424 61454 61427 61456 61426 61455 61426 61456 61425 61456 61421 61456 61420 61456 61420 61455 61420 61455 61419 61456 61419 61457 61456 61456 61456 61456 61457 61455 61456 61455 61456 61455 61455 61456 61425 61456 61420 61456 61456 61456 61455 61456 61455 61451 61455 (+/-) 0.382 0.384 0.645 0.39 0.792 0.38 0.828 0.377 0.684 0.385 0.67 0.376 0.763 0.373 0.596 0.373 0.455 0.388 0.37 0.376 0.393 0.357 0.369 0.375 0.373 0.383 0.41 0.386 0.415 0.377 0.38 0.375 0.377 0.368 0.389 0.392 0.387 0.377 0.386 0.38 0.38 0.401 0.455 0.378 0.406 0.372 0.386 0.363 0.374 0.367 0.367 1.85 0.37 408 Table D2: Continued. Sample 14-3-9-30 tr-8-30.3 14-3-12-30 tr-8-30.4 14-3-15-30 tr-8-30.5 14-3-18-30 tr-8-30.6 14-3-21-30 tr-8-30.7 14-3-30-30 tr-8-30.8 14-3-50-30 tr-8-30.9 anhy-5-30 tr-8-30.10 tr-5-30 tr-8-30.11 tr-8-30.1 VG2-5-30 tr-8-30.2 VG2-9-30 tr-8-30.3 VG2-12-30 tr-8-30.4 VG2-15-30 tr-8-30.5 VG2-18-30 tr-8-30.6 VG2-21-30 tr-8-30.7 VG2-30-30 tr-8-30.8 VG2-50-30 tr-8-30.9 tr.1 anhy.1 barite.1 tr.2 05-011-4 tr.3 05-011-6 tr.4 05-011-7 tr.5 tr.6 NEF 05-013-3 tr.7 NEF 05-013-14 tr.8 NEF 05-013-22 tr.9 tr.10 Analysis Date 2/28/2005 2/28/2005 2/28/2005 2/28/2005 2/28/2005 2/28/2005 2/28/2005 2/28/2005 2/28/2005 2/28/2005 2/28/2005 2/28/2005 2/28/2005 2/28/2005 2/28/2005 2/28/2005 2/28/2005 2/28/2005 3/7/2005 3/7/2005 3/7/2005 3/7/2005 3/7/2005 3/7/2005 3/7/2005 3/7/2005 3/7/2005 3/7/2005 3/7/2005 3/7/2005 3/7/2005 3/7/2005 3/7/2005 3/7/2005 3/7/2005 6/3/2005 6/3/2005 6/3/2005 6/3/2005 6/3/2005 6/3/2005 6/3/2005 6/3/2005 6/3/2005 6/3/2005 6/3/2005 6/3/2005 6/3/2005 6/3/2005 6/3/2005 6/3/2005 6/3/2005 6/3/2005 spec 3 61453 61452 61448 61452 61448 61453 61447 61453 61446 61453 61455 61453 61444 61454 61419 61454 61454 61454 61422 61420 61422 61419 61423 61419 61424 61417 61424 61417 61425 61416 61425 61417 61426 61416 61426 61425 61388 61393 61425 61421 61425 61417 61425 61424 61425 61426 61426 61425 61419 61424 61424 61424 61424 (+/-) 1.85 0.315 0.72 0.305 0.732 0.33 0.655 0.328 0.613 0.322 0.417 0.327 0.409 0.322 0.334 0.322 0.315 0.32 0.311 1.15 0.325 0.877 0.32 0.619 0.311 0.698 0.316 0.656 0.32 0.652 0.317 0.463 0.327 0.414 0.316 0.313 0.327 0.336 0.327 0.399 0.32 0.448 0.316 0.449 0.316 0.315 0.491 0.313 0.767 0.307 0.496 0.313 0.306 SinT spec 4 61456 61463 61456 61463 61458 61463 61458 61464 61457 61464 61454 61464 61454 61461 61429 61464 61464 61464 61431 61426 61431 61427 61432 61427 61433 61426 61433 61427 61434 61430 61434 61425 61435 61425 61435 61430 61393 61398 61430 61426 61430 61421 61430 61427 61430 61430 61431 61430 61425 61430 61430 61429 61429 (+/-) 1.39 0.193 1.21 0.212 1.25 0.215 0.245 0.205 0.9 0.207 0.772 0.226 0.681 0.21 0.183 0.215 0.192 0.185 0.189 1.54 0.195 1.33 0.196 1.58 0.196 1.23 0.204 1.01 0.199 1.1 0.192 0.973 0.2 0.644 0.189 0.207 0.189 0.165 0.193 0.626 0.212 0.483 0.179 0.51 0.189 0.189 0.751 0.193 1.31 0.198 0.878 0.185 0.194 spec 5 61453 61455 61451 61455 61451 61456 61449 61456 61448 61456 61447 61456 61446 61456 61421 61456 61456 61456 61424 61415 61424 61424 61425 61419 61425 61420 61426 61417 61426 61420 61426 61419 61427 61415 61427 61421 61384 61389 61421 61417 61422 61413 61421 61419 61422 61421 61420 61421 61416 61421 61421 61421 61421 (+/-) 1.85 0.378 1.2 0.366 1.11 0.396 0.981 0.373 0.909 0.35 0.827 0.364 0.653 0.375 0.365 0.372 0.378 0.362 0.382 1.7 0.384 1.63 0.373 1.14 0.376 1.19 0.378 1.06 0.384 1.18 0.382 0.979 0.386 0.73 0.386 0.372 0.388 0.352 0.35 0.697 0.362 0.569 0.375 0.613 0.363 0.366 0.939 0.366 1.3 0.365 0.828 0.366 0.369 409 Table D2: Continued. Sample anhy.2 barite.2 py.1 tr.11 tr.12 QV 05-014-1 tr.13 tr.14 QV 05-014-7 tr.15 anhy.3 py.2 tr.16 tr.1 05-017-12 tr.2 anhy.1 py.1 tr.3 05-017-20 tr.4 15xglass-A-1 tr.5 15xcrystal-A-3 tr.6 15xcrystal-B-2 tr.7 30x-A-1 tr.8 30x-B-1 tr.9 30x-C-2 tr.10 lo-02-04iiglass tr.11 14-3glass tr.12 tr.13 anhy.2 py.2 tr.14 tr.1 lo-02-02-unheated.3 tr.2 lo-02-02-unheated.2 tr.3 lo-02-02-unheated.1 tr.4 py.1 anhy.1 tr.5 tr.6 tr.7 Analysis Date 6/3/2005 6/3/2005 6/3/2005 6/3/2005 6/3/2005 6/3/2005 6/3/2005 6/3/2005 6/3/2005 6/3/2005 6/3/2005 6/3/2005 6/3/2005 7/19/2005 7/19/2005 7/19/2005 7/19/2005 7/19/2005 7/19/2005 7/19/2005 7/19/2005 7/19/2005 7/19/2005 7/19/2005 7/19/2005 7/19/2005 7/19/2005 7/19/2005 7/19/2005 7/19/2005 7/19/2005 7/19/2005 7/19/2005 7/19/2005 7/19/2005 7/19/2005 7/19/2005 7/19/2005 7/19/2005 7/19/2005 7/19/2005 10/29/2005 10/29/2005 10/29/2005 10/29/2005 10/29/2005 10/29/2005 10/29/2005 10/29/2005 10/29/2005 10/29/2005 10/30/2005 10/30/2005 spec 3 61388 61394 61422 61425 61426 61404 61425 61425 61398 61424 61390 61422 61424 61418 61416 61418 61382 61416 61418 61417 61418 61406 61418 61409 61418 61406 61418 61407 61418 61411 61418 61412 61418 61403 61418 61417 61419 61419 61383 61417 61420 61418 61413 61418 61411 61418 61411 61418 61416 61385 61419 61419 61418 (+/-) 0.302 0.324 0.322 0.326 0.317 0.434 0.319 0.315 0.423 0.31 0.302 0.322 0.327 0.32 0.641 0.345 0.331 0.342 0.326 1.01 0.338 0.545 0.332 0.54 0.334 0.554 0.331 0.518 0.332 0.47 0.324 0.469 0.32 0.722 0.325 0.494 0.32 0.328 0.367 0.331 0.322 0.316 0.574 0.308 0.471 0.313 0.553 0.309 0.326 0.329 0.309 0.313 0.298 SinT spec 4 61392 61398 61427 61430 61431 61408 61430 61429 61402 61429 61394 61427 61429 61426 61423 61426 61390 61425 61426 61426 61426 61412 61426 61414 61426 61417 61426 61414 61426 61420 61426 61419 61426 61410 61426 61424 61426 61427 61392 61426 61427 61423 61417 61423 61415 61422 61416 61423 61420 61390 61423 61423 61422 (+/-) 0.177 0.168 0.194 0.184 0.186 0.442 0.201 0.203 0.383 0.189 0.188 0.18 0.166 0.18 0.84 0.201 0.182 0.172 0.188 1.81 0.197 0.128 0.194 0.663 0.199 0.919 0.195 0.804 0.19 0.551 0.186 0.588 0.185 0.859 0.182 0.708 0.191 0.187 0.197 0.185 0.196 0.187 0.629 0.198 0.741 0.194 0.755 0.202 0.184 0.172 0.198 0.198 0.175 spec 5 61384 61390 61419 61421 61422 61401 61421 61421 61394 61421 61386 61419 61421 61412 61409 61412 61376 61411 61412 61411 61412 61400 61413 61403 61412 61399 61412 61402 61412 61406 61412 61406 61412 61395 61413 61412 61414 61413 61378 61412 61414 61403 61397 61403 61395 61403 61393 61403 61401 61371 61403 61403 61403 (+/-) 0.375 0.35 0.363 0.357 0.362 0.504 0.37 0.362 0.43 0.364 0.383 0.36 0.402 0.367 0.992 0.264 0.416 0.356 0.359 1.46 0.351 0.791 0.369 0.719 0.362 0.863 0.362 0.723 0.368 0.598 0.381 0.677 0.371 0.975 0.267 0.818 0.38 0.378 0.386 0.36 0.37 0.383 0.754 0.377 0.655 0.379 0.964 0.383 0.368 0.359 0.385 0.377 0.38 410 Table D2: Continued. Sample 31-7b1177-1.2 tr.8 31.7b1231-3.1 tr.9 py.2 anhy.2 tr.10 tr.11 31.7b1177-1.1 tr.12 tr.13 31-7b1206-1.2 tr.14 tr.15 14-3.1 tr.16 14-3.2 tr.17 py.3 anhy.3 tr.18 tr.1 py.1 anhy.1 tr.2 tr.3 31-7b-26 tr.4 31-7b-15 tr.5 31-7b-1 tr.6 14-3.3 tr.7 tr.8 tr.9 M7 tr.10 31-7b1177-2.1rpt tr.11 31-7b1206-2.1 tr.12 31-7b1206-3.1 tr.13 14-3.4 tr.14 tr.15 lo-02-04ii tr.16 anhy.2 py.2 tr.17 bar-5-30 Analysis Date 10/30/2005 10/30/2005 10/30/2005 10/30/2005 10/30/2005 10/30/2005 10/30/2005 11/1/2005 11/1/2005 11/1/2005 11/1/2005 11/1/2005 11/1/2005 11/1/2005 11/1/2005 11/1/2005 11/1/2005 11/1/2005 11/1/2005 11/1/2005 11/1/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 spec 3 61409 61417 61413 61417 61414 61383 61417 61409 61396 61408 61407 61396 61407 61406 61407 61406 61408 61406 61404 61373 61406 61421 61420 61386 61421 61421 61406 61420 61409 61420 61415 61420 61419 61420 61420 61420 61419 61420 61412 61420 61416 61420 61411 61420 61419 61420 61420 61407 61420 61385 61417 61420 61390 (+/-) 0.248 0.314 0.771 0.312 0.316 0.343 0.315 0.302 0.509 0.303 0.314 0.802 0.308 0.306 0.463 0.304 0.444 0.299 0.322 0.324 0.309 0.303 0.334 0.315 0.318 0.315 0.543 0.317 0.473 0.307 0.57 0.308 0.534 0.31 0.305 0.317 0.638 0.316 0.498 0.318 0.502 0.313 0.456 0.311 0.478 0.304 0.306 0.542 0.326 0.342 0.33 0.311 0.322 SinT spec 4 61412 61421 61417 61421 61419 61287 61421 61424 61409 61423 61422 61411 61422 61421 61422 61421 61422 61421 61419 61388 61421 61425 61424 61390 61425 61425 61408 61424 61411 61424 61417 61423 61424 61423 61423 61423 61420 61423 61417 61423 61416 61423 61414 61423 61421 61423 61423 61410 61423 61388 61420 61423 61393 (+/-) 0.591 0.186 0.985 0.179 0.185 0.185 0.206 0.167 0.635 0.2 0.185 1.26 0.179 0.173 0.504 0.178 0.496 0.179 0.184 0.208 0.179 0.202 0.186 0.168 0.18 0.19 0.756 0.195 0.554 0.187 0.732 0.187 0.606 0.179 0.186 0.169 1.05 0.186 0.575 0.199 0.836 0.173 0.641 0.178 0.534 0.198 0.195 0.774 0.187 0.177 0.179 0.181 0.198 spec 5 61393 61402 61397 61402 61399 61369 61402 61405 61390 61404 61403 61390 61304 61402 61402 61402 61403 61402 61400 61370 61402 61406 61404 61371 61406 61405 61388 61405 61393 61405 61399 61405 61404 61405 61405 61404 61401 61405 61395 61405 61399 61405 61394 61405 61404 61404 61404 61391 61405 61370 61402 61405 61374 (+/-) 0.759 0.385 1.05 0.389 0.384 0.366 0.396 0.399 0.813 0.388 0.396 1.35 0.382 0.374 0.698 0.286 0.672 0.418 0.37 0.366 0.396 0.383 0.383 0.41 0.399 0.372 0.656 0.382 0.762 0.294 1.01 0.382 1.12 0.395 0.392 0.281 1.05 0.291 0.866 0.4 0.764 0.385 0.908 0.393 0.694 0.379 0.393 0.751 0.387 0.353 0.372 0.39 0.386 411 Table D2: Continued. Sample tr.18 bar-9-30 tr.19 bar-12-30 tr.20 bar-15-30 tr.21 bar-18-30 tr.22 bar-21-30 tr.23 bar-30-30 tr.24 tr.1 anhy.1 py.1 tr.2 31-7b-gm3 tr.3 31-7b-25a tr.4 31-7b-28a tr.5 tr.6 tr.1 10-3-1 tr.2 10-4-1b tr.3 10-6-1 tr.4 tr.5 anhy.1 tr.6 bar.1 tr.7 py.1 tr.8 tr.9 IW-4-2 tr.10 IW-6-1 tr.11 anhy.2 py.2 tr.12 tr.13 IW-1-1 tr.14 20-1-2b tr.15 20-3-1 tr.16 Analysis Date 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/9/2005 11/21/2005 11/21/2005 11/21/2005 11/21/2005 11/21/2005 11/21/2005 11/21/2005 11/21/2005 11/21/2005 11/21/2005 11/21/2005 12/28/2005 12/28/2005 12/28/2005 12/28/2005 12/28/2005 12/28/2005 12/28/2005 12/28/2005 12/28/2005 12/28/2005 12/28/2005 12/28/2005 12/28/2005 12/28/2005 12/29/2005 12/29/2005 12/29/2005 12/29/2005 12/29/2005 12/29/2005 12/29/2005 12/29/2005 12/29/2005 12/29/2005 12/29/2005 12/29/2005 12/29/2005 12/29/2005 12/29/2005 spec 3 61420 61390 61420 61390 61420 61390 61420 61391 61421 61389 61421 61392 61421 61419 61386 61417 61419 61409 61419 61405 61418 61401 61418 61418 61453 61442 61453 61443 61453 61438 61452 61452 61418 61452 61421 61452 61449 61453 61454 61443 61452 61444 61451 61419 61450 61451 61453 61438 61453 61446 61453 61440 61453 (+/-) 0.307 0.319 0.315 0.329 0.298 0.32 0.301 0.322 0.309 0.315 0.317 0.339 0.316 0.327 0.332 0.332 0.311 1.06 0.313 0.627 0.328 0.649 0.308 0.308 0.329 0.423 0.322 0.589 0.322 0.511 0.329 0.33 0.335 0.337 0.336 0.328 0.342 0.345 0.331 0.464 0.534 0.576 0.331 0.367 0.338 0.331 0.329 0.543 0.329 0.546 0.34 0.412 0.319 SinT spec 4 61423 61393 61424 61393 61424 61394 61424 61394 61424 61393 61425 61395 61424 61425 61392 61423 61425 61410 61424 61410 61424 61405 61424 61424 61428 61416 61428 61416 61427 61413 61427 61426 61393 61426 61395 61427 61424 61427 61428 61417 61427 61416 61426 61393 61425 61426 61427 61413 61427 61422 61427 61413 61427 (+/-) 0.181 0.19 0.205 0.177 0.181 0.184 0.194 0.182 0.185 0.17 0.197 0.168 0.199 0.208 0.216 0.187 0.193 1.87 0.185 0.947 0.193 1.01 0.187 0.186 0.196 0.579 0.178 0.889 0.203 0.57 0.175 0.188 0.175 0.173 0.195 0.168 0.181 0.175 0.188 0.776 0.187 0.894 0.195 0.164 0.177 0.18 0.182 0.661 0.18 0.885 0.185 0.534 0.177 spec 5 61405 61374 61405 61374 61405 61374 61405 61374 61405 61373 61405 61375 61405 61404 61371 61402 61404 61389 61404 61391 61403 61384 61403 61403 61433 61421 61433 61423 61432 61417 61432 61432 61398 61432 61400 61432 61429 61432 61433 61421 61433 61423 61432 61399 61431 61432 61433 61420 61433 61426 61433 61419 61433 (+/-) 0.387 0.376 0.399 0.382 0.379 0.376 0.37 0.365 0.37 0.578 0.393 0.363 0.396 0.39 0.353 0.383 0.382 1.87 0.395 0.855 0.402 0.148 0.409 0.393 0.384 0.685 0.388 0.883 0.399 0.721 0.391 0.379 0.332 0.387 0.374 0.388 0.383 0.382 0.367 0.789 0.391 1 0.386 0.351 0.37 0.398 0.391 0.697 0.381 0.992 0.398 0.75 0.387 412 Table D2: Continued. Sample 20-6-1 tr.17 30-2-1a tr.18 30-6-1 tr.19 tr.20 30-1-1 tr.21 tr.22 tr.23 anhy.3 py.3 tr.24 Analysis Date 12/29/2005 12/29/2005 12/29/2005 12/29/2005 12/29/2005 12/29/2005 12/29/2005 12/29/2005 12/29/2005 12/29/2005 12/29/2005 12/29/2005 12/29/2005 12/29/2005 spec 3 61439 61452 61442 61452 61443 61452 61452 61443 61452 61452 61452 61419 61450 61453 (+/-) 0.437 0.336 0.663 0.33 0.485 0.334 0.338 0.694 0.337 0.325 0.329 0.35 0.341 0.333 SinT spec 4 61414 61426 61416 61426 61416 61426 61427 61416 61426 61426 61426 61394 61424 61427 (+/-) 0.528 0.194 0.898 0.176 0.696 0.209 0.188 1.04 0.186 0.208 0.176 0.295 0.286 0.201 spec 5 61417 61432 61420 61432 61424 61432 61432 61422 61432 61432 61432 61400 61430 61432 (+/-) 0.729 0.384 0.974 0.4 0.765 0.388 0.409 1.03 0.388 0.401 0.4 0.352 0.385 0.393 413 APPENDIX E 40 Ar/39Ar AGE DATING Argon-argon age determination of forearc shoshonitic basalts were conducted at The Geochronology Laboratory at Oregon State University by J. Huard on a Mass Analyser Products model 215-50 rare gas mass spectrometer. Whole rock measurements were made for Quartzville basalt (QV03-1) and Pepper Mountain basalt (PEP03-1; Latitude 45.427°N, -122.173°W) following the method of Duncan et al (1997) and Duncan and Keller (2004). The following appendix includes incremental heating step data and plots of age plateaus and inverse isochrons. ²# ²# ²# ²# ²# ²# -2 16 WHOLEROCK % JH # AS CADES /3 5# 0 ROJECT )RRADIATION * VALUE 3 TANDARD 6 4 OTAL& US ION!GE 7EIGHTED0 LATEAU 2 ES ULTS 3 AMPLE -ATERIAL ,OCATION !NALYS T )NFORMATION ON!NALYS IS # # # # # # !RA !RCA !RCL KA ¼ ¼ % XTERNAL% RROR ¼ !NALYTICAL% RROR ¼ ¼ ¼ ¼ ¼ ¼ ¼ ¼ ¼ ¼ ¼ !GE rV KA !GE rV ¼ ¼ % XTERNAL% RROR ¼ !NALYTICAL% RROR ¼ !RR R K rV !RK ¼ ¼ ¼ ¼ ¼ ¼ + # A rV + # A rV ¼ ¼ 3 TATIS TICAL4 RATIO % RROR-AGNIFICATION N !RK !RR !RK 06:' )NC REMENTAL (EATING 7DEOH(,QFUHPHQWDOKHDWLQJGDWDIRU$U$UDJHGHWHUPLQDWLRQRI4XDUW]YLOOHEDVDOW49 414 415 &$*(!!!0549!!!&DVFDGHV $U$JHVLQ.D :HLJKWHG3ODWHDX 7RWDO)XVLRQ 1RUPDO,VRFKURQ ,QYHUVH,VRFKURQ 06:' $JH.D .D 6DPSOH,QIR ZKROHURFN ( MK 268& - ! &XPXODWLYH$U5HOHDVHG $U$U " $U$U )LJXUH($$JHSODWHDXDQG%LQYHUVHLVRFKURQSORWVIRUDJHGHWHUPLQDWLRQRI 49IRUHDUFVKRVKRQLWHLQGLFDWLQJDSODWHDXDJHRIND ²# ²# ²# ²# ²# ²# ²# ²# ²# ²# -ARIANAS &DVFDGHV 0 ROJECT )RRADIATION * VALUE 3 TANDARD /3 5# -2 0 % 0 WHOLEROCK % JH 6 4 OTAL& US ION!GE 7EIGHTED0 LATEAU 2 ES ULTS 3 AMPLE -ATERIAL ,OCATION !NALYS T )NFORMATION ON!NALYS IS # # # # # # # # # # !RA !RCA !RCL -A ¼ ¼ % XTERNAL% RROR ¼ !NALYTICAL% RROR ¼ ¼ ¼ ¼ ¼ ¼ ¼ ¼ ¼ ¼ ¼ ¼ ¼ ¼ ¼ !GE rV -A !GE rV ¼ ¼ % XTERNAL% RROR ¼ !NALYTICAL% RROR ¼ !RR R K rV !RK ¼ ¼ ¼ ¼ ¼ ¼ ¼ ¼ ¼ ¼ + # A rV + # A rV ¼ ¼ 3 TATIS TICAL4 RATIO % RROR-AGNIFICATION N !RK !RR !RK 06:' )NC REMENTAL (EATING 7DEOH(,QFUHPHQWDOKHDWLQJGDWDIRU$U$UDJHGHWHUPLQDWLRQRI3HSSHU0WQEDVDOW3(3 416 417 &$*(!!!053(3!!!&DVFDGHV $U$JHVLQ0D :HLJKWHG3ODWHDX 7RWDO)XVLRQ 1RUPDO,VRFKURQ ,QYHUVH,VRFKURQ 06:' $JH0D 0D 6DPSOH,QIR ZKROHURFN ( MK 268& - $ &XPXODWLYH$U5HOHDVHG $U$U % $U$U )LJXUH($$JHSODWHDXDQG%LQYHUVHLVRFKURQSORWVIRUDJHGHWHUPLQDWLRQRI 3HSSHU0RXQWDLQ3(3IRUHDUFVKRVKRQLWHLQGLFDWLQJDSODWHDXDJHRI 0D6DPSOHORFDWLRQLVR1R: 418 APPENDIX F FLUX MELT MODELING Calculated results of flux melt modeling are presented in Tables F1 and F2. Results have been reduced to 1% melting (Table F1) and 0.5% melting (Table F2) for enriched and depleted peridotite sources, respectively. Enriched peridotite source is from Reiners et al (2000) and depleted peridotite source is from Borg et al (1997). The modeled subduction component is from Reiners et al (2000) with Pb from Borg et al (1997) and Cl from Kent et al (2002) and Stolper and Newman (1994). Bulk partition coefficients (D’s) are from Borg et al (1997) assuming a mineralogy of 55% olivine, 30% orthopyroxene, 10% clinopyroxene, 2.5% garnet, and 2.5% spinel for the enriched peridotite and 64% olivine, 26% orthopyroxene, 4% garnet, and 6% amphibole for the depleted peridotite. Flux melting was calculated following Reiners et al (2000) using equation 1: dF dSC 3 * 10 6 e [ 0.012*(To F'Hf / Cp )] equation 1 Where: 'Hf = 753 J/g Cp= 1.3 J/g*K To= Initial peridotite temperature (K) SC = 0.01 wt% increment of subduction component Equation 1 is iteratively solved for degree melting assuming the initial step has 0% melt (F=0). Melting is modeled as a modal batch partial melt of the peridotite source 419 with calculated amount of subduction component added based on the percentage of melt generated. Initial peridotite temperatures for the enriched peridotite range from 1250°C to 1500°C and 1075°C and 1175°C for the depleted peridotite. Element Peridotite SC D 'SC % F% 1250C 0.01 0.00 0.12 1.04 0.23 2.02 0.35 3.01 0.48 4.01 0.62 5.01 0.77 6.02 0.93 7.02 1.1 8.01 1.29 9.04 1.48 10.00 1.69 11.00 1.92 12.01 2.16 13.00 2.42 14.00 2.7 15.00 3 16.01 3.32 17.00 3.67 18.02 4.03 19.00 4.43 20.01 4.85 21.00 5.31 22.01 5.79 23.00 6.32 24.01 6.88 25.01 7.47 26.00 6.57 0.79 0.61 0.55 0.52 0.52 0.52 0.52 0.53 0.55 0.56 0.58 0.59 0.61 0.63 0.66 0.68 0.71 0.74 0.76 0.79 0.83 0.86 0.90 0.94 0.98 1.02 Cs 0.00465 3.5 0.000762 692.12 50.39 33.14 27.11 24.26 22.76 21.95 21.56 21.43 21.50 21.70 22.02 22.45 22.95 23.53 24.19 24.91 25.70 26.57 27.47 28.47 29.52 30.66 31.84 33.13 34.48 35.89 30145.30 1004.96 607.48 468.22 400.13 361.75 338.65 324.49 316.04 311.33 309.70 310.18 312.52 316.30 321.42 327.75 335.16 343.56 353.12 363.22 374.65 386.78 400.14 414.11 429.50 445.70 462.67 Rb Ba 0.413 9 120 1500 0.000614 0.0003035 37.64 6.95 4.53 3.61 3.15 2.89 2.74 2.64 2.59 2.57 2.57 2.58 2.61 2.65 2.70 2.76 2.83 2.91 3.00 3.09 3.19 3.30 3.41 3.54 3.67 3.81 3.96 Th 0.07 13 0.001894 Table F1: Flux melt models with an enriched mantle source. 8.70 2.06 1.43 1.19 1.07 1.01 0.97 0.95 0.95 0.95 0.96 0.97 0.99 1.02 1.04 1.07 1.10 1.14 1.17 1.21 1.26 1.30 1.35 1.41 1.46 1.52 1.58 0.02 5.3 0.00236 U 101.74 60.24 43.76 34.31 28.23 24.01 20.93 18.60 16.78 15.25 14.09 13.08 12.21 11.48 10.85 10.31 9.83 9.41 9.04 8.73 8.44 8.19 7.97 7.78 7.60 7.46 7.33 1.5 8 0.01475 Nb 7.65 4.90 3.67 2.92 2.42 2.06 1.80 1.60 1.43 1.30 1.19 1.10 1.01 0.95 0.88 0.83 0.78 0.74 0.70 0.67 0.63 0.60 0.58 0.55 0.53 0.51 0.49 Ta 0.14 0.05 0.0183 427776.88 30399.20 18570.24 14331.51 12237.35 11048.30 10327.40 9881.23 9610.96 9455.45 9395.73 9400.90 9462.85 9569.24 9716.85 9901.37 10119.04 10366.62 10649.57 10949.32 11288.92 11649.91 12047.97 12464.39 12923.85 13407.72 13914.82 K 283.85 45000 0.000674 62.39 39.66 31.43 27.01 24.37 22.71 21.63 20.95 20.54 20.32 20.26 20.32 20.49 20.75 21.08 21.49 21.97 22.51 23.13 23.78 24.52 25.30 26.16 27.07 28.06 29.11 30.21 La 0.815 99 0.01322 420 Element Peridotite SC D 'SC % F% 1250C 0.01 0.00 0.12 1.04 0.23 2.02 0.35 3.01 0.48 4.01 0.62 5.01 0.77 6.02 0.93 7.02 1.1 8.01 1.29 9.04 1.48 10.00 1.69 11.00 1.92 12.01 2.16 13.00 2.42 14.00 2.7 15.00 3 16.01 3.32 17.00 3.67 18.02 4.03 19.00 4.43 20.01 4.85 21.00 5.31 22.01 5.79 23.00 6.32 24.01 6.88 25.01 7.47 26.00 Table F1: Continued Pb 0.17 17 0.001458 117.79 16.01 9.67 7.27 6.04 5.32 4.87 4.56 4.36 4.22 4.13 4.08 4.06 4.06 4.09 4.13 4.18 4.26 4.34 4.44 4.55 4.67 4.81 4.95 5.11 5.29 5.47 Ce 2.47 297 0.02155 115.98 88.90 76.25 68.68 63.90 60.84 58.90 57.74 57.15 56.99 57.18 57.66 58.41 59.37 60.54 61.91 63.46 65.18 67.11 69.13 71.41 73.80 76.44 79.18 82.20 85.37 88.70 1788.32 1077.22 860.75 754.22 695.15 661.01 641.68 631.95 628.85 630.79 636.32 645.16 656.98 670.89 687.16 705.59 726.02 748.29 772.96 798.53 826.99 856.85 889.43 923.22 960.25 999.02 1039.47 18 3500 0.01026 Sr 53.72 42.63 36.92 33.29 30.88 29.25 28.15 27.43 26.99 26.75 26.70 26.79 27.01 27.32 27.75 28.26 28.87 29.55 30.33 31.16 32.10 33.09 34.20 35.35 36.63 37.98 39.39 1.4 130 0.0263 Nd 8.12 7.32 6.84 6.52 6.31 6.17 6.10 6.08 6.09 6.13 6.20 6.29 6.41 6.54 6.70 6.87 7.07 7.28 7.51 7.75 8.02 8.31 8.62 8.94 9.30 9.67 10.06 Sm 0.35 35 0.043525 241.42 226.08 214.19 203.99 195.31 187.94 181.73 176.52 172.19 168.46 165.61 163.24 161.39 160.07 159.21 158.78 158.78 159.17 159.97 161.10 162.65 164.54 166.84 169.44 172.50 175.90 179.62 25 500 0.10375 Zr 5.38 5.02 4.77 4.57 4.42 4.30 4.22 4.17 4.14 4.12 4.12 4.14 4.18 4.22 4.28 4.35 4.43 4.53 4.64 4.75 4.88 5.02 5.17 5.34 5.52 5.71 5.91 0.4 20 0.07475 Hf 2.50 2.26 2.11 1.99 1.91 1.85 1.81 1.79 1.78 1.77 1.78 1.79 1.81 1.83 1.86 1.90 1.94 1.99 2.04 2.10 2.16 2.23 2.30 2.38 2.47 2.56 2.65 Eu 0.13 9 0.0523 18675.98 16276.78 14656.43 13407.12 12431.90 11663.61 11054.65 10570.58 10185.97 9867.34 9632.81 9444.50 9300.96 9202.76 9140.57 9112.07 9114.82 9146.38 9206.46 9289.42 9400.67 9533.91 9694.45 9874.27 10083.77 10314.44 10565.11 Ti 1000 30000 0.0537 421 Element Gd Peridotite 0.45 SC 30 D 0.070185 'SC % F% 1250C 0.01 0.00 6.45 0.12 1.04 6.08 0.23 2.02 5.82 0.35 3.01 5.64 0.48 4.01 5.51 0.62 5.01 5.42 0.77 6.02 5.37 0.93 7.02 5.35 1.1 8.01 5.36 1.29 9.04 5.39 1.48 10.00 5.44 1.69 11.00 5.51 1.92 12.01 5.59 2.16 13.00 5.70 2.42 14.00 5.82 2.7 15.00 5.95 3 16.01 6.10 3.32 17.00 6.27 3.67 18.02 6.45 4.03 19.00 6.65 4.43 20.01 6.87 4.85 21.00 7.09 5.31 22.01 7.35 5.79 23.00 7.61 6.32 24.01 7.90 6.88 25.01 8.20 7.47 26.00 8.52 Table F1: Continued 4 11500 0.001 5149.60 1557.54 1439.76 1425.01 1441.75 1473.24 1513.45 1559.62 1610.32 1667.71 1725.19 1788.42 1857.04 1927.81 2003.45 2083.71 2168.37 2257.22 2352.80 2449.49 2555.12 2664.16 2781.58 2902.04 3032.81 3168.67 3309.45 2.60 2.55 2.52 2.49 2.46 2.45 2.44 2.43 2.43 2.44 2.45 2.46 2.49 2.51 2.54 2.58 2.62 2.67 2.72 2.78 2.85 2.92 3.00 3.08 3.17 3.27 3.37 Cl 0.5 12 0.19305 Yb 422 Element 'SC % F% 8.12 27.01 8.81 28.01 9.55 29.01 10.34 30.00 1300C 0.01 0.00 0.07 1.04 0.13 2.01 0.2 3.06 0.27 4.05 0.35 5.09 0.43 6.06 0.52 7.09 0.61 8.04 0.71 9.03 0.82 10.05 0.93 11.00 1.06 12.04 1.19 13.02 1.33 14.00 1.49 15.04 1.65 16.01 1.83 17.04 2.02 18.04 2.22 19.03 2.43 20.00 2.67 21.03 2.92 22.03 3.18 23.00 3.47 24.01 3.78 25.02 Table F1: Continued 37.42 39.03 40.73 42.53 692.12 45.12 27.46 20.88 17.93 16.15 15.15 14.49 14.11 13.89 13.79 13.80 13.89 14.05 14.26 14.54 14.85 15.22 15.64 16.08 16.56 17.11 17.69 18.29 18.96 19.68 6.57 0.64 0.44 0.37 0.34 0.33 0.32 0.32 0.32 0.32 0.33 0.34 0.34 0.35 0.36 0.38 0.39 0.40 0.42 0.43 0.45 0.46 0.48 0.50 0.52 0.55 Rb 1.07 1.11 1.16 1.22 Cs 30145.30 938.51 536.33 387.38 319.69 277.74 252.93 235.47 224.27 216.21 210.69 207.45 205.54 205.04 205.59 207.18 209.48 212.67 216.53 220.96 225.92 231.85 238.22 245.00 252.68 260.96 481.24 500.77 521.52 543.44 Ba 37.64 6.44 3.95 2.95 2.48 2.19 2.01 1.89 1.81 1.76 1.72 1.70 1.70 1.70 1.71 1.73 1.75 1.78 1.82 1.86 1.91 1.96 2.02 2.08 2.15 2.22 4.13 4.30 4.48 4.67 Th U 8.70 1.86 1.20 0.93 0.80 0.72 0.68 0.65 0.63 0.62 0.62 0.62 0.62 0.63 0.64 0.65 0.66 0.68 0.69 0.71 0.73 0.76 0.78 0.81 0.84 0.87 1.65 1.72 1.80 1.88 101.74 60.19 43.66 33.67 27.79 23.46 20.51 18.14 16.38 14.91 13.66 12.68 11.76 11.03 10.39 9.80 9.32 8.87 8.47 8.13 7.83 7.54 7.29 7.07 6.86 6.68 7.22 7.13 7.06 7.00 Nb 7.65 4.91 3.68 2.89 2.41 2.05 1.79 1.59 1.43 1.30 1.19 1.10 1.02 0.95 0.89 0.84 0.79 0.75 0.71 0.67 0.64 0.61 0.59 0.56 0.54 0.52 0.47 0.45 0.43 0.42 Ta 427776.88 28473.10 16474.78 11929.71 9843.92 8543.21 7769.88 7222.75 6869.59 6613.54 6435.90 6328.92 6262.69 6240.71 6251.01 6292.79 6357.05 6448.24 6559.89 6689.49 6835.05 7009.75 7198.27 7399.14 7626.96 7873.21 14469.66 15053.79 15674.47 16330.44 K 62.39 37.63 28.52 23.28 20.33 18.26 16.93 15.94 15.28 14.78 14.42 14.20 14.05 14.00 14.01 14.09 14.22 14.40 14.63 14.90 15.20 15.57 15.97 16.39 16.88 17.40 31.42 32.69 34.03 35.46 La 423 Element 'SC % F% 8.12 27.01 8.81 28.01 9.55 29.01 10.34 30.00 1300C 0.01 0.00 0.07 1.04 0.13 2.01 0.2 3.06 0.27 4.05 0.35 5.09 0.43 6.06 0.52 7.09 0.61 8.04 0.71 9.03 0.82 10.05 0.93 11.00 1.06 12.04 1.19 13.02 1.33 14.00 1.49 15.04 1.65 16.01 1.83 17.04 2.02 18.04 2.22 19.03 2.43 20.00 2.67 21.03 2.92 22.03 3.18 23.00 3.47 24.01 3.78 25.02 Table F1: Continued 5.67 5.88 6.11 6.34 117.79 15.35 8.91 6.35 5.15 4.38 3.91 3.57 3.34 3.16 3.03 2.93 2.86 2.82 2.79 2.77 2.77 2.79 2.81 2.84 2.88 2.93 2.99 3.05 3.13 3.21 115.98 84.35 69.22 59.37 53.41 49.06 46.19 44.03 42.57 41.50 40.76 40.34 40.12 40.12 40.30 40.65 41.12 41.75 42.51 43.37 44.32 45.46 46.69 47.99 49.47 51.06 Pb 92.33 96.14 100.20 104.48 Ce 1788.32 994.29 747.12 615.14 544.78 497.78 469.14 449.09 436.77 428.74 424.36 423.06 424.20 427.32 432.21 439.15 447.09 456.86 467.83 479.88 492.92 508.13 524.20 541.04 559.91 580.09 1083.55 1129.81 1178.82 1230.51 Sr 53.72 40.90 34.17 29.52 26.60 24.39 22.88 21.71 20.89 20.25 19.77 19.47 19.25 19.15 19.13 19.20 19.33 19.53 19.79 20.11 20.47 20.92 21.41 21.93 22.54 23.19 40.94 42.57 44.31 46.15 Nd 8.12 7.00 6.30 5.76 5.39 5.11 4.91 4.76 4.66 4.59 4.54 4.52 4.52 4.54 4.57 4.62 4.69 4.77 4.86 4.96 5.08 5.21 5.36 5.51 5.68 5.87 10.48 10.93 11.40 11.90 Sm 241.42 224.04 210.39 197.78 187.72 178.50 171.04 164.23 158.68 153.62 149.10 145.42 141.89 139.07 136.64 134.46 132.79 131.39 130.33 129.59 129.14 128.95 129.05 129.41 130.05 130.95 183.84 188.43 193.45 198.88 Zr 5.38 4.90 4.56 4.26 4.04 3.85 3.70 3.58 3.48 3.41 3.34 3.30 3.26 3.24 3.23 3.24 3.25 3.26 3.29 3.33 3.37 3.43 3.49 3.56 3.64 3.72 6.13 6.37 6.62 6.89 Hf 2.50 2.19 1.98 1.82 1.70 1.60 1.53 1.47 1.43 1.40 1.37 1.36 1.35 1.34 1.34 1.35 1.35 1.37 1.38 1.41 1.43 1.46 1.49 1.52 1.56 1.61 2.76 2.87 2.99 3.11 Eu 18675.98 16056.88 14270.16 12794.53 11723.10 10812.66 10124.31 9529.57 9067.81 8665.45 8319.92 8048.66 7798.40 7604.85 7443.86 7305.30 7203.48 7122.33 7066.05 7031.85 7017.35 7021.59 7044.29 7083.26 7141.09 7215.93 10847.89 11153.49 11485.51 11843.20 Ti 424 Element 'SC % F% 8.12 27.01 8.81 28.01 9.55 29.01 10.34 30.00 1300C 0.01 0.00 0.07 1.04 0.13 2.01 0.2 3.06 0.27 4.05 0.35 5.09 0.43 6.06 0.52 7.09 0.61 8.04 0.71 9.03 0.82 10.05 0.93 11.00 1.06 12.04 1.19 13.02 1.33 14.00 1.49 15.04 1.65 16.01 1.83 17.04 2.02 18.04 2.22 19.03 2.43 20.00 2.67 21.03 2.92 22.03 3.18 23.00 3.47 24.01 3.78 25.02 Table F1: Continued 3.49 3.61 3.74 3.88 2.60 2.52 2.46 2.40 2.35 2.31 2.27 2.24 2.21 2.19 2.17 2.15 2.14 2.14 2.13 2.14 2.14 2.15 2.16 2.18 2.20 2.22 2.25 2.29 2.32 2.37 6.45 5.89 5.50 5.16 4.91 4.71 4.56 4.44 4.35 4.28 4.23 4.20 4.19 4.19 4.21 4.24 4.28 4.33 4.40 4.48 4.56 4.66 4.77 4.89 5.03 5.17 Yb 8.87 9.24 9.63 10.04 Gd 5149.60 1057.61 898.82 854.01 846.10 853.09 867.63 888.34 911.46 938.61 969.39 1000.59 1037.61 1074.55 1114.09 1158.85 1203.10 1252.25 1303.40 1356.47 1411.37 1473.15 1536.47 1601.31 1672.47 1747.32 3462.00 3621.27 3789.31 3965.83 Cl 425 Element 'SC % F% 4.1 26.00 4.46 27.02 4.84 28.02 5.24 29.00 5.67 29.99 1350 0.01 0.00 0.04 0.96 0.08 2.14 0.11 2.96 0.15 3.99 0.19 4.96 0.24 6.07 0.29 7.11 0.34 8.08 0.39 8.98 0.45 10.00 0.52 11.10 0.58 11.98 0.66 13.08 0.73 13.97 0.82 15.04 0.91 16.04 1.01 17.07 1.11 18.04 1.22 19.03 1.34 20.04 1.47 21.05 1.6 22.00 1.75 23.03 1.91 24.04 Table F1: Continued 20.41 21.24 22.10 22.99 23.95 692.12 45.35 23.15 18.02 14.61 12.77 11.42 10.60 10.08 9.73 9.46 9.28 9.20 9.16 9.17 9.23 9.33 9.46 9.62 9.81 10.03 10.29 10.55 10.86 11.20 6.57 0.59 0.34 0.28 0.24 0.22 0.21 0.21 0.20 0.20 0.20 0.20 0.21 0.21 0.21 0.22 0.23 0.23 0.24 0.25 0.26 0.27 0.27 0.29 0.30 Rb 0.57 0.59 0.62 0.65 0.68 Cs 30145.30 973.92 470.48 355.60 279.27 237.36 206.10 186.62 173.57 164.41 156.68 150.57 146.98 143.80 142.08 140.86 140.46 140.70 141.44 142.70 144.45 146.68 149.15 152.24 155.72 269.55 279.24 289.45 300.17 311.64 Ba 37.64 6.58 3.46 2.68 2.14 1.84 1.62 1.48 1.38 1.32 1.26 1.22 1.19 1.17 1.16 1.16 1.16 1.16 1.17 1.19 1.20 1.23 1.25 1.28 1.31 2.30 2.38 2.47 2.57 2.67 Th U 8.70 1.86 1.02 0.81 0.66 0.58 0.52 0.48 0.46 0.44 0.43 0.42 0.42 0.41 0.41 0.42 0.42 0.42 0.43 0.44 0.45 0.46 0.47 0.48 0.50 0.90 0.94 0.98 1.02 1.06 101.74 62.19 42.04 34.30 27.90 23.79 20.32 17.91 16.13 14.77 13.50 12.36 11.58 10.75 10.15 9.53 9.02 8.56 8.17 7.81 7.48 7.18 6.93 6.68 6.45 6.52 6.37 6.24 6.12 6.02 Nb 7.65 5.06 3.56 2.95 2.43 2.09 1.79 1.59 1.43 1.31 1.20 1.10 1.03 0.95 0.90 0.84 0.79 0.75 0.71 0.68 0.65 0.62 0.59 0.57 0.54 0.50 0.48 0.46 0.45 0.43 Ta 427776.88 29523.12 14510.39 10998.25 8645.37 7346.06 6373.15 5764.38 5354.99 5066.52 4821.97 4627.24 4511.97 4408.28 4350.59 4308.06 4291.02 4293.34 4311.89 4345.98 4395.19 4458.88 4530.50 4620.37 4722.47 8129.03 8417.63 8722.26 9042.16 9384.62 K 62.39 37.72 26.05 21.74 18.28 16.12 14.36 13.19 12.36 11.76 11.23 10.80 10.53 10.29 10.14 10.02 9.96 9.94 9.96 10.01 10.10 10.22 10.36 10.54 10.74 17.95 18.56 19.22 19.90 20.64 La 426 Element 'SC % F% 4.1 26.00 4.46 27.02 4.84 28.02 5.24 29.00 5.67 29.99 1350 0.01 0.00 0.04 0.96 0.08 2.14 0.11 2.96 0.15 3.99 0.19 4.96 0.24 6.07 0.29 7.11 0.34 8.08 0.39 8.98 0.45 10.00 0.52 11.10 0.58 11.98 0.66 13.08 0.73 13.97 0.82 15.04 0.91 16.04 1.01 17.07 1.11 18.04 1.22 19.03 1.34 20.04 1.47 21.05 1.6 22.00 1.75 23.03 1.91 24.04 Table F1: Continued 3.29 3.39 3.50 3.61 3.74 117.79 16.07 8.05 6.07 4.72 3.96 3.39 3.02 2.77 2.58 2.43 2.29 2.21 2.13 2.08 2.03 2.00 1.98 1.97 1.96 1.96 1.97 1.99 2.01 2.03 115.98 83.76 63.73 55.28 48.02 43.25 39.23 36.48 34.51 33.06 31.79 30.74 30.11 29.53 29.20 28.95 28.85 28.87 28.98 29.19 29.49 29.88 30.32 30.88 31.52 Pb 52.72 54.59 56.56 58.63 60.85 Ce 1788.32 983.67 661.79 551.50 466.38 414.99 374.49 348.42 330.77 318.44 308.26 300.59 296.48 293.41 292.34 292.52 293.95 296.60 300.06 304.53 310.00 316.42 323.23 331.41 340.42 600.88 624.18 648.63 674.19 701.44 Sr 53.72 40.77 31.90 27.95 24.43 22.05 20.00 18.56 17.51 16.71 16.00 15.40 15.01 14.64 14.41 14.21 14.08 14.02 14.00 14.03 14.11 14.23 14.37 14.57 14.81 23.88 24.66 25.49 26.36 27.30 Nd 8.12 6.91 5.91 5.40 4.92 4.57 4.26 4.04 3.87 3.75 3.64 3.54 3.48 3.43 3.40 3.38 3.38 3.38 3.40 3.43 3.46 3.51 3.56 3.63 3.70 6.06 6.28 6.51 6.75 7.01 Sm 241.42 224.29 206.51 195.87 184.25 174.81 165.24 157.49 151.09 145.73 140.34 135.17 131.47 127.34 124.34 121.12 118.46 116.04 114.05 112.27 110.70 109.36 108.32 107.41 106.73 132.08 133.53 135.23 137.17 139.39 Zr 5.38 4.88 4.40 4.13 3.84 3.63 3.41 3.25 3.12 3.02 2.92 2.83 2.77 2.70 2.66 2.62 2.59 2.57 2.56 2.55 2.55 2.55 2.56 2.58 2.61 3.82 3.92 4.04 4.16 4.29 Hf 2.50 2.18 1.89 1.74 1.59 1.48 1.38 1.30 1.24 1.20 1.16 1.12 1.09 1.07 1.05 1.04 1.03 1.03 1.02 1.02 1.03 1.03 1.04 1.05 1.07 1.65 1.70 1.76 1.82 1.88 Eu 18675.98 16123.74 13841.96 12624.79 11404.51 10487.76 9620.22 8959.98 8441.65 8024.78 7622.02 7249.83 6992.47 6714.71 6518.25 6313.68 6150.38 6005.67 5890.76 5791.02 5707.05 5638.86 5589.25 5550.13 5525.25 7304.15 7413.71 7538.51 7677.70 7834.18 Ti 427 Element 'SC % F% 4.1 26.00 4.46 27.02 4.84 28.02 5.24 29.00 5.67 29.99 1350 0.01 0.00 0.04 0.96 0.08 2.14 0.11 2.96 0.15 3.99 0.19 4.96 0.24 6.07 0.29 7.11 0.34 8.08 0.39 8.98 0.45 10.00 0.52 11.10 0.58 11.98 0.66 13.08 0.73 13.97 0.82 15.04 0.91 16.04 1.01 17.07 1.11 18.04 1.22 19.03 1.34 20.04 1.47 21.05 1.6 22.00 1.75 23.03 1.91 24.04 Table F1: Continued 2.41 2.46 2.52 2.58 2.65 2.60 2.51 2.42 2.36 2.30 2.24 2.18 2.13 2.09 2.05 2.02 1.98 1.96 1.93 1.91 1.89 1.87 1.86 1.85 1.85 1.84 1.84 1.85 1.85 1.86 6.45 5.84 5.26 4.94 4.61 4.35 4.11 3.93 3.79 3.68 3.57 3.48 3.42 3.36 3.33 3.30 3.28 3.27 3.27 3.28 3.30 3.33 3.36 3.40 3.45 Yb 5.33 5.50 5.69 5.88 6.09 Gd 5149.60 815.54 590.56 544.02 519.36 511.58 512.13 518.29 527.39 538.17 552.41 570.05 585.66 606.84 625.52 649.58 673.56 700.03 726.27 754.83 785.63 818.56 851.05 888.03 926.89 1823.36 1907.55 1994.98 2085.56 2181.42 Cl 428 Element 'SC % F% 2.08 25.05 2.26 26.05 2.45 27.03 2.66 28.04 2.88 29.02 3.11 29.99 1400C 0.01 0.00 0.03 1.16 0.05 2.24 0.07 3.23 0.09 4.17 0.11 5.04 0.14 6.26 0.16 7.02 0.19 8.08 0.22 9.08 0.23 9.39 0.25 10.00 0.29 11.15 0.33 12.21 0.37 13.20 0.41 14.13 0.45 15.00 0.5 16.01 0.56 17.15 0.61 18.02 0.67 19.01 0.74 20.09 0.81 21.08 0.88 22.02 Table F1: Continued 11.56 11.94 12.35 12.80 13.27 13.76 692.12 36.69 20.59 15.08 12.32 10.68 9.19 8.54 7.86 7.40 7.28 7.08 6.78 6.58 6.45 6.37 6.32 6.29 6.30 6.32 6.37 6.45 6.54 6.64 6.57 0.46 0.28 0.21 0.18 0.17 0.15 0.14 0.14 0.13 0.13 0.13 0.13 0.13 0.13 0.13 0.14 0.14 0.14 0.14 0.15 0.15 0.16 0.16 Rb 0.31 0.32 0.33 0.35 0.36 0.38 Cs 30145.30 792.15 430.01 307.70 246.46 209.84 176.31 161.58 145.87 134.90 131.96 126.90 119.19 113.72 109.72 106.77 104.57 102.59 101.04 100.25 99.75 99.62 99.86 100.37 159.58 163.79 168.33 173.43 178.83 184.51 Ba 37.64 5.47 3.16 2.31 1.88 1.61 1.37 1.26 1.15 1.06 1.04 1.01 0.95 0.91 0.88 0.86 0.85 0.83 0.82 0.82 0.82 0.82 0.82 0.83 1.35 1.38 1.42 1.47 1.52 1.57 Th U 8.70 1.55 0.92 0.68 0.56 0.49 0.42 0.39 0.36 0.34 0.33 0.33 0.31 0.30 0.29 0.29 0.29 0.29 0.29 0.29 0.29 0.29 0.30 0.30 0.51 0.53 0.55 0.57 0.59 0.61 101.74 57.32 40.86 32.27 26.98 23.39 19.75 18.00 16.02 14.54 14.12 13.38 12.19 11.26 10.52 9.92 9.41 8.88 8.36 8.00 7.64 7.28 6.98 6.72 6.25 6.07 5.90 5.75 5.61 5.49 Nb 7.65 4.71 3.48 2.80 2.36 2.06 1.75 1.60 1.43 1.30 1.27 1.20 1.09 1.01 0.94 0.89 0.84 0.80 0.75 0.71 0.68 0.65 0.62 0.59 0.52 0.50 0.49 0.47 0.45 0.44 Ta 427776.88 24182.98 13298.64 9550.04 7658.77 6522.76 5478.86 5019.19 4527.54 4183.36 4091.03 3931.60 3688.52 3514.97 3387.81 3293.12 3222.01 3157.45 3105.87 3078.64 3059.92 3052.48 3056.56 3069.29 4836.04 4960.35 5094.78 5245.97 5406.31 5575.24 K 62.39 34.20 24.48 19.58 16.62 14.66 12.70 11.79 10.77 10.03 9.83 9.48 8.92 8.52 8.21 7.98 7.80 7.63 7.48 7.40 7.33 7.29 7.28 7.29 10.97 11.23 11.51 11.82 12.16 12.51 La 429 Element 'SC % F% 2.08 25.05 2.26 26.05 2.45 27.03 2.66 28.04 2.88 29.02 3.11 29.99 1400C 0.01 0.00 0.03 1.16 0.05 2.24 0.07 3.23 0.09 4.17 0.11 5.04 0.14 6.26 0.16 7.02 0.19 8.08 0.22 9.08 0.23 9.39 0.25 10.00 0.29 11.15 0.33 12.21 0.37 13.20 0.41 14.13 0.45 15.00 0.5 16.01 0.56 17.15 0.61 18.02 0.67 19.01 0.74 20.09 0.81 21.08 0.88 22.02 Table F1: Continued 2.07 2.10 2.15 2.19 2.25 2.30 117.79 13.40 7.50 5.38 4.30 3.64 3.03 2.75 2.46 2.25 2.19 2.09 1.94 1.83 1.74 1.68 1.63 1.57 1.53 1.50 1.48 1.46 1.45 1.44 115.98 77.70 60.26 50.30 43.89 39.42 34.81 32.60 30.10 28.26 27.75 26.85 25.44 24.40 23.61 23.01 22.55 22.12 21.76 21.56 21.41 21.32 21.31 21.36 Pb 32.24 33.02 33.87 34.83 35.85 36.92 Ce 1788.32 874.94 609.34 483.43 410.34 362.87 316.74 295.67 272.69 256.39 252.00 244.42 232.93 224.86 219.12 215.03 212.16 209.83 208.38 208.00 208.27 209.36 211.05 213.19 350.21 360.73 371.96 384.45 397.57 411.29 Sr 53.72 38.24 30.46 25.78 22.67 20.45 18.11 16.97 15.66 14.68 14.40 13.92 13.14 12.56 12.11 11.76 11.48 11.21 10.97 10.82 10.70 10.60 10.54 10.52 15.08 15.38 15.72 16.11 16.52 16.96 Nd 8.12 6.60 5.66 5.03 4.57 4.23 3.85 3.66 3.44 3.27 3.22 3.14 3.00 2.90 2.82 2.75 2.71 2.66 2.62 2.60 2.58 2.57 2.57 2.58 3.78 3.87 3.97 4.08 4.20 4.32 Sm 241.42 220.22 203.86 190.84 180.21 171.36 160.55 154.58 147.00 140.72 138.85 135.41 129.50 124.60 120.48 116.97 113.94 110.71 107.45 105.16 102.80 100.49 98.55 96.92 106.25 105.98 105.90 106.01 106.30 106.77 Zr 5.38 4.75 4.29 3.95 3.69 3.47 3.22 3.09 2.92 2.79 2.75 2.68 2.57 2.47 2.40 2.34 2.29 2.23 2.18 2.15 2.12 2.09 2.07 2.06 2.63 2.67 2.71 2.76 2.81 2.87 Hf 2.50 2.10 1.83 1.64 1.50 1.40 1.28 1.21 1.14 1.08 1.06 1.03 0.99 0.95 0.92 0.89 0.87 0.85 0.84 0.83 0.81 0.81 0.80 0.80 1.09 1.10 1.13 1.15 1.18 1.21 Eu 18675.98 15589.98 13550.97 12101.66 11017.56 10175.49 9213.67 8711.86 8103.76 7621.34 7481.97 7229.38 6808.61 6472.52 6198.26 5970.60 5778.97 5578.75 5382.71 5247.73 5112.17 4982.58 4876.95 4790.13 5513.77 5514.85 5527.68 5552.91 5589.20 5635.69 Ti 430 Element 'SC % F% 2.08 25.05 2.26 26.05 2.45 27.03 2.66 28.04 2.88 29.02 3.11 29.99 1400C 0.01 0.00 0.03 1.16 0.05 2.24 0.07 3.23 0.09 4.17 0.11 5.04 0.14 6.26 0.16 7.02 0.19 8.08 0.22 9.08 0.23 9.39 0.25 10.00 0.29 11.15 0.33 12.21 0.37 13.20 0.41 14.13 0.45 15.00 0.5 16.01 0.56 17.15 0.61 18.02 0.67 19.01 0.74 20.09 0.81 21.08 0.88 22.02 Table F1: Continued 1.87 1.88 1.90 1.92 1.95 1.97 2.60 2.49 2.40 2.32 2.25 2.19 2.12 2.08 2.02 1.97 1.96 1.93 1.88 1.84 1.81 1.78 1.76 1.73 1.70 1.68 1.67 1.65 1.63 1.62 6.45 5.67 5.11 4.69 4.38 4.12 3.83 3.67 3.48 3.33 3.29 3.21 3.08 2.98 2.90 2.83 2.78 2.73 2.68 2.65 2.62 2.60 2.59 2.58 Yb 3.51 3.58 3.65 3.74 3.83 3.92 Gd 5149.60 590.49 417.58 361.61 336.54 324.05 316.25 314.91 316.08 319.55 321.04 324.40 332.19 340.89 350.14 359.72 369.51 381.90 396.88 409.38 424.34 441.70 458.92 475.99 967.57 1010.00 1054.13 1102.16 1151.72 1202.77 Cl 431 Element 'SC % F% 0.96 23.01 1.05 24.06 1.14 25.03 1.24 26.04 1.35 27.07 1.46 28.04 1.58 29.02 1.71 30.01 1500 0.01 0.00 0.02 1.97 0.03 3.69 0.04 5.21 0.05 6.58 0.06 7.83 0.07 8.97 0.08 10.03 0.09 11.01 0.1 11.93 0.11 12.79 0.13 14.36 0.14 15.09 0.15 15.78 0.17 17.06 0.19 18.24 0.21 19.33 0.23 20.34 0.25 21.28 0.27 22.17 0.29 23.00 0.32 24.16 Table F1: Continued 6.77 6.92 7.08 7.27 7.48 7.69 7.92 8.18 692.12 21.52 11.98 8.74 7.12 6.15 5.50 5.04 4.71 4.45 4.24 3.94 3.83 3.74 3.60 3.50 3.43 3.37 3.34 3.31 3.30 3.29 6.57 0.26 0.15 0.11 0.10 0.09 0.08 0.07 0.07 0.07 0.07 0.06 0.06 0.06 0.06 0.06 0.06 0.06 0.06 0.06 0.06 0.07 Rb 0.17 0.17 0.18 0.18 0.19 0.20 0.21 0.21 Cs 30145.30 465.01 254.18 183.11 147.40 125.92 111.59 101.36 93.71 87.77 83.05 76.03 73.36 71.10 67.50 64.78 62.68 61.04 59.74 58.70 57.88 56.94 101.20 102.39 103.77 105.48 107.51 109.66 112.11 114.86 Ba 37.64 3.37 1.91 1.39 1.13 0.97 0.86 0.79 0.73 0.69 0.65 0.60 0.58 0.56 0.53 0.51 0.50 0.49 0.48 0.47 0.46 0.46 0.84 0.85 0.86 0.88 0.90 0.92 0.94 0.97 Th U 8.70 0.96 0.55 0.41 0.33 0.29 0.26 0.24 0.22 0.21 0.20 0.18 0.18 0.17 0.17 0.16 0.16 0.16 0.15 0.15 0.15 0.15 0.30 0.31 0.32 0.33 0.34 0.34 0.35 0.37 101.74 43.95 29.40 22.73 18.88 16.37 14.59 13.26 12.22 11.39 10.71 9.65 9.24 8.87 8.26 7.78 7.38 7.04 6.76 6.51 6.29 6.02 6.47 6.23 6.02 5.83 5.64 5.48 5.33 5.19 Nb 7.65 3.72 2.57 2.01 1.69 1.47 1.32 1.20 1.11 1.03 0.97 0.88 0.84 0.81 0.75 0.71 0.67 0.64 0.62 0.59 0.57 0.55 0.57 0.55 0.53 0.51 0.49 0.47 0.46 0.44 Ta 427776.88 14381.72 7921.86 5719.19 4607.33 3936.75 3488.48 3168.00 2927.81 2741.41 2592.84 2371.73 2287.65 2216.24 2102.06 2015.63 1948.75 1896.17 1854.38 1820.93 1794.06 1763.36 3091.86 3124.98 3164.27 3213.37 3272.35 3335.24 3407.16 3487.98 K 62.39 25.56 17.02 13.21 11.05 9.66 8.68 7.97 7.41 6.98 6.62 6.08 5.88 5.70 5.41 5.18 5.01 4.87 4.75 4.66 4.58 4.49 7.31 7.37 7.43 7.52 7.63 7.76 7.90 8.06 La 432 Element 'SC % F% 0.96 23.01 1.05 24.06 1.14 25.03 1.24 26.04 1.35 27.07 1.46 28.04 1.58 29.02 1.71 30.01 1500 0.01 0.00 0.02 1.97 0.03 3.69 0.04 5.21 0.05 6.58 0.06 7.83 0.07 8.97 0.08 10.03 0.09 11.01 0.1 11.93 0.11 12.79 0.13 14.36 0.14 15.09 0.15 15.78 0.17 17.06 0.19 18.24 0.21 19.33 0.23 20.34 0.25 21.28 0.27 22.17 0.29 23.00 0.32 24.16 Table F1: Continued 1.43 1.43 1.44 1.45 1.46 1.48 1.50 1.52 117.79 8.21 4.57 3.30 2.66 2.26 2.00 1.81 1.66 1.55 1.46 1.32 1.27 1.23 1.16 1.10 1.06 1.02 0.99 0.97 0.95 0.92 115.98 61.95 44.39 35.67 30.45 26.96 24.47 22.61 21.16 20.00 19.05 17.60 17.04 16.55 15.76 15.14 14.66 14.27 13.95 13.69 13.48 13.23 Pb 21.47 21.65 21.87 22.16 22.50 22.88 23.32 23.81 Ce 1788.32 628.33 407.31 313.57 261.76 228.93 206.30 189.80 177.26 167.44 159.57 147.81 143.34 139.55 133.52 129.01 125.57 122.93 120.89 119.32 118.12 116.86 216.06 219.69 223.63 228.29 233.66 239.23 245.45 252.32 Sr 53.72 31.35 23.13 18.84 16.20 14.41 13.11 12.13 11.35 10.73 10.22 9.43 9.12 8.85 8.41 8.06 7.79 7.56 7.37 7.22 7.09 6.93 10.52 10.56 10.61 10.70 10.82 10.95 11.11 11.30 Nd 8.12 5.72 4.57 3.90 3.45 3.13 2.89 2.71 2.56 2.44 2.34 2.18 2.12 2.07 1.98 1.91 1.85 1.80 1.77 1.74 1.71 1.68 2.59 2.61 2.63 2.66 2.70 2.75 2.80 2.85 Sm 241.42 206.71 183.79 167.42 155.07 145.38 137.55 131.07 125.62 120.94 116.89 110.20 107.40 104.88 100.54 96.92 93.86 91.22 88.92 86.91 85.12 82.80 95.35 93.90 92.71 91.63 90.69 89.95 89.34 88.86 Zr 5.38 4.34 3.73 3.32 3.02 2.80 2.62 2.48 2.36 2.27 2.18 2.05 1.99 1.95 1.86 1.80 1.74 1.69 1.65 1.62 1.59 1.55 2.04 2.04 2.04 2.04 2.04 2.05 2.07 2.09 Hf 4709.19 4636.58 4579.46 4530.39 4490.34 4461.92 4441.53 4429.49 Ti 2.50 18675.98 1.86 13903.75 1.52 11385.48 1.31 9819.36 1.17 8745.97 1.07 7961.37 0.99 7361.00 0.93 6885.62 0.88 6499.11 0.84 6178.14 0.81 5906.98 0.75 5473.07 0.73 5296.46 0.71 5140.34 0.68 4876.49 0.65 4661.81 0.63 4483.55 0.61 4333.07 0.60 4204.31 0.59 4092.88 0.58 3995.52 0.56 3870.62 0.80 0.80 0.80 0.80 0.81 0.82 0.83 0.84 Eu 433 Element 'SC % F% 0.96 23.01 1.05 24.06 1.14 25.03 1.24 26.04 1.35 27.07 1.46 28.04 1.58 29.02 1.71 30.01 1500 0.01 0.00 0.02 1.97 0.03 3.69 0.04 5.21 0.05 6.58 0.06 7.83 0.07 8.97 0.08 10.03 0.09 11.01 0.1 11.93 0.11 12.79 0.13 14.36 0.14 15.09 0.15 15.78 0.17 17.06 0.19 18.24 0.21 19.33 0.23 20.34 0.25 21.28 0.27 22.17 0.29 23.00 0.32 24.16 Table F1: Continued 1.61 1.60 1.60 1.59 1.59 1.59 1.60 1.60 2.60 2.40 2.26 2.15 2.05 1.98 1.91 1.86 1.81 1.77 1.73 1.67 1.64 1.61 1.57 1.53 1.50 1.47 1.45 1.43 1.41 1.38 6.45 5.15 4.39 3.89 3.54 3.27 3.06 2.90 2.76 2.65 2.55 2.40 2.33 2.28 2.19 2.11 2.05 2.00 1.95 1.92 1.89 1.85 Yb 2.58 2.59 2.60 2.61 2.64 2.66 2.70 2.74 Gd 5149.60 304.63 196.86 162.03 146.00 137.56 132.92 130.42 129.26 128.98 129.31 131.13 132.44 133.93 137.30 141.03 144.98 149.08 153.27 157.52 161.81 168.29 495.29 516.76 537.96 561.22 586.46 611.35 638.14 666.76 Cl 434 Element 'SC % F% 0.35 25.24 0.38 26.23 0.41 27.17 0.44 28.04 0.48 29.13 0.51 29.90 Table F1: Continued 0.07 0.07 0.07 0.07 0.07 0.08 Cs 3.29 3.30 3.32 3.34 3.38 3.42 Rb 56.29 55.85 55.58 55.44 55.42 55.49 Ba 0.45 0.45 0.45 0.45 0.45 0.45 Th U 0.15 0.15 0.15 0.15 0.15 0.16 5.78 5.58 5.41 5.25 5.07 4.96 Nb 0.53 0.51 0.49 0.48 0.46 0.45 Ta 1741.52 1726.40 1716.51 1710.77 1708.20 1709.32 K 4.42 4.37 4.33 4.30 4.28 4.27 La 435 Element 'SC % F% 0.35 25.24 0.38 26.23 0.41 27.17 0.44 28.04 0.48 29.13 0.51 29.90 Table F1: Continued 13.04 12.90 12.80 12.72 12.67 12.65 Ce 0.90 0.89 0.88 0.87 0.86 0.85 Pb 116.09 115.71 115.62 115.77 116.25 116.78 Sr 6.80 6.70 6.63 6.57 6.51 6.48 Nd 1.65 1.64 1.62 1.61 1.60 1.60 Sm 80.81 79.10 77.60 76.29 74.77 73.77 Zr 1.52 1.49 1.47 1.45 1.43 1.42 Hf 0.55 0.54 0.54 0.53 0.53 0.52 Eu 3765.78 3676.67 3600.16 3533.88 3458.43 3409.79 Ti 436 Element 'SC % F% 0.35 25.24 0.38 26.23 0.41 27.17 0.44 28.04 0.48 29.13 0.51 29.90 Table F1: Continued 1.82 1.79 1.77 1.75 1.74 1.73 Gd 1.36 1.34 1.33 1.31 1.30 1.29 Yb 174.78 181.25 187.71 194.13 202.64 208.97 Cl 437 Element Cs Rb Peridotite 0.0003 0.026 SC 3.5 40 D 0.000575 0.000415 'SC % F% 1075C 0.01 0.00 1.1 72.2 0.43 0.50 2.8 36.8 0.87 1.00 2.9 36.0 1.33 1.50 3.0 36.1 1.8 2.00 3.1 36.5 2.28 2.50 3.1 36.9 2.79 3.00 3.2 37.5 3.31 3.50 3.3 38.1 3.85 4.00 3.3 38.7 4.41 4.50 3.4 39.4 4.99 5.00 3.5 40.1 5.59 5.50 3.5 40.8 6.21 6.00 3.6 41.5 6.85 6.50 3.7 42.3 7.51 7.00 3.7 43.0 8.2 7.50 3.8 43.8 8.92 8.00 3.9 44.7 9.65 8.50 4.0 45.5 10.42 9.00 4.0 46.4 11.21 9.50 4.1 47.3 12.03 10.00 4.2 48.2 1175C 0.01 0.00 1.1 72.2 0.14 0.51 0.9 14.9 0.27 1.00 0.9 12.8 0.41 1.51 0.9 12.2 0.55 2.01 0.9 12.0 9.0 10.7 11.0 11.3 11.5 11.7 12.0 12.2 12.4 12.6 12.9 13.1 13.4 13.6 13.9 14.2 14.4 14.7 15.0 15.3 15.6 9.0 4.1 3.8 3.7 3.7 8942.6 1623.7 1471.5 1434.7 1428.4 1434.3 1446.9 1463.4 1482.7 1504.1 1527.2 1551.6 1577.2 1603.8 1631.4 1660.2 1690.3 1720.6 1752.4 1784.9 1818.4 8942.6 767.5 589.1 529.3 503.8 9.2 1.8 1.6 1.6 1.6 9.2 4.8 4.7 4.7 4.8 4.9 5.0 5.0 5.1 5.2 5.3 5.4 5.5 5.6 5.7 5.8 5.9 6.0 6.1 6.3 6.4 Th U 2 0.006 0.0025 1500 13 5.3 0.00024 0.000814 0.000328 Ba Table F2: Flux melt models with a depleted mantle source. 22.1 16.9 14.0 11.9 10.6 22.1 18.2 15.9 14.4 13.4 12.7 12.1 11.7 11.4 11.2 11.0 10.9 10.8 10.8 10.7 10.7 10.8 10.8 10.9 10.9 11.0 Nb 0.32 8 0.0145 0.4 0.3 0.3 0.2 0.2 0.4 0.3 0.3 0.2 0.2 0.2 0.2 0.2 0.2 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 72976.5 16370.7 14256.6 13613.8 13403.1 72976.5 40952.0 40227.0 40432.3 40890.3 41453.9 42099.8 42782.0 43502.2 44254.3 45034.3 45839.3 46667.6 47517.4 48387.8 49290.8 50225.3 51164.6 52146.7 53145.1 54171.8 141.1 93.1 73.9 63.2 56.8 141.1 117.7 108.6 104.3 102.2 101.2 101.0 101.2 101.8 102.6 103.7 104.8 106.2 107.6 109.1 110.8 112.5 114.3 116.2 118.1 120.2 Ta K La 0.0075 27.7 1 0.05 45000 99 0.0189 0.000441 0.007156 71.4 73.3 74.9 76.4 77.9 71.4 144.6 178.6 199.6 214.4 226.1 236.2 245.1 253.3 261.0 268.4 275.6 282.7 289.7 296.6 303.6 310.7 317.7 324.8 332.1 339.4 Ce 0.49 297 0.00728 438 Element Pb Sr Nd Peridotite 0.029 5.77 0.654 SC 17 3500 130 D 0.000422 0.002348 0.01056 'SC % F% 1075C 0.01 0.00 72.7 2606.2 63.2 0.43 0.50 19.0 2850.3 78.2 0.87 1.00 17.0 2940.0 87.1 1.33 1.50 16.5 3010.0 93.3 1.8 2.00 16.4 3073.3 98.1 2.28 2.50 16.4 3133.9 102.2 2.79 3.00 16.5 3195.8 105.8 3.31 3.50 16.7 3257.0 109.2 3.85 4.00 16.9 3319.2 112.3 4.41 4.50 17.1 3382.5 115.4 4.99 5.00 17.4 3447.0 118.4 5.59 5.50 17.6 3512.7 121.3 6.21 6.00 17.9 3579.6 124.2 6.85 6.50 18.2 3647.9 127.1 7.51 7.00 18.5 3717.3 130.0 8.2 7.50 18.9 3789.1 132.9 8.92 8.00 19.2 3863.1 135.9 9.65 8.50 19.5 3937.3 138.8 10.42 9.00 19.9 4014.6 141.9 11.21 9.50 20.3 4093.1 145.0 12.03 10.00 20.6 4173.7 148.1 1175C 0.01 0.00 72.7 2606.2 63.2 0.14 0.51 9.6 1434.0 53.5 0.27 1.00 7.2 1231.3 49.0 0.41 1.51 6.3 1151.2 46.4 0.55 2.01 6.0 1116.1 44.9 Table F2: Continued 7.2 500 0.0732 99.0 119.8 139.3 157.8 175.1 191.4 207.3 222.5 237.3 251.8 265.9 279.8 293.4 306.9 320.3 333.7 347.2 360.4 373.9 387.3 400.8 99.0 101.2 103.4 105.7 107.9 13.6 16.6 18.8 20.6 22.1 23.4 24.6 25.7 26.7 27.7 28.6 29.5 30.4 31.3 32.1 33.0 33.9 34.7 35.6 36.5 37.3 13.6 12.7 12.2 11.9 11.7 Zr Sm 0.293 35 0.02184 4.5 4.6 4.7 4.8 4.9 4.5 5.8 6.9 7.9 8.8 9.5 10.3 11.0 11.6 12.3 12.9 13.5 14.0 14.6 15.2 15.7 16.3 16.8 17.4 17.9 18.4 0.2 20 0.0444 Hf 3.8 3.6 3.5 3.4 3.3 3.8 4.3 4.8 5.2 5.5 5.8 6.1 6.3 6.6 6.8 7.0 7.3 7.5 7.7 7.9 8.1 8.4 8.6 8.8 9.0 9.3 Eu 0.119 9 0.03146 38263.1 32938.3 29220.3 26302.6 24110.5 38263.1 34866.1 32441.5 30658.1 29344.1 28357.9 27583.6 27001.5 26558.6 26228.8 25992.4 25834.0 25741.8 25706.1 25719.5 25776.7 25874.2 26004.5 26169.9 26363.6 26585.6 9.0 8.9 8.8 8.8 8.8 9.0 10.4 11.7 12.9 14.0 15.0 16.0 16.9 17.8 18.6 19.4 20.3 21.1 21.8 22.6 23.4 24.2 25.0 25.7 26.5 27.3 1.7 1.7 1.8 1.8 1.8 1.7 1.8 2.0 2.1 2.3 2.4 2.6 2.7 2.9 3.0 3.2 3.4 3.5 3.7 3.9 4.1 4.2 4.4 4.6 4.8 5.0 Gd Yb 996 0.467 0.402 20000 30 10 0.02608 0.052408 0.23624 Ti 5149.6 3297.4 3181.5 3170.3 3190.9 5149.6 8973.4 9483.4 9788.4 10033.7 10255.4 10474.2 10686.6 10899.4 11114.2 11331.5 11552.1 11776.0 12003.6 12235.0 12473.5 12719.2 12965.2 13221.5 13481.4 13748.0 4 11500 0.001 Cl 439 Element 'SC % F% 0.7 2.52 0.85 3.01 1.01 3.52 1.17 4.01 1.34 4.52 1.51 5.01 1.69 5.50 1.88 6.01 2.07 6.50 2.27 7.00 2.48 7.51 2.69 8.00 2.92 8.51 3.15 9.01 3.38 9.50 3.63 10.00 Table F2: Continued Cs 1.0 1.0 1.0 1.0 1.0 1.1 1.1 1.1 1.1 1.1 1.2 1.2 1.2 1.2 1.2 1.3 11.9 12.0 12.1 12.2 12.3 12.5 12.7 12.8 13.0 13.3 13.5 13.7 14.0 14.2 14.4 14.7 Rb 490.8 485.0 483.0 483.6 486.0 489.5 494.2 499.7 505.8 512.5 519.8 527.4 535.8 544.4 553.0 562.4 Ba Th 3.7 3.8 3.8 3.9 3.9 4.0 4.0 4.1 4.2 4.3 4.3 4.4 4.5 4.6 4.7 4.7 U 1.6 1.6 1.6 1.6 1.6 1.6 1.7 1.7 1.7 1.7 1.8 1.8 1.8 1.9 1.9 1.9 9.5 8.7 8.1 7.6 7.2 6.8 6.5 6.3 6.1 5.9 5.8 5.6 5.5 5.4 5.4 5.3 Nb Ta 0.2 0.2 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 0.1 13361.1 13409.8 13515.0 13652.3 13819.5 14000.6 14202.2 14422.2 14646.8 14886.3 15139.8 15394.4 15673.6 15952.5 16230.7 16532.0 K 52.4 49.4 47.2 45.7 44.5 43.6 43.0 42.5 42.2 42.1 42.0 42.0 42.1 42.3 42.5 42.8 La 79.4 80.9 82.5 84.0 85.6 87.2 88.8 90.6 92.3 94.0 95.9 97.7 99.6 101.6 103.5 105.6 Ce 440 Element 'SC % F% 0.7 2.52 0.85 3.01 1.01 3.52 1.17 4.01 1.34 4.52 1.51 5.01 1.69 5.50 1.88 6.01 2.07 6.50 2.27 7.00 2.48 7.51 2.69 8.00 2.92 8.51 3.15 9.01 3.38 9.50 3.63 10.00 Pb Table F2: Continued 5.8 5.7 5.6 5.6 5.6 5.7 5.7 5.8 5.8 5.9 6.0 6.0 6.1 6.2 6.3 6.4 1099.5 1094.1 1095.0 1100.3 1108.8 1119.3 1131.9 1146.4 1161.6 1178.3 1196.3 1214.6 1234.9 1255.4 1275.9 1298.3 Sr 43.9 43.4 43.2 43.1 43.2 43.4 43.7 44.0 44.5 45.0 45.5 46.1 46.7 47.4 48.1 48.8 Nd 11.5 11.5 11.4 11.4 11.5 11.5 11.6 11.7 11.8 12.0 12.1 12.3 12.4 12.6 12.8 13.0 Sm 110.3 112.6 115.0 117.4 119.9 122.4 125.0 127.7 130.4 133.1 136.0 138.9 141.9 145.0 148.0 151.2 Zr Hf 4.9 5.0 5.1 5.2 5.3 5.4 5.5 5.6 5.7 5.8 5.9 6.1 6.2 6.3 6.4 6.6 Eu 3.2 3.2 3.2 3.2 3.2 3.2 3.2 3.2 3.2 3.2 3.3 3.3 3.3 3.4 3.4 3.4 22300.9 20879.8 19670.0 18692.1 17843.1 17143.3 16528.1 15988.3 15537.5 15139.6 14789.7 14496.3 14227.7 14004.3 13818.1 13650.8 Ti 8.8 8.9 8.9 9.0 9.1 9.1 9.2 9.3 9.5 9.6 9.7 9.8 10.0 10.1 10.3 10.5 Gd Yb 1.8 1.9 1.9 1.9 2.0 2.0 2.0 2.1 2.1 2.1 2.2 2.2 2.3 2.3 2.4 2.4 3226.7 3269.1 3318.2 3369.4 3425.0 3481.3 3541.2 3604.5 3667.7 3734.0 3803.3 3872.1 3946.9 4021.2 4094.9 4174.4 Cl 441