Substellar Atmospheres II. Dust, Clouds, Meteorology PHY 688, Lecture 19 Mar 11, 2009 Outline • Review of previous lecture – substellar atmospheres: opacity, LTE, chemical species, metallicity • Dust, Clouds, Meteorology Mar 11, 2009 PHY 688, Lecture 19 2 Previously in PHY 688… Mar 11, 2009 PHY 688, Lecture 19 3 Opacity of M/L/T Dwarfs is Non-Grey (VB10, M8) Mar 11, 2009 PHY 688, Lecture 19 (Allard & Hausschildt 1995) 4 Neutral Atoms and Molecules Are Strong Wavelength-Dependent Absorbers Mar 11, 2009 PHY 688, Lecture 19 5 From Lecture 3: Radiative Transfer The optical depth τλ accounts for interaction between photospheric matter and radiation field. Mar 11, 2009 PHY 688, Lecture 19 6 Non-Grey Opacities • Exact interaction between radiation field and matter is complicated and often intractable – vast number of excitable atomic and molecular transitions • Assume local thermodynamic equilibrium (LTE) – radiation and matter characterized by the same temperature T – gas: Maxwell-Boltzmann, radiation: Planck Mar 11, 2009 PHY 688, Lecture 19 7 Non-Grey Opacities, LTE • In LTE, level populations completely determined by T from the Boltzmann and Saha equations Z i = # gie"E i kT i • Need “only” find all important transitions in dominant atoms and molecules – also a formidable problem ! – H2O alone has hundreds millions of lines(!) Mar 11, 2009 PHY 688, Lecture 19 8 Infrared Opacities at Late-L: Dominated by Molecules Mar 11, 2009 PHY 688, Lecture 19 (Burrows et al. 2001) 9 Chemical Abundances and Species Mar 11, 2009 PHY 688, Lecture 19 (Burrows et al. 2001) 10 Solar Metallicity vs. Metal-Poor Spectra • the depletion of metals changes the ingredients for atmospheric chemistry • thin condensate clouds, strong metal hydrides, strong H2O Mar 11, 2009 PHY 688, Lecture 19 11 (Burgasser et al. 2006) With Decreasing Metallicity • • • • • double-metal species (e.g., TiO) disappear metal-hydrides survive preferentially H– continuum dominant at <1.1 micron CIA H2 dominant over 1.1–4 micron deeper layers revealed Teff = 3000 K – stronger metal-hydrides – pressure-broadened atomic absorbers Mar 11, 2009 PHY 688, Lecture 19 12 (Allard et al 1997) Validity of LTE Assumption Depends on Fate of Excited Atom/Molecule • bound-bound case: – if excited state is collisionally de-excited • photon energy is absorbed by the gas • absorption couples radiation to matter through collisions • if absorption dominates opacity, LTE approximation is valid – if excited state is radiatively de-excited • original photon is scattered; its energy radiated away • no collisions, weak dependence on temperature of matter • transitions have finite energy width; re-emission at a low absorption probability wavelength can lead to further decoupling of radiation and matter • if scattering dominates opacity, LTE approximation is not valid • bound-free and free-free (continuum) cases, Thomson, Rayleigh scattering – unimportant at low T, high P Mar 11, 2009 PHY 688, Lecture 19 13 Complications with Atmospheric Modeling • departure from LTE due to: – pressure broadening (Na I, K I; van der Waals), interaction potentials (H2) – micro-turbulent velocity broadening • generally small; 1–2 km s–1 • formation of large grains; condensation of grains into clouds – grain sedimentation rate – cloud distribution and variations (“weather”) • chemistry, especially non-equilibrium mixing • depth of convection zone (10–3 < τ < 1) Mar 11, 2009 PHY 688, Lecture 19 14 Outline • Review of previous lecture – substellar atmospheres: opacity, LTE, chemical species, metallicity • Dust, Clouds, Meteorology Mar 11, 2009 PHY 688, Lecture 19 15 The Optical to IR SEDs of UCDs Mar 11, 2009 (Cushing et al. 2006; Marley & Leggett 2008) PHY 688, Lecture 19 16 UCD Spectral Classification • largely based on strengths of atomic or molecular absorbers • e.g.: – CaH and TiO indices for M dwarfs – CrH, Rb I, Cs I for L dwarfs, among others CaH TiO TiO M9 (latest M dwarf) L0 (earliest L dwarf) CrH Rb L2 dwarf (like GD 165B) Cs L8 (latest L dwarf) T6.5 dwarf (Gl 229B) Mar 11, 2009 (Kirkpatrick et al. 1999)19 PHY 688, Lecture 17 But Atoms and Simple Molecules Do Not Make Up the Whole Picture forsterite (Mg2SiO4) ruby corundum (Al2O3) Mar 11, 2009 PHY 688, Lecture 19 18 (Burrows et al. 2001) Simplified Chemical Picture • As gas temperature of a (brown) dwarf drops, atoms: – first favor an ionized state • e.g., Ca II, Fe II in Sun – then favor a neutral state • e.g., Na I, K I in M/L/T dwarfs – then form molecules • e.g, H2O, TiO, FeH, CH4 in M/L/T dwarfs – then condense into a solid or liquid • e.g., Mg2SiO4, Al2O3 in L/T dwarfs • dust clouds • • More refractory elements tend to condense first Exact sequence of molecule and condensate formation depends on – gas pressure – metallicity – turbulent mixing from warmer or colder layers, etc Mar 11, 2009 PHY 688, Lecture 19 19 Preview of Dust Cloud Chemistry (Burrows et al. 2001) Mar 11, 2009 PHY 688, Lecture 19 20 Example: the M/L Dwarf Transition • • • Teff ~ 2300 K first TiO and then VO weaken at early L and then disappear by mid-L TiO converts into TiO2 or condenses into CaTiO3 (pervoskite) – or into other Ti-bearing molecules • • VO, less refractory, then converts into VO2 or into solid VO/Ti-bearing condensate Al, Ca, Si similarly removed – no directly observable effect – however, if present would have bound and removed K I from atmosphere • K I, Na I left as dominant absorbers over 4000–10000 Å by mid-L Mar 11, 2009 PHY 688, Lecture 19 KI (Kirkpatrick 2005) Wavelength (Å) 21 Dust in Substellar Atmospheres • Once dust condenses, it may: – remain suspended at level of formation – sediment to deeper, optically thick layers • Either can occur, depending on temperature, surface gravity • Presence of suspended dust (clouds) is required to explain very red colors of L dwarfs Mar 11, 2009 PHY 688, Lecture 19 22 From Lecture 8: Near-IR CMD of Stars and Brown Dwarfs F–K M L T Mar 11, 2009 PHY 688, Lecture 19 23 (Kirkpatrick 2005) From Lecture 3: Extinction and Optical Depth • Light passing through a medium can be: – transmitted, absorbed, scattered • dLν(s) = –κν ρ Lν ds = –L dτν – medium opacity κν [cm2 g–1] – optical depth τν = κν ρs [unitless] • Lν = Lν,0e–τ = Lν,0e–κρs =Lν,0e–s/l – photon mean free path: lν = (κν ρ)–1 = s/τν [cm] • If there is extinction along the line of sight, apparent magnitude mν is attenuated by Aν = 2.5 lg (Fν,0/Fν) = 2.5 lg(e)τν = 0.43τν mag – reddening between two frequencies (ν1, ν2) or wavelengths is defined as Eν1,ν2 = mν1 – mν2 – (mν1 – mν2)0 [mag] – (mν1 – mν2)0 is the intrinsic color of the star AV / E(B–V) ≈ 3.0 Mar 11, 2009 PHY 688, Lecture 19 24 From Lecture 3: Interstellar Extinction Law extinction is highest at ~100 nm = 0.1 µm decreases at longer wavelengths Mar 11, 2009 PHY 688, Lecture 19 25 L Dwarfs Are Dusty Objects M L • models that incorporate suspended dust (DUSTY) can reproduce L dwarf colors T DUSTY models (dust remains suspended) • but these same models do not work for T dwarfs COND models (dust is removed) – late T’s better fit by COND models (dust removed upon formation) Mar 11, 2009 PHY 688, Lecture 19 26 (Baraffe et al. 2003) Detailed Dust Cloud Chemistry (Burrows et al. 2001) Mar 11, 2009 PHY 688, Lecture 19 27 Cloud Formation: Meteorology 101 • A cloud appears where adiabatic cooling of an air parcel in an upward draft results in saturation • Further cooling condenses vapor in excess of saturation onto cloud particles • The particles grow through condensation and coalescence until their sedimentation velocities exceed the updraft speed and then fall out of the parcel • Why is there convection in a supposedly radiative region (the atmosphere)??? Mar 11, 2009 PHY 688, Lecture 19 28 Radiation, Convection, and Conduction in Earth’s Atmosphere Mar 11, 2009 PHY 688, Lecture 19 29 Cloud Formation: Meteorology 102 Mar 11, 2009 PHY 688, Lecture 19 30 Sedimentation • Cloud condensates will settle under gravity to a level where there is enough upward convective (turbulent) motion to keep them afloat. • Level and vertical extent of clouds depend on – droplet size (i.e., mass) – convective velocity, mixing efficiency – K: eddy diffusion coefficient; qt: mixing ratio; w*: convecitve velocity scale, frain: sedimentation efficiency Mar 11, 2009 PHY 688, Lecture 19 31 Condensate Clouds (AM01 Baseline Models) L dwarf Mar 11, 2009 T dwarf PHY 688, Lecture 19 giant planet (Ackerman & Marley 2001) 32