II. MICROWAVE SPECTROSCOPY Academic and Research Staff Dr. T. E. McEnally, Jr. Prof. M. W. P. Strandberg Prof. R. L. Kyhl J. G. Ingersoll J. D. Kierstead Graduate Students A. M. K. Maul S. R. Reznek B. N. Yung J. U. Free R. M. Langdon, Jr. J. M. Ditz R. L. Espino L. R. Fox VELOCITY SURFACES IN LITHIUM NIOBATE The method for determining an analytical approximation for the velocity of sound sur1 faces for previously reported crystals has been applied to lithium niobate. This method expresses an approximation to each of the three surfaces as a sum over functions of the appropriate symmetries. The method determines the coefficients in the sum by a leastsquares fit to the exact surface. Lithium niobate has the symmetry of quartz or sapphire. The basis functions are those listed in Quarterly Progress Report No. 84. Table II-1 ). ( = 1, 2, 3 for each of the CW(, lists the coefficients in the expansion V(0, 4) = three surfaces.) Table II-1. Coefficients C n . =3 -=2 =1 n 1.4484 1 .7920 .8610 2 -.003786 -.02802 .07939 3 -.06458 -.01514 .04267 4 .04947 -.04637 -.001434 5 .04148 -.03404 -.004503 6 .02470 -.02417 .1117 X 10- 7 8 -. 1190 x lo6 .009004 6 -.008396 -.001100 -.006630 -. 6717 X 10- 8 -.001841 9 10 .006779 .70618 X 10- 11 .0003993 -.0007653 12 .0007973 -.0007792 13 -89 .1125 X 10- 8 -.8639 X 10 14 .1676 X 10- 10 -. 1638 X 10- 10 8 -.006694 .3242 X 108 -. 9156 X 10- 9 .0004249 -.0002178 9 -9 -.2138 X 10 .1692 X 10- 1Z SThis work was supported by the Joint Services Electronics Programs (U.S. Army, U.S. Navy, and U.S. Air Force) under Contract DA 28-043-AMC-02536(E). QPR No. 85 5 LITHIUM NIOBATE 260 270 280 . TRUE 340 I~U - 350 180 0 170 10 .60 160 20 084 150 30 1.08 140 40 1.32 130 50 1.56 120 60 I10 100 Fig. II-1. QPR No. 85 1.80 90 70 80 True and approximate values for the velocity of sound in Lithium Niobate. 260 LITHIUM NIOBATE 0= 240 270 280 290 250 * TRUE 240 300 x APPROXIMATE \ 230 310 220 320 / 330 210 340 200 .600 1 160 20 84 150 30 1.08 40 140 50 130 1.56 60 120 110 100 1.80 90 Fig. II-1. QPR No. 85 70 80 Continued. LITHIUM NIOBATE 260 270 280 . TRUE 340 350 0 10 0.60 20 8784 1.08 1.32 40 \50 1.56 60 70 1.80 100 Fig. II-1. QPR No. 85 90 80 Continued. 30 LITHIUM NIOBATE 260 270 280 9 TRUE 350 100 Fig. II-1. QPR No. 85 90 Continued. LITHIUM NIOBATE 260 270 280 . TRUE 340 350 0 1O 00 Fig. II-1. QPR No. 85 90 80 Continued. LITHIUM NIOBATE 270 260 TRUE 280 240 300 x APPROXIMATE 230 310 220 320 210 330 200 340 190 180 350 - - - 170 10 O/60 160 20 0.84 150 1.0 / 30 1.08 \' 130 50 1.56 120 60 110 100 1.80 90 Fig. II-1. QPR No. 85 70 80 Concluded. (II. MICROWAVE SPECTROSCOPY) Figure II-1 shows the surfaces computed exactly and those computed by using the analytical approximations. S. R. Reznek References 1. S. R. Reznek, "Expansion of Velocity Surfaces in Spherical Harmonics," Quarterly Progress Report No. 84, Research Laboratory of Electronics, M.I.T., January 15, 1967, pp. 17-26. QPR No. 85