Inorganic Faculty with Research Interests Presentation to 2/c Chemistry Majors February 22, 2016 Assoc. Prof. Wayne Pearson X-ray Crystallographic Studies of Small Molecules Possible Student Projects: 1. Identification of crystalline by-products resulting from the synthesis of sapphire in a cryolite flux ( Experimental project involving solid state syntheses, XRF, and SCXRD ) 2. Use of ionized form factors in the determination of crystal structures ( Computational project investigating a novel approach to the determination of routine crystal structures ) Assoc. Prof. William Heuer Overview: Synthetic Inorganic chemistry. Preparation and study of metal complexes with interesting photophysical and redox properties. Characterization by NMR, IR, UV-Vis, Luminescence, MALDI-MS, Cyclic Voltammetry, X-Ray diffraction (with Prof. Pearson). Active projects: •Synthesis and photophysical studies of mono- and bi-metallic transition metal complexes with a-diimmine-dithiolene ligands for solar cell applications. •Synthesis and characterization of new mixed-ligand Pt(II) complexes. Solidstate structure (x-ray crystallography), luminescence studies, aggregation in solution, potential sensor properties & interaction with DNA. •Synthesis and Ligand-exchange reactions of soluble colloidal semiconductor nanocrystals and development of solution-based methods for fabrication of thin-film solar cells. Assoc. Prof. Joseph F. Lomax • Collaboration with the National Gallery of Art and Dr. Suzanne Q. Lomax • Investigating historical modern organic pigments •Synthesis • Analytical • IR and Raman • NMR • MALDI • Research project or Capstone • Collaboration with Prof. Peter Brereton, Physics Department • Synthesis of ‘monolayer’ transition metal dichalcogenides • Similar to graphene, monolayer graphite • Potential optical computer components • Interactions with organic bases • Occurs in layered transition metal dichalcogenides • May give insight into the intercalation reaction Assoc. Prof. Amy MacArthur Research interests: • development of inexpensive catalysts (Co, Cu, and Ni) to replace traditional, expensive Pd, Pt, Rh, and Ir catalysts • development of catalytic reactions with two catalysts operating simultaneously in solution (tandem catalysis) 1/C Qualifies Brice Clairmont for current biochemresearch concentration! student Hydrodehalogenation of ArCl Cyanation of ArCl Cannon, K. A.; Geuther, M. E.; Kelly, C. K.; Lin, S.; MacArthur, A. H. R. Organometallics 2011, 30 (15), 4067-4073 Coughlin, M. M.; Kelly, C. K.; Lin, S.; MacArthur, A. H. R. Organometallics 2013, 32 (12), 3537-3543