New Mexico Bureauof Mines and Mineral Resources Open File Report # 307 Column Leach Testing of Gold Ore from the Ortiz goldmine: The effect of surfactant additions to the leaching solution. Michael J. Harris Metallurgist New Mexico Bureauof Mines and Mineral Resources September 1987 Abstract Five column leaching tests were carried out to determine the ppn) to effects of adding various surfactants (at a level15 of the cyanide leaching solution, on the extraction of gold from ore taken from the Ortiz gold mine, located near Cerrillos, N.M. Based on this significant ore. test effect work on the surfactant over all the additions extraction of did gold not from have the a Introduction This open file report is based on work carried out for the Ortiz to February 1985. gold mine during the period of October 1984 The Ortiz gold the materials mine (owned needed for by this Consolidated Gold Fields) provided study. Summary 1. The ore as received had been crushed to 100 percent parsing 1 inch. The material was moderately damp with an 8.3 percent moisture. Triplicate fire assays yielded a head analysis of 0.02 troy ounces of gold per ton of ore. 2. The cyanide leaching solution contained 1 gram per liter sodium cyanide at a pH 11.8 of with a residual gold concentration of 0.086 ppm (0.0025 oz/ton of solution). 3. Five column leaching tests were carried out to test the effects of various surfactants on the extraction of gold. The surfactants Column 1 2 3 4 5 tested and the extraction Surfactant None 1.0602 Nalco 2DA-375 Nalco 7811-V1179 Nalco 3DA-78s Nalco 8801-B3159 results are shown Gold Extracted. (mg Au/ Kg of ore) 1.0181 1.0320 1.0350 1.0502 below: 4. The extraction rate of gold as a function of effluent flow rate was determined to be a constant during the initial portion of each of the five column leaching tests. This constant value was 5 . 0 0 mg of gold per liter of leaching solution. 5. The quantity of gold dissolved in solution was found to peak early in the test and declined there after. This peak in the concentration to occur the 6. of dissolved between column the 5th gold and in 8th the leaching liter of solution effluent for was each found of tests. In each of the fivetests, 90 percent (or better) of the gold was extracted with the first 2 0 liters of leaching solution. 7. Based on these results the surfactant additions had little if any, effect on the extraction of the gold at a surfactart addition of 15 ppm. Discussion Ore Description: The gold ore used in this test work was provided by the Ortiz gold mine. The sample consisted of about 750 pounds of wet material contained in55a gallon drum. A head sample was split out €rom the bulk sample for prelimicary analysis. Tests were carried out on the head sample to determine gold content, percent moisture and particle size distribution. The results are shown below: Gold Content (triplicate fire assay) 0.02 oz/ton Percent Moisture (air dry) 8.3 Particle Size Distribution Cumulative Passing Percent Weight Mesh Tyler 1 inch 3/4 inch 1/2 inch 4 m 10 m 20 m 28 m 35 m 48 m 65 m 100.0 99.7 91.7 45.6 30.1 20.7 17.2 13.3 9.8 5.0 0.9 100 rn Leaching Solution: The leaching solution as provided by Ortiz consisted of approximately 110 gallons of one sodium cyanide gram per with a residual gold solution, 11.8, pH concentration of 0.086 ppm ( 0 , 0 0 2 5 oz/ton of solution). solution was liter modified for the test work by the addition Tfis of the surfactants, which werealso provided by Ortiz. Each surfe.ctant was added at a rate of 15 ppm by weight. The surfactant w e d in each test is shown below: Test 1 2 3 4 5 Surfactant None (control) Nalco 2DA-375 Nalco 7811-V1179 Nalco 3DA-785 Nalco 8801-B3159 Bulk samples of each five gallons of the leaching cyanide solution solution were with prepared enough by mixing surfactant to make the designated1 5 ppm concentration. The bulk solutions were stored needed in each stoppered five gallon containers and used as day. Column Desoription: Five columns were used in this test work. Each column consisted of a ten foot long, 6 inch ID, schedule 40 PVC pipe. On the bottom of each column6 a inch schedule 40 PVC cap was installed to contain the in orethe column. Each cap was drilled and fitted with a short length of PVC 1/2 inch tubing to allow the leaching solution to flow out of the column. Inside the cap a small wad of glass wool was placed over the exit hole. The glass wool was held in place by a section of screen which was laid over the gilledthen in and wool place with PVC solvent. This arrangement allowed the solution to flow The out columns of the were floor and the floor tailing column mounted tops with of while on the metal a retaining wooden 14 frame inches columns straps the were and ore particle?. above the to the sec0r.d secured screws. 55 gallor drum Column Loading Procedure: Ore was taken from the by shovelfuls and placed sequentially into one of five numbered buckets (one bucket for each column). After every three rcunds a shovelful was placed into a sixth bucket to serve as a head sample, When the ore buckets were filled they were weighed and the contents were loaded into the respective columns. After loading the ore contained in the columns varied in height between 7.5 and 8 feet. Leaching procedure: Approximately two liters of leaching solution was introduced into each column each day. The solutions were held in two liter flasks which were suspended above the columns in a rack which was attached to the ceiling. The solution flowed out of the flask through tubing and into the column. The flow rate was regulated by a screw clamp on the tubing. By tightening the clamp the solution flow rate was decreased. Each day the flasks were filled and the column effluents were collected. Each effluent sample was weighed and portions vere taken for cyanide, pH and dissolved gold determinations. The bulk effluent sample was then disposed of after the residuF.1 cyanide had been destroyed with sodium The columns were leached for 42 days, hypochlorite. drained for two days, washed with two liters of water, drained fordays, five waphed, drained for five days and washed a final time. The columnr were then drained for seven days after which the leached residues were removed and air dried for several days. The residues were then split into quarters and a fire assay sample was split from each quarter, the bulk residues were then stored. Test Results: The test results are summarized in Table I and out Figures 1-4. A complete listing of the leaching test data for each column is From these presented results there in the would appendix. seem to be little to differentiate these tests. Figure 1 shows gold extraction (based on percent) as a function of effluent flow. The data are grouped in difference a at Figure 2 shows narrow any band without 8 percent than an more time. gold extraction (in milligrams) as a function of 15 liters of each test. The most effluent flow for the initial interesting feature of these results is the linear aspect of the extraction between 2 liters and 11 liters. A least squares fit of these results gave an equation =of5.00 y (X) coefficient of fit of 0.98. good, again indicating - 11.20 rlith a The coefficient of fit is very that there was little difference between the five tests. The slope of the line gives a value for tk.e rate of extraction during the initial stage of the test. The value of 5 . 0 0 mg of gold per liter of solution is equivalert to 0.146 oz of gold per ton of solution. Figure 3 shows the concentration of dissolved gold as a furction of effluent flow rate.Of primary interest is that the amcunt of and gold then in solution declined reached gradually a peak through very out early the rest in the of test the This peak occurred between 5 and 8 liters total effluent flow, which corresponds to between 6.7 and 10.8 gallons effluent per work time. square . foot The only real difference in these results is shown in 4Figure which presents total gold extraction (mg) a as function of effluent flow. Yet even this difference is only a function of the weight of ore placed in the column. Column 4 yielded the lowest overall extraction and had the lowest total weight of ore. Column 5 yielded the highest overall extraction and had the highest total weight. The ratio of gold extracted (mg) to total weight of ore was calculated to overcome the effect of different weights of ore in each test. The results are shown below: Column Gold Surfactant Extracted of ore) ( m g Au/ Kg None 1.0181 2DA-375 Nalco 7811-Vl179 Nalco 1.0320 3DA-78s Nalco Nalco 8801-B3159 1.0502 1.0350 1.0502 These results vary (lowest to highest) by only 3 percent, c.gain indicating very little difference in the test results, Finally using the total amount o f gold calculate a head Column 1 2 3 assay gave the dissolved following in each results. Calculated Head (oz/ton) 0.0306 0.0297 0.0301 0.0302 0.0306 Assay test to the These results 0.02 oz/ton, are somewhat higher than the fire assay result but still within experimental limits. Therefore it is the conclusion of this study that the use of the various significantly surfactants effect the Ortiz ore. the at a ppm did not level1 5 of extraction of gold from this sample of of Summary of Table 1 Column Leaching Results Column Test Number 1 2 3 4 5 62.007 59.185 61.569 58.293 64.038 Effluent flow (liters) 8 4 . 2 72.2 80.8 77.7 79 .O Cyanide consumed (gms) 28.698 27.044 28.396 27.941 28.766 Feed Weight (wet, kg) 64.004 62.943 64.601 60.985 66.024 Feed Weight (dry, kg) 59.110 58.130 59.661 56.322 60.975 Gold Extracted (mg) Gold Extraction mg Au/liter mg Au/kg of ore Calculated Head (oz/ton) 0.7371 1.0502 0.8197 1.0181 0.0306 0 .00.02 0.09 3 0.7 0 31 0 32 06 0.00 0.00 0.00 0.00 trace trace trace trace 0.7612 1.0320 0.7495 1.0350 0.8103 1.0502 0.00 trace trace trace trace trace trace Assay Leached Residue Assays (oz/ton) 1 2 3 4 trace less than 0.01 oz/ton 0.02 0.00 0.02 trace trace I ! 11 i.l a 3 a 0 0 I- I Figure 3 D i s s o l v e d Gold C o n c e n t r a t i o n a s F u n c t i ooT nfo t aElf f l u e n t '3r a A I 0 0 0 0 2 3 4 5 I i 0 V 0 " 0 0 1 0 I I I 2 3 4 5 6 FTFL.!!FNT 7 8 9 FI O W (Ii t o r s ) IO II I2 13 14 I 15 64- 63 6261 - 60 - - 59CT E z 58 - v 0 - 57Q E tX W 0 56- 55 - _I 0 w 54- 5352 V 3 4 0 5 0 515049 1 0 I IO I 20 I I I 30 40 50 EFFLUENT FLOW ( l i t e r s ) I I 60 70 APPENDIX I Column 1 - Control sumrnvy of Leaching Data Date . 11/ 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 12/ 1 2 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 21 26 1/2/05 (g) SampleSampleWelght NO. Individual cumulative 803 2618 4260 6570 Extraction Gold Gold (ug) (ppm) Individual Cumulative 53694 55147 55014 56543 57201 57604 57949 93223 58419 58790 550 625 690 665 670 700 750 725 760 700 392 255 209 134 289 198 40 97 74 59102 59437 59616 59780 GO069 60267 60307 60404 60178 60536 800 2176 1959 1492 960 2220 2208 1324 1933 2482 1930 39485 41444 42936 43896 46116 48324 49648 51581 54063 55993 0.13 0.14 0.14 0.13 0.09 0.03 0.05 0.03 0.03 131 132 133 134 135 136 137 138 139 140 2041 2026 2008 2106 2002 1671 2328 58034 0.04 "60 0.02 0.04 0.06 2391 2070 62068 64174 66176 67847 70175 71981 74372 76442 111 142 143 141 2092 1809 2166 1709 78534 80343 82509 81218 0.05 0.05 0.04 0.00 1806 1094 1149 1312 1219 919 1177 2046 1169 1453 667 729 658 403 345 274 196 377 121 122 123 124 125 126 127 128 129 130 118 180 0.8 0.8 119 120 117 1601 200 300 375 425 445 475 19736 21552 23457 25429 27648 29088 31385 33490 35450 37309 116 25 402 2217 9770 21320 28500 36180 41846 45971 49364 52025 2086 1816 1905 1972 2269 1390 2297 2105 1960 1859 111 112 113 114 115 8Offi 787 1779 20 402 1815 7553 11550 7180 7688 5658 4125 3393 2661 9881 11832 13482 15603 17650 102 103 104 105 106 107 108 109 110 M <0.5 1.0 4.6 5.0 5.0 4.1 2.9 2.5 1.6 1.3 803 1815 1642 2310 1436 1875 1951 1650 2121 2047 101 Effluent Cyanide (w) per liter Consumed Cumulative 0.35 0.37 0.29 0.29 0.15 0.13 0.10 0.20 0.18 0.06 .05 .05 .05 .05 .04 58 775 770 705 725 660 750 810 795 805 126 120 60618 60658 60738 60864 60984 e4 61OG8 780 116 90 120 83 61184 61274 61394 61477 8h) 860 875 865 105 235 260 61582 61817 62077 62077 775 810 300 75 82 40 80 - 850 800 825 800 800 707 2566 4167 6061 7210 8522 9711 10690 11067 13913 @I 8.1 8.1 8.2 8.2 8.4 8.9 9.3 9.5 9.8 10.1 14852 15533 16121 16785 17531 17951 10525 19104 19574 20132 10.5 10.5 10.0 10.6 10.5 751 331 367 509 376 20567 21m 21351 21634 22245 22996 23327 23694 21203 24579 10.7 10.7 10.5 10.5 10.4 10.3 10.1 10.5 10.4 10.5 306 405 351 421 400 360 466 253 2'39 279 21805 25290 25641 26062 26,162 26030 27236 27519 27848 281 27 10.6 10.6 10.6 10.6 10.7 471 28590 9.9 10.1 9.7 9.4 939 681 591 661 719 417 574 579 470 558 435 "1 343 283 611 10.0 10.1 10.3 10.4 10.5 10.8 10.5 10.5 10.5 10.5 ,diumn 2 smry 11f 8 9 10 11 12 13 14 15 16 17 18 19 21 20 22 23 24 26 25 27 28 29 30 12/ 1 2 4 5 6 7 8 9 15 16 17 18 19 21 26 1/2/05 246 1950 3244 5165 6935 7999 8616 10899 11752 13503 a 5 - SurTactant L u ~ - 3 / 5 of Leaching Data 123 852 3235 9605 9558 6171 3208 201 ?02 203 201 205 206 207 208 209 210 246 1704 1294 1921 1770 1064 617 2283 853 1751 211 212 213 214 215 216 217 218 219 220 2230 760 2799 1173 845 1715 2080 799 2096 13503 15733 16493 19292 20465 21310 23025 25105 25904 280M) 1.6 0.87 0.57 0.41 0.40 0.25 0.17 0.25 0.24 3560 662 1595 481 338 429 354 200 503 221 222 223 224 225 226 227 228 229 230 2000 2292 704 835 2093 2096 1865 1905 1880 2190 30000 32292 32996 33831 35924 38020 39885 41790 43670 45860 0.21 0.12 0.12 0.14 0.12 0.11 0.07 0.09 0.03 0.05 4 20 275 84 117 251 231 130 171 57 231 232 233 234 235 236 237 238 239 240 1272 2235 2020 1636 2017 2294 614 2629 1968 1933 47132 49367 51387 53023 55070 57364 57978 60607 62575 €4408 0.05 0.05 0.07 0.08 0.07 0.06 0.05 0.05 0.04 0.04 63 112 141 131 143 138 31 241 24 2 243 214 2363 66771 68617 70637 72196 0.05 0.05 0.03 0.00 - 1846 2020 1559 <O. 5 2.5 5.0 5.4 5.8 5.2 3.9 2.8 2.2 - 8904 2380 3052 ” 110 131 79 73 118 92 61 123 975 4210 13815 23373 29544 32752 41656 44044 47896 15 20 30 90 175 200 225 NO 280 310 242 1670 1259 1718 J1 G o 851 479 1598 GI 4 12011 ; :12 1912 3167 4C)l 5 6375 7226 7705 3303 9917 11125 8.0 0. 1 0.3 8.4 11.4 8.5 0.8 9.1 9.6 9.9 47896 51464 52126 53721 54202 51540 54969 55323 55523 56026 - - 475 410 595 550 550 610 625 605 650 1171 448 1134 528 300 669 780 316 734 114% 1478G 15155 16235 16551 17205 3*7 10.1 10.3 10.3 10.3 10.4 10.6 10.4 10.7 56446 56721 56805 56922 57173 57404 57534 57705 57762 57872 750 760 650 57 5 675 650 7 20 OW 7Eo 775 500 550 246 355 680 734 522 301 414 49 3 17705 10335 18501 18336 19616 20350 20872 21253 21667 22160 10.4 10.5 10.3 10.5 10.4 10.3 10.4 10.4 10.3 10.4 57935 58047 58189 58319 58462 58600 58631 58762 58841 58914 750 725 790 760 725 780 550 805 815 318 614 424 393 563 504 276 513 364 312 22478 23092 23516 23909 21472 24976 25252 25765 26129 26441 10.4 10.5 59032 59124 59185 59185 745 770 325 70 GO3 27044 830 11125 12296 12744 J 3878 ” 10.5 10.5 10.6 10.7 10.1 10.4 10.4 10.5 10.1 9.9 9.8 9.1 - Surfactant 7811-VU79 summary of Leaching Data column 3 7 - D3 tC e No. Sample Wei ht ( ) Individual &rulittive Gold (ppm) 1017 711 604 042 130114 6230 675 406 704 497 531 0.10 0.19 37005 39500 40920 42343 44544 46735 48654 49822 52220 53323 0.20 0.17 0.13 0.16 0.13 0.12 0.09 314 200 105 220 286 263 173 55415 57503 59191 61537 63264 65355 67443 63422 70891 73152 0.07 0.05 0.05 0.02 0.02 75233 77005 79172 W818 0.03 0.04 0.02 0.00 2164 1800 1099 2308 1004 2108 1619 24 27 1914 1042 18516 20316 22215 24523 26327 28435 30054 32401 34395 36237 1.1 78 321 322 323 324 325 326 327 320 329 330 1568 1695 1420 1423 2201 2191 1919 1168 2390 1103 9 IO 333 11 334 12 13 335 I4 I5 16 330 331 332 17 339 123 340 2092 2000 1GE8 2346 1727 2091 2008 979 2169 2261 341 342 26 343 1/2/05 344 2001 1772 21 67 1646 19 21 530 605 640 635 640 53516 54776. 55536 56205 56728 57255 57611 57902 50093 58143 10 311 312 19 313 20 314 21 315 22 316 23 317 24 310 25 319 26 320 27 ' 0hl 2372 4245 5252 647ll 7772 0022 1020s 11295 12367 2380 1260 760 669 523 527 356 291 191 350 <0.5 0.6 3.7 5.6 6.2 5.2 3.3 2.7 2.0 1.3 336 337 m 1560 1873 1007 1226 1294 1050 1303 1090 1072 20 15 50 75 210 295 305 390 400 435 020 2412 4304 5173 7025 8861 10372 12639 14456 16352 0.7 0.40 0.29 0.29 0.25 0.22 0.12 0.09 105 0.06 0.06 144 66 58757 59045 59230 59450 59744 60007 60180 60205 60429 60495 0.01 0.03 21 63 135 164 121 146 101 49 49 45 60516 60579 60714 60878 60999 61145 61249 61298 61318 61393 62 71 43 61455 61526 61569 61569 0.08 0.07 0.07 " " anido(mg) per liter CYConsumal CkmulilLivc. 410 1365 0661 14760 24302 33929 38916 45037 40671 51136 020 1592 1972 1009 1552 1036 1511 2267 1017 1096 29 30 12/ 1 2 4 5 6 7 0 Individual Cumulative - 410 955 7296 6099 9622 9547 4987 6121 3634 21 65 301 9 302 10 303 11 304 305 12 306 13 307 14 300 15 16 309 17 310 11/ 0 Gold Extraction (ug) 700 710 740 710 700 GM 11W5 14779 15621 1627 16946 17432 10136 10632 I9lGG 755 700 750 750 700 705 790 790 735 345 415 426 356 550 650 566 2415 504 292 795 429 775 170 790 755 725 355 575 475 410 595 215 303 306 23952 24422 21777 25352 25027 26245 26040 27055 274.30 27031 562 211396 800 715 700 845 825 730 775 325 00 19511 1997.6 20352 20700 21250 2191 6 22402 22727 23231 23523 pll 8.1 8.1 0.3 0.5 0.5 0.5 9.2 9.1 9.9 9.9 9.9 10.0 10.2 10.5 10.5 10.5 10.5 10.7 10.6 10.7 10.6 10.7 10.5 10.5 10.5 10.2 10.1 10.5 10.4 10.4 10.5 10.5 10.6 10.6 10.7 10.7 10.4 10.4 10.5 10.5 10.1 10.2 9.7 9.5 column4 - S u r f a c t a n t 3a4-785 summsry of Leaching Data sample a2t C NO. Sample Weight (3) Individunl Cumulative Gold (pp) 18 19 20 21 22 23 24 25 411 41 2 413 414 415 416 417 418 419 420 2419 1348 2049 1487 1205 2100 18318 19991 22244 23704 26123 27471 29520 31007 32212 34320 421 422 423 424 425 426 427 420 429 430 1061 1716 1568 1826 1308 2358 1154 1368 2446 1547 35381 37097 38665 40491 41799 44157 45311 46679 49125 50672 13 14 15 1.6 17 10 431 432 433 434 435 436 437 438 439 440 2146 1510 2450 2225 622 2594 1966 1712 2043 2346 52018 54328 56778 59003 59625 62219 64105 65897 67910 70286 0.01 0.05 0.07 0.05 0.05 0.05 0.02 0.02 0.02 19 21 26 1/2/05 4.1 1 44 2 443 444 2000 1049 2060 15GO 72206 74135 76203 77771 0.05 0.03 0.03 0.00 26 27 28 29 30 12/ 1 2 4 5 6 7 0 9 10 11 12 1673 2253 1460 1203 5r>on GI371 1460 11339 49016 250 300 385 395 430 072 9G9 1159 1220 l0ln0 11333 12567 1089 1003.8 743 409 532 297 451 104 145 379 51705 52709 53453 53062 54394 54690 55141 55245 55390 55769 535 6.15 625 GOO 670 725 750 625 700 715 078 6.14 1344 5 9.9 I,llrn*> 10.0 845 1 .1~'3.1 10.3 9 4 15510 790 371 512 550 362 60 1 16116 10.4 10.5 I Grill7 17199 17757 I0110 111720 10.5 10.6 10.7 10.6 10.7 159 257 172 183 131 109 69 96 196 62 55928 56186 56358 56541 56671 56860 56930 57025 57221 57283 710 730 700 750 675 700 700 750 770 795 300 463 170 457 425 707 316 M2 563 317 1TxI%l1 19,191 199Gl 20'1 I fl 201343 21550 21 nCG l 22230 22001 23110 10.5 10.5 10.5 10.5 64 15 122 156 31 130 98 34 41 47 57347 57362 57485 57641 57672 57001 57900 57934 57975 58022 800 710 730 800 830 015 429 138 430 556 107 519 531 342 347 434 23547 23905 24475 25031 25210 25737 262GO 26610 26957 27391 100 55 62 50122 58177 50293 58293 725 760 350 70 550 27941 0.15 0.15 0.11 0.10 0.10 410 0.08 0.06 0.07 0.08 0.04 0.03 P(1 130 1.0 0.6 0.33 0.28 0.22 0.22 0.22 0.07 0.12 0.18 1089 17 C~lmUlntlVf 1 ow 1.0 (0.5 (0.5 4.4 7.2 5.6 3 ..7 2.7 2.3 1.6 Effluent Cyonidc m (Jr") per l i t e r ConSlUned 20 10 35 175 510 1298 8259 22047 30363 37607 40972 44597 47662 1020 2597 4179 Go34 7579 9537 10783 12359 14275 16429 16 11 Individual Cumulative 510 788.5 6960.8 13700 0316 7244.6 3364.2 3624.8 3065.6 2154 1020 1577 1582 1915 1485 1958 ,1246 1576 1916 2154 401 402 403 404 405 406 407 408 403 111 0 9 10 Gold EXtractim (ug) - 800 750 700 000 1561 . 1527 15110 ~ura 2561 m m 9211 0.0 8.0 0.1 0.3 0.4 0.6 9.1 9.3 9.7 9.9 10.4 10.2 10.3 10.3 10.4 10.4 10.5 10.4 10.5 10.6 10.5 10.7 10.4 10.5 10.5 10.5 10.1 3.7 9.5 9.4 Column 5 n1 t C 11/ 8 9 10 - ". '".. I S u r f a c t a n t 88Ol-B3159 Sunlmary of Leaching aata .I Effluent Sample Sample Weight (g) No. Individual Cumulative Gola (ppn) 501 1158 502 503 501 1901 851 1768 1834 2123 1771 1613 2104 2210 1158 3059 3910 5678 7512 9935 11709 13352 15156 17666 <0.5 0.5 4.5 7.6 7.1 4.4 2.6 2.1 1738 1245 2447 1323 2536 1771 1629 2182 1123 2329 1032 1535 1549 21 10 Gold E x t r a c t i o n (ug) Individual Cumulative Cyanide (tq) per l i t e r Consumed ~ ~ m u ] . a t i v a p~ 0.9 519 950 3829 13437 13201 10661 4612 3450 3366 1989 579 1529 5359 18796 31817 42478 47091 59541 53907 55896 15 25 40 100 193 255 310 385 435 475 1141 1853 817 1591 1486 1805 1221 1010 1189 1160 8.0 8.2 8.2 0.2 8.4 0.6 9.0 9.4 9.7 10.0 19404 20649 23096 24419 26955 28726 30355 32537 33660 35909 0.8 0.8 0.39 0.25 0.21 0.17 0.11 0.19 0.17 0.16 1390 596 954 331 533 301 179 115 191 373 57287 50283 59237 59568 60100 60401 60500 60995 575 530 625 625 660 700 739 5H5 910 45% 862 531 505 709 10.0 0.17 0.13 0.11 0.10 311 - 37821 39356 40905 43015 41703 47015 18669 49573 51948 51948 540 1262 2270 1918 1521 1946 1910 2344 2135 1582 2517 53210 55480 57428 58949 60895 62835 65179 67311 68896 71413 511 542 543 1/2/05544 2036 1891 2058 1634 73449 75340 77390 79032 11 505 12 13 14 506 507 508 15 509 16 510 17 18 I9 20 ?I 511 512 513 514 515 22 516 23 24 517 518 7.5 519 26 520 27 521 20 29 30 12j 1 2 1 5 G 7 8 9 10 11 12 13 I4 522 523 524 525 526 527 528 529 530 531 532 533 534 535 536 537 15 16 538 539 17 18 19 21 26 1688 2342 1624 904 2375 1.6 0.09 0.09 0.06 0.06 0.01 - 200 1 70 21 1 152 211 97 54 24 " 61186 61559 61870 62070 52210 62451 62603 62814 62911 62965 62989 G2989 675 700 690 331 722 725 150 700 765 750 710 755 705 750 504 34 465 496 4 22 G79 300 2G7 594 10.6 10.5 10.5 10.5 10.5 10.3 10.3 10.3 10.4 " " 0.07 0.05 0.06 0.05 0.05 0.02 0.02 133052 63075 63211 63318 63415 63531 63619 63756 63788 63fl38 605 775 805 740 765 750 725 025 825 850 0.03 0.03 0.04 61 57 02 0.00 " 63899 63956 64038 64038 765 000 325 70 0.07 10.6 10.6 10.5 10.7 10.6 10.9 6'X 63 23 136 107 97 116 117 107 32 50 0.05 0.01 10.0 1.0.3 10.4 190 511 380 395 4 57 ,185 615 37.1 277 377 17fl - 10.3 10.5 10.5 10.6 10.7 ~0.7 10.3 IO.,^ 10.5 10.5 10.2 9.8 9.5 9. G I