I ! . New Mexico B u r e a u of Mines & . Mineral R e s o u r c e s O p e n - F i l eR e p o r t 86 HYDROGEOLOGIC STUDIES OF THE SOCORRO L A N D F I L LS I T E BY NEW MEXICO BUREAU OF MINES AND MINERALRESOURCES William J. Stone and R o y W. zoster ..” December, 1977 Contents ..................... 1 Results of Auger-Hole Investigations . . . . . . . . . 1 Water-Well Study . . . . . . . . . . . . . . . . . . . 6 General Statement . . . . . . . . . . . . . . . . 6 . Results of Chemical Analyses . . . . . . . . . . 6 Ground-Water Table and?qovement . . . . . . . . . . . 11 References Cited . . . . . . . . . . . . . . . . . . .18 Acknowledgements . . . . . . . . . . . . . . . . . . .18 Appendix A: Results of Textural Analyses . . . . . . .19 Appendix B: Trilinear Plot of Dissolved Solids . . . .6 2 Introduction INTRODUCTION Operations a t t h eS o c o r r os a n i t a r yl a n d f i l lb e g a ni nO c t o b e r , The l a n d f i l l s i t e i s i n a t r i b u t a r v o f N o g a lA r r o y ol o c a t e dn o r t h w e s t Socorro Bldg. a t Escondida. o ft h eC i t yo f l o c a t e di nt h es o u t h e a s tq u a r t e ro fS e c . fromthe Most o ft h eo p e r a t i o n 26, T.2.S.; o ft h el o c a l water s u p p l y . R?.1 W. is Citizens over t h e l o c a t i o n o f community of Escondidavoicedconcern thelandfillfromthestandpointof 1977. l i t t e r a n dp o t e n t i a lc o n t a m i n a t i o n I n r e s p o n s et ot h i sc o n c e r na d d i t i o n a l investigationshavebeenconductedbytheEnvironmentalImprovement Agency a n d t h e Thisreport New Mexico Bureau of Mines and Mineral Resources. i s a summary o f t h e s t u d i e s d o n e of t h eB u r e a u .I n c l u d e d are a n a l y s e so f by members o f t h e s t a f f two a u g e r h o l e s d r i l l e d f o r theCityofSocorrobyAlbuquerqueTestingLabsunderthesupervision ofDennisEngineering C o . and b a s e l i n e water d a t a f r o m wells i n t h e v i c i n i t yo ft h el a n d f i l lo p e r a t i o n .D e t a i l e di n f o r m a t i o no nt e x t u r a l a n a l y s e sa n d dataon water c h e m i s t r y a r e on f i l e a t t h eB u r e a u .A d d i t i o n a l trace e l e m e n t s a n d c l a y a n a l y s e s w i l l be. forwarded as soon as available. R E S U L T S Q F A~UGER HOLE- INVESTIGATIONS ~~ On November 1 7 and 1 8 , 1 9 7 7 two a u g e rh o l e s determinethedepth u n d e r l y i n gt h e t o ground water a n d t h e n a t u r e were d r i l l e d t o of t h e s e d i m e n t s area of t h e S o c o r r o s a n i t a r y l a n d f i l l . D u r i n g d r i l l i n g o p e r a t i o n ss a m p l e s ofDennisEngineering were c o l l e c t e d a t 5-fOOt i n t e r v a l s b y p e r s o n n e l Co. a n dt h e N e w Mexico BureauofMines. t e s t (Auger Hole 1) was d r i l l e d n e a r t h e n o r t h e a s t c o r n e r T.2 S., R . l W. t o a d e p t ho f 8 0 f e e t .T h i s The f i r s t of Sec. 35, t e s t i s a t t h e s i t e o ft h e planned water well f o r t h e C i t y o f S o c o r r o a n d r e a c h e d t h e a t a d e p t ho f 73 feet. Auger Hole 2 was l o c a t e d i n t h e l a n d f i l l about 1 2 0 0 f e e tn o r t ho fH o l e T.2 S., R . l W. e n c o u n t e r e dt h e water t a b l e 1 inthesoutheastquarterof T h i s t e s t was d r i l l e d t o a d e p t ho f Sec. 2 6 , 9 5 f e e t and water t a b l e a t 8 7 f e e t .E l e v a t i o n sm e a s u r e db yD e n n i s E n g i n e e r i n g show t h a t Hole 2 i s s l i g h t l y over 1 5 f e e t h i g h e r t h a n Hole 1; t h e water table i s t h e r e f o r e n e a r l y in the t w o wells. a t t h e same e l e v a t i o n During d r i l l i n g it was n o t e d b y t h o s e p r e s e n t t h a t t o t h e water t a b l e . samples were m o i s tf r o mt h es u r f a c e t h e water c o n t e n t a p p e a r e d t o b e g r e a t e r i n H o l e Further, 2 a t the landfill. The g e n e r a l n a t u r e o f t h e s a n d s a n d g r a v e l s p e n e t r a t e d i n t h e two a u g e rh o l e s are shown i nF i g u r e on m i c r o s c o p i c e x a m i n a t i o n o f 1. The i n t e r p r e t a t i o n i s b a s e d the cuttings and the general distribution sizes i s estimated. ogfr a i n S e d i m e n t sp e n e t r a t e di nH o l e c l a y e ys a n d s and g r a v e l s .I nH o l e to light yellowish o fc l a ya n d 1 consist of light to silt. medium brown 2 s e d i m e n t sc o n s i s to fl i g h t brown s a n d s a n d g r a v e l s w i t h I n Hole 1 t h e l a r g e r brown a smaller p e r c e n t a g e c l a s t s c o n s i s tm o s t l y v o l c a n i c material; i n Hole 2 t h e s e are m i n o r v o l c a n i c of clasts with most of t h e material c o n s i s t i n g o f f r a g m e n t s o f q u a r t z , q u a r t z i t e , feldspar and granite. Sedimentsunderlyingthehighersurfacenorth inthevicinityof sourceforthese Hole 2 were depositedbytheRioGrande. sediments i s t o t h e n o r t h a n d , of c l a s t s p r e s e n t , was d e r i v e df r o m i n t h e Ladron o r Manzano Mountains. . I ) of NogalArroyo The based on t h e t y p e a P r e c a m b r i a nt e r r a n es u c h as The m a t e r i a lu n d e r l y i n gt h el o w e r , " .. Auger Hole # I City Water Well Location Elev.4664.84' Deoth 3 Auger Hole %A2 Sanitary Landfill Eiev.4680.22 sd:mbn,vf-c,gran&pebs,cly,sity; ang-sr:qtz,fisp,&volc frogs; few.frags sdy caliche; pebs increase toward base, . .~ sd; I f hn,peb,vf-c,.sa-rdd,sliy; sdgrns qtz8qtzt;pobsof qtz,qtrt, granit-e 6. fewvolc. gravel;m bn,voic pebsto2" matrix sim to above; few sdy,gran clay balls gravei:Iibn-Itywlibn,vf-vc,y& becoming c-pabinlawarport, sa; pebs ofqtraqtzt; sd g r n s o f q t r , q t z t & f I s p peb s d sim too-10'interval sim to io-25'interval but lacking cloy balls sd:ltywhbn,peb,gron~~l-vc,ongrdd;grnsofqlz,qizt,&flsp,fsvr volc pobs. . . sd: It bn,gran t o small pebs; frogs f-m,ang-sr,minorwrgrns; small amaunt o f silt;qtz,flsp, volc . . .. -sim taabave;inein lurgorpabs and some small cobs, sd: rn bn, peb, ciy,slty: f-rn WT-73' (no samples) i, dim: decreasain amount ofpsbs s i m b 65-70; less clay - WT- 87' sim;grns in upper partcootcd'wiih clay . NENE Sec.35,T.Z.S;jR.I W. SESE S e c 2 6 , T2S, R.1 W. X-301665.03' Y- 1127815.78' - clayey - silty s d - sand sdy - sandy vf: -- -veryfine f: . - f in'e m -. cly slty ., . c vc :grampebs kobs - I. I- . .. medium coarse very coarse granules pebbles cobbles . .~ ang sa sr rdd qtz qtzt flsp volc bn ywh It fmgs slm grns inc WT -X textural analysis - angular - subangular - subrounded - rounded quartz - quartzite - feldspar - volcanic - brown - - - . . yellowish light fragments similar grains increase watertable Hales drilled by Albuquerque Testing Lob. Figure 1.. Logs of Auger Holes 1 and 2 * . . -. . . . . . . ... - 4 area near drainage site of Hole 1 is younger the system of Nogal Arroyo andwas deposited following by the dissection of the high surface to the north. The primary source for the material would be from a volcanic and Lemitar terrane analyses were and seven from Hole2. an asterisk Only one as exposed to west the inthe Socorro Mountains. Textural by such of on made 13 of samples, Figure 1 and the textural in the 1. than in Auger Hole determined, important minerals can substances in a sanitary thus ingeneral. coarser In addition the average amount of clay and attenuate and size range, is canbe seen that the landfillare The silt is only 3.37 percent in Hole2. is highly in Table 1. resultsare summarized parameters 2 at the Hole Auger 1, Hole from The location of these samples is indicated presented in the table. From these data it sediments six presence landfill lateral potential or in. that vertical of clay certain movement contamination.of minerals clay of toxic ground-water supplie " It is doubtful from encountered at the an effective the small landfill natural amount that barrier to of fine-grained there is sufficient material clayto form of possibly migration hazardous substances. The clay mineralogy was determined by George Austin of the Bureau staff. Samples were divided into plusand minus twornicron fractions Samples and were following the finer analyzed saturation heated to 375OC for material by with one x-ray sedimented on glass slides. diffraction of the ethylene hour. gylcol and original material, finally after being 4a All of the eleven samples contained illite, kaolinite and random mixed-layer illite-smectite. One sample (G 780001) from Auger Hole 1 contained a small amount of smectite. Non-clay minerals in the minus 2 micron fraction included quartz, feldspar and calcite. The depth interval studies for each of the auger holes are and given relative in 2.. table proportion of clay minerals (in parts of 10) TABLE 1: TFXNRAL ANALYSES AUGER HOLES 1 AND 2* (Values given in weight percent) Auger Hole 1 I n t e r v a l (depth i n feet) 5-10 15-20 25-30 35-40 55-60 75-80 11.23 7.433.75 1 4 ;45 6.53 38.37 4.27 5.47 28.64 __ 4.18 16.20 6.89 - 4.81 18.84 29.53 54.62 19.24 46.79 10.82 6.21 26.58 Very Coarse 1-2nan Coarse 0.5" 5.33 5.78 13.10 15.98 ~ 10.36 4.86 6.56 9.55 8.51 , 7.10 *Complete results given in ?.pp.ndix A Medim Sand Fine 11.58 10.06 8.38 4.44 6.23 18.90 14.02 . ' 17.69 8.32 31.87 15.78 - 12.55 14.54 9.48 7.00 12.59 - - 8.02 11.23 12.88 12.87 14.15 17.76 3.87 5.43 ;11.97 20.06 6.16 14.09 13.82 10.05 24.63 6.58 14.46 ; 15.55 8.0725.39 9.91 29.35 22.58 17.42 15.41 24.49 7.94 4.88 8.78. 6.86 - 9.16 21.48 13.54 18.05 S i l t and Clay Very Fine <O.OGh 0.25-0.5m 0.125-0.25mn 0.062-0.125mn 13.74 8.70 Averages Auger Hole 2 5-10 20-25 30-35 45-50 5.05 65-70 75-80 .90-95 Averages Gravel Pebble G r a n u l e s >4m 2-4mn 16.81 9.62 15.21 - . 27.85 18.16 28.09 - ~~ ~ 13.78 10.69 _ . 16.91 10.8K ". ._ 11.63 5.42 23.27 ~. 9.10 22.72 l d .." 31 -. 16.95 7.32 R.4K _... 7.50 - - 11.70 2.25 13.45 2.50 0..5.6 ~ . ~ 1.0 1.91 n_." ~ w " " 1.48 1.66 . - 5.02 3.57 0.63 0.86 4.54 ~~ 3.37 5a Table 2: Sample E Well De9th CLAY MINERALOGY CLAY MINERALOGY x Layer I11 Kao Smec M Remarks " " G 780001 1 10' 2 3 1 4 w/quartz, feldspar, calcite G 780002 1 25-30' 3 3 0 4 w/quartz, feldspar G 780003 1 35-40' 5 3 0 2 w/quartz, feldspar 55-60' 4 4 0 2 w/quartz, 57-80' 3 5 0 2 w/quartz,.feldspar,calcite G 780004 feldspar, calcite G 780005 1 G 780006 2 5-10' 5 5 0 0 w/quartz, f e l d s p a r ,c a l c i t e G 780007 2 20-25' 3 3 0 4 w/quartz, feldspar, calcite G 780008 2 30-35' 0 5 0 5 very little clay 780009 2 65-70' 3 3 0 4 w/quartz G 780010 2 75-80' 3 .4 0 3 w/quartz, G 780011 2 90-95' 3 4 0 3 w/quartz, feldspar G, Q - size material , feldspar feldspar .. . . . 6 WATER-WELL STUDY General Statement In order to determine the present water-table position and baseline ground-water chemistry in the vicinity of the new Socorro landfill, a study of water wells (Sec. 25, 26, 35, and 36,T. 2 S . , in the Escondida-Florida 1 W.) R. area was carried out during early October, 1977. This study focused on 25 wells; five wells (1, 3, 4, 20, and 23) lie outside the area cited above but add useful information (fig. 3). Results of the well inventory are given in Table 3. Water samples were obtained from 23 of the 25 wells inventoried. Results of analyses foricommon dissolved constituents are given in Table 4. Analyses for trace elements have not yet been completed; results will be furnished as Table 5 w B. available. A trilinear plot of dissolved solids appears in Appendix Results of Chemical Calcium (Table 4). and Analyses sodium are the major anions present in the samp Calcium may be readily derived from various sedimentary rocks (limestone, dolosfone, gypsum, gypsiferous shales), whereas sodium is available mainly from clay and feldspar minerals and salt beds. Sewage,and industrial waste may also be sources for both constituents. The concentration of sodium approaches the recommended limit for domestic use in only of 2 the samples (wells1 and 11, Table 4). There is no recommended limit for calcium. Bicarbonate is the principle cation detected in the samples; sulfate, or in some case chloride, is the next most abundant ca Bicarbonate rocks as and listed sulfate above may for be derived calcium and from sodium the same whereas sedimentary chloride is . 7 . .. . A . Figure 3. Portion of Socorro.7.5' topographic'quadrangle showing location of study area andmajor wells inventoried .(see Table-3 for .additional Information).. .. . . ., . . Lt.< . .. .-x . . .. Table 3. 1 Field Well NJnr No. Location No. 2 Records of Wells Included i n Sooorro L m c l f i l l Study WPrnX. Blev. ABS- Nogal No. 1 1 Sanitariwn Olguin 2 3 Olguin A Shaw Citv No. 2 5 6 7 a 10 9 11 12 Sickle Cole Torres Mossberg Nuanz Herron mice Kennedy Daniel Kelly house Kelly ranch Nogal Eo. 2 13 14 15 16 17 18 19 20 21 23 22 24 25 2.1.29.423 2.1.35.221 2.1.31.222a 2.1.31.22233 2.1.25.341 2.1.35.221 2.1.25.344 2.1.36.122a ~ ~~~~ 2.1.36.12233 2.1.36.122~ 2.1.25.231 2.1.25.344 2.1.25.342a 2.1.25.34233 2.1.25.3422 2.1.36.323 2.1.36.321 2.1.36.312 2.1.36.314 3.1.2.244 2.1.36.143 2.1.36.241 2.1.22.133 2.1.26.333 2.1.26.313 , 4900 4682 4600 4600 4640 4685 4625 4625 4630 4630 4625 4620 4620 4620 4620 4628 4630 4640 4630 4610 4630 4605 4835 4755 4760 WaterTable Elev. ( f t ) 5 SWled (ft) water (ft) 34 16 4884 Drilled s NA NA NA Drilled D D "P:' 18 R 14 R 42 R 4582 4586 4598 NA NA NA NA NA NA 52.5 R 35.5 R 4590 NA NA NA NA NA NA NA NA NA NA NA NA 35 R 25 R 110 R 120 60 130 NA 89 80 94 NA 259 >500 (.15 R R R 35 R 4593 NA 4545 (?) NA. 20 NA 35 R , NA 4605 NA NA 90-100 R R R NA NA NA NA R NA N A 140.5 >500 m. Driven Driven NA NA NA Drilled Drilled Drilled Drilled Drilled Drilled Drilled Drilled Drilled Drilled Drilled NA Drilled X X s X X D X P X X X X D D D D D D X X D X s X S X X IR p q x d a t 600 gpn D D D X X X l e v e l s uncertain sample kcn i tap sanple fm tap IR X D D X NA D X X .. 4615 NA S PNX NA S PNW < 4260 WL = 9 ' , 1960(R) X Drilled Drilled Drilled 4590 N4 4570 Renwrks m L . . 9 R A N G E -IO E. . ' SECTION 2.4 i 212 "(2IO)"" 211 221 I222 (2iO)- 213: 214 223j 224. : Eo01 : * ; [zoo] : i 132 141 142 231 232 241 242 ---(130)------(14!3--- --~(230)--(240)133 i 134 I43 i 14-4 233 234 2433 244 : 311 : 312 321 322 411 : 412. 421 : 422 131 I I I I I ---(310)- ~"1320)"--(4lO)- 6 miles ~ ~ I mile of numbering wells and springs: a) suhdivision of a township into sections, b) subdivision of a section 'into quarter-quarter-quarter section blocks (dot indicates locationof a well numbered . 5dfO'.24.213) PIGURX 2-Method - . I -4420)" % 10 Table 4. Dissolved Solids in Ground Water, Escondida-Florida Area AnionsWell (ppm) Ca No. Mg Na K ABS- HC03 Cations (ppm) c1 co3 s04 N03 Calculated TDS ( PPd 1 59.4 9.8 108.0 2.6 227.0 179.0 21.0 12.0 0.0 496.3 2 31.0 5.6 26.3 1.2 120.0 4.3 13.4 4.0 .5 182.0 3 124.0 34.0 94.0 3.6 270.0 175.0 94.0 0.0 .9 660 .O 4 95.0 28.0 69.0 4.6 195.0 238.0 65.0 10.0 1.0 600.0 5 37.0 7.5 24.0 3.4 112.0 53.0 17.0 6.0 1.3 201.0 6 40.0 6.9 27.0 1.4 112.0 59 .O 15.0 6.0 .04 207.0 7 25.0 7.2 28.0 2.9 100.0 29.0 19.0 8.5 .7 164.0 9 46.0 10.0 48.0 3.3 224.0 23.0 29.0 11.0 2.0 276.0 10 86.0 22.5 76.0 4.3 212.0 193.0 57.0 11.0 7.9 555.0 11 99.0 19.0 112.0 13.0 261.0 228.0 80.0 11.0 0.0 684.0 12 46.0 21.0 79.0 3.4 114.0 216.0 25.0 11.0 019 516.0 13 57.0 15.0 38.0 3.2 134.0 104.0 45.0 0.. 0 1.5 330.0 14 49.0 15.0 30.0 3.2 134.0 97.0 33.0 0.0 0.6 294.8 15 66.0 19.0 36.0 3.7 151.0 124.0 42.0 0'. 0 0.4 367.0 16 35.0 12.0 30.0 3.0 146.0 56.0 19 .o 0.0 7.0 235.0 17 36.0 8.5 30.0 2.5 144.0 42 .O 19 .o 0.0 0.8 211.0 18 36.0 8.3 27.0 2.8 151.0 39.0 13.0 0.0 0.6 202.0 19 63.0 16.0 38.0 3.2 171.0 128.0 29.0 0.0 1.5 450.0 20 26.0 5.0 50.0 1.5 146.0 46.0 17.0 0.0 0.8 219.0 21 56.0 14.2 40.0 3.4 188.0 89.0 31.0 0.0 3.3 331.0 22 100.0 17.0 41.0 4.3 220.0 138'.0 52.0 0.0 1.2 464.0 Recommended Limits (ppm) None 125.0 115.0 None None 250.0 250.0 None 44.0 'See Appndix B f o r trilinear plot of dissolved solids. 'For - domstic use (California State Water Pollution Control % a d ) 500.0 8 31000.0 ppm ~~ i S acceptable ~ but 500 is recolrnnended by U.S. Public Health Service 3 Trace Elements i n Ground Water (ppm), E s c o n d i d a - F l o r i d a Area Table 5. Well No. 1 2 3 4 5 6 7 ' 8 ' ' 0.7 - 9 10 11 12 13 14 15 16 17 18 19 20 21 22 24 F p04 0.16 0.39 0.22 0.31 0.25 <O.l 0.28 0.25 0.19 0.13 . 0.26 0.18 0.23 0.22 0.38 <0.1 0.25 ' CO.1 0.33 <0.1 <0.1 0.22 Fe' 0.66 0.62 0.52 0.41 0.47 0 -52 0.52 0.43 0.42 0.47 0.42 0.43 0.46 0.49 0.40 0 -56 0.57 0.56 0.52 0.51 0.51 0.38 0.45 Mn Cd cu Zn 0.0008 .51 .005 0.0 6. 968 <0.0005 -008 .06 0. 14 .8 3 0.0013 -003 -39 1.1 0.33 0.0009 <.05 .008 1.0 0.15 <0.0005 c.05 -01 2.7 <0.05 0.0026 <.05 -01 < .001 0.26 0.35 0.012 . <.05 0.22.10 0.0026 -50 < .001 1.05 0.07 0 "034 .37 < .001 0 -01 1.05 0.04 .06 < .001 0.004 0.51 0.66 < .OOl -05 0.024 0.45 0.41 < .001 <.05 0.0 3. 506 0.007 130 .003 0.0 1. 405 < .05 .005 0.018 0.0 2. 009 0.024 < .05 .002 0.45 0.09 < .001 . o.oas <.05 0.16 0.07 < .001. 0.006 < -05 0. 20 .6 1 .44 0.005 < .OOl 0.11 0.05 < .001 0.02 -07 .15 0.7 06 .04 < .001 0.007 0.19 0.02 0.150 .18 < .OOl. 0.3 0. 66 0.022 < -001 < -05 0.23 <0.01 < -001 -16 0.068 38.0 0.19 Cr <.Ol <.01 <.01 <.01 <.01 <.01 <.01 <.01 <.01 <.Dl <.01 <.01 <.Ol, <.01 <.01 <.01 < .01 <.01 <.01 < -01 <.01 < .01 <.01 Recamended limits1 f o r None 1.5 1.0 0.2 0.01 1.0 Healthnamestic Use (PP) 'U.S. Environmental Protection Agency . . . . 10.0 0'.05 11 e available from most rocks and soils, sewage, and industrial effluen Only three wells approach the recommended (well numbers4, 11, and 12, Table 4). limit for sulfate None of the samples analyzed contains excessive chloride. There is no recommended limit for bicarbonate. The presence of nitrate in most of the samples is of speci interest. This cation may be derived from decayed organic matter, nitrate fertlizers, animal excrement, and sewage. Although nitrate does not exceed the recommended limit in any of the samples, its presence in may contact bean indication with the that domestic ground-water supply sewage and is locally septic tanks coming should examined. e Total dissolved solids (TDS) contents of the waters are excellent, falling generally well below the recommended 500 ppm do not (parts per million) standard for drinking water: several even approach half of this value (Table 4 and fig. 4). Only 5 samples 3 , 4, 10, 11,and 12); oneof these exceeded this standard (wells (number 4) is not used for domestic purposes. There is no need for concern over remaining 4 wells the as water is considered potable and fresh if TDS content does not exceed 1000 ppm; lacking better quality saline supplies, waters Ground-Water Local e wells owing many without Table water communities harmful and levels mainly to have reportedly used even more effects. Movement were methods difficult of well to measure completion at 4all of (no but the access for water-level-indicator cable). Reported values were obtained, however, 12 26 13 - for 10other wells (Table 3). reported not values are necessarily for It should different be times noted in that se the the past and thus ar compatible or representative of the present situation. Based on levels measured in the present study, the water table near the landfill appears to slope toward the Rio Grande (fig. 5). It occurs at an elevation of about 4964 ft. at well number1 ( 3 miles west of the landfill), at about 4620 ft. in well number 24 (1 mile west of the landfill) at 4592 ft. and 4593 ft. in Auge.n. Holes 1 and 2 at the ,landfill and at about 4590 ft. at well number 8 ( . 2 mile east of Interstate 25). An anomalous water-level measurement was obtained at well number 25. At this well, located just short of a mile of west the landfill, the entire length of a 500-ft. water-level-indicator cable If was this lowered well is without open to reaching the water water or table, the bottom this means of the that the water table there lies at an elevation less than 4250 ft. At we number 24, located directlv across Nogal Arroyo to the west (fig. water was encountered at a depth of 140.5 ft. (elevation 4590 ft.) or atleast 340 ft. above that at well 25. One explanation separated vertical by a of this discrepancy is that fault or fracture movement displacing along the which the there water-bearing 2 wells has strata are been upward on the . west and downward on the east. Although wells 24 and 25 did not exist, Waldron (1956) postulated the presence of a fault in the sa area on the basis of a refractive seismic wrofile which showed 14 Figure .5. Map showing generalized ground-water'table and movement in study.area. Upper values are depths to water; lower values are elevations of water table (reported valuesa r e - i n parentheses). See Table 3 for other well da,ta; A-1 and A-2 are auger holes sh.own in fig. 1:'' .. ~. .. I ._ 15 was i n t e r p r e t e d t o b e t h e abrupt35-ft.offsetinwhat water t a b l e . a fault t h e presenceof Furtherstudywouldbenecessarytoconfirm and t o d e t e r m i n e why seismic d a t a show a 3 5 - f t i r r e g u l a r i t y i n water t a b l e w h e r e a s w e l l 25 s u g g e s t s more t h a n 300 f t . of offset.: The q u e s t i o n may be merelyacademic seem t o becompatible water a t t h e i n a d j a c e n tE s c o n d i d a levels n e a r t h e r e a n d landfillbecausewater a n dF l o r i d a as r e g a r d s g r o u n d ( a l l a v a i l a b l e water l e v e l s , well 25 a n da nu n c e r t a i n w i t ht h ee x c e p t i o no ft h ea n o m a l o u sv a l u ef o r well 1 8 , are p l o t t e d on f i g . 5 ) . r e p o r t e dv a l u ef o r B e c a u s el o c a ld a t a water are s p a r s e , r e g i o n a l c o m p i l a t i o n s o f l e v e l were c o n s u l t e d t o c o n f i r m t h e d e t e r m i n e d w a t e r - t a b l e c o n f i g u r a t i o n .R e g i o n a lw a t e r - l e v e l maps were p l o t t e d byWaldron(1956) and Bushman ( 1 9 6 3 ) .I nc o n j u n c t i o nw i t h for the a r e c o n n a i s s a n c es t u d y New Mexico BureauofMinesandMineralResourcesofthe a r e a , Stone h y d r o g e o l o g i ca s p e c t so ft h eS o c o r r oP e a kg e o t h e r m a l ( 1 9 7 7 ) p r e p a r e d maps f r o m g r o u n d - w a t e r d a t a a v a i l a b l e i n v a r i o u s B u r e a uC i r c u l a r s . The BureauofMines Magdalena t o j u s t across theRioGrande few miles n o r t h of P o l v a d e r a t o Basedon maps c o v e rt h e area from e a s t ofSocorroandfrom a a few miles s o u t h o f S o c o r r o . thesevariousregional maps t h e f o l l o w i n g may b e concluded: 1. Two f l o ws y s t e m so p e r a t eo nt h e flow i s e a s t e r l y andone e t ihne i s southerly. zone where the Rio t o themountainfrontinwhich G r a n d eV a l l e y :o n en e x t whichflow west s i d e o f t h e i n t h e lower f l o o d p l a i n areas i n The r e s u l t a n tf l o wd i r e c t i o n 2 systems merge i s southeasterly 16 ( f i g . 5 ; flow i s p e r p e n d i c u l a rt ow a t e r - l e v e lc o n t o u r s ) The s o u t h e a s t e r l y t r e n d of thelowerpartofNogalArroyo may be a r e f l e c t i o n o f t h i s r e s u l t a n t f l o w d i r e c t i o n . 2. The w a t e r - c h e m i s t r yo ft h e 2 f l o ws y s t e m sd i f f e r s ;g r o u n d waters n e x t t o t h e m o u n t a i n f r o n t 3. less waters on t h el o w e rf l o o d t h a n 1 0 0 0 ppm) whereasground p l a i n are s l i g h t l y s a l i n e are f r e s h (TDSmuch (TDS i n e x c e s s o f 1 0 0 0 ppm). L o c a l l y ,o p p o s i t ef a v o r a b l ep l a c e so nt h em o u n t a i nf r o n t , ground waters i n t h e lower f l o o d p l a i n are anomalously f r e s h owing t o d i l u t i o n by f r e s h waters from the mountain flow s y s t e m( f i g . 4. 4). The waters o ft h em o u n t a i nf l o ws y s t e m they originate only Magdalenasand a short distance to the travelrapidly Spring have been determined a r a t e ofabout mountains,and 5. west i n t h e (waters d i s c h a r g i n g a t S o c o r r o t o move t h r o u g h t h e g r o u n d Ranch F l a t s , t h r o u g h f r a c t u r e s i n t h e down t h e d r a i n a g e of NogalArroyo. The s a l i n i t y o f waters o ft h ef l o o dp l a i nf l o ws y s t e m b ee x p l a i n e di n several ways. i s c l o s e l y related t o r i v e r f l o w i s onesourceof both the river A l s o ,t h e r e at 7 times normal;Holmes,1963) 35 f t / d a y o r a c r o s st h eS n a k e are f r e s hb e c a u s e may F i r s t of a l l , t h i s water water. S a l i n ei r r i g a t i o nr e t u r n elevated t o t a l d i s s o l v e d s o l i d s i n and a s s o c i a t e d f l o o d p l a i n g r o u n d waters. are n a t u r a l s o u r c e s f o r t h e d i s s o l v e d c o n s t i t u e n t s as m e n t i o n e da b o v e :l i m e s t o n e s ,d o l o s t o n e s , and gypsum ( o c c u r r i n g as l a y e r s i n b o t h t h e a n c i e n t b e d r o c ka n dv a l l e y f i l l and as v e i n s o r f r a c t u r e - f i l l i n g material i n m u d s t o n e s o f t h e a n c i e n t b e d r o c k a n d v a l l e y fill). 17 e mind, t h e l o c a l ground-water With t h i s r e g i o n a l p i c t u r e i n s i t u a t i o n a t t h el a n d f i l lc a nb e lies in an area i n whichground f l o ws y s t e m .I nt h i sa r e a , more r e a d i l y summarized. The l a n d f i.11 water i s dominated by the mountain a t o n g u eo ff r e s hg r o u n d water flows e a s t e r l y f r o mt h em o u n t a i nf r o n t ,a l o n gN o g a lA r r o y o ,t o w a r dt h e Grande.Thistongueofground Rio water i n t e r r u p t st h ef l o o dp l a i nf l o w is s y s t e mi nt h ev i c i n i t yo fE s c o n d i d aa n dF l o r i d a .T h i sc o n d i t i o n s u g g e s t e d by b o t h a v a i l a b l e w a t e r - t a b l e a n a l y s e so fl o c a lg r o u n d w a s n o tt h ep u r p o s e not the landfill t h es c o p e data a n d r e s u l t s waters ( f i g s . 3 , 4 , and 5 ) . of c h e m i c a l Although it of t h e water-well s t u d y t o d e t e r m i n e w h e t h e r o r w i l l r e s u l t i n ground-watercontamination, it i s w i t h i n of t h i s r e p o r t t o p o i n t o u t t h e s i g n i f i c a n c e o f t h e water s e t t i n gd e t e r m i n e df o rt h ea r e a . The s i g n i f i c a n c eo fs u c h a a t t h el a n d f i l l , it s e t t i n g i s t h a ts h o u l da n yc o n t a m i n a t i o no c c u r canbeexpectedtomigrateeasterlytoward ground- various r e s i d e n c e s i n EscondidaorsoutheasterlytowardthoseinFlorida. 18 REFERENCES CITED Bushman, E. X., 1 9 6 3 , Ground water in the Socorro Valley: New Mexico Geological Society, Guidebook 14th field conference, p. 1 5 5 - 1 9 5 . Folk, R. F., 1 9 7 4 , Petrology of sedimentarv rocks: Austin, Hemphill Publishing Company,182 p . Holmes, C. R., 1 9 6 3 , Tritium studies, Socorro Spring: New Mexico Geological Society, Guidebook 14th field conference, p. 1 5 2 - 1 5 4 . Stone, W. J., 1 9 7 7 , Preliminary hydrologic mawsof the Socorro Peak area: New Mexico Bureau of ?lines and Mineral Resources, Open-File Maps,4 sheets. Waldron, J. F., 1 9 5 6 , Reconnaissance geology and ground-water study of a part of Socorro County, New Mexico: Stanford University, Ph.D. thesis, 2 5 5 p. Nentworth, C. K . , 1922, A scale of grade and class terms for clastic sediments: Journal of Geology, v.30, p . 3 7 7 - 3 9 2 . ACKNOWLEDGEMENTS Chemical analyses were performed under the direction of Lynn A. Brandvold, Bureau chemist. Water wells were inventoried by Robert C. Brod and Scott K. Anderholm, Bureau research assistants. Textural analyses were made by Robert C. Brod. The trilinear plot was prepared by X. Anderholm. Scott 19 Appendix A qesults of Textural Analyses e e 20 EXPLANATION The texture of the 13 * samples studied was determined by sieving with a whole phi sieve set (difference between adjacent sieves in the stack was 1 phi unit). The pages which follow are Xerox reductions of computer-printout sheets designed to present the various results of sieve analyses. For each sample there are 3 sheets. The first gives raw weights, calculated percentages (by weight), and cumulative percentages (by weight) for each size class based on the sieving (see Table 1 for names corresponding The sheet shows by second means Textures of of a bar the graph samples to numerical grain-size or both classes). distribution histogram may be compared size and a for the cumulative visually and sampl curve. statistically through the use of these graphs. The third sheet presents the statistical characteristics of the grain-size distribution. The statistical parameters given are defined below following Folk (1974): Mean (measure of arithmetic D is class the average mean= grain DW where Z m e a n s the Z W sum, / size of the phi size) class midpoint, and W is the weight. + @84 : ayecage of grain 3 sizes (in phi units) corresponding to the 16th, 50th, graphic mean = l percentiles 84th and e * (@16 + 450 on cumulative curve. The phi unit( 4 ) is a logarithmic transformation of the Wentworth (1922) millimeter grain-size scale,employedfor ease in computations. 21 Median = g r a i n s i z e c o r r e s ' p o n d i n g t o t h e 5 0 t h p e r c e n t i l e . Mode = m o s t f r e q u e n t l y o c c u r r i n g g r a i n s i z e ; n o t g i v e n on computer-printoutsheetsbutapparentinTable S t a n d a r dd e v i a t i o n( , m e a s u r e 'of c e n t r a l t e n d e n c y o r , 1. i n the c a s e of s e d i m e n t s ,s o r t i n g ) q u a r t i ldee v i a t i o n = ($75 - ; f o c u s e s on 625) 2 central half of the distribution'. = y r a p h i cs t a n d a r dd e v i a t i o n (484-016) 2 broader portion of the distribution. inclusiv'e graphic deviation ; covers = (084-416) 4 coversextremes'ofthedistribution; ~ + -,,(1$195-65); 6.6 b e s t measure o f s o r t i n g : lnclusive Graphic Devia'kion . . . 0.350 = v e r y w e l l s o r t e d 0.35-0.'500 = w e l l sorted 0,50-0.710 = m o d e r a t e l y well s o r t e d 0.71-1.000 = moderately sorted 1.'00-2.'000 = poorly sorted 2.00-4.000 = very poorly sorted 4 . 0 0 0 = extremely poorly sorted Skewness(measure presenceof of symmetry of g r a i n - s i z e d i s t r i b u t i o n o r excess f i n e o r c o a r s e m a t e r i a l ) 22 best measure of symmetry (excess fines or coarse materials): +1.0 to + 023 = strongly fine skewed +0.3 0.1 = fine skewed (excess fines) -0.1 to + - to - to +0.1 to -0.3 0.1 = nearly symmetrical 0.3 - coarse skewed (excess coarse) 1.0 = strongly coarse skewed Kurtosis (measure of peakedness of grain-size distribution). graphic kurtosis = $95-6.5 2.44 (@75-$25) " " _," . . -- . . pH I 1.690 .. -3.000000 8.000000 -2.000033 4.000000. 4.340 -t.000000 2.000000 0.570 0.0 1.000900 .I. 000000 2.000000 .~ .. 1.05054 2.60783 5.3272 R 9.375h 11.959 .7.42036 16.5043 19.070 11.23268 27.7357 0.500000 22.100 13.73750 41.4745 18.89723 60.7717 27.200 16.90R05 17.2707 4,.0 0 0 0 0 0 0. 2 5 0 0 0 0 0.125000 . 0.062500 36.550 99.9991 0.031000 27.72320 5.000303 3.000000 . . ,. . . 30.400 . . .. . N W ' 41 0 . 0" *. . 0 . . C 0- a. 0 . . In. n ** ** * *n ** 0 0 0 I 0 D * **x *s * *x ** 0 * i ** *** * i *t x *** ff c q n, o ** ** ** 0 0 x 0 O * f ' C i *x t* ** *D* u * ** *+*a o m cot 0 0 0 0 0 0 0 0 0 c I C 0 0 0 0 p. (u x * *x* * x ** x * *** * *** x E *x * it 31 ii *z it *U ** x Z ** .. *x ul 0 C 0 0 0 4 0 0 0 0 0 24 I i I I I I I ! I I I I i 1 I I I I 1 I I j 0 0 0 0 0 0 . . 0 0 0 0 0 0 o o o o c o o ...... I 1 N - O N m . + f ; c 2.5 0. 0 \[; 9 0 9 N . 9 d o m O II . L? 0 D L n N ' m N . c . 0 m 9 0 It LL UI t- z tu . l 0 I h: V C Y c L L i u N n U: r” 6-8 N n m . . I .. O 0 0 O 0 0 O 0 0 m 0 0 O 0 0 a- O 0 0 h 0 Dco n o C 0 0 . U 0 N h O 0 0 0 0 . U 0 f m O . T . ~ 0 0 0 0 0 0 L n h ” ‘ I r* . d 0 . o e O . . O c) 0 0 0 0 o 0 0 0 o .. 0 0 0 0 0 0 cc. e LF. 0 0 0 0 m o o o o L n N d c ~ 0 Q 0 \ L . m ; ’ 0 m 0 0 0 n n 0 o n 0 0 o n .. 1 hl 0 0 0 0 0 0 0 1 rn 26 . 0 N I Ln d d . -1 0c. 0. 4. G.. 0- 0b. r-. 0 . . UJ. 0- 0 . 4 Ln. U. 0.. . or * n * U 0 " 0 r% n n N I n C *U b U * U U U U U U U x * ** * a x U *Q x . CI U * U *U U *UU 0 0 0 m 0 0 0 0 * U U *U* U ** ** U ** 0 0 0 0 0 0 0 in 0 * 0 0 (i U x U U U U **' x * 4 **x U b *U U *ii 0 0 U U U 0 h ** ** 0 U ** d 0 0 0 0 0 " 9 0 0 n 0 d 27 R 1 I$ L 4 N D F l L L 1/15-20 .. . 4 .. . STATISTICS 5 6 '> 1 8 0 CUMUL~TIVE PERtEUT PHI VALUE 5. -3.000 16. -2.000 25. -1.000 50. 1.000 75. 3.003 04. 3.000 95. 4.000 ' ' ' . . . . . . . . . . .. . . , , . . . .. . .. .. .. . ,.. . . . . . . .. .. . , . . . ... . . . . N m * a _" LANDFILL 1125-33 PHI . "- - ..,.. WEIGHT P F 4 C DIAMETER f MY) CtlY P'RC 3.88443 3.8344 2.65413 6.5386 5.77827 12.316E 14.560 10.06359 22.3904 . 21.330 14.53552 36.9159 0.250000 24.323 16.80951 5.3.7254 0.125000 25.600 17.60421 71.4197 3.000333 0.062500 Lh.820 11.62566 83.3453 4 . 000000 0 . 0 3 1000 24.530 16.95465 100. I 3 3 0 5.000303 . . 5.620 -3.000000 8.000300 -2.000000 4.000000 3.840 - 1.009093 2.000000 8.360 0.0 1 .000000 1.000030 0.500000 2.000003 .. ' ' ~ ' '' . .. . ' 'N W . 0 n t VI^ N . 0.- 0. d. 0C . 0- In. Cr 4. 0- 0 * X * *il c ** X Q 0 *' X *** *** * X ** a x x ** ** ** ** ** ** ** 0 x 8 * X X ** 9: X X 0 - rn 0 x ** 0 ** * 0 t X * 0 0 0 0 0 0 0 * *X D 0 c *r O 0 0 0 0 0 0 0 0 0 0 0 0 I N I m n * ** X *** ** ** ** II d ** 0 n C 0 0 VI 30 I . . I .+ I LANDFILL 1/25-30 2 1 3 3 4 i " STATISTICS a VALUE 9 IO . i I4 5. -3.000 16 16. -1.ooc) .2I5 -i I7 18 i"' 19 20 i :: 21 22 25. : r . . 75. , " u e z . ' !i 2 c) , $ 5 D k I. =' 41 . . . 0.7076033 = I N C L U S I V E STPNDA'?D D Z V T A T I D N = u4, 42 G T 4 Q H I t 45 FKEWNESS = 41 2.500CO 2.31061 0.29'39c) T\!l3LUSIVE kRAPt!IC SKEWNESS c, 4: (31APHIT, I<URT"Sl\ = 0,956284 = . .. .. . . , . .. .. 1.50000 rnGRAPVI(: ST4VDAPO DEVTATTON . ' ' :i ct?i . . . . 4.000 37G)U4f7TTLE DEVIATI'lN 38 I . . . r Y . . M E D T ~ N= I.OOOOO 5 u 3 1 5 31 C R A P H I C Y F t N = 1.33333 . . . . ,. . 3.000 $ $+ 2 .' 3 2 A R T i V M E T I C ME4U D I A Y C T F R = z 0 . . . . 4.000 84. 95. 24 21 26 27 28 29 30 31 . 0.0 1.000 5r). 'a23 t .. . . . . 12 13 , Pt!I CUMIIL4TIVE PERCEUT ' i l l ' . . . . , 6 7 'J .. . . ... . ' 5 : . 0.028571. . . . . . . . . . . 1 67 L A N D F I L L 1135-40 2 i 7 3 ' 4 PHI 5 . b '& 7 8 8.000300 10 I1 -?.000003 4.000000 I? 13 -L.000303 2.00000'0 33.400 0.0 1 .000300 21.363 1.000333 0.500000' 24.180 2.000003 0.250000 24.530 1.00001)3 3.125300 21.230 4. 000000 5. 000003 0.062500 .- 1 16 '7 j 18 2 i -1s z > 2 4 ,:5 ' 2 65.513 32.340 -7.000,333 . 14I5 20 21 ".21 13 ' P ERC CU" PFK (MY) 9 ... i W E IGHT OIAMETER 0.031000 . ' , .. . . 13.810 18.660 ' . ... .. ,; # . . .. . ... , 25.68816 25.6882 12.68136 38.3695 13.09701 51.46.65 8.37501 0.48161 59.8423 9.61885 78.9426 8.32484 5.4L 526 8 7. ?b76 92.h82P 7.31?07 99.9339 69.3239 W N L 0' c 0 a 0r-. a. 0 " 0- .?. - . . 7 . g : w 0" " 10. CL. w . a : 2 : 5 N . w or. 0" .: d. 7 0" 0 m In . n *U ** ** U *U !UL * *UU * x 0 0 C U ** *** U b ** ** U P 0 0 0 0 0 0 **U *U* *U* 4 0 0 CI x U U ** * *. U 0 0 0 f.l 0 c 9 0 N c: 0 - 9 0 . P 7 0 0 n 0 I d 0 0 c ! n 0 0 0 0 0 0 0 0 0 0 * I n 33 V 0 0 0 0 0 0 . 0 0 . . 0 0 0 0 0 0 IJ 0 0 0 0 0 0 0 I l l 1 . m m m t u r r ~ l f ....... 3 J 3 5 >k- UI -7 t u.1 UU -IC11 3 W 3 sa V 34 * I UY 0 I U1 CL C) a T I" i5 c I 0. o o o o c o o o o 0 0 0 0 0 0 0 0 6 o o o o o o n o 0 0 0 0 0 0 0 ~ ( v " ' ...... ~ o o c . o ~ ~ . o r n - 0 0 0 t n N ~ ~ O 0 Q 0 0 O 0 0 0 O 0 O O o c I 0 0 0 d O O O o c I o o o c 3 0 0 0 m 0 0 ' ; r ; - . 0 0 0 0 0 0 0 O O Q O O C O 0 0 0 0 0 ......... 0 0 0 0 O m R l d Q . - r N r n * L n I I I 35 0 10 I VI VI UJ or C . 4. . 0C 0- I-. 00 . 0- In. 0- \t. or e- 4. 0- 3 N. . i .L n z Q -I 5 0 c * x c u c * *o 0 I n 0 0 0 0 0' 0 0 I 0 0 0 0 0 0 4 \ N I n 0 x ** * x x 4t n 0 0 0 0 - CI *x * ** * x x *x *x x 0 * '4 * ** c *U *x * ** x U U *U.x ** *t: .x ** :: ++ rn 9 U * c 0 D 0 0 0 0 0 0 0 N * E *** *xb *x x b x x ** ** *x c *. 0 F *x it ** 0 0 0 0 0 U U 0 0 0 I n x. 0 0 T . 36 i 6 . '. STATiSTICS . . CUMIJL4TIVE PERZENT 5. 16. PHI VALUE -3'. 000 0.0 .. , . 1 .e00 2.000 , . 3.000 3.000 4.003 . . 0.5771675 W 4 L A N D F I L L 1/75-80 CUM P E R C PHI OIAMETER -3.000000 8.000000 -2.000000 4.000000 7.570 -1.000000 2.000000 4.593 0.0 1.300333 1.00@0@0 {MY) . 23.800 . . 21.65802 ? 1.6590 6.9797 1 28.6317 4.17693 32.8146 6.850 6.23351 3 9,043 1 0.500000 13.340 12.59442 51.6425 2 . OOO3OO 0.250000 .17.5hO 15.97962 67.6221 3.000003 0.125OOO 15.77942 83.4016 .. 4.000033 0.062500 17.340 l.o.303 9.10031 92.-5916 5. oonoo3 0.031000 8.240 .. 7.4934 1 . '... . 190.0@09 w co Ob. n . 4. 0 . h. 0 . . a. O r u. - . * 0 ** * * *** * *U* ** U ** x* I I 0 0 0 0 0 c 0 c * ** *** ** * ** U E x 1 c * *x I I ** x *** * U It *x- 0 m 0 c1 U 0 0 0 " 0 c 0 0 0 0 N 0 0 0 0 Z 0 0 0 0 0 0 0 O 0 0 0 0 0 0 0 I i 0 I N L c, 0 0 0 0 0 O 39 " . . . .. . . . . . . , . . CUMULATIVE PEPCEVT PHI VALUE . .. . .. . . . . '3TATI'STICS . . . . . , , .. . .. 13 5. -3.000 th. -3.000 25. -3.000 50. 0.0 75. 2.000 84. 3.000 95. 4.000 .... , , . .. . . .. 0.8335965 s. D " a .. -I : I I . . P 6 H7 11.31s 1 8 -3.000005 9 -2 e 0 0 0 0 0 0 - 1.000000 15.8331 " , , . 0.0 . '-:2. ooooob . . . ........ La oOOooo ,.'.':,': . . ,.. ., 7.003033 .. . . . . . " 4 ~ 0 0 0 7 0 3' '' . . . . . . . . . ...... ....... . . . . . . . . . . . ...... ., ' . . 23.6436 32.9435 . 50.3702 24.48843 74.'3597 11.69565 8 b . 55.43. 13.4456L 93.3999 . , . . . . . .. .................... . . . . . . . .. 24.5L0 . . . ........... . " .. 5 . 4 3 0 9 1 17.42273 , ., 27.5166 ..... :, " 0.031000 5.000330 x_ 4 4 .h40 3 o ........ ..... 21.3 . . . . . . ' .. . . 31.763 ........ ..... 0.062500 1. .. - 4.99553 .... .... .......I ...."....... 7.0(,0 ..I:.. 7 . . . 3 . 8 7 2 9 5 ' ..... .: 9.900 ... . . . . . . 0. 2 5 0 3 0 . 0 0.125030 ' .... .,. . '3.000303 ' ..... ". . 0.500000 1.000000 ....... . . .. . .. . . . . 8.760 . . . . . . ~ . . . . . . . . . . . . . . . . . . . . ,*" . . . . . . Ip P . . . . . . . . . . . . . . . . . . , , I ,, .. . . 4 . 0 . 0- 00 : OS- ?-. . .. . . . , . , . . ., 0 . . .. .. . . . . . .. ,. . . 0 ,. . . . I . ' . . . .: 0 . . Y . .. . . : . ." i... . .. . . i . ... .: ' 8 . . ! 'I *91 U **x a ** x +Q ' .. .. . . .. . .. . . . . . . . . ' . *' **it . ** 4 4 *x ** E .. ** ** x U Q 4 s : .. . . . . . . !. . :. , . . . . . . V L UJ Y a L a U hl (\I U> 0 O' N m e . . N 0. 0 0 0 0 0 0 0 0 0 0 0 0 0 - . i. . . ~. . . ' . . . ,. .... . : . .. j :3. . .. . . .. . . . . . .. . . . ..: . . ' . . . ~ ... .~ i . . ' : I .. . . . 1 . : , I 44 , .. ., . . . . ..I I ., ? . % . . .. , . .. .. .. i . I ,. . : *.~ . i .. ... . i . . : ~.' , . . , ? . . . . . . . . . . ., .... 1.. . . 3 . . . . . . -: . ... : ... .. . I J , . . . . . . J dy . .. or . * e . * * 2. . . '. . . . . 0 ,; 0 . . ..: . . . . . . . . . . . . .. .. .. . . .. , . . . . . . . . 45 - .... ! 1 i . i ! I .. - " L - ___."" * . "d i 1 A2 : . ; . -:3 . .-! ! PH 1 ''11 , ,. .I -.5 - 12 - 2 3 ! ? ). 'j 12 5 4-31 .2 29 31 37 2 . 3; = 34 :: "35. 2 , $ "39 I 1:. !% 2 ,: -? . . 36 37 3 <D 41 42 i3 41 45 46 4rt :7 . . . . . . . ... '' . .t' 000000 5 .000000 . . . . . 1. . , '' ".,, . . . . .WEIGHT P E R C 1: ....,.......... ..... . 47.O892 . . . . . . . 59.4822 5'4.b 15 5 ' . . . . . . 7.340 . . . . . . . . . . 4.86364 ' .................. ., .,.. ~ . . . . . . . . . . . . . . .. ............ 9.910 22.003 ..... . . . ;. .. . . . . . ' :,,:... 6.16438 . . 65.h456 ' 13.82431 79.4709 14,09451 ,93.4654 ': . . 22.430 . . . . . . . .,. .. . . . . . . . . . . .......... . ... . . . ." ..................... . . 8 I .. .............. .' O R . 't416 . 99. $437 90.39?Q .. . . . . . . . . . . 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P.00c)000 0.503000 0.250000 . 29 '9 0G0 .I.., 2eOODOOO.' . , 3.000000 2s -27 0001c13 ?. 000000 24 26 s 1.0031)OO 21 . 5 . L ' io i' ' 2 ',.. 'J 15 I& 17 18 *dl9 i ,& 1 -1 , e,O+JOOOO Ip,OOOOOO" -20 0 0 ~ 0 0 3 ii I _ 1 -3a003331 IO I2 I . I M I j . .................. .,........ , ,. .... . . ...~. .......>. .... . . 8 . 'DIAMETER:",::"'. .,"':::: ....'. :..'~ ...'WE'IGHT :.' 6 7 9 , . . . . . ? I : . , ..... 3: ' . . . . . . . . . . .." ... . . . . ...... . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . , . . . . . . . . . . . . . ...,....... ..,......... ............................. .. ... ,.. . . . .,. ........................... !.. ..... ... s:. . , : ~ .-_ ~ -*. . . . . . . .. . .. . . . . . LAhIOFILL 2330-35 . , _" ._ ... ...... ... .. ., ; . . . . . . . .,. . . . . . . . . . . . . " , .! P ,. . . . . . . .. . , . . . . . . . ................................... . . . . . . .d a ii -~ ,. %""*.ao1.N1:zaz.nsf3a~:":3rE2x + . ?I.=: 0.C . . . I 0- D In.. a n 0 0 0 ... . . '. .. . . t *u I 0 n 0 0 0 0 m 3 I 0 n .. r. 0 .. 0 go , 0 0 n 0 0 *.. V I r . . , ! ./ ,. . . .. : :. . . . . . .... . . .. 48 . . . I i i ! Ii I 1 i I i _ :. 1. .> +. : . .! : ' : i .. - . .. .. . . I. . . ' . . .. . : _ .. , . . : (F. 4- d 0 m e 0 w . I m . . 49 . 0' II I! c) e (A . 4 ....-..".."X_"I_ ; -3.000000 -2eooo3G3, 6;; I? -1: 16' 17 1- 2 ?"IP .. la '. . 2 . i 11 14 1s Yn .; G:; 2 = 2 ' -35 W * ' ....... ... ............ 31 ' : 17 -g b;; ' % .A Q , . . ..: 41 . . ' , I" ., . . , ,. . I, 19.2357 .. ~ s i 1.380 . ... :: ~ ;:. : .. . . . . . . . ...... . . . ... .. I . . . . . . . . . . . . . . . . .. .' . . ... . . . . . . . . . ...X.._.. . . . . . . . . . . . . . . . .I 60.4793. ~e.3295 517.1072 ' :. 99.9ZL5 0.97845 :100.3035 ................ . . . .. . . .. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . ... :. ; . .... . . .. 3 50 5 4 g o " .I"" .. I . . . . . . . . . . . .~ . ,. . .. . . . . . . . . . . . . . . . . ". ... . . . . . . ... .. . , ..... . . .. . . . . . . . . . . . . . . . . ..... . . . :... . . . . .. .. . . . . . . . . . . . . . . . . . :._ 2 5 . 7 0 4 1 . l.. . . . . . . . . . . ..... I z 2B 2 ." . . . . ..... '. . :T -13.a634 I" "' .. 36' ,,. 5 i ~, ' 32 33 34 _ ~ CUY P 5 P C *.. 3". .. '"1 .... '' 5 a 000935 . 12 19 30 b 31 L v . I . 7 a 000333 4 . 000303 $ q>I,2 i .... '1 ' 2s 0 0 3 3 0 3 ?B 21 6 ' 0-0 1. boo003 . - II . . . . :., , ..... :. . . . ...... .... .......... ....... ';.'. ,.,I. ~, I', 8 * 0 ~ 0 ~ ......... 0:..:. 0 . ..':..:. ....... 19rfh0 ...... .:. L 3 ~ 8 6 8 4 2 . . . ,;.; . ....... .....I_. l;.OOOODO .......... ...... .......... . . . . s ) c . . , ..!. .... 7 . 5 7 0 . . . . . . . . 5,36727 "_....... ..". '' ." ... . . . . . . . . . ~ " 2 ~ O O c 1 ~ 3 ' G::O : , . '....... .""' 9.253.,;: . . . . . . . . . . . 6,55842 . . . . . . . . . . . . . I D oOo3co ....... . . . . . . so ,~...,' .. ",....~ ~. " . 10.05389 .... . . . 0.500000 . 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B . . . . . ... . ...... . .. - . . . . . . ! 1 . .~ e l .... . . . .. . . .. . . . . . ". . .. . ' . ... . .. ... 5 4 . _ .. . . .. . . . .. . .. . . ~ - . . . I I 1 i . I' ! ! ! ! i I i ii i I ii I I ! I . . .. . .. .. . . . . ... . . :. , .. . .. . '. . ; . . . : . . . . .. .... .. ... .. . . . . . , ... .. .. . ' . . . .. . . . h . . 0 RI . . 0 0 0 *m I- @ . if a. r- . . .. .: > .. ,. .. I . . .. 0 0 0 0 0 In N 0 . : .. .. . ., . .. . r , .. >. . . 2 . . ! : . . . .. . . . 1 : . I. :. I . . . . . . . . .I . .; . . .. . . . , . ,. .' j ..... -. . .. . .> :. . . . i ... :. .. _ . . . . 56 . * . . : z .: . . . . ... .. : . I . . . . . . s . . . . . . . . . . . : . I .. . . .. . . . . . . . J 1 U a z Q _I * .. 0- e. . I . 0- m. D 0- * * . . . ., D : . . . .. n . . .. '. . . ' . . . . , . .. . . .. :. . , .. 1: . ' n . . , . n .. *x 0 b 0 0 0 x M 0 0 0 0 U 0 ; I r . , . . . . . . . : . I I . ? ' . , . ' .. . . .. , . . 57 .. .. . .. . . . , ! ' 1!' 1 i '.. .' . , . ! . . . . . " ~. I : .. ., f? . : . , : t f . i . . 62 Appendix B Trilinear Plot of Dissolved Solids 63 EXPLANATION The total dissolved solids contents the-.water of samples were plotted on a trilinear diagram to permit their comparison and classification. Trilinear diagrams consist of3 parts: 2 triangular fields and a diamond-shaped field. The triangular fields depict the distribution of cations and anions separately, whereas, the diamond-shaped field shows the combined chemistry of the water. Each sample is thus represented 3by points on the trilinear diagram, 1 in each of the 3 parts. Points in the cation and anion fields are located on the basis of percentage of specific ions. Points on the diamond field are located at the intersection of lines projected, parallel to percentage boundaries, from the cation and anion triangles (see points plotted for "PI' in In . accompanying making diagram) trilinear plots, the concentrations of dissolved solids are converted from parts per million values (as used in Ta 4) to a value which better reflects the true chemical character of the water,equivalents per million(eprn). The epm value is obtained as follows: ppm epm = equivalent equivalent wt. = The conversion of The accompanying of ion and weighto,f iqn atomic weight of ion chemical valence of ion ppm to epm table is a in Xerox this study reduction was of done the by printout giving epm values and computed percentages for each ion. The 0 trilinear diagram given here was prepared from these computer. data. sheet 64 Waters from different aquifers may plot in distinctly different portions of the trilinear diagram. The waters involved in this study, however, all come crom essentially the same (single) aquifer and thus plot in about the same region on each Ground part waters of the diagram. may be classified on the basis constituents. T o facilitate this, the cation and anion triangles the in trilinear diagram are subdivided of into dissolved 'smaller fields, corresponding to dominant ions in the water. These (see small subdivisions are used in classifying the water triangles at sides of the diagram); a water is assigned a name from first triangle. fill the cation triangle and then another from The waters in the vicinity of the Socorro land wouldbe classified bicarbonate waters. as calcium-sodium-magnesium-sulfate- the anion . . . ~. e ..* . . " ' YKLL 1 4.71,7 R.53J AU.R(II 7.021 2 3 1.1'17 3.716 62.?93 11.197 1.613 t(;.m 41.325 74.720 4 3.117 lC.157 34.033 17,779 5 6 7 9 10 l.l3h 7.166 56.3h9 13.216 I .?'.S 1.177 55.140 !.?la I 1.454 3.1Jh 62.745 11.516 7.1'15 5.>17 75.600 15.377 3.421 9.561 11 42.5hl 12.870 5.?G3 11.6'13 19.RRe 12 19.3R1 3.523 7.t.53 13 3O.OP7 9,469 1:r37 39.001 22.518 1b.G74 14 .I 3 ,J 7 5 . 42.710 15 16 . 5.603 I.Irr5 6.515 39.647 ln.9~1 1.3h7 4.124 58.J5C 17 13.OQ6 1.3'14 l.sj73 62.S99 18 tq.z!n 1.717 2.775 67.b90 ,19 20 10.0sa . 1.737 6,.1'9? 44.1.01, 13.U10 21 22 ' I.7 7 7.710 3.'47" 62.451 12.>16 (.D27 9.797 53.Of.7 15.053 l . v n n.>ns 45.4~3 18.491 . . m m - ' 66 NewMexicoBureau o f Mines and Mineral Resources Water Q u a l i t y D i a g i a m Trilinear plot of dissolved solids encountered in ground waters of Socorro landfill study area