PRELIMINARY EVALUATION OF THE MINERAL RESOURCE POTENTIAL OF THE PETACA PINTA WILDERNESS STUDY AREA, CIBOLA COUNTY, NEW MEXICO Mark J. L o g s d o n New Mexico B u r e a u of Mines and Mineral R e s o u r c e s Socorro, NM 8 7 8 0 1 D e c e m b e r 23, 1981 TABLE OF CONTENTS Page Abstract Statement of Purpose Introduction Location and Accessibility Physiography Previous Geologic Investigations Acknowledgments Mining and Exploration History Geologic Setting Stratigraphy Structure Resource Potential Summary Base Metal and Uranium Oil and Gas Potential References Appendices 5 5 7 9 9 Potential 10 13 18' LL F I G U R E CAPTIONS Figure 1 Geologic map a n d s t r a t i g r a p h i c PintaWildernessStudy column of t h e Petaca Area. A l t e r a t i o n zone i n t h e r e g i o n of t h e Petaca P i n t a WSA. Uranium c o n c e n t r a t i o n i n w a t e r s a m p l e s n e a r the Petaca P i n t a WSA. O i l tests i n t h e v i c i n i t y o f t h e G e n e r a l i z e da x e s 1959) . Petaca P i n t a WSA. of s u r f a c e s t r u c t u r e s ( a f t e r Wengerd, ABSTRACT The Petaca P i n t a W i l d e r n e s s S t u d y Area (WSA) a p p r o x i m a t e l y 90 km west ofAlbuquerque, southeastof New Mexico,and 2 0 km Acoma P u e b l o , i s i n t h e Acoma s a g , an embayment on Juan B a s i n o f t h e C o l o r a d o the southeastern side of the San Rocks i n t h e Petaca P i n t a area r a n g e P l a t e a ut e c t o n i cp r o v i n c e . i na g ef r o m , located L a t e T r i a s s i c t o Holocene. Triassic S y s t e m ; t h e F o r m a t i o na n dW i n g a t eS a n d s t o n eo ft h e E n t r a d aS a n d s t o n e , They i n c l u d et h eC h i n l e Summerville FormationandZuniSandstoneof t h e J u r a s s i c System;theDakotaSandstoneoftheCretaceousSystem; g r a v e l sa n db a s a l t so ft h eT e r t i a r yS y s t e m ;a n dl a n d s l i d e ,e o l i a n , a l l u v i a l , a n ds p r i n gd e p o s i t s graphicrelationshipsofthe of t h eQ u a t e r n a r yS y s t e m . Strati- Jurassic t o Q u a t e r n a r y u n i t s r e f l e c t e p e i r o g e n i c movements. A narrowzone of a l t e r a t i o n i n t h e J u r a s s i c s t r a t a , w i t h some are similar t o a l t e r ' a t i o n p a t t e r n s a s s o c i a t e d w i t h a s p e c t sw h i c h uranium m i n e r a l i z a t i o n i n t h e G r a n t s d i s t a n c e i n t o t h e WSA. District, e x t e n d s a s h o r t Uranium v a l u e si ns u r f a c es a m p l e s are v e r y low, b u t t h e a l t e r a t i o n z o n e is a potential exploration target. There i s no s u p p o r t i n f i e l d or g e o c h e m i c a l e v i d e n c e f o r r e s o u r c e p o t e n t i a li nc o a l ,p r e c i o u s metals, b a s e metals, i r o na n d m a n g a n e s e ,g e o t h e r m a le n e r g y ,h i g h - c a l c i u ml i m e s t o n e ,f l u o r i t e , or b a r i t e . Shows of o i l a n d g a s h a v e b e e n r e p o r t e d f r o m e a s t e r n C i b o l a County.The o i l a n dg a sp o t e n t i a lo ft h e m o d e r a t e l yf a v o r a b l e ,p a r t i c u l a r l y carbondioxide. Petaca P i n t a r e g i o n i s f o r c o m m e r c i a lq u a n t i t i e so f 2 PURPOSE The purposeof this study is to compile the known data on geologic setting, mineral exploration history, and mineral resource The potential of the report can be Petaca used by the Pinta Wilderness Bureauof Land Study Management Area. and other interested parties to evaluate the resource potential of the a Petaca Pinta wilderness area. as one factor in its potential designation as INTRODUCTION Location and Accessibility The Petaca Pinta Wilderness Study Area (WSA) is located approximately 90 km west of Albuquerque, New llexico, and approximately 20 km southeast of Acoma Pueblo. Access to the Petaca Pinta areais poor. Improved gravel roads from El Rito on Interstate-40 or from a poorly maintained access to the of the WSA. Coreoon dirt 1? Ranch road of Acoma Route6 lead to NewMexico along Arroyo Puebloon the Colorado southeast which gives border At many times of year, this road is passable only for four-wheel-drive vehicles. Jeep trails and unimproved dirt roads approach the western boundary of the WSA across East, Blue Water, and Victorino Mesas. However, these roads do not provide practical accessto the formidable cliffs WSA which because form the they deadend western above the of the WSA. boundary Physiography The Petaca Pinta WSA lies within the Acoma-Zuni section of the Colorado Plateau physiographic province. The climate is semi-arid; vegetationis characterized by grama-tobosa-mesquite shrub steppe with some stands of piiion-juniper woodland on the higher mesas (Morain and others, 1977). Elevationsin the mapped area range from 1760 m in the extreme northeastern corner of the map to2230 m on Blue Water Mesa. There are four principal 1) high mesas formedon landforms in the Petaca Pinta area: 2 ) landslides Mesozoic sedimentary rocks along the western margin: composed of sandstone, basalt, and shale of Jurassic and younger .. Y ages which have slid over shales of the Triassic Chinle Formation in the central part of the area: 3) low, basalt-capped mesas (with vent complexes) along the eastern margin; and 4) alluvial lowlands formed along the drainages of Big Sandy wash and Arroyo Colorado. Previous Geologic Investigations Stratigraihic studiesin the region include Gregory (1917), , Kelley and Wood (1946) , Landis Harshbarger and others (1957) and others (1973), Maxwell (1976b), and Silver (1948). Structural geology and tectonics of the region are considered by Kelley (195 1955), Kelley and Wood (1946), and Maxwell (1976b). Geologic maps which include part or all of the WSA have been published Jicha by (1959), Kelley and Wood (1946), Machette (1978), and Maxwell (1976b, 1979). Detailed geologic mapsof adjacent areas have been prepared by Maxwell (1976), Moench (1963, 1964), and Moench and Schlee (1967). C.H. Maxwell of the U . S . continuing his field quadrangle maps mapping of the Broom Geological Survey is further into Mountain, Marmon the ofarea the WSA Ranch, and with Cerro del Oro 7 . 5 minute quadrangles (in preparation). Acknowledgments The author gratefully acknowledges the of C.H. willingness Maxwell of the U.S. Geological Survey to share unpublished maps of portions of the Petaca altered Mesozoic Pinta sedimentary WSA rocks and and chemical Quaternary analyses spring of deposits of the WSA. The map of the area and the description of the geology profited from discussion R.N. with Chamberlin of the New Mexico on oil and Bureau of Mines and Mineral Resources. The section I 5 gas potential was prepared by R.A. Bieberman theof New Mexico Bureau of Mines and Mineral Resources. This preliminary mineral resource New evaluationwas performed Mexico Bureau of Mines and under a Mineral contract Resources between the and U the .S. Bureau of Land Management. The report was typedby Sue Ness and Lynne McNeilof the New MINING There has Mexico AND been no Bureau of Mines EXPLORATION mining of and Mineral Resources. HISTORY metallic or non-metallic minerals in the areaof the Petaca Pinta WSA. There is no record of detailed exploration for minerals in the area. Two test wells for oil and gas in the of the VISA are vicinity described in the section on oil and gas (below). GEOLOGIC SETTING Stratigraphy Figure 1 is a geologic map of the Petaca Pinta WSA and adjacent areas, compiled from published maps of Jicha (1959), Machette (1978) and Maxwell (1976b, 1979), unpublished maps of Maxwell (1981, personal communication), and field work conducted for this study. Rocks in the Petaca Pinta area range in age from Late Triassic to Holocene. The stratigraphic units used on the map are described in the composite stratigraphic column which accompanies the map. The Petaca Pinta area is located in the region of the Jurassic overlap. The wedge of Jurassic rocks which lies between the Chinle Formation (Upper Triassic) and the Dakota Sandstone (Upper b Cretaceous) disappears southward due to depositional thinning against a positive area and to truncation by pre-Dakota erosional surfaces (Silver, 1948). In terms of mineral resources, the stratigraphic relationships are important, because the principal of New uranium-bearing Jurassic formations Mexico (Todilto Formation and Morrison Formation) are ab'sent in the Pinta Petaca WSA. The Upper Triassic Chinle Formation is unconformably overlain , T. 6 N., by Middle Jurassic Entrada Sandstone north of 3Sec. R. 7 W. of the From section 13, T. 6 N., R. 7 W., to the southern end map area, by the RockPoint the Chinle Formation is unconformably overlain Memberof the Wingate Sandstone (Upper Triassic) (Maxwell, 197633; 1979). The Entrada Sandstone unconformably overlies the Rock Point Member of the Wingate Sandstone as far south as sect.T. 19, 6 N., R. 6 W., where the Entrada is truncated by an angular unconformity . of the base of the Middle Jurassic Summerville Formation (Maxwell, 197633). South of the Entrada pinch-out, the Rock Point Member of the Wingate Sandstone is overlain unconformably by the Summerville Formation. The contact between the Summerville Formation and the overlying Upper Jurassic Zuni Sandstone is gradational. The Zuni Sandstone is truncated by Cretaceous erosion and pinches out very near the Entrada pinch-out (Maxwell, 197613). the Summerville unit of the Upper The high Formation is Cretaceous mesas along the overlain Dakota South of this point, unconformably by the basal Sandstone. western boundary of the map are 7 capped by D a k o t aS a n d s t o n e .T e r t i a r yg r a v e l s ,c o n t a i n i n g ofmiddleTertiary l i e o na ne r o s i o n D a t i l Formationvolcanics, s u r f a c eo nt h eD a k o t a clasts (Maxwell, 1 9 7 6 b ) .T e r t i a r yb a s a l tf l o w s on Petaca P i n t a , B l u e W a t e r unnamed mesa s o u t h o f Mesa a n d t h e Blue Water Canyon cover g r a v e l b e d s a n d p a r t o f t h e e r o s i o n b a s a l t s may b e correlative w i t h t h e b a s a l t s s u r f a c e .T h e s e of Cerro d e l Oro, t o t h es o u t h e a s t ,w h i c hh a v eb e e nd a t e d3 . 1 i 0 . 5 m.y. Love, 1981, personal communication). (D.W. whichcap The b a s a l t s are o n s u r f a c e s w h i c h Gunn Mesa andMiddleTsidu-Weza are 2 0 0 m lower t h a n t h e s u r f a c e o n w h i c h t h e B l u e Cerrodel Oro b a s a l t s l i e ; t h e s e b a s a l t s formed on incompetent WSA p e r se. may b e Q u a t e r n a r y i n age. e o l i a n d e p o s i t sc o v e r Q u a t e r n a r yc a l i c h e ,c o l l u v i u m ,a n d p a r t of Blue Water and E a s t Mesas. Water Mesa- Q u a t e r n a r yl a n d s l i d ed e p o s i t s Triassic C h i n l e s h a l e s c o v e r Q u a t e r n a r ya l l u v i u mf i l l st h ev a l l e y s Wash a n dA r r o y oC o l o r a d o .A c t i v es p r i n g s travertine in the Arroyo Colorado valley much o f t h e of BigSandy are d e p o s i t i n g a t thesouthernend of t h e map area. Structure The Petaca P i n t a area i s l o c a t e d i n t h e Acoma s a g , a n embayment on t h e s o u t h e a s t e r n side o f t h e San J u a n B a s i n Colorado P l a t e a u t e c t o n i cp r o v i n c e( K e l l e y , of t h e 1955;Maxwell,1976b). The c h a n g i n g l i t h o l o g i e s a n d t h i c k n e s s e s o f t h e J u r a s s i c u n i t s t h er e g i o n( M a x w e l l , 1 9 7 6 b , 1 9 7 9 ) r e f l e c tr e c u r r i n ge p e i r o g e n i c movements d u r i n gt h eJ u r a s s i c( S i l v e r ,1 9 4 8 ) . Regionaluplift E a r l yC r e t a c e o u s a n ds u b s e q u e n te r o s i o ni n time t r u n c a t e d o l d e r u n i t s Late Jurassic o r (Maxwell,1976b),and in 8 t h e DakotaSandstone was d e p o s i t e d on t h e e r o s i o n a l s u r f a c e . StratigraphicrelationshipsoftheCretaceousandTertiaryQuaternaryunitsindicatethat a t l e a s t minor u p l i f t c o n t i n u e d time (Maxwell, 197613) i n t oT e r t i a r y . map area o f o u r s t u d y h a v e n o t Althoughfaultswithinthe by e a r l i e r w o r k e r s , a t l e a s t one area o f major beendescribed f a u l t i n g i s probable.AlongArroyoColorado, east o ft h eA l c o n WSA and Gunn Mesa, C h i n l e F o r m a t i o n c r o p s o u t a n ds o u t ho ft h e along a lowscarp:theChinlestrikes N78E and d i p s 10"NW. i t s e x t e n s i o n t o t h e e a s t are t h e t h r e e S o u t h of t h e s c a r p a n d a c t i v e ,t r a v e r t i n e - d e p o s i t i n gs p r i n g s . The s c a r p ,t h es t r i k e a n dd i po ft h eC h i n l e ,a n dt h el i n e a ra r r a n g e m e n to ft h es p r i n g d e p o s i t s( w h i c h a r e up h y d r o l o g i c g r a d i e n t f r o m t h e s c a r p ) s u g g e s t are c o n t r o l l e d by a high-anglenormal that a l l three features f a u l t , down thrown t o t h e s o u t h . A l t h o u g ht h eM e s o z o i cs e d i m e n t a r yr o c k sa p p e a rt ob e a structurecontour essentially flat-lying, r e g i o n (Maxwell, 1976b,Fig. r e p o r t show t h a tt h e r eh a sb e e n 1 3 , T. 6 N., R. dome fromwhich 1976b). 7 W., 2 ) a n dt h eg e o l o g i c some f o l d i n g . i s l o c a t e d onBlue high-point of the region Acoma map i n t h i s The s t r u c t u r a l Water Mesa i n Sect. a t t h e crest o f a s h a l l o w ,n o r t h e a s t - t r e n d i n g therocksdip away i n a l l d i r e c t i o n s (Maxwell, The n o r t h w e s t - t r e n d i n gA l c o n Maxwell (1976b) a s b e i n g Duringfield map o f t h e formedby dome was i n t e r p r e t e d by i n t r u s i o no f a b a s a l t i cp l u g . a small work f o r t h i s p r o j e c t , t h e a u t h o r o b s e r v e d basaltic plug partially buried a r r o y on o r t ho ft h e by Q u a t e r n a r y a l l u v i u m i n Ranch i n s e c t . 2 8 , T. 6 N . , R. 6 a small p7., n e a r t h ec e n t e ro ft h e domal s t r u c t u r e shown o nF i g . theoutcroppatternofthisdeformed it p r o b a b l y r e p r e s e n t s i n t e r f e r e n c e intersection of 1. Indetail area i s exceedinglycomplex; s t r u c t u r e s formed by t h e several small domes o f v a r y i n g i n d i v i d u a l i s r e l a t e d t o a small i n t r u s i v e p l u g . g e o m e t r i e s ,e a c ho fw h i c h The b a s a l t i c p l u g a single whichwas.observedprobablyrepresents a largerplugwhichunderliesthedeformed apophysisfrom area. RESOURCE POTENTIAL Summary There i s l i t t l e o r n o s u p p o r t i n f i e l d or g e o c h e m i c a le v i d e n c e i n u r a n i u m ,c o a l ,p r e c i o u s forsignificantresourcepotential metals, b a s e metals, i r o na n dm a n g a n e s e ,h i g h - c a l c i u m limestone, or f l u o r i t e a n d b a r i t e . The T e r t i a r y g r a v e l s m i g h t be used as a g g r e g a t e , a n d t h e T e r t i a r yb a s a l tc o u l db eu s e df o rr o a d metal o r r i p - r a p . However, access compared t o o t h e r s o u r c e s o f remotelocationandpoor aggregateorroad-building materials d i s q u a l i f y t h e Petaca P i n t a area a s a r e a s o n a b l e s o u r c e . Tertiary basaltic a c t i v i t y s u g g e s t s t h e p o s s i b i l i t y g e o t h e r m a lr e s o u r c e si nt h e area. a l o n gA r r o y oC o l o r a d od i s c h a r g ec o l d of However, t h e a c t i v e s p r i n g s waters. Although no d e t a i l e d h e a t - f l o wm e a s u r e m e n t sh a v eb e e nm a d e ,t h ep o t e n t i a lf o rg e o t h e r m a l energyinthe oil Petaca P i n t a r e g i o n a n dg a s i s poor. are theonlynaturalresourcecommoditiesfor which t h e Petaca P i n t a area h a s s i g n i f i c a n t r e s o u r c e p o t e n t i a l . O i l andgaspotential p r e p a r e d by R.A. are d i s c u s s e d i n a f o l l o w i n g s e c t i o n , Bieberman. 10 Base Metal and Uranium P o t e n t i a l A zone o f a l t e r a t i o n is present along the eastern margin Blue Water Mesa w i t h i nt h e WSA ( F i g . 2 ) . of i s a l o n gt h e Thiszone projectionofthenorth-south-trendingalterationzoneeastof was d e s c r i b e db y Acoma P u e b l ot h a t zone d e s c r i b e d byMaxwell, Maxwell ( 1 9 7 6 b ) . A s w i t ht h e thealterationaffectsprincipallythe J u r a s s i cS u m m e r v i l l eF o r m a t i o na n dZ u n iS a n d s t o n e ,w i t hr e l a t i v e l y m i n o ra l t e r a t i o ni nt h eb a s a l The a l t e r a t i o n i s DakotaSandstone. characterizedbybleaching,corrosionofsandgrains,kaolinitic v o i d - f i l l i n g s ,t a b u l a rz o n e si nw h i c hc a r b o n a c e o u so rm a n g a n i f e r o u s m a t e r i a lc o a t ss a n dg r a i n s ,a n dc r o s s - c u t t i n gc o n c e n t r a t i o n so f p y r i t e ,w h i c hw e a t h e rt ol i m o n i t ea n dg o e t h i t e .C o n c e n t r a t i o n so f limoniteandcarbonaceousormanganiferous material cemented by of a l t e r a t i o n . c a r b o n a t ea r ea b u n d a n ti nt h ez o n e y e l l o w i s h - b r o w n" l i e s e g a n g "b a n d s Dark-brownand are common a l o n g t h e b o r d e r s o f thealterationzone. S e m i q u a n t i t a t i v es p e c t r o g r a p h i ca n a l y s i s 1 9 8 1 ,p e r s o n a lc o m m u n i c a t i o n ) a l t e r a t i o nz o n e s and Zn. are h i g h (10-500 ppm) i n Mn, B a , Co, Cu, N i , The b l e a c h e d core of o n er o l l - l i k es t r u c t u r e i nt h eS u m m e r v i l l ec o n t a i n s V, shows t h a t w h i l e t h e b l e a c h e d c o r e s o f are r e l a t i v e l y low i n most trace metals, c o n c r e t i o n s i nt h ea l t e r a t i o nz o n e s Pb, Sc, S r , V, of samples(Maxwell, 5-30 ppm o f Co, C r , Cu, Mo, Pb, S r , and and 1 5 0 - 2 0 0 ppm o f Mn and B a . S u m m e r v i l l es h o w sv a r i a b l ee n r i c h m e n t C r , Cu, Pb, S c , S r , and V. fractureorjointfillings " L i e s e g a n g "b a n d i n gi nt h e ( 5 t o 3 0 0 ppm) i n Mn, B , B a , C a r b o n a t e -a n di r o n - r i c hv e i n l e t sa n d show v a r i a b l ee n r i c h m e n t ppm) i n Mn, B a , Co, C r , Cu, P b , S r , V , and Zn. (1.5 t o 300 Copies of t h e analytical results are included The significance of in the thealteration appendices of this report. zone is problematical. The presence of a very similar larger, north-south-trending alteration zone alteration may north of the be Petaca regionally Pinta significant area suggests and that that the the alteration 'zone is stratigraphically controlled. The alteration pattern has numerous similarities to the Grants-type sandstone uranium mineralization in the Jurassic system north of the Petaca Pinta area: Eh-pH-controlled mineralogy, elevated concentrations of Cu, Mo, and V, tabular geometry of carbonaceous zones. The most obvious differences are the apparent absenceU and of the absence of stream and channel sands and conglomerates where the permeability porosity would be sufficiently high to allow significant ore accumulation. Elevated values of Ba, Sr, Pb and Zn, which are characteristic of sedimentary basin "brines" (Hanor, 1979) together with Cu, Co, Mo, and V, which are easily carried in vadose waters or oxidizing, shallow groundwaters (Garrels and Christ, 1965), suggests that the zone of alteration at the interfaceof oxygenated, may shallow represent a redox groundwaters boundary and oxygen- poor, deep basin brines, a model recently developed for the formation of some sandstone uranium deposits in southeastern Utah(M.B. Goldhaber, 1981, personal communication). Alternatively, the alteration maybe related to deep weathering along fractures buried by the Dakota Sandstone. Unconformity-related uranium deposits in Upper Cretaceous sandstones in the Datil Mountains of west-central . (1981) New Mexico have been described recently by Chamberlin The true natureof the alteration zone needs much more work. Whether U was never present in this alteration zone, or of the whether U was removed during later leaching oxidizing groundwaters cannot be resolved on the zoneby basis of the present data. Water from a well on the southeast marginof the WSA (Fig. 3 ) contains a slightly anomolous concentration of This suggests that 1980). 17 ppb uranium (Planner and. others, uranium may have been leached from the near-surface portion of the altered zone. Alternatively, there may be subsurface uranium mineralization that is unrelated to the zone of alteration. While the alteration zone and one the U value provide some support for anomolous uranium water-well mineralizatios, the is relatively author believes for3 reasons that the potential U low within the WSA. First, thereis no direct evidence for in the alteration zone. Second, most of the alteration zone lies outside the WSA; it has apparently been removed by erosion along Blue Water and East Mesas. Third, only one of10 water U anomaly, and that value is less than wells tested shows any a factorof two derived from Geochemistry greater than sedimentary of Spring the 10 ppb value common for waters terrains. Deposits Semiquantitative spectrographic analyses of travertine from active springs along Arroyo Colorado (Maxwell, 1981, personal communication), show very high (700-10,000 ppm) SrMnand and high but variable (10-150 ppm) values for Ba, Co, Cu, and Ni. Detectible (1-3 ppm) amounts of Ag,Be, and Cr are present. Pb, Zn, and V 13 limits o f d e t e c t i o n . a r e a t o r b e l o wt h e metals. d e p o s i t sc o n t a i n se c o n o m i cq u a n t i t i e so f s o u r c e areas f o r t h e Oil - metals are up hyd::olngic WSA a n d t h e south,outsidethe None o f t h e s p r i n g Potential gradienttothe mapped a r e a . and Gas P o t e n t i a l Commercial o i l a n d / o r g a s p r o d u c t i o n h a s n o t , a s y e t , b e e n N e w Mexico. found i nC i b o l aC o u n t y , p r o d u c t i o n t o t h e Petaca P i n t aA r e a T. 15N., t h en o r t h w e s ti n R. S t u d i e s made b yF o s t e r , low., The n e a r e s tc o m m e r c i a l i s l o c a t e da b o u t5 5 miles t o McKinleyCounty. 1 9 5 7 , andWengerd,1959,have shown that an excellent petroleum possibility exists in eastern Cibola County, New Mexico. Shows o f o i l t e s t wells, a n dF o s t e ra n dG r a n t , CibolaCounty andgashavebeenreportedfrom 1 9 7 4 , h a v ec l a s s i f i e de a s t e r n as a c l a s s 2 e x p l o r a t i o n area i n a systemwhere 1 i s m o s tf a v o r a b l ea n d class 4 i s l e a s t f a v o r a b l e . must be made i n Wengerd'sstudy class Some m o d i f i c a t i o n in regard to thethicknessof P e n n s y l v a n i a nm a r i n er o c k s .V e r yf e wc o n t r o lp o i n t so nt h e time ofWengerd's Pennsylvanian existed at the showing t h e t h i c k n e s s o f P e n n s y l v a n i a n m a r i n e t h eP e n n s y l v a n i a n wouldhave work a n d h i s map rocks s u g g e s t s t h a t a t h i c k n e s s of a b o u t 1 8 0 0 f e e t i n t h e Petaca P i n t a a r e a . S u b s e q u e n t d r i l l i n g i n t h e v i c i n i t y o f t h e PetacaPintaarearevealsthatthePennsylvanianshouldhave t h i c k n e s so fa b o u t 700 f e e t . Cretaceousrocksaspotentialreservoirs t h eP e t a c aP i n t a n o r t hi n a area. are n o t p r e s e n t i n T h e s er o c k sa r et h eb i gr e s e r v o i r sf a r t h e r McKinley,Sandoval,SanJuan,andRioArribacounties. The P e t a c a P i n t a a r e a h a s a stratigraphicsectionapproximately I4 feet in thickness, comprising Pennsylvanian, Permian, 4,800 and Triassic rocksof marine and non-marine origin. The Triassic rocks are largely continental in origin and are not considered Two to test have wells a petroleum have been Petaca Pinta area (Fig. 4 ) . the # l - M Santa Fe in potential. drilled in In 1 9 5 9 , Spanel the & vicinity of the Heinze drilled Section5, Township 5 North, Range7 West. The footage location of the test 7 0is 0 feet from the South line 5. Precambrian and 1070 feet from the West line of Section 4 feet and the granite was encountered at a depth4 9 7of test 4 9 9 2of feet. In was abandoned as a dry hole at a total depth 1960, Sun Oil Co. drilled the # l Pueblo of Acoma in Section 2, Township 7 North, Range 7 West. The footage location of the 9 0 0 feet from the test is 1900 feet from the South line 1and 2. East line of Section Precambrian granitic gneiss was 7 0 2 feet and the test was abandoned encountered at a depth 4of 4 7 9 4 feet. as a dry hole at a total depth of The Spanel test was spudded in the Cretaceous Dakota sandstone on Half Dome, a structure along the Red Lake Fault. The Permian 0 0 5 feet and consistedof, in was reached at a depth 2of descending order,3 3 5 feet of limeston, dolomite, sandstone and shale of the San Andres 2 4 0 feet of Glorieta Formation, Sandstone, 1 1 3 0 feet of sandstone, shale, anhydrite, limestone, and dolomite of the Yeso Formation, and 6 2 4 feet of siltstone, shale, and sandstone of the Abo Formation. Pennsylvanian rock were reached at a depth 4 3 3 4 feet and consisted of about 6 4 0 feet of of limestone, shale, and sandstone. Igneous sills (diorite?), two and thirty feet and thickness, were encountered in the Triassic and San Andre 15 and two sills, fifteen and twenty feet in thickness, were found in the Yeso Formation. Slight shows of gas were reported from drill stem tests made 4 4at 3 0 - 4 5 3 3 feet and 4 5 3 7 - 4 6 3 7 in the Pennsylvanian. The Sun test started in the Triassic on a structure known as the Acoma Nose. The Permian was reached at a depth 1 7 6 5 of feet and consistedof, in descending order,4 2 5 feet of limestone, dolomite, sandstone, and shale of the San Andres 8 7 0 feet of limestone, Formation, 150 feet of Glorieta Sandstone, of the Yeso Formation, and silty dolomite, and silty sandstone 3 7 2 feet of siltstone, shale and sandstone of the Abo Formation. The Pennsylvanian, at a depth of 3 8 8 2 feet, consisted of8 2 0 feet of limestone, shale, and sandstone. An igneous sill 1 8 3 0 and 1 9 2 0 feet in the San Andres (diorite?) was found between Formatiol. A show of gas was reported 'Ln the San Andres at in a depth of2 0 9 6 feet and heavily gas-cut mud was recovered a drill stem test at 4 4 8 6 - 4 5 2 6 in the Pennsylvanian. Gas from this drill stem test was sent to the Oil Co. Research Sun Laboratory for analysis. It was found to contain9 5 % carbon dioxide and 0 . 1 3 % helium. The remaining fraction was not identified. The petroleum potential of the Petaca Pinta area is in rocks of Permian and Pennsylvanian ages. Suitable source and reservoir rocks occur in the stratigraphic section. Carbonate reservoirs may be expected in the San Andres Formation, Yeso Formation and Pennsylvanian. Sandstone reservoirs may also be expected in these formations as well as in the Glorieta Sandstone. are p r e s e n t i n t h e Numerous f a u l t a n d a n t i c l i n a l s t r u c t u r e s vicinity of the Petaca P i n t a a r e a a n d some a r e p r e s e n t w i t h i n t h e P e t a c aP i n t aa r e a itself (Fig. 5 ) . structuraltraps, numerous p o s s i b i l i t i e s f o r s t r a t i g r a p h i c a n d I na d d i t i o nt op o t e n t i a l exist. c o m b i n a t i o ns t r u c t u r a l - s t r a t i g r a p h i ct r a p s CARBON D I O X I D E POTENTIAL C a r b o nd i o x i d eh a s a g r e a t many u s e s i n a d d i t i o n and d r y ice and i s becoming insoftdrinks,fireextinguishers, oil. i n c r e a s i n g l yi m p o r t a n ti nt h ee n h a n c e dr e c o v e r yo f dioxide is highly soluble in crude oils p r e s s u r e sa n dt e m p e r a t u r e s . t o i t s use a n dw a t e r Carbon a t reservoir When o i l and water c o n t a i n a s u b s t a n t i a l amount of d i i s s o l v e d c a r b o n d i o x i d e , t h e i r v i s c o s i t i e s , d e n s i t i e s , and compressibilities are m o d i f i e d i n a d i r e c t i o n w h i c h h e l p s to increase the oil-recovery efficiency. A t p r e s e n t time, o i l companies are e a g e r t o h a v e u n d e r c o n t r a c t a s u p p l yo fc a r b o nd i o x i d e . The i n c r e a s i n g p r i c e make it e c o n o m i c a l l y more a t t r a c t i v e i n t h e t o r e c o v e ra d d i t i o n a l c a r b o nd i o x i d e are b e i n g d e v e l o p e d i n n o r t h e a s t e r n C o l o r a d o .P i p e l i n e s oil. of c r u d e o i l w i l l coming y e a r s t o i n j e c t C a r b o nd i o x i d ef i e l d s New Mexico a n d s o u t h w e s t e r n w i l l t r a n s p o r tt h ec a r b o nd i o x o d et oo i l f i e l d s i n west Texas a n d s o u t h e a s t e r n N e w Mexico. The s o u r c ef o rc a r b o nd i o x o d ea c c u m u l a t i o n sb e n e a t ht h e s u r f a c eo ft h ee a r t h i s n o tc l e a r l yu n d e r s t o o d . t h a t it mightbegeneratedthroughthermalaction a r ei n t r u d e d by i g n e o u sr o c k s .I ft h i st h e o r y PetacaPintaarea One t h e o r ys u g g e s t s when l i m e s t o n e s i s c o r r e c t ,t h e may have a p o t e n t i a l f o r c a r b o n d i o x i d e p r o d u c t i o n . Numerous v o l c a n i c p l u g s o c c u r i n t h e v i c i n i t y , a n d t h e S p a n e l a n d Sun t e s t wells r e v e a l e d t h e p r e s e n c e of i g n e o u s s i l l s a t d e p t h a n dl i m e s t o n ei nt h eP e r m i a na n dP e n n s y l v a n i a n .I na d d i t i o n , gas r e c o v e r e d i n a d r i l l stem t e s t i n t h e Sun well was f o u n d t o c o n t a i n 95% c a r b o nd i o x i d e . REFERENCES Chamberlin, R.M., 1 9 8 1 ,U n c o n f o r m i t y - r e l a t e du r a n i u md e p o s i t si n Datil Mountains Area, west- Upper C r e t a c e o u ss a n d s t o n e s , c e n t r a l N e w Mexico ( a b s . ) : P e t r o l .G e o l . , Rocky MountainSection-Am. 2 9 t h AnnualMeeting, Assoc. Program w i t h A b s t r a c t s . 1 9 5 7 , S t r a t i g r a p h y of w e s t - c e n t r a l New Mexico: F o s t e r , R.W., FourCornersGeol. , Guidebook 2, p . 6 2 - 7 2 . SOC. a n dG r a n t , 1 9 7 4 , The f u t u r eo f P.R., o i l a n dg a sr e s o u r c e s : N.M. N e w Mexico's Bur.MinesMineralResources, Resource Map 3. , 1 9 8 0 ,C a r b o nd i o x i d es o u r c e sa n du s ef o re n h a n c e d New Mexico I n s t .M i n i n ga n dT e c h . , o i lr e c o v e r y : Report No. 80-4, Garrels, R.M. 73 p. a n dC h r i s t , C.L., EquilibriaS : a nF r a n c i s c o , Hanor, J.S., 1 9 6 5 , S o l u t i o n s ,M i n e r a l sa n d Freeman-Copper, 1 9 7 9 , The s e d i m e n t a r yg e n e s i s i n B a r n e s , H.L. PRRC 450 p . of h y d r o t h e r m a lf l u i d s , ( e d . ) , G e o c h e m i s t r y of Hydrothermal O r e D e p o s i t s( 2 n de d i t i o n ) : N e w York, JohnF?ileyandSons, p.137-172. Gregory, H . E . , 1 9 1 7 , Geology of t h eN a v a j o Country-A r e c o n n a i s s a n c e of p a r t s o f A r i z o n a , New Mexico,andUtah: Geol. Survey 161 p . P r o f .P a p e r9 3 , Harshbarger, J . W . , U.S. Repenning, C . A . , a n dI r w i n , J.H., 1957, S t r a t i g r a p h y of t h e u p p e r m o s t T r i a s s i c a n d J u r a s s i c r o c k s theNavajoCountry: J i c h a , H.L., SJ.S. Geol.SurveyProf.Paper J r . , 1 9 5 8 ,G e o l o g ya n dm i n e r a lr e s o u r c e s O r 0 q u a d r a n g l e ,S o c o r r oa n dV a l e n c i aC o u n t i e s , 291, of 74 p . of Mesa d e l N e w Mexico: N.M. Bureau of Mines Mineral Resources B u l l . 56, 6 7 p . K e l l e y , V.C., N.M. 1 9 5 0 ,R e g i o n a ls t r u c t u r eo ft h eS a nJ u a nB a s i n : Geol. S o c . ~ G u i d e b o o k 1, p . 101-108. , 1 9 5 5 ,R e g i o n a lt e c t o n i c so ft h eC o l o r a d oP l a t e a ua n d relationship t o the origin New MexicoPubs.Geology , and d i s t r i b u t i o n of uranium:Univ. No. 5 , 1 2 0 p. J r . , 1 9 4 6 , Geology of t h eL u c e r o and Wood, G . H . , u p l i f t ,V a l e n c i a ,S o c o r r o ,a n dB e r n a l i l l oC o u n t i e s , Mexico: U . S . New Geol. Survey O i l and Gas I n v . Prelim. Map 4 7 . . . Landis, E.A., Dane, C . H . , andCobban, W.A., t e r m i n o l o g y of t h e DakotaSandstoneand w e s t - c e n t r a l N e w Mexico: U . S . Machette, M . N . , Mancos S h a l e , Geol. SurveyBull.1372-J, 1 9 7 8 ,P r e l i m i n a r yg e o l o g i c q u a d r a n g l e ,c e n t r a l 1 9 7 3 ,S t r a t i g r a p h i c New Mexico: U . S . 4 4 p. map o fS o c o r r ol " x 2 " Geol.SurveyOpen-file Report 7 8 - 6 0 7 . Maxwell, C . H . , 1 9 7 6 a , Geologic map o f Acoma P u e b l oq u a d r a n g l e , New Mexico: U.S. , Geol. Survey Geol. Quad. Map GQ-1298. 197613, S t r a t i g r a p h y a n d s t r u c t u r e o f t h e r e g i o n , New Mexico: ,N.M. Acoma Geol. SOC. S p e c i a l P u b l i c a t i o n 6, p. 95-101. , - 1 9 7 9 , Geologic map Eoaf s t Mexico: U.S. Moench, R . H . , U.S.. 1963,Geologic Map GQ-208. 1 9 6 4 , Geology o fS o u t hB u t t eq u a d r a n g l e , Geol. SurveyGeol.Quad. , Map GQ-1522. map o f Laguna q u a d r a n g l e , New Mexico Geol. SurveyGeol.Quad. , U.S. Geol. SurveyGeol.Quad. Mesa q u a d r a n g l e , N e w a n dS c h l e e , J.S., New Mexico: Map GQ-355. 1 9 6 7 , Geologyanduraniumdeposits e e of t h e Laguna d i s t r i c t , New Mexico: U.S. Paper519, Geol. S u r v e yP r o f . 117 p. Morain, S .A., Budge, T . K . , andWhite, and l a n d use i n N e w Mexico: M.E., N.M. 1977, Vegetation Bur.Mines Min. Res. Resource Map '8. Planner, H.N., and o t h e r s , 1 9 8 0 , Uranium hydrogeochemicaland stream s e d i m e n t r e c o n n a i s s a n c e d a t a release f o r t h e S o c o r r o NTMS Q u a d r a n g l e , New Mexico, i n c l u d i n g c o n c e n t r a t i o n s f o r t y - t w oa d d i t i o n a le l e m e n t s : ReportGJBX-12(80), U.S. Wengerd, Dept. o f EnergyOpen-file 1 4 5 p. S i l v e r , Caswell, 1 9 4 8 , J u r a s s i c o v e r l a p Am. i n w e s t e r n New Mexico: A s s o c .P e t r o l e u mG e o l o g i s t sB u l l . ,v . S.A., I i I 3 2 , p . 68-81. 1 9 5 9 ,R e g i o n a lg e o l o g yr e l a t e dt ot h ep e t r o l e u m potentialoftheLuceroRegion,west-central N.M. of Geol. SOC. Guidebook 1 0 , p . 121-134. New Mexico: Fig. 1 GEOLOGICMAP OF THE PETACA PINTA WSA COMPOSITE STRATIGRAPHIC COLUMN - PETACA PINTAWSA TRAVERTINE DEPOSITS (HOLOCENE)- Calcium carbonate (travertine) with minor gypsum and silica, deposited by active springs. EOLIAN DEPOSITS (HOLOCENE)- Recent windblown sand and silt in sheets and small longitudinal duces. ALLUVIUM (HOLOCENE AND PLEISTOCENE) - Fine s a d and silt with lenses of coarser sand and gravel. Includes both Qa and Qoa (old alluvial deposits) of Maxwell (1979). COLLUVIUM (HOLOCENE AND PLEISTOCENE) - Extensive mantleof soil and colluvial and eolian deposits on Blue Water Mesa and East Mesa. - LANDSLIDE DEPOSITS (HOLOCENE AND PLEISTOCENE) Toreva-block (rotational slump block) slides composed of sandstone or basalt and shale which have slid over shales of the Chinle Formation (TRc). Landslides are generally older than alluvium (Maxwell, 1979). CALICHE AND OLD SOILS (HOLOCENE AND PLEISTOCENE) - Partly exhumed caliche pavement; includes some old soil zones and remnants of old alluvium and gravel. BASALTIC LAVA FLOWS (PLIOCENE) - Black to dark gray,finegrained to porphyritic, alkali-olivine basalts (Jicha, 1959). Flow tops are scoriaceous to amygdaloidal. Flows are probably2.5 to 3.1 m.y. (Machette, 1978). - CONGLOMERATE (PLIOCENE? AND MIOCENE?) Slightly indurated alluvLal deposits composed of coarse sand, pebbles and cobbles derived from Precambrian granite, Paleozoic sedimentary rocks and Tertiary volcanics in a matrix of sand andsilt, largely cemented by caliche. UNCONFORMITY - DAKOTA SANDSTONE (UPPER CRETACEOUS) Comprises both the basal unit and the Oak Canyon Member described by Maxwell (1979). The Oak Canyon Member is composed of light grayish-tan (weathers yellowish tan), finegrained, lenticular sandstone which is interbedded with dark gray, silty shale. The basal unit is light gray to white (weathers dark brown), medium- to coarse-grained, poorly sorted sandstone and conglomerate. The basal unit truncates the underlying formations. UNCONFORMITY ZUNI SANDSTONE, SUMMERVILLE FORMATION AND ENTRADA SANDSTONE Formations mapped as a single unit where vertical cliffs impractical at this scale. make separation of formations - Variably colored ZUNI SANDSTONE (UPPER JURASSIC) (white-gray-green), fine-to medium-grained, eolian sandstone. A basal fluviatile sandstone was mapped separately as the Bluff Sandstone the in Acoma Pueblo Quadrangle (Maxwell, 1976a). The Bluff Sandstone is yellowish-gray to white, very fine-grained to mediumgrained, fairly well sorted, quartzose sandstone cemented with calcite. The Zuni Sandstone, truncated by the erosional interval which preceded deposition of the Dakot Formation, is absent south of 19, sect. T. 6N., R. 6W. JS - White to pale brown, SUMXERVILLE FORMATION (UPPER JURASSIC) very fine-grained, medium-beddedto massive sandstone, intervedded with grayish-green and light maroon siltstone and thin, brick-red to brown mudstone. South of sect. 19, T. 6N., R. 6 W., the Summerville Formation is the only Jurassic unit, and it is labeled as Js in this area. UNCONFORMITY - Very pale orange to ENTRADA SANDSTONE (MIDDLE JURASSIC) chalky white, fine- to coarse-grained, well-sorted sandstone with basal pebble conglomerate. The pale colors reflect a wide-spread zone of alteration characterized by eroded sand grains and clots and coatings of kaolinite (Maxwell, 1976b). The Entrada Sandstone is truncated by an erosional interval which preceded deposition of the Summerville Formation and is absent south of sect. 19, T. 6N., R. 6W. UNCONFORMITY TRr ROCK POINT MEMBER OF THE WINGATE SANDSTONE (UPPER TRIASSIC) Pale- to moderate-red, thick-bedded to massive siltstone and shaly mudstone with local bleaching. Present only in the southern half of the area.map UNCONFORMITY TRc CHINLE FORMATION (UPPER TRIASSIC) - Grayish-red and moderate reddish-purple, shaly siltstone and mudstone with inconspicuous stratification. Contains lenses of very fine-grained sandstone. Largely covered by landslides. I .. "., " I 1961 ' N O l l V N l l 3 3 0 NV3W 3lVVLIXOIJddV " " " " " ... I l l " t SEMIQUANTITATIVE6-STEPSPECTROGRAPHIC , - .. . =Not looker: for . ANALYSIS or below value shown SEMIQUANTITATIVE 6-STEP SPECTROGRAPHIC ANALYSIS Repart No. (CONTINUED) . . Job. No. . . M 176 . . . I .' lob No. M 183 ults are to be identificd wlll geomemc t are reported arbitrarily as mid-points !ported value i s approximately plus or : . ice ;ted. at limit of detection 18 shown but below limit of determination value shown SEMIQUANTITATIVE6-STEPSPECTROGRAPHICANALYSIS (CONWED) Job. No. . Report . No. M 183 'I. .. : .. . . ..,.: . . . . ' 3 c c . HI ' I I I I I 'I I I I I I I I I I I In I Ii I I I