M i n e s a n dM i n e r a lR e s o u r c e s N e w M e x i c oB u r e a uo f Open F i l e R e p o r t No. OF-202 PETROLEUM SOURCE-ROCK STUDY OF SELECTED WELLS I N THE R I O GRANDE RIFT A R E A , by A l a n H. L e u t l o f f a n dD a v i d Conoco, I n c . G o l d e nC , olorado D e c e m b e r1 4 , 1982 NEW MEXICO J. Curry Wells s e l e c t e d : 1.) Conoco No. 3 S t . L o u i s R o c k yM o u n t a i n( C o l f a xC o u n t y ) No. 1 S a n t aF e( S a n d o v a C l ounty) 2 . )S h e l l 3.) S h e l l No. 1 L a g u n aW i l s o n( B e r n a l i l l oC o u n t y ) 4.) Sun No. 1 V i c t o r i oL a n da n d C a t t l e Co. ( S i e r r aC o u n t y ) 5.) S u n r a yM i d - C o n t i n e n t No. 1 F e d e r a l M ( S i e r r a Counnfy) 6.) C i t i e s S e r v i c e No. 1 C o r r a l i t o sF e d e r a l A ( D o n a Ana county) 7.) S i n c l a i r No. 1 Doza Ana F e d e r a l 18 (DoGa Ana C o u n t y ) Conoco Inc. 13949 West Colfax h e . . Suite P.O. BOX 1219 Denver west ~xpioratlon loo Golden, CO 80402 (303) 232-0727 December 14, 1982 Sam Thompson New Mexico Bureau of Mines New Mexico Tech. 87801 Socorro, New Mexico Dear and Mineral Resources Sam, I am enclosing a copy of the report on our source bed study from selected wells in the Rio Grande Rift. Thank you for allowing us to collect samples from your log library. I hope this report is beneficial toyou and your endeavors. Sincerely, Alan Leutloff AHL/mn cc: W. E. Zabriskie M. L. Johnson Robert Bieberman SUMMARY &+b; n 3 3 Core samples,from seven wells in the Rio Grande Rift system of New Mexico were evaluated for source potential. The Sinclair No. 1 Dona Ana was very in low organic carbon content and not analyzed further. The other six wells ranged from poor to good in potential richness. Maturity levels varied from moderately mature in some Cretaceous sections to overmature in some Pennsylvanian and older sediments. The Conoco No. 3 St. Louis Rocky Mountain and Shell Santa Fe No. 1 both showed source potential (in terms of maturity and richness) in the Cretaceous and possibly in the Triassic sections. The presence of lignite made it difficult to evaluate the richness of the Cretaceous age sections in the Shell Laguna Wilson No. 1, Sun Victoria No. 1, and Sunray Midcontinent No. 1, but maturities were within the oil generation phase. In these last four wells the older sections are probably poor sources due to overmaturity, lack of organic carbon, or both. The CitiesNo. 1 Corralitos had only one interval of fair richness; this interval was very mature. INTRODUCTION The organic geochemistry of core samples from seven in wells the Rio Grande Rift system was analyzed to evaluate the source potential of Mesozoic and Paleozoic 5omtions in this area. The wells analyzed are locatedorinadjacent to the basins which form a part of the Rio Grande Rift. These basins are generally oriented with north-to-south long axes and are roughly parallel to the course of the Rio Grande River from southern Colorado to west Texas. The basins show evidence of complex faulting and uplift in places. Well locations are 1. shown in Figure SAMPLE AND ANALYTICAL DESCRIPTION y Conoco North American Exploration from of the New Mexico Bureau of Mines of 114 he sample he stored coFes. antities of sui5:tAgroisted h The size and nature of the samples limited the organic geochemical techniqueswhich could be used. No light hydrocarbon and the small sample size precluded data were possible, solvent extraction and the isolation of kerogen for pyrolysis. The samples were analyzed for total organic carbon (TOC) content, kerogen type and visual maturity estimation, some vitrinite reflectance data (again limited by sample size), and whole rock pyrolysis. Pyrolysis showed many of the samples to have been contaminated, possibly during storage, since some of the contaminants are very similar from well to well. In addition, some samples, especialiy from the Cretaceous fomtions,. contained appreciable amounts of coal, which interfered with evaluation of source richness. Page 2 INDIVIDUAL 1. WELL EVALUATIONS Conoco No. 3 St. Louis Rocky Mountain (Colfax County) The three Cretaceous age samples (1,550, 3,400, and 4,360 feet) in this well are of fair-to-good richness and are mature to very mature. Kerogen is chiefly woody and herbaceous; this and the pyrolysis results indicate that the expected production type is gasand oil. These samples have large amounts of P I pyrolyzates (thermally extractable material), which resemble an oil which has lost its 2). light ends rather than a refined product (see Figure It cannot be determined if this is a native (i.e., in situ generated) or migrated bitumen. The Triassic age sample (5,330 feet) is fair in richness (TOC) and probably gasprone. Maturity (based only on pyrolysis data) appears to be high. 2. Shell No. 1 Santa Fe (Albuquerque Basin, Sandoval County) This well appears to have the best potential. The Cretaceous in richage samples (4,000 to 6,800 feet) are fair to good ness (two contain lignite) and are moderately mature to mature (i.e., within the oil generation stage). Kerogen type is principally amorphous, and pyrolysis data indicate these samples to be oil or oil- and gas-prone. The Jurassic 7,050 feet is fair in richness and mature. age sample at The intervals from 7,400 to 10,500 feet are all low in organic carbon and of poor potential (most samples contain less than 0.3 percent organic carbon). The Pennsylvanian age sample at 10,700 feet has a fair potential according to TOC content. However, a large proportion of the kerogen is coaly, which is likely to be inert (i-e., dead carbon). Pyrolysis also shows little active carbon left in the sample, implying that the kerogen has already generated its hydrocarbons, and so the presence of gas or in oilthese sediments is dependent on geologic factors. 3. Shell No. 1 Laguna Wilson (Albuquerque Basin, Bernalillo County) (2,640 to 3,850 feet) all contain The Cretaceous age samples lignite, which makes it impossible to assess richness by TOC and restricts pyrolysis data. Limited optical kerogen data show the 3,420-foot sample to be moderately mature and contain chiefly amorphous kerogen. The same Cretaceous formations in other wells (e.g., the Shell Santa Fe No. l), generally show fair-to-good richness and moderate maturity; it is uncertain, however, if these data can be extrapolated to this well. Similarly, the Jurassic sample at 3,950 feet is lignite-contaminated, but the same formation (Morrison) in the nearby Shell Santa Fe No. 1 is fair in potential. From 4,560 to 8,400 feet, the richness is generally very poor. From 8,450 feet to thebottom, the richness is poor from 9,750 feet to the bottom). to generally fair (especially Page 3 Maturity data are somewhat contradictory, but the kerogen is probably extremely mature (condensate- and wet-gas-prone) at the top of this interval and overmature and dry-gasprone at the bottom (as indicated by pyrolysis). The samples at 9,750 feet and below all contain significant amount of coaly kerogen, and pyrolysis indicates very little generating capacity. In addition, these samples all showed contamination by what appears to be a distillate. The presence of a significant proportion of inert carbon in the kerogen and the presence of contamination imply that the source potential of these samples may be less than that indicated by the TOC values. As with the adjacent Santa Fe No. 1, the kerogen in the bottom of this well has probably been buried more deeply at than present and has already generated its hydrocarbons; hence the preservation of any gas depends on structural and tectonic factors. 4. Sun Victoria No. 1 (Jornada del Muerto Basin, Sierra County) This well shows evidence of uplift and erosion, since the Cretaceous age samples at less than a 1,000-foot depth are very mature to extremely mature (condensate to wet gas generation stage). Kerogen type is chiefly amorphous and coaly, and production type (from pyrolysis data) is wet gas and condensate. These samples also appear to be contaminated by a remnant bitumen (either native or migrated). The Triassic, Permian, and Pennsylvanian age samples from 1,140 to 5,300 feet are all of poor source potential (low TOC values). The samples from 5,600 to 5,970 feet are poor to generally fair in richness. However, these ( . u 2 percent samples are all at very high levels of maturity vitrinite reflectance) and show very little generating capability, being at the phase-out of dry gas generation. As with the other wells, the presence of gas will depend on lithology and trapping. 5. Sunray Midcontient No. 1 (Sierra County) The Cretaceous and the Permian San Andres (3,690 feet) and Glorietta (4,040 feet) samples are poor to fair in richness (two are lignite-contaminated) and are mature to very mature (late stage generation). The kerogen type in these samples is woody and herbaceous in the 2,280-foot sample and generally amorphousin the other samples. The samples at 7,030 and 7,070 feet (Pennsylvanian) are of fair richness (by TOC content) but .are overmature (vitrinite reflectance of 2.73 percent) and, as in the previously discussed wells, past the generation stage. The other samples in this well are poor in richness and overmature. Page 4 6. Cities No. 1 Corralitos (Dona Ana County) This well contains only Permian and older strata and is, in general, low in organic carbon. The samples at 2,120 and 2,740 feet are of poor potential, very mature to extremely mature, and probably wet-gas-prone. The 2,630foot (Pennsylvanian) interval isof fair richness, possibly oil- and gas-prone, and extremely mature (condensate to wet gas stage). 7. Sinclair No. 1 Dona Ana (Dona Ana County) This well contains only Permian and older strata, and no potential source rocks were found in any of the sampled intervals (TOC never exceeded 0.29 percent). I 'I i ! I I I I . w vu = a QZ 6$ e > f' # :5 0 0 C m .- oa 0 0 2 ^t c " 0 0 0, b r 0 * o b 0 b P 0 0 0 * 0 0 0 o 0 Lo c N 0 0 0 55 0 ID 0 0 mu) o n 0 0 0 u) 1 1 P u) bb b o r mo u)t. .r 0 ! I , 0 0 0 m 0 .r I b N m m 0 ' 0 0 01 II 9 0 0 bbb . C 09- " 0 0 ~X 1. - . . ... . .., r 0. 9. OJ 0 0 9. *0 0 ?-I I 0 0 *? 0 d ' 0 N (... d .. . .,r. . .. 0 . 0 d d 0 m d ._-... ,LO1+ 'lzlH l d 3 a d 0 d 0 m 0 0 0 m 0 0 m tOLt O l z l - 0 3 0 ._ . d 0 ID d m 0 , t . . , * r...... . . . 0 0 0 ID ID 0 0 0 Hld3a d 'UH l d 3 a ' LO11 'UH l d 3 a N 0 9*, x"--- 0 ?. 0 0 N 0 0 . N rOl* . d 0 d 0 (D - t- d 0 (D .- It. .It d 0 * - m d * . d m t. N d ID ID 0 * , . .. .i .. :. .. I ~ . . ....: ? .. :XI C L . rOL. 'UH l d X l I ... .* . 0 0 8 U %/ - 0 c _ . . c N d 1011 'U Hld3a __c_c_c_ 0 u) c 'UHld3a m 101. 0 U m . . I (. " ". ... ...... _. .. - . _ .... 0 P u) .. SunrayMidcontinent'No. 1 INTERVAL ORGC 0.00 2.00 MATURATION INDEX 4, 1 4. ,. 2 ,-3 1. I. 4. 4 6 20.4 40. 40.- 40 4c 60.- 60, 60 80.- 80, .80 . .. . VISUAL KEROGEN 3.00 40.00 80.00 20 20 ..:. Sierra Co., NM 2c 1 5 60. %- t r c n W L3 80. !, :i ,... . . 100. 100.- 100. 100 , .. I 0 = Permian = Pennsylvanian 3 . " ' / ' .. : _ . E . 2 d 0 v) I b) ..- C 0 ! Denver West Explwatlan Conoco Inc. 13949 West Colfax h e . . Suite 100 P.O. BOX1219 Golden, CO 80402 (303) 232-0727 October 2 51, 9 8 2 Sam Thompson New Mexico Bureau of Mines and Mineral Resources New Mexico Tech. Socorro, NM 8 7 8 0 1 Dear Mr. Thompson, Enclosed are theraw data results of the geochemical analysis NM. I have been informed from wells in the Rio Grande Rift, by our researcher in Ponca City, that a formal report should be presented to me sometime in late December. Thank you so much for allowingus to collect these well samples. If I can beof any further help to you, now or future, please feel free to contact me. Sincerely, Y Alan Leutloff Geologist Pdr cc: W. E. Zabriskie M. L. Johnson R. A. Bieberman any time in the ... -. . . . . . . . . . D A T A SKEET CONOCO ST. _" DEPTH FT SAMPLE NUMBER .~7..";-i-p.-.""1.tjoo 1287 1287 ---E"?i 91 91 2 3 4 , - . . -"_ .... . P 5 0 ." ....... " -" . 0.00 0. 0. ... O*"O 0 .oo 0. . ,- , I ..- . ....."_..."__.~._..."-..._..-..I ...". _, _"_..I HC PPM, "-0 " " 0. 0. . . . . . . . . 0 ........ HC/OC SAT 9 4. _" o"O* 0.00 . 0.00 ..o"oo". .. .................... ........ . .. " .- . .._.I TE EPPC % PPM - 0 .".I."@."Lo."-I OROC 1.42 3370 4330 1.95 5.31.0... - 6 2 NM .-. .....- ....... . . . . . . . . . . . . . . . CO.', __COLFPX ...... _......... LOUIS R O C K Y M T N .............. . __ ._ (y..@o"---0.00 0.00 . O...OO"* ......... -............ " " ARO P. RASP 'HC/TE % 0"_..... 9i ~"@o"-ol)(f;"-o-o 0.00 0.00 0.00' ,: :o.oo :, ' . " 0.00 0.00 o.;o~"-~oo-".o~~~ ..- _" .... " ,..~ , .. --- .- I ". .... ..; . . . ...... *5*.-"tf.yDRO~ - " " " F2.87"-88".4 1287 8R 5 " 1287 88 0 1287 88 1287 ..E8 8 9 ---";26"---88---7-. DEPTH FT 40 10 4370 4520 6500. 6700 6790 . - ' 7 0 1 ti .87 10.10 9.90 1.39 1.2U 7440 8920 ti7 .10 ' :> 88 1 1 931 0 9370 8 8 12 . lr. 1 7 - 7 - 8 8+3-"---.9-7-1~0 : 10290 :.. 1 2 8 7 , 88 ,14 . .. . '... :;::j2f37,;.: 8.8. >15 10440 :, , . ,,, , .'., I. ,I?, ib I P W " ~ % "o"-"* o9 I I L ... 0.0. 0. 0. 0 (J .. 9. .11 .12 10 -32 .221 ... . . 0*UO 0.00 . ..(I, 0. 0.00 O'U0 0.uo 0.00 0.00 0.00 .o.(,o 0. 0. 0.00 0. 0.00 O.r"---O"+.*".--" . . . . . -, - ~ . . . . ......... . " .".......... ......... . . . . ... 4 0.00 0.00 "OiOO. 0.00 0.00 0.00 0.00 0.00 0-00 0. 0. 0. 0. 0 0. 0.00 0. 0.00 .o.. 0. 0. 0. -...... __ .- .." ...... - ..- P R O HC/TERASP % 9 0 , O O . - ..... 0.0.0 ......... % 0 00 ....... 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 . o . .0 0 .. ."O, 0 0 O.*.OO - 0 .oo. ..... 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 . . . 0.00 0.00 0.00 -........ 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0"OO (y..O@---"f)< 0~-0.--000.00 0.00 n 0.0 0.00 0.00 0.00 0.00 0.00 ..o..,-,o~ ~-.~~-"-.&rO@-"O-.~~----. 0.00 0.00 . 0.00 , , . 0.00 .... ... .. - .. . .. . 0 .oo .. 0.00 0.00 t .#o" . ..... . . . . o.no 0. 0.UO ' 0. 0. -. PC SAT hC/CC PPV 9 0. 0.00 ur 0. o*Uo 0. 0.00 ......... 0 ....... O'O@ ." . -. ..... .- ................. " EPOC ti. ' - .............. P ?'I 1.08 .40 . NM TF OWGC . 1287 1287 . . . . . . . . . . . . S P N D A U A L C0.r . .. ._ .......... SAMPLE NUMRER #8-/"88 -1"1287 88 2 1207 88 3 PRBON. DATP"-SI!EET... .- FE-1 S H E LSLP k T A "&*~"91.40". ._. ... 0.00 , I 0.00.:':. Or00"--ds0.0 - _.-. . . . . . . . . . o.oo..i:~i:i::~o.oo ,OB . . . - . ,OJ-"f 'U . , ......... " "_ .I .- . .............. " . . -. .__ . ........... -. Cis+ .. -. .... . . . . ". .... - .. . . . . . . ". -. ._..... - -. . . . hYDROCPQHOR O A T P SHEET . . . . . -. ............ . . . . . . . ... ." ...... -.- .- . - ..- ..._ " " " - ". ~ DEPTH SAkPLE "eEg-."-. 1287 i287 85 85 23 22 --"2i3"Ys2.4"-".8 1287 1287 85. 25 8 5 26 "--fiL8.F"65 -2-7" 1287 28 85 1287 85 29 ~ f f F - - . B f - 3 ------l.0630 0 1287 85 31 10870 . n. 94 0. T ... ..... 6. 0. 0 0. 0. . 0.u0 0.60 . 0 ..u 0 0.00 n. ...... ... A R O H C / TREA S P .. 0.00 0.00 0.00 0.00 0.00 .. 0.00. 0.00 . . . 9. o.no . o...no 0. 0.00 0.00 0.00 0.00 n.oo 0.00 0.00 . n. no ..o n o 0.00 g" . .." . . . . . . . . . . . 0.00 0.00 0.00 0.0.0 0.00 p..oo 0"00""~".00"~. 0.00 0.00 0.00 0.00 0.00 0.00 ... 0 0 0 . . . . . ..@. 0 0." . 0 -.oo 0.00 0.00 0.00 0.00 0.00 0.00 0 00 . o--oo 0-00 0.00 0.00 0.00 - .... ". c$ . - ........... - .. E ..(I . -6 1 .60 _" . S A Th C / C C PPN (t 0 0 . 0. 0. 0. .49 10510 kC 0."0 0. 0. 0.00 0. 0.00 0.00 0. 0.00 0.00 0 ._ . . . . .o 0 . . . -. .O.". ...... -..o.-oo .3h .40 .63 9450 975 0 9P.50 EPOC PPM 8670 .21 8e70 .e4 95 0 '.36 9060 -. TF O2FC 5 FT ... ... ....... ....... e ..__I ......... .- ..... .................. . .. . . . . . . . , , .. -- . " .. ,e - ........... -. . . . .-. ............ -. ...... SUN OIL CO. 1-VICTORIA ........ -.. SAMPLE NUMBER ",7~~"8 1287 1287 ~ ~ 1287 ,1287 ... ~. 2 3 ~ 5 86 86 ~ . . DEPTY FT "E80 910 1140 " 00 " 1500 86 86 6 1750 1 T B b 7""I 9 10 12A7 8 6 8 2020 1287 8 6 9 2530 ' - " ~ r 1287 1287 - - - 3 8 6 11 8 6 12 reo S ~ E R R AC O . ? NM EPUC 1E PPM OIlGC v .e1 % 0. n. .53 .OR . - . 21 h 3 ?h .34 .15 o*un 0 0;'oo 0. 0. .1H n. .33 0. .OR 3350 .07 0. 0. 3690 .lo n. ..13na . 0. 0 0. .lh .14 .SA n. n. 5600 1287 8 6 17 1281 8 6 18 5650 54 1 2 t 1 7 "5" 7 -7 0 .2h .Bb i281 86 2 0 5870 1287 8 6 - 21 5 9 5 0 .72 .. - 0'00 0.00 0. . n. !I . 0. n. 0. .... ........ 0.bO '0.00 0.00 0.00 0.00 HC/OC PFM 4 0.00 0.00 0.00 0. 0. 0. -. 0. _- .. 0 0. 0. ..... . ..n.o 'o' 0.00 0.00 0.00' 0. 0.00 0. 0.00 '0.00 0. (IO 0*00 0. 0.00 0.00 0.00 0.00 0.00 0'. 0 0 0*00 0.00 0.00 0.C0 0.00 0. 0. 0. 0. 0. 0; 0. 0. 0. 0. 0. 0.00 0.00 0 .oo 0.00 ' 0 o; 0 0.00 0.00 '0.00' 0.00 0.00 . . . . . . _.. . . . . SPT -- " . ... .- .- o..oo.-. .. PRO H C / TREA S P v 9r 0.00 0.00 R 0;oo 0.00 0.00 0.00 0.00 0.00 o o .... 0.00 0.00 0.00 0.00 0.00 n.no o;no n.no . o;oo'. 0.00 0.00 n.no n. n o 0.00 0.00 0.00 ".oo... n.no n.no 0.00 n. o o o.no ........ n,nn,:. .- 0.00 o.nn n*nn n.oo n.no .... .. " oo .. ." . . o"(To " " a-oo . -"o-oo - .o,oo n.no o.no n.nn n. no 0.00 g. 0.00 . n. 0 0 0.00 0.00 . - . . " n.00 " , 0.00 " " 0 0.00 (1.00 -....... .. 0.00 0.00 ...-o-;ao 0.00 0.00 - n.;.oo".-~~"o.o - ..- . . 0.00 '0.00 o xo0.00 0.00 o..oo 0.00 0.00 6;oo 0.00 0.00 n.; * 0.00 n.00 __ . 0.00 0.00 ... o,o 0.00 0.00 = ~~ " " ." _" . ." ". . .. "_ ......... - - ........ = PERCENT ORGANIC CARRON PPEA OF EXTRACT I N R O C K ........................................... ?. 1 R A T T ' A S . A PERCENT OF O R G A N I C C A R P O N LIJVL HC PPM = PPP OF PYOHOCAHHONS I N R O C K f l y !LC HC/OC % = HYDROCPRSONS AS A PERCENT O F O R G A N T C CARHON ..... ......... -="PERCENT SPTURATFS I N E X T R A C T t i Y ! L C ARO % PEHCEKT AROMATICS I N EXTRACT B Y T L C RASP .% = P E F C E N R T ESINS AND ASPHALTEKES I N FXTRACT @ Y TLC -n"~y~ROCflRRoh$s. A S A PFHCENT. o r .EXTRACT B Y . .TLc... ............... ORGC 'x T E PPM ..... ....... ._ ......... ._-._ - .. ................ tic " " " -...... ................... ., . . " ......... . ......... . C15+ hYDHOCPRRON DATA SHEET ... " ~ttmRb"-M-ft3CON-7..Ih'ENT-1 S I E R R A CO.* ..... NM DEPTH SAMPLE --"--NQMB* .......... OHGC EPbC HC hC/OC SAT TE PRO HC/T REA S P -g . 9: 9 - . PPM . . . 5? ..FT PPM e % i287 . 87 1 2280 0'00 0. +41 0. 0.00 0.00 0.00 0.00 0.00 128787 2 2330 2.07 0.UO 0. 0. 0.00 0.00 0.00 0.00 0.00 24.30 0.00 0. 0.00 n.00 . 0 00 . --~-..oo o.oo . . . . . 1 c t ( l " .44 0. 1207 8 7 6 2P50 0. b @ .33 0. 0. 0.00 0.00 0.00 0.00 0.00 128787 5 0'00 0. 0.00 3410 .7R n. 0.00 0.00 0.00 0.00 0.00 . . . . .o ..... o-..oo ....... 0.. - .... o " o o 0. .33 "6":3690. o"Oo o"oo 0-00 . 0. 0.00 0.00 0.00 0.00 0.00 4040 1287 8 ? 7 1.76 0. 0.00 1287 87 8 4790 n. 0. 0.00 n.oo .14 0.00 0.00 0.00 o.un " V .--551 B 0 c I n. " . 0. .o.oo 0. 00 o--.oo -.-o-.oo---o.-oo.. . 0 7I 0.00 0. 0.00 0.00 0.00 1287 87 10 6760 0. .31 0.00 0.00 1287 8 7 1 1 0.00 0. 0.00 0.00 n.no 0.00 0 . 7030 .44 0.00 . . . . . o 00 0 co I. --f2"-:7Q 5 0. 0 osbo"---1)~-oo"-"oso+oToo-~oo---""-0900 0. '0.00 .09 '.' f287: 13 8710 0. 0.00 0.00 :. :.o.Oo:"~;.:.': 0.00 0. 0.00 0. 0.00 0.00 0.00. .;, 0:oo .O.OO' .(Jo _"... 0 Q"oo' 90-...n-o""oo+osao 0. . @()"l."" n. 0.00 0. 0.00 0.00 0.00 0.00 0.00 ".. "' . . .. ~ i; . . . " " " . . " -. ' 0. - - - . "- . , . . . . . . . ..... - .............. " " " " . . . ._ .. ". . .. ............ " .. - ...... .. .......................... " C 1 5 + HYDHOCPRROh DATA SHEET .. ..... " " ' ..: . . . CTTTt5 . .. , - .RFfix.TOS I F 0 1 ' . , 1 2 8 79 89 1287 7 .49 8 , 89 1 0 89 11 . .. . . .1287; ' . T " 89. 13 .i . 1287 .. :i. : : 5070 4750 89"14 = ORGC % T E PPM 2630 3SAO 0: 0..; ........ ... ," o.,.()u -o;".L+ 0. ..... . 0. o; . 0 00 , . 0.00 i.o.00 : " . . 0.00 o~~~ *lo.o 0. ., 0. ! oT".-F;oF " " 0.bO 0'00.00 0.00 0.00 0.00 o".o . 0.00 0.00 0.00 0.00 . Y 0. '0.bO 0.00 0. 0. 0.00 0.00 " " 0 ".- .. o-o%--"-. f y " " " 0.00 . 0.00 . o-.oo"" 0.00 " " 0.00 o-oo"7 . 0.00 -o"oo" 0.00 0.00 0.00 0.00 ......... . ; __. ... CARROh ~ ~ O C A ~ B ' D N S . ' - A S - ' A . - P E R C E N T --' O~F " 0. 0.00" 0.00 , i 0.00 "oD Io o;-oo' 0.00 "_ .I - - 0.00 "0 0.00 0.. I . . . OIDO 0.00 o;-oo .o.oo 0.00 o,oo oo 'OF-ORGANI.~FCARFON""" 'HC P P k = PPI' OF HYDROCARBONS Ih' ROCK B Y !LC HC/OC B = HYDROCARBONS AS A PERCENT O F OR!"ANIC CPRBON *~EAT~.TURpTE'S"TN'EXTRACT .AYTL.C 5AT % A R O % = PERCENT PROMPTICS I N EXTRACT H Y ! L C RASP 3 ' = PERCENT GESINS AND ASPHALTENES I N EXTRACT BY TLC iiL/.It ' 0. 0. . . HCITE'. (J;-o.Cr7L"~-~r--csl;o 0.00. 0.00 t X l W c n C T .-AS-A"PERCENT -- 0.00 , 0.00 0.00 . . ~ 0.00 0.00 0. 0. o.; , , .o o u , o o " " ~ = ' P P M OF EXTRPCT I N ROCK - POC .:... . . . '!. .; . __ . _ I I 0.00 0.00 0.00 0.00 " g L_ .. , . ; O . O O . i .8 ' ....... , . i j ~ o ~ : : ~ ~, ..,., i , .~. . . o ~::d o : ; , ' . ' 0.00 :'r: 110..00. :.,~.;.o.Oo;..,. . 0.- ,I.; ,.. .. , ..... .!. i '/ RASP ': 0. 0.00 PRO SPT PC/OC . 0. 0.00 0. 0.UO 0 ;-- o"00"7""0. .o*uo 0.00 0. o * . . ....o-oo" . .07 0. .16 ". ...............0. PERCENT ORGANIC HC PPM , :.. . . .: .. ... " _ I 0.00 .20 4150 e25 ~3 o,o- ........ ,12 1 .. . . . .f L 8 I . ' 8 9 ":. o . .08 37-00''. '.07 4010 .11 " " .. . . . . .~, TE PP,~ 4 a5 1287 1287 ORGC EPOC % 2120 0 . .34 56"---i)47 2 1 8 0 ............24 ... 89 ..1cr6r.: ... 1700 .09 l1'820 i80 "----I1287 ' 1 2-8897 DOF!A..'ANNA "co.~.,.-N1.: pT 89 . ' 2 ~.>. ... , ;', .. . .>.. . . ,:'::'.:.,i ~ DEPTH SAHPLE ER- .. __ . , ..: . : - ~ ~ .......... . . . . . . . .- . . . . ~ ~ ~ ._ ~ ~ ~ ............ ._....... - ..... 0 - f " - ...... ........ " ~ f " "_ . - " ~ , , ~ - - ' " .... " .- . " ..~ !:. .. .:, ' -.. " .~ . ", " .- .. " ~ .. ................ ..... . "_ " " , ..... ....- ._ ~ - ~~ RASP % . = PERCENT RESINS .UrltF = AND ASPHALTENES N I EXTRACT BY TLC HVnROCAREONS AS A PERCENT OF EXTRACT BY TLC c ... I