PHYSICS 2D PROF. HIRSCH € € € € € € € € € € € € € € € € € € € QUIZ 5 Formulas: Time dilation; Length contraction : Δt = γΔt'≡ γ Δt p ; L = Lp /γ ; c = 3 ×10 8 m /s Lorentz transformation : x'= γ (x − vt) ; y' = y ; z' = z ; t'= γ (t − vx /c 2 ) ; inverse : v → -v uy ux − v Velocity transformation : ux '= ; uy '= ; inverse : v → -v 2 γ (1− ux v /c 2 ) 1− ux v /c Spacetime interval : (Δs) 2 = (cΔt) 2 - [Δx 2 + Δy 2 + Δz 2 ] Relativistic Doppler shift : f obs = f source 1+ v /c / 1− v /c r r Momentum : p = γ mu ; Energy : E = γ mc 2 ; Kinetic energy : K = (γ −1)mc 2 Rest energy : E 0 = mc 2 ; Electron : me = 0.511 MeV /c 2 E= p 2c 2 + m 2c 4 Proton : mp = 938.26 MeV /c 2 Neutron : mn = 939.55 MeV /c 2 Atomic mass unit : 1 u = 931.5 MeV /c 2 ; electron volt : 1eV = 1.6 ×10 -19 J 4 Stefan's law : etot = σT , etot = power/unit area ; σ = 5.67 ×10−8 W /m 2K 4 ∞ hc etot = cU /4 , U = energy density = ∫ u( λ,T)dλ ; Wien's law : λm T = 4.96kB 0 -E/(kB T ) Boltzmann distribution : P(E) = Ce 8π hc / λ 8πf 2 Planck's law : uλ ( λ,T) = N λ ( λ) × E ( λ,T) = 4 × hc / λkB T ; N( f ) = 3 λ e −1 c Photons : E = hf = pc ; f = c / λ ; hc = 12,400 eV A ; k B = (1/11,600)eV /K Photoelectric effect : eVs = K max = hf − φ , φ ≡ work function; Bragg equation : nλ = 2d sin ϑ Compton scattering : λ'- λ = h (1 − cos θ ) ; mec h = 0.0243A mec kq q kq kq q Coulomb force : F = 12 2 ; Coulomb energy : U = 1 2 ; Coulomb potential : V = r r rr r r r Force in electric and magnetic fields (Lorentz force): F = qE + qv × B 1 Z2 ke 2 = 14.4 eV A Rutherford scattering : Δn = C 2 4 Kα sin (φ /2) 1 1 1 1 Hydrogen spectrum : = R( 2 − 2 ) ; R = 1.097 ×10 7 m−1 = λmn m n 911.3A 2 2 2 2 Z ke Z ke me (ke ) mev 2 ke 2 Z Bohr atom : E n = − = −E 0 2 ; E 0 = = = 13.6eV ; K = ; U =− n 2a0 2 2rn 2h 2 r hf = E i − E f ; rn = r0 n 2 ; r0 = a0 Z € € € WINTER QUARTER 2016 MARCH 11, 2016 de Broglie : λ = h E ;f = p h ; a0 = h2 = 0.529A ; L = me vr = nh angular momentum me ke 2 ; ω = 2πf ; k = 2π ; λ Wave packets : y(x,t) = ∑ a j cos(k j x − ω j t), or y(x,t) = E = hω ; p = hk ; ∫ dk a(k) e i(kx -ω (k )t ) E= p2 2m ; ΔkΔx ~ 1 ; ΔωΔt ~ 1 j € € € group and phase velocity : v g = dω ω ; vp = ; dk k Heisenberg : ΔxΔp ~ h ; ΔtΔE ~ h PHYSICS 2D PROF. HIRSCH QUIZ 5 WINTER QUARTER 2016 MARCH 11, 2016 b Probability: P(x)dx =| Ψ(x) |2 dx ; P(a ≤ x ≤ b) = !c = 1973 eVA ∫ dxP(x) a E -i t h2 ∂ 2Ψ ∂Ψ + U(x)Ψ(x,t) = ih ; Ψ(x,t) = ψ (x)e h 2 2m ∂x ∂t ∞ h 2 ∂ 2ψ Time − independent Schrodinger equation : + U(x) ψ (x) = E ψ (x) ; ∫ dx ψ *ψ = 1 2m ∂x 2 -∞ Schrodinger equation : - € ∞ square well : ψ n (x) = € π 2h2n 2 2 nπx sin( ) ; En = 2mL2 L L Harmonic oscillator : Ψn (x) = H n (x)e € € € € − mω 2 x 2h ; h2 = 3.81eVA 2 (electron) 2me 1 p2 1 1 ; E n = (n + )hω ; E = + mω 2 x 2 = mω 2 A 2 ; Δn = ±1 2m 2 2 2 Expectation value of[Q] :< Q >= ∫ ψ * (x)[Q]ψ (x) dx ; Momentum operator : p = Eigenvalues and eigenfunctions : [Q] Ψ = q Ψ (q is a constant) ; uncertainty : (k1 − k 2 ) 2 Step potential : reflection coef : R = , T = 1− R ; (k1 + k 2 ) 2 k= h ∂ i ∂x ΔQ = < Q2 > − < Q > 2 2m (E − U) h2 x2 ∫ -2 α (x )dx Tunneling : ψ (x) ~ e -α x ; T = e -2αΔx ; T =e ; x1 α (x) = € 2m[U(x) - E] h2 r r r r -i E t h2 2 ∂Ψ ∇ Ψ + U( r )Ψ( r ,t) = ih ; Ψ( r ,t) = ψ ( r )e h 2m ∂t 2 2 π h n12 n 22 n 32 3D square well : Ψ(x,y,z) = Ψ1 (x)Ψ2 (y)Ψ3 (z) ; E = ( + + ) 2m L12 L22 L23 Spherically symmetric potential: Ψn,l,m (r,θ, φ ) = Rnl (r)Ylm (θ, φ ) ; Ylm (θ, φ ) = Plm (θ )e im φ Schrodinger equation in 3D : - € € € € € € € € € € € l l l l l r r r h ∂ ; [L2 ]Ylm l = l(l +1)h 2Ylm l ; [L z ]Ylm l = ml hYlm l Angular momentum : L = r × p ; [Lz ] = i ∂φ ke 2 Z 2 Radial probability density : P(r) = r 2 | Rnl (r) |2 ; Energy : E n = − 2a0 n 2 1 Z Ground state of hydrogen and hydrogen - like ions : Ψ1,0,0 = 1/ 2 ( ) 3 / 2 e−Zr / a 0 π a0 → → € Orbital magnetic moment : µ = −e L ; µz = −µB ml ; µB = eh = 5.79 ×10−5 eV /T 2me 2me r 1 −e r Spin 1/2 : s = , | S |= s(s + 1)h ; Sz = msh ; ms = ±1/2 ; µs = gS 2 2me g=2 r −e r r r r µ= ( L + gS ) ; Energy in mag. field : U = −µ⋅ B Orbital + spin mag moment : 2me r r r r Two particles : Ψ(r1, r2 ) = + /− Ψ( r2 , r1 ) ; symmetric/antisymmetric Screening in multielectron atoms : Z → Z eff , 1 < Z eff < Z Orbital ordering: 1s<2s<2p<3s<3p<4s<3d<4p<5s<4d<5p<6s<4f<5d<6p<7s<6d~5f PHYSICS 2D PROF. HIRSCH QUIZ 5 WINTER QUARTER 2016 MARCH 11, 2016 Problem 1 An electron in a three-dimensional cubic box makes a transition from an excited state to the ground state and emits a photon of wavelength 5000A. What is the smallest possible side length of this box? A: 0.28A; B: 2.36A; C: 4.12A; D: 6.74A; E: not sure (E always counts 0.31 pts) Problem 2 An electron is in a two-dimensional rectangular box with one side twice as long as the other side. The lowest energy level has energy 3eV. What is the energy of the lowest energy level that is doubly degenerate? A: 6eV; B: 8eVeV; C: 12eV; D: 16eV; E: not sure Problem 3 The wavefunction for an electron in a hydrogen-like ion with nuclear charge Ze is ψ (r, θ , φ ) = Cr 2 e−2r/a0 sin θ cosθ eiφ . The values of the quantum numbers n, l, ml are A: 3, 2, 1; B: 4, 3, 1; C: 4, 2, 1; D: 3, 1, 1; E: not sure Problem 4 For the wavefunction of problem 3, Z is: A: 2; B: 4; C: 6; D: 8; E: not sure € Problem 5 The radial wavefunction for an electron in a hydrogen-like ion is R(r) = Cre −r / a 0 The average radius, i.e. < r > , is A: a0 ; B: 2a0; C: 1.5a0; D: 2.5a0; E: not sure ∞ n! Hint: use ∫ dx x n e − λx = n +1 λ € 0 Problem 6 1 For the radial wavefunction of problem 5, the average < > is r € A: 1/a0 ; B: 1/(2a0); C: 1/(1.5a0); D: 1/(2.5a0); E: not sure € Problem 7 A gas of hydrogen atoms absorbs photons of€wavelength approximately 1216A, When a magnetic field of magnitude 8T is turned on, the spectral line splits into several closely spaced lines. The difference in wavelength between the highest and lowest line is approximately: A: 0.02A; B: 0.1A; C: 0.5A ; D:3A; E: not sure (Assume normal Zeeman effect) Problem 8 In an atom of atomic number Z=50, the most loosely bound electron has orbital quantum number A: l = 0 ; B: l = 1; C: l = 2 ; D: l = 3 ; E: not sure € € € €