GEOLOGY OF THE PRECAMBRIAN ROCKS OF THE LEMITAR MOUNTAINS, SOCORRO C O U N T Y , NEW M E X I C O V i r g i n i a T. Submittedin McLemore Partial Fulfillmept o f t h er e q u i r e m e n t sf o rt h eD e g r e eo f Master of S c i e n c e i n G e o l o g y V New M e x i c o I n s t i t u t e o f M i n i n ga n dT e c h n o l o g y Socorro, N e w M e x i c o May, 1980 TABLE OF CONTENTS ABSTRACT ACKNOWLEDGMENTS. INTRODUCTION Purpose Methods .............................................. 1 .............................................. 3 of ............................. 4 ........................................ 6 ......................................... 7 ......................................... 7 of U n i t ...........11 Investigation P r e v i o u s Work SEDIMENTARYROCKS Introduction Distribution and discussion Distribution and discussion Lower of U p p e r U n i t ...........12 ........................................ P r o v e n a n c e a n d S e d i m e n t a t i o n ........................ IGNEOUSROCKS ............................................ I n t r o d u c t i o n ........................................ L e m i t a r d i o r i t e j g a b b r o.............................. I n t r o d u c t i o n ................................... D e s c r i p t i o n .................................... M i g m i t i z a t i o n .................................. G e o c h e m i s t r y .................................... G a b b r o o f G a r c i a C a n y o n ........................ O r i g i n ......................................... M a f i c D i k e s ......................................... Geochemistry 20 25 31 31 33 33 35 40 44 46 4. 48 ................................... 48 D e s c r i p t i o n .................................... 49 G e o c h e m i s t r y ................................... 53 O r i g i n of t h e M a f i c R o c k s ........................... 54 G r a n i t i c Complex .................................... 57 I n t r o d u c t i o n .................................... 57 G n e i s s i c g r a n i t e ............................... 59 M u s c o v i t e - b i o t i t e g r a n i t e ...................... 61 B i o t i t e g r a n i t e ................................ 63 L e u c o g r a n i t e ................................... 65 P o l v a d e r a G r a n i t e ................................ 65 Pegmatites and quartz veins .................... 68 G e o c h e m i s t r y ................................... 69 O r i g i n ......................................... ~4 C a r b o n a t i t e D i k e s ................................... 76 I n t r o d u c t i o n ................................... 76 D i s t r i b u t i o n ................................... 77 D e s c r i p t i o n .................................... 87 G e o c h e m i s t r y ................................... 98 F e n i t i e a t i o n .................................. 104 O r i g i n ........................................ 114 STRUCTURE AND METAMORPHISM .............................. 117 MINERALIZATION .......................................... 127 HISTORY. TECTONIC SETTING. AND CONCLUSIONS .....1 3 0 Distribution I GEOLOGIC REFERENCES CITED........................................l36 APPENDICES .......................... A - Analytical B - Brief Petrographic Description of the Procedures 149 Analyzed Rocks.................................157 C - Chemical .............................. Analyses 162 TABLES 1 2 3 4 5 6 7 8 .G e o c h e m i s t r y o f s a n d s t o n e s ......................... 21 - Chemical c l a s s i f i c a t i o n o f s a n d s t o n e s ..............2 3 - G e o c h e m i s t r y o f L e m i t a r s e d i m e n t s ..................2 9 - Difference between gabbro and diorite ..............36 - C h e m i s t r y of t h e m a f i c r o c k s ....................... 45 - C h e m i s t r y of t h e L e m i t a r g r a n i t i c c o m p l e x ..........7 0 - 10 11 9 Chemistry of granites .............................. MineralsofCarbonatiteComplexes 73 ..................78 .......................... 79 element chemistry of carbonatites ............80 Chemistry of.carbonatites Trace S i m i l a r i t i e sa n dd i f f e r e n c e s Lemitar c a r b o n a t i t e s ..............8 2 1 2 - X-Ray d i f f r a c t i o n l i n e s o f b a s t n a e s i t e ............83 1 3 - M i n e r a l o g y o f t h e L e m i t a r c a r b o n a t i t e s .............89 14 - Distribution of elements i n c a r b o n a t i t e s ..........1 0 2 1 5 - M i n e r a l s o f t h e L e m i t a r c a r b o n a t i t e s a m p l e s .......1 0 3 1 6 - C l a s s i f i c a t i o n of f e n i t e s ......................... 105 1 7 - Summary o f c h e m i c a l c h a n g e s d u e t o f e n i t i z a t i o n ...1 0 9 and other occurrences of carbonatites 18 - Chemicaltrends 19 - Summary of geologic history ..........110 ....................... 1 3 1 of f e n i t i z e d m a f i c r o c k s FIGURES 1 2 .I n d e x map ........................................... - P r e c a m b r i a ng e o l o g i c map of t h e Lemitar M o u n t a i n s 2 (inpocket) 3 - Diagrammatic stratigraphic section 4 - Classification of sandstones 5 - 6 7 - Na20 K20 p l o t o f s a n d s t o n e s Geochemical classification ..................8 ........................ ...................... of ........... 22 sandstones 22 Tectonic provenance of Proterozoic sandstones ......2 6 .................... 9 AFM d i a g r . a m ........................................ 1 0 - M a f i c - F e l s i c i n d e x d i a g r a m ....................... 8 11 12 13 - C l a s s i f i c a t i o n of igneous rocks - CaO Rb - Na20 - K20 d i a g r a mo f Srdiagramof L e m i t a r i g n e o u sr o c k s ' . . Lemitar g r a n i t i c c o m p l e x C a r b o n a t e - a p a t i t e - m a g n e t i t ep l o to ft h e carbonatites 9 32 55 56 71 ........7 2 Lemitar ....................................... ..................... ...................... 88 14 - Chemical plot of carbonatites 100 15 - CaO-Na20-K20 108 p l o t of f e n i t e s PLATES 1 2 .P h o t o g r a p h . a r k o s e a n d q u a r t z i t e ...................14 - P h o t o g r a p h . c r o s s b e d d i n g i n a r k o s e .................14 ............................ 1 6 ................................. 1 6 ......................... 1 8 .................... 38 ......................... 38 ......................... 39 .....4 1 in .....4 1 3 .P h o t o m i c r o g r a p h . a r k o s e 5 - 6 - Photomicrograph. dioritelgabbro 7 - Photograph. dioritelgabbro 4 9 10 11 12 13 14 8 Photograph. arkose Photomicrograph. subarkose Photograph. dioritelgabbro Photograph. foliated muscovite-biotite granite Photograph. migmatitic layer dioritelgabbro Photograph. agmatitic structure i n dioritelgabbro Photograph. agmatitic structure in dioritelgabbro ..4 2 ..4 2 i n diorite/gabbro.,43 P h o t o g r a p h .b o u d i n a g es t r u c t u r e Photomicr.ograph, altered mafic dike ................5 1 ..................6 0 15 - 16 .P h o t o g r a p h . g n e i s s i c g r a n i t e 17 .P h o t o m i c r o g r a p h . m u s c o v i t e - b i o t i t e g r a n i t e Photomicrograph. gneissic granite ....................... .........64 ...................64 ...............84 .....:......... 84 ................86 62 18 .P h o t o m i c r o g r a p h . b i o t i t e g r a n i t e 1 9 .P h o t o g r a p h . b r e c c i a c a r b o n a t i t e d i k e 20 - 21 .P h o t o g r a p h . b a n d e d c a r b o n a t i t e d i k e 22 .P h o t o m i c r o g r a p h . p r i m a r y c a r b o n a t i t e d i k e Photograph. breccia carbonatite dike 24 ..........9 0 .P h o t o m i c r o g r a p h . r e p l a c e m e n t c a r b o n a t i t e d i k e ......9 1 - Photomicrograph.replacementcarbonatitedike ......9 1 25 .P h o t o g r a p h . c a r b o n a t i t e d i k e 26 - 23 ....................... 93 ..................9 4 Photomicrograph. carbonatite dike 27 - 28 29 Photograph, carbonatite dike ....................... P h o t o g r a p h ,c a r b o n a t i t e dike.......................97 P h o t o g r a p h ,c a r b o n a t i t e dike.......................97 MAPS 1 2 - G e o l o g i c Map o f t h eP r e c a m b r i a nr o c k s G e o l o g i c Cross S e c t i o n s ( i n pocket) (in p o c k e t ) 94 ABSTRACT T h eP r e c a m b r i a nr o c k si nt h eL e m i t a rM o u n t a i n sc o n s i s t of a sequenco e sf e d i m e n t st,h C e orkscrew C a n y oSne q u e n c e ( 5 % ) , i n t r u d e ds e q u e n t i a l l yb ym a f i cd i k e s , a diorite/gabbro ( 7 5 % ) , a ncda r b o n a t i tdei k e s . b o d(y2 0 % g ) ,r a n i t irco c k s a Lower U n i t composed o f a T h es e d i m e n t sc o n s i s to f of a r k oaU sanenpdpUe n cr o i tm p o s e d i n t e r b e d daendd f o l i a t e da r k o s e s ,s u b a r k o s e s ,a n dq u a r t z i t e s . The s e d i m e n t s l o w S i 0 2 / A 1 2 0 3r a t i o sa n d i n S i 0 2 ( > 6 2 % ) a n dh a v e a r eh i g h K20/Na20 r a t i o se q u a lt oo rg r e a t e rt h a no n e . o fq u a r t za n df e l d s p a ri n d i c a t e s g r a n i t e or fluvial massive T h ea b u n d a n c e a s o u r c ea r e ac o n s i s t i n go f a g n e i sw s ,h i b l ee d d i ns gt r u c t u r ei ns d i c a t e a continental-rift or d e l t a i ce n v i r o n m e n ti ne i t h e r o r a r a p i d l y r i s i n g c o n t i n e n t a l - m a r g i ns e t t i n g . The Lemitar diorite/gabbro a is lithologically mafic u n i tr a n g i n gi nc o m p o s i t i o nf r o mg a b b r o heterogeneous ( > A n 5 0a )nddi o r i t( e< A n 5 0tq1ou a r tgza b b raonqdu a r t z d i o r i t e (5-10% q u a r t z ) .T h i sl i t h o l o g i ch e t e r o g e n e i t yc o u l d abcec o u n t e d gabbroic for magma late be yi t h e r pre-granite, - Stage I, of 11, and post-granite). and a o f g r a n i t i c magmas o ir n j e c t i o na n dm i x i n g w i t h a g a b b r o bi co d T y .h r es et a g e s recognized d i f f e r e n t i a t i o nf m a f di ci k e s are I11 ( p r e - d i o r i t e / g a b b r o , T h em a f i cr o c k sp l o ti nt h e tholeiite field o f a n AFM d i a g r a m . six T h eg r a n i t i cr o c k sa r eg r o u p e di n t o one or - m o rpe l u t o n s v a r i a t i o n so f gneissig c r a n i t em , uscovite-biotite g r a n i t eb, i o t i t e g r a n i t el, e u c o g r a n i t eP, o l v a d e r a granite, a n dp e g m a t i t e sa n dq u a r t zv e i n s . Age r e l a t i o n s h i p sb e t w e e n t h eg r a n i t i cr o c k sa r eu n c e r t a i nb e c a u s et h eg r a n i t e sa r e are of a n oicn to n t a cwt i tohnaen o t h earnpdr o b a b l y similar a g eT.hger a n i t ir co c k s fall - into wgor o u p s G r o u p I ( g n e i s s i cg r a n i t ea n db i o t i t eg r a n i t e )c h a r a c t e r i z e d by low S i(0626 - 7 0ah2ni)dg h CaO (0.8-1.5% aG n)dr o u p . I1 (1.5-32) MgO ( m u s c o v i t e - b i o t igt er a n i t e . and (73-76%) a n d P o l v a d e r ag r a n i t e c) h a r a c t e r i z e db yh i g hS i 0 2 l o w C a O ( < 1 . 5 % )a n d and MgO ( < 0 . 8 % ) . C a r b o n a t i t ed i k e si n t r u d et h ee a r l i e rP r o t e r o z o i cr o c k s and are c o m p o s>o e 5fd 0c% a r b o n a(tcea l c i tdeo, l o m i t e , a n d / oa rn k e r i t ea )n d magnetite are ( u pt o T h ec a r b o n a t i t e s rich in lo$), a p a t i t(eutpo 15%), a n db i o t i t e / p h l o g o p i t e( u pt o f a l l i n t ot w op o p u l a t i o n s - 15%). l o wi r o na n d h i igrhorne ,l a t tpehordee s e naocnfek e r iatne d 4% m a g n e t i t eC. a r b o n a t i t e as r rei c ihp n h o s p h o r u (su tpo P 2 0a5un)r d ,a n i (u tu omp 0.1% U308). Norm s oadl i c f e n i t i z a t i o nh a sa l t e r e dt h eL e m i t a rd i o r i t e / g a b b r oa d j a c e n t t ot h ec a r b o n a t i t ed i k e s a s e v i d e n c e d by t h ei n c r e a s ei n sodium i n p l a g i o c l a s e s a n d t h e i n c r e a s e i n K - f e l d s p a r . C h e m i c a l l y ,t h ei g n e o u sr o c k s populations - f a l l i n t ot h r e ed i s t i n c t t h em a f i cr o c k s ,t h eg r a n i t i cr o c k s ,a n dt h e c a r b o n a t i t e sn; o c h e m i c atlr e n d as r ae p p a r e nbt e t w e e n the is consistent o f t h e sreo c k s groupT s .hbei m o d anla t u r e w i t h a c o n t i n e n t a l - r i f ts e t t i n g . T hPer e c a m b r i arno c kotsfhLee m i t aM r o u n t a i nhsa v e of u n d e r g osnuec c e s s ipveer i o d s and r e t r o g r amdeet a m o r p h i s m m e t a m o r p h i sp m r it oo r o t hael rt e r a t iaoannrde s t r u c t u r a lcloym p l ecxo,n s i s t fioo nflgi a t i of na ,u l t s , s h e a r i n ga,n bd r e c c i a t i o (nm o sotw f h i c ahrL e a r a m i doe r 1. T e r t isat rr yu c t u r e s P r o t e r o z ori oc c k s are M i naesr sael m btlhaoegf e. s representative of t ht er a n s i t i o n b e t w e e tnh ge r e e n s c h i sat n ad m p h i b o l i t fea c i e sF. o l i a t i o n ot h fCe o r k s c r e C w a n y osne q u e n caep p r o x i m a t e lpya r a l l e l s i s d i s t i n g u i s h e d by t e x t u r a la n dc o l o r relicb t e d d i n ga n d contrasts. A n o r t h e a s t - t r e n d i n gs h e a rz o n ec u t sa c r o s st h e at s e d i m e nat n es d nds t hi en t r u s i vceo n t a cwt i t. ht h e -. m u s c o v i t e - b i o t i tger a n i t eS. h e a r i nogt fhdei o r i t e l g a b b r o may b e r e l a t e d t o t h e e m p l a c e m e n t of t h e& r a n i t i cr o c k s . D e t a i l e dm a p p i n g ,p e t r o g r a p h i c ,a n dg e o c h e m i c a ls t u d i e s i n d i c a t et h a t h eP r o t e r o z o i cr o c k sa r ec o n s i s t e n w t ith c o n t i n e n t a l - r i fst e t t i n g . b e t w e e nt h e T h e l a c k of a ncyh e m i c at lr e n d m a f i c , g r a n i t i c ,a n dc a r b o n a t i t eg r o u p ss u g g e s t s t htaht e artrehe r se ee p a r a t e magma s o u r cfetoh sre a formation of i g n e oruosc k s in Lemitar the Mountains. H o w e v e r ,c o n t a m i n a t i o nb yc r u s t a lm a t e r i a la n do t h e r c o u l db er e s p o n s i b l ei np a r t trend. for t h i sl a c k An a l k a l i p r o v i n c e may h a v e x i s t e d a n ds o u t h e r nC o l o r a d o e, v i d e n c e d magmas o f a n yc h e m i c a l in New by t h ep r e s e n c e and New Mexico (Monte t o Largo, Lemitar F l oM r ioduan t aPianj sa M ,r o i tuon t T a ihne) . M o u n t a i n sw o u l db ep a r t of 0 . 4 (Wet 1 . 2 b a ya .l k a rl io c kssc a t t e r etdh r o u g h o uCt o l o r a d o M o u n t a i n Isr, oM nountains) Mexico of t h i sa l k a l ip r o v i n c e . ACKNOWLEDGMENTS T h e a u t h o r i s i n d e t)te d t 'o Mr. f o ar c c e s tstoh e B. J. a n d Mrs. f i e l d a r e aS.p e c i a lc k n o w l e d g m e n t made t o D r . K. C. C o n d i ef o r as d u r i n g t h e p r e p a r a t i o n T haeu t h o r as w e l l J o aPne n d l e t o n , 'J. M. of t h e m a n u s c r i p t . i s g r a t e f u lt o some of is many h e l p f u sl u g g e s t i o n a s nd commentspertainingtothefieldandlaboratorywork helw p ith Kelley J. Dr. R. R e n a u l ft o hr i s t h ae n a l y t i c aal n a l y s i sR . o b e rN t orth, Drs.' K. C. C o n d i e , J. R. R e n a u latn, d for R o b e r t saocr n ek n o w l e d g e d their critical r e v i e w so ft h em a n u s c r i p t O . t h e rp e o p l eh a v ea s s i s t e dw i t h thisproject a r e a c k n o w l e d g e df o rt h e i r a t v a r i o u st i m e sa n d a s s i s t a n c eL: a r r H y o l(t f i e l da' s s i s t a n t ) , ( a s s i s t e dw i t h L y nBnr a n d v o l d s o m eo ft h ec h e m i c a la n a l y s e s ) G , a r yM o r r i s ( e x c h a n g eo ff i e l da n dp e t r o g r a p h i cd a t aa n dd i s c u s s i o n so f Dr. tohcec u r r e tn co hacfere b o n a t i t e as n ) ,d A. J. B u d d i(nagc c o m p a n itaehudetfhisen oelrnvd e r a l occasions). Dr. Clay Smith also l e ntth ae u t h o r maps a n d a i r p h o t o so ft h ea r e a . Iand d i t i o na ,p p r e c i a t i o n is e x t e n d et do Dr. Frank husband, James; K o t t l o w s kfiohr i isn t e r e sat n sd u p p o rottfh i ps r o j e c t . F i n a l l ya ,p p r e c i a t i o n field is e x t e n d etdo assistan s at ,m pcloel l e c t oacrna,dm e r a m aTnh. i s my study was financed in part by a grant from the New Mexico Geological Society and by an assistantship from the New Mexico Bureau o f Mines. G e o l o g yo ft h eP r e c a m b r i a nR o c k so ft h eL e m i t a rM o u n t a i n s , S o c o r r oC o u n t y , New Mexico INTRODUCTION T h e L e m i t a r M o u n t a i n sa r el ' o c a t e da p p r o x i m a t e l ye l e v e n km. n o r t h w eS os fot c o r r o , N e w M e x i c( foi g . u n p a v e dr o a d sw e s to fL e m i t a r , 1). Several New M e x i c o ,p r o v i d ee x c e l l e n t two- a c c e stt sohaer ebeayi t h e r foor u r - w h e e l - d r i v e v e h i c l ePs r. e c a m b r i ar o nck c rs oo p au lt o nt hg e ea s t e r n f l a n k so ft h em o u n t a i n s . T h e map a r e a( f i g . limit 2 ) e x t e n d sf r o mt h es o u t h e r n sec. o fP r e c a m b r i a ne x p o s u r e( n e a rt h es e c t i o nl i n eb e t w e e n 1 8 a n d 1 9 , T.2S., in sec. 32 R.lE.), (T.lS., b o u n d a r i e s o f t h fe i e l d n o r t h w a r dt ot h em i c r o w a v et o w e r R.1E.). a r eaar e Tehaes t earnw nde' s t e r n f o r m ebtdy heenodf P r e c a m b r i a ne x p o s u r e . T h e a r e a s o u t ho fC o r k s c r e wC a n y o n( l o c a t e da l o n gt h e 7 a n d 1 8 ) h abde epnr e v i o u s l y s e c t i olni nbee t w e esne c . mapped by Chamberlin (1978 as a n1d9 8 0ipn ,reparation) P r e c a m b r i a nu n d i f f e r e n t i a t e dm e t a m o r p h i cr o c k s T . h i sr e p o r t d i v i d etsh seo u t h e r an r e ian t toh r e m e a p p a b l lei t h o l o g i c units (Map 1 )C. h a m b e r l i (n1 9 7 a8 n 1 d 9 8 0i,p nr e p a r a t i o n ) a l s or e c o g n i z e dd e f i c i e n c i e si nt h eg e o l o g i cm a p p i n g of the LL 0 2 a a s 0 I fn >I- z 3 0 0 0 K K 0 0 0 v) LL 0 n Q I I W I I I I I I I I I I r I I I -. I , Page 3 Woodward (1973) i n t h ea r e an o r t h Precambrian r o c k bs y P r e c a m b r i a nr o c k s . t o r e m a pt h e it w a s n o th i si n t e n t i o n C o r k s c r e wC a n y o n ,b u t A s a p a r t of t h i sr e p o r t ,t h e C o r k s c r e wC a n y o nn o r t h w a r d of area from t ot h ei n t r u s i v ec o n t a c to ft h e P o l v a d e r aG r a n i t eh a sb e e nr e m a p p e d (Map 1). W h e r e v e rp o s s i b l e t, h en a m e so fp a r t i c u l a rl i t h o l o g i c u n i ht sa vbee eand o p t e d or t e r m i n o l ougsbyeyd Woodward m o d i f i ef d r otm hi ne f o r m a l (1973). e s p e c i a l lw y i t thh ge r a n i t i rco c k s , many cases, new l i t h o l o g i u cnits informal, w e r em a p p e db yt h ea u t h o ra n da s s i g n e d names In descriptive of S e v e r .apl e r i o d s P r e c a m b r i a nr o c k se x p o s e d m e t a m o r p h i shm a av fef e c t tehde i n t h e L e m i t a r M o u n t a i n sa n dt h e l i t h o l o g inca m essh o u lbdper e f i x ew d i tthhtee r m meta. However, the currentrend among P r e c a m b r i a ng e o l o g i s t s is leave off t ou s et h eo r i g i n a l i t h o l o g i cn o m e n c l a t u r ea n d t h ep r e f i x meta: t h a ts t y l e i s a d o p t e df o rt h i sr e p o r t . PURPOSE T h ep u r p o s eo ft h i sr e p o r t i s t o d e s c r i b ea n dd e t e r m i n e t h eg e o l o g i ch i s t o r yo ft h et h i c ks u c c e s s i o n of P r e c a m b r i a n s e d i m e n t sa n dg r a n i t i c ,m a f i c ,a n dc a r b o n a t i t er o c k se x p o s e d in t hLee m i t M a ro u n t a i nTs h . si tsu di ny c l u d d e se t a i l e d Page 4 m a p p i n g ,p e t r o g r a p h i cs t u d i e s ,a n dm a j o r -a n dm i n o r - e l e m e n t “a a n a l y s eosf of s a m p l e D s .e t a i l e d r e p r e s e n t a t i v se u i t e o n e i g h tc a r b o n a t i t es a m p l e s . c h e m i c a ls t u d i e sa r ei n c l u d e d From t h e result’s t h e f o l l o w i n g w i l l b ed i s c u s s e d : (1) t hsee d i m e n t a reyn v i r o n m e n t . (2) t h se e d i m e npt r o v e n a n c e (3) t h en a t u r eo ft h em a f i ca n dg r a n i t i c m a g m a t i s m a, n d (4) t h et e c t o n i cs e t t i n g . METHOD OF INVESTIGATION T h ea u t h o r ,a s s i s t e db yL a r r yB o l ta n dJ a m e s McLemore, area ( f i g . s p e nat p p r o x i m a t e l y fivm e o n t hm s apping the idne t a i l at a s c aol ef 1:6000. 7 . 5 - m i n u t eq u a d r a n g l e map a r e shown on r a d i o a c t i v i t yo ft h e was Lemitar U.S.G.S. was u s e d as a b a s e for g e o l o g i c m a p p i n gA. r e aom sf a j ooru t c r o p s c i n t i l l a t i ocno u n t e r The the map. m a f i c a n dc a r b o n a t i t ed i k e sa n do t h e r were s t a n d a r d i z e du, s i n g t h er o c kc o l o rc h a r tb yG o d d a r d ,e t al. (1975). One h u n d r e dt h i ns e c t i o n sw e r e x a m i n e dw i t h p o l a r i z i n gm i c r o s c o p et od e t e r m i n el i t h o l o g i ca n d Twenty of A u s em t ode a s u tr hn e ea t u r a l r o c kistnh fei e l dR. o c ck o l o r s variations. 2) the thin a Zeiss textural s e c t i o nocsfa r b o n a t i t e s Page on were 5 l o a nf r o mG a r r yM o r r i s ,a l s os t u d y i n gt h e s er o c k s . . Many o f t h e s l i d e s w e r e s t a i n e d t o a i d i n t h e i d e n t i f i c a t i o n K o -f f e l d s p aPrl.a g i o c l acsoe m p o s i t i ow n sedr ee t e r m i n e d 1959). u s i n gt h eM i c h e l - L e v ym e t h o d( K e r r , in M i n e r ai dl e n t i f i c a t i o n s c a r b o n a t i st ea m p l e s d e t e r m i n e d from t h i ns e c t i o ns t u d ya n d M i n e r a ls e p a r a t i o n s byX-ray were diffraction. were made w i t h a n a c e t i c a c i d l e a c h a n d a h e a v ym i n e r a ls e p a r a t i o nt e c h n i q u eu s i n gt e t r a b r o m o - e t h a n e ( s p e c i gf ir ca v i t y of 2 . a9 i dn6ed) n t i f i e d X-ray by in diffractA i onna. l y t pi cr o a lc e dduai rs ec su s s e d a p p e n d i x A. S e v e r a cl o m p u t e rp r o g r a m sw e r eu s e dt oc a l c u l a t e and MESO Norms ( K . C. CIPW C o n d i ep,e r s o n aclo m m u n i c a t i o na)n d o t h epre t r o l o g ipca r a m e t e r( sP e t c abB ly i n g l e re ,t 1976). T h ee d i t i n g mode e n a b l e dr a p i dr e v i s i o no f RUNOFF DEC20 a t New M e x i cToe c h a s e m i - f o r m a t e dt h e s i st e x t ,w h i l e ( a f o r m a t e rp r o g r a i toobtain o tfh e al., a c o m p l e t e dv e r s i o n a t New M e x i c oT e c h ) of t h e t h e s i s t e x t . was e m p l o y e d 6 Page PREVIOUS WORK of T hPer e c a m b r i arno c k s first t hLe e m i t aM r o u n t a i nws e r e a n d Lasky (1932). b r i e f l yd e s c r i b e db yD a r t o n( 1 9 2 8 ) small L a s(k1y9 3a2lms) eo n t i o n e d f i s s u r e - f i l l io n rge of d e p o s i at sl o nt g hwee s t e rcno n t a c t s of e x p o s u r eTs h .o ec c u r r e n c e t hPer e c a m b r i a n ' u r a n i utim h nc ea l c a r e o u s o f t h eL e m i t a r b a s i cd i k e si n t r u d i n gt h eP r e c a m b r i a nr o c k s M o u n t a i n s w a s f i r s t r e p o r t e d by S t r o u da n dC o l l i n s (1954, an Adn d e r s o n 1957). The (1954) f i r s t m i n i n g claims f o r in u r a n i u m ,f l u o r i t e ,a n ds u l p h i d e si nt h ea r e aw e r ef i l e d 1954 ( S o c o r r oC o u n t yC o u r t h o u s eR e c o r d s ) . B o n n i c h(s1e9n6 2 ) made a g e n esrttahuoledf y was P r e c a m b r i a nr o c k si nt h eL e m i t a rM o u n t a i n sa n dt h ea r e a (1973) a s p a r ot f mapped by Woodward the Lemitar a m a p p i n gp r o j e c it n (1979) d e s c r i b e M o u n t a i n sC. o n d iaenB dudding of t hlei t h o l o g ayn sdt r u c t u r ahl i s t o r y Lemitar r o c k si nt h e Precambrian r o c k isn central a n 1d 9 8 0 , i n M o u n t a i n s as p a r t o f a ' s t u d y o f t h e New M e x i c o ; Chamberlin p r e p a r a t i o nr)e m a p p e tdh L e e m i t aM r ountains, i n c l u dr ei nc go n h a i s s amnacpe p i n g exposures. t hPer e c a m b r i a n of Ptrheec a m b r i a n (1978 P a g e 7. SEQIMENTARY ROCKS INTRODUCTION A d e t a i l e dc o m p o s i t eP r e c a m b r i a ns t r a t i g r a p h i cs e c t i o n L e m i t a r M o u n t a i n s i s d i f f i c u l tt od e t e r m i n eb e c a u s e o ft h e epxopooorfs uf ar eu sl ,ts ihnego a,rtah innedgr , d e f o r m a t i o nT . hicknesses may o n l yb eb r o a d l ye s t i m a t e dd u e t o p o o r l ye x p o s e da n df a u l t e dp r i m a r yb e d d i n gs t r u c t u r e s . A i s shown i n d i a g r a m m a t i cs k e t c ho ft h es t r a t i g r a p h i cs e c t i o n 3. f'ig. 5% P r e c a m b r i a ns e d i m e n t a r yr o c k sc o m p o s ea p p r o x i m a t e l y o tf h eP r e c a m b r i a ne x p o s u r e( f i g . 2 ) a n dh a v ea e e nc a l l e d 1 9 7 3 ) . ' T h e yc a nb e t h eC o r k s c r e wC a n y o ns e q u e n c e( W o o d w a r d , c l a s s i f i e d a s q u a r t z i t e s ( > 9 0 $ q u a r t z ) ,s u b a r k o s e s (75 - 90% ( ( 7 5 % q u a r t zT) .hCeo r k s c r eC wa n y o n q u a r t z )a,nadr k o s e s Lemitar s e q u e n c ec o n t a i n tsh eo l d e srt o c k es x p o s e di nt h e Mountains. Two s t r a t i g r a p h i cu n i t sc a n aL nd ower Unit; be d i s t i n g u i s h e d ,a nU p p e r a nbdo u t hn iht sa vb ee ei n t r u d ebdy Unit g r a n irtoi cTk Lhso.ew e r is a recrystallized, Unit f i n e - g r a i naerdk o as, n etUh ,dpe p e r c o n s i sotfs r e c r y s t a l l iiznet d e r, b e d a rdkeod s suebsa, r k oasneds , q u a r t z i t e s( f i g . 4). S m a l l e n s e so fg r e e na n dg r a ys c h i s t ' * I MUSCOVITE- BIOTITE GRANITE INTRUSIVC EONTACT U P P E RU N I T I N T E R B E D D E DA R K O S E S , SUBARKOSES, AND QUARTZITES KEY c] ARKOSE SUBARKOSE 0 QUARTZITE M A F I CD I K E S .._.. . ,. G R A D A T I O N A LC O N T A C T LOWER U N I T M A S S I V EA R K O S E I l N T R u s l v E CONTACT G N E I S S I CG R A N I T E FIGURE 3 - D l A G R A M A T l CS T R A T I G R A P H I CS E C T I O N OF T H E PROTEROZO'ICCORKSCREWCANYONSEQUENCE, L E M I T A RM O U N T A I N S QUARTZ & QUARTZITE SUBARKOSE 6 N U M B E R E DS A M P L E SW E R E A L S OA N A L Y Z E D FOR M A J O R A N DM I N O RE L E M E N T S (APPENDIX E ) , 523 524f ARKOSE LlTHlCARENlTE FELDSPAR FRAGMENTS F I G U R E 4- C L A S S I F I C A T I O N O F S A N D S T O N E S FROM T H E CORKSCREWCANYONSEQUENCE (MODIFIEDAFTERPETTIJOHN, 1957) BASED ON ESTIMATEDMODALANALYSIS Page 1 0 is a r e f o u n dl o c a l l yt h r o u g h o u t h es e q u e n c e T . h es e q u e n c e representativ tohfefee l d s p a t h qi cu a r t z i at ena dr k o s e a s s o c i a t i oenx p o s et d hroughou so t u t h e ranncde n t r a l New 1979). M e x i c o( C o n d i ea n dB u d d i n g , F a i n tc r o s s b e d d i n ga n dg r a d e db e d d i n ga r ep r e s e r v e di n a r k o s e sa n ds u b a r k o s e s i n C o r k s c r e wC a n y o n ,i n d i c a t i n gt h a t t h eC o r k s c r e wC a n y o ns e q u e n c ee x p o s e di nC o r k s c r e wC a n y o n ? u p r i g h ty,o u n g i ntgo w a rtdh e east. A l t h o u gthh i n c r o s s b e d s a r e common, t h e y a r e is laminar n opth o t o g e n ibce c a u soef p o oerx p o s u raenlda cok cfo n t r a s F t .o l i a t i opna r a l l e l s relib c te d d i n g m, a k i nt g hdei s t i n c t i obne t w e et n h tew , o d i f f i c u l tF . a i n ct r o s s b e d d i n ga n dg r a d e db e d d i n ga r eo f t e n poorlp y r e s e r v e idfnl o aat n idp n o o r l ey x p o s e o dutcrops s o u t h o f C o r k s c r e wC a n y o n . A c o n f o r m a b l eg, r a d a t i o n aclo n t a c t Units, t hUep p ae n rLdo w e r may exist a l t h o u gthhnea t u r e between of t h e c o n t a c t i s d o u b t f u lb e c a u s eo fp o o re x p o s u r e sa n de a s t - w e s t faults. If f o l i a t i o pn a r a l l e lrse l i cbt e d d i n tgh r o u g h o u t t h ee n t i r es e d i m e n t a r ys e q u e n c e , e l s e w h e r e ,t h a nt h eL o w e r a s i n C o r k s c r e wC a n y o na n d U n i t i s o l d e rt h a nt h eU p p e rU n i t . P a g e 11 DISTRIBUTION AND DESCRIPTION OF THE LOWER UNIT U n i t c o n s i s t so f2 5 0t o3 0 0m e t e r s TheLower to 18. of arkose s u b a r k o s ea n dc a nb ef o u n di nt h es o u t h e r nh a l fo fs e c . may b eg r a d a t i o n a lw i t ht h eU p p e r Unit o ft h eC o r k s c r e wC a n y o ns e q u e n c ea n dt h es o u t h e r nc o n t a c t is ThL e o w eU r nit i n t r u s i v ew i t ht h eg n e i s s i cg r a n i t e cm. d i k e( s2 - 1 5 (Map 1 ) : t h i c ki)n t r u d teh e S m a l lg n e i s s i c L o w eUr n ai tl o ntgh e s h a ri sn t r u s i vseo u t h e rcno n t a cwt h e rfeo l i a t i oitnnh e i s prominent. L o w eU r n iatr k o s e Also, small i n c l u s i o n s o f t h e Lower U n i t c a n b e f o u n d w i t h i n t h e g n e i s s i c g r a n i t e , consists i s l o c a l l yf o l i a t e da n d T hL e o w e rU. n i t of a a r k o s e t os u b a r k o s e O . utcrops d a r kg r a y v, e r yf i n e - g r a i n e d a r e p o o ra n dg o o de x p o s u r e so c c u ro n l ya l o n gt h ei n t r u s i v e c o n t a cw t i t ht h eg r a n i t e . I n t h i ns e c t i o n p, o o r l y sorted, r o u n d e dt os u b r o u n d e ds a n dg r a i n as r ep r e s e r v e da n do f t e n a gr er a d e d . A s e r i c i t e ,3 5 - 4 0 % ) fine-grained matrix ( p r o b a bql y u a rat n zd i s p r e s e n t i nt h ea r k o s ea l o n gw i t hs a n d - 1, untwinned , muscovite IncontrasttotheinterbeddedandfoliatedUpperUnit, the Lower U n i t c o n s i s t so f foliation and a m a s s i v ea r k o s ew i t ho n l yl o c a l r e l ibcet d d i pn rge s e r v eQd u. a r t z iatne d P a g e1 2 common i n t h eU p p e r s u b a r k o s ei n t e r b e d s ,a l t h o u g h n o tp r e s e n t i n t h e Lower U n i t . o tfh eL o w e r q u a r t z i t efso u n d Unit. Unit, are I n h a n d s p e c i m e n t, h ea r k o s e U n i t i s s i m i l a r i n g e n e r a al p p e a r a n c et ot h e i n t hoe v e r l y i n sge d i m e n tostfhU e pper i n t h i ns e c t i o nw h e r et h eL o w e r T h eu n i t sd i f f e r i s n o t a s w e l ls o r t e da n d i s composed of a Unit l a r g e rq u a n t i t y i n t h eU p p e r o ff i n e - g r a i n e dm a t r i xt h a nt h ea r k o s e s Unit. DISTRIBUTION AND DESCRIPTION OF THE UPPER U N I T Introduction A p p r o x i m a to tehnloy eu s a mniedntoet fer rs b e d d e d a r k o s e sa n dq u a r t z i t e s U n i t t o t h e south. or i n t h eU p p e r U n i t o v e r l i et h e Lower is i n fault A m u s c o v i t e - b i o t i t eg r a n i t e Unit i n t r u s i vceo n t a cwt i tt hhUe p p e r f o r m i n g a n e a r l vy e r t i c acl o n t a c t i n sec. on t hneo r t h 7. p o oerx p o s u r et shnea t u rotefh icso n t a c t B e c a u soef is uncertain. C h a m b e r l i n ( 1 9 7 8 ) m a p p e d ' t h i sc o n t a c t as t h ee x t e n s i o no f a f a u lct u t t i n tgh K e e l l e lyi m e s t o n eh; o w e v e rt ,h lea c ok f s l i c k e n s l i d e s a n d b r e c c i a s is c o n t a cr at t h et hr a n i n c l ugssrcio ahoy fins st m u s c o v i t e - b i ogtriatfan ealivstoe r s a suggestive of an intrusive f a ucl ot n t a cTt .hoec c u r r e n coef and a r kwoist eh e in an intrusive Page 13 relationship M. a f idci k e ps ,e g m a t i t e qs ,u a r tvze i n as n , d c a r b o n a t i t ed i k e sa l s oi n t r u d et h es e d i m e n t s . in A f a u lbt l o c k o sf e d i m e n t cs r o p os u t 7. p o r t i so enf c . It t h es o u t h e r n i s b o u n dm be ydu s c o v i t e - b i o t i t e g r a nLti h et em e,d i tiaorr i t e / g a b bP arn hod a,n e r o z o i c sediments. th l oi sc a l tsi hteyed i m e n h tabsveee n At b r e c c i a t e da n dr e c e m e n t e d . of Tbheesxtp o s u r e s Unit tU hp eper aar leo n g C o r k s c r eCwa n y ownh, esreev e rhaul n d rm e de t teohrfes s e q u e nacerexep o s eSde. v e rParle c a m b r iaaT nnd ertiary s o t h ee x a c tt h i c k n e s so ft h es e q u e n c e f a u l t sc u tt h er o c k s , I n a d d i t i o n s, t r o n gd e f o r m a t i o n i s d i f f i c u l t od e t e r m i n e . in a n sdh e a r i n g thw e estern q u a r t e or tfh se e c t i o n along C o r k s cCraenw oybol int e roartiegst ienxatalunr d es a n d d i k e l e t so g f r a n i t i cp e g m a t i t e sa n d s t r u c t u r e sL . enses a p l i taerse common in small tshhee a rr eodc ak ns ,d l e n s - s h a p e db o u d i n a g es t r u c t u r e sa r ep r e s e r v e d . Bedding is d i s t i n g u i s h a bb cl o y e l coor n t r a sat ns d t e x t u rvaal r i a t i o(nPsI . compositions can 1 be and 21, bmuitn e r a l o g i c a l d e t e r m i noe ndm l yi c r o s c o p i c a l l y . A t e n - m e tbeheor o df m o g e n e o um s ,a s s i v q eu a r t z ict ab e ne d i s t i n g u i s h e df r o mt h eo t h e rs e d i m e n t sb u t C o r k s c r e wC a n y o n (Map 1 ) . a r ep o o ar n df e w i n number. i s s e e no n l y O u t c r o p so u t s i d eC o r k s c r e wC a n y o n Relicc t r o s s b e d d i n ga n dg r a d e d in PL. 1: T h i n l yl a m i n a t e di n t e r b e d d e da r k o s ea n dq u a r t z i t e c u tb y a n a p l i t ev e i n . PL; R e l i c t c r o s s b e d d i n gi na r k o s e . 2: Page 1 5 can bedding b ed e t e c t e d i n Corkscrew Canyon and elsewhere, i s u p r i g h tA. r k o s e as r teh e i n d i c a t i n tgh atth se e q u e n c e m o s ta b u n d a n ts e d i m e n t f, o l l o w e db y( i no r d e ro fa b u n d a n c e ) s u b a r k o s em s ,a f d i ci k e qs ,u a r t z i t e as n ,gdr e eanngdr a y schist. Arkose T haer k o s easr e as occur common throughou t hts ee q u e n caen d f i n ea-n m d e d i u m - g r a i n e idn t e r b e d sF. o l i a t i o on f is tfhi en e - g r a i naerdk o s e p r o d udcbaeyrdk - g raanyd g r a y i s h - p i n lka y e r cs o n s i s t i n o gpf o o r l sy o r t e sd a n da- n d s i l t - s i zger a i n s biotite of q u a r(t2z5 - 3 0 %f )e,l d s p(a1r5 - 2 5 % ) , muscovite (5-15%), and a trace a m o u not f (10-20%), h o r n b l e n d ae n m d a g n e t i t (ef i g . may bpe r e s e n t 4). Up t o 1 5 - 20% matrix i n t hfei n e - g r a i n eadr k o s e sC. r o s s b e d d i n g a n d g r a d ebde d d i nagroef t epnr e s e r v eadl o nw g i t.ht h i n l a y e r s o f c o a r s ea r k o s i c or s u b a r k o s i c s a n d ( p l . 3 and 4). M e d i u m - g r a i n eadr k o s ed si f f ferrotm hf ien e - g r a i n e d a r k o s e sb yh a v i n g l i t t l e o rn om a t r i x a n d l a r g e ar n dm o r e r o u n d e ds a n dg r a i n s .F o l i a t i o no ft h em e d i u m - g r a i n e da r k o s e is s i m i l a r tfh tion e e - g r a i naerdk o sMe e. d i u m - g r a i n e d a r k o s ec so n s i os atf n d - s i zger a i n s K-feldspar (5-15%), of q u a r (t 5z 0 - 7 0 % ) , p l a g i o c l a s e , A n 1 0 - 4(01 5 - 3 0 % )b,i o t i t e (10-20%), m u s c o v i t e( 2 - 5 % ) a, n dm i n o ra m o u n t so fm a g n e t i t e . PL. 3: P h o t o m i c r o g r a p h ( 2 5 x , cross-polars) showing graded bedding in arkose. PL. 4: Fine-grained'arkose, showing crossbedding. P a g e 17 T hi en t e r b e d d eadnfdo l i a t eadr k o s eotsh fUe p p eUr n i t d i f f e r sf r o mt h e U n i t b yh a v i n g massive a r k o s eo ft h eL o w e r of q u a r t z iat n se ud b a r k o isnet e r b e ad n tsp hdre e s e n c e K-feldspar. Subarkose T h es u b a r k o s e sa r ed i s t i n g u i s h a b l ef r o mt h ei n t e r b e d d e d a r k o s e sb yt h e i rh i g h e rq u a r t zc o n t e n t( 7 5 - 9 0 %q u a r t z ) .T h e r o c k sa r ef o l i a t e dw i t hd a r k - g r a ya n dg r a y i s h - p i n kl a y e r s , similar t oa r k o s e s ;t h e yo c c u r as t h i ni n t e r b e d s (less than s e v e r a lm e t e r st h i c k )s c a t t e r e dt h r o u g h o u tt h es e q u e n c e -I n f i n e - t o medium-sand t h i ns e c t i o n r, o u n d e da n dw e l l - s o r t e d (70-80$), g r a i nc so n s i o qs fu t artz ( p r o b a b lm y icrocline, amounts Of 5-15$), p e r t h i tK i c- f e l d s p a r b i o t i t(e1 0 - 1 5 % )a,nm d inor matrix plagioclasm e ,u s c o i r i t m e , a g n e t i t ae n , d r 4 and pl. (fig. 5). Quartzite qTuha er t z i t e s are m a s spi ivneg tk,ori as h y m e d i u m - g r a ya,nvde rfyi n e d - g r a i n e dT. h ilna m i n abre d d i n g i s o f t e np r e s e r v e da l o n gw i t h w e l l r o u n d e d ,w e l l - s o r t e d ,a n d ( > g o % ) w i tmh i n o r f i n e - s a ngdr a i n sc,o n s i s t i nogqfu a r t z amounts .~ probably opf e r t h i t i K c -feldspar matrix p l a g i o c lma u s es c , om v iat g e ,n eat n i tde , photomicrograp f ihg, . -microcl-ine), 8, p. 11, Woodward, 1973). (see The PL. 5: Photomicrograph ( 2 5 x , cross-polars) o f a subarkose. 19 Page as q u a r t z i toecsc u r . cm. t hbien(ds se v e r a l thick) i n t e r b e d d e dw i t ha r k o s e sa n ds u b a r k o s e s . Schist S c h i s lt e n s e so c c u sr c a t t e r e dt h r o u g h o u t h es e d i m e n t as s e q u e n caen d i n c l u s i o nw s ithin v a r i o u gs r a n i t i rc o c k s . T hoer i g i n ar ol c k s may Most lenses. tgheeo l o g i c h a vbee emn a f d i ci k eos sh r ale small t ob e o ft h e s el e n s e sa r et o o map w tieh txhec e p t ioofn some larger (Map 1, sec. i n c l u s i o n sf o u n dw i t h i nt h eg r a n i t i cr o c k s . T h es c h i s t s shown on 7). a r e s t r o n g l yf o l i a t e d ,g r a y i s ho l i v eg r e e n , f i n e - g r a i n e d. ,m i c a e o urso c kas n cd o n s i sotcf h l o r i t ae n d biotite (40-50%), ( 5 - 1 0 % a) ,n d plagioclase, magnetite An40-50 (30-35%), quartz ( 5 - 1 0 5 )T. hceh l o r i taenbdi o t i t e c o n t e n t may r a n g e as h i g h as 9 0 5 , w i t hc h l o r i t eo f t e nm o r e a b u n d a n tt h a nb i o t i t e . as G r as yc h i lset n s eo sc c u r i n c l u s i o nwsi t h it n he m u s c o v i t e - b i o t gi tr ea n aiwtneidt hs ienv e ir saol l a t e d i n sec. o u t c r o p so fP r e c a m b r i a nr o c k s composed of t h i n( s e v e r a l cm. ~ 7 (Map 1 ) ; t h e ya r e t h i c k )a l t e r n a t i n gl a y e r so f m a s s i vqeu a r t p z ,l a g i o c l a s b e ,i o t i t ae n , md u s c o v i t T e .h e g r a ys c h i s ot f t e ng r a d e si n t o o f t eonc c u r s a thinlb yeddea d r k o s ae n d as i n c l u s i o nw s i t h i tnh ce a r b o n a t i t de i k e s . T h e s eg r e e nc h l o r i t ea n dg r a ys c h i s tl e n s e s a r e s e l d o mm o r e P a g e2 0 we t e lros nagnadr e t h a n a f em common a l o nsge c o n d a r y 7 a n d1 2 . arroyos i n sec. GEOCHEMISTRY A r e p r e s e n t a t i v se u i t oesf a m p l e fsr o m t hC e orkscrew was a n a l y z e d f o r e i g h t m a j o r a n d f o u r t r a c e C a n y o ns e d i m e n t s e l e m e n t (sA p p e n d i x fig. 2. B). T h es a m p l el q c a t i o n sa r ep l o t t e do n c oI nm p a r i swao t ih vnt eh r af egled s p a t h i c q u a r t z i t e - a r k o s ef r o mt h eP r e c a m b r i a no sf o u t h - c e n t r a l 1979), M e x( iCcoonB adnuide d i n g , A1203, Fe203, a n d B a ( t a b l e 1). MgO, N a 2 0S, rR, b , 401) i s h i g h e r i n S i 0 2 F , e203, a n d Sr a n dl o w e r i n K20, T i 0 2 a, n d MgO, C a O , A1203 r o c k sf o rt h e Na20, Ba, Rb, t h a nt h ea v e r a g e in P r e c a m b r i faenl d s p a t hqi u cartzite-arkose T h e s ed i f f e r e n c e s The U n i t o ft h eC o r k s c r e wC a n y o ns e q u e n c e a r k o s ef r o mt h eL o w e r (Lem and at hr k eoses U n i t a r el o w e ri nS i 0 2 ,a n dh i g h e r s u b a r k o s e so ft h eU p p e r in New New Mexico. may r e p r e s e n tt h eh e t e r o g e n e i t yo fs o u r c e New M e x i c oP r e c a m b r i a nf e l d s p a t h i cs e d i m e n t s . T hLe e m i t asre d i m e n tcsabnceo m p a r etdaoanv e r a g e graywacke and a r k o s(et a b l e s e d i m e n tasrhei g h e r in 2 a nfdi g . Na20 an ,d K20 5). t h atnhaev e r a g e g r a y w a c k ea n da r k o s e .G e n e r a l l y ,t h eL e m i t a rs e d i m e n t s i n t h ea r k o s ef i e l d( f i g . 5). T hLee m i t a r fall Page 21 TABLE 1 GEOCHEMISTRY OF SANDSTONES 1 4 3 5 77.1 66.1 0.3 66.7 0.6 77.8 0.54 65.6 0.3 8.7 8.1 13.5 11.1 2.28 5.4 2.4 5.5 4.57 2.1 2.5 2.9 0.94 16.8 6.67 1.49 K20/Na20 1.8 Si02/A1203 6.0 1.9 0.9 - 113 52 530 0.5 2.7 1.5 2.8 6.2 0.9 1.3 95.88 90.7 1.4 8.2 , 1.39 2.45 2.6 2.9i 95.8 101.70 0.7 4.9 I 6 Si02 77.5 Ti02 0.63 A1203 12.8 Fe203* 2.71 MgO 0.34 CaO 0.96 Na20 1.71 3.14 K20 TOTAL 99.79 Rb Sr Ba * 2 0.73 75.2 0.62 13.2 4.74 1.20 2.02 2.37 2.70 4.71 3.00 99.14.102.68 0.77 2.0 3.9 1.1 7.0 139 223 78 156 1189 202 162 1.2 1172 5.7 1186 Total iron expressed as Fe203. average feldspathic quartzite-arkose from the Precambrian o f New Mexico (Condie and Budding, 1979) 2 - average arkose (Pettijohn, 1963) 3 - average lithic arenite (Pettijohn, 1963) 4 - average graywacke (Pettijohn, 1963) 5 - arkose, Lower Unit, Lemitar Mountains (1 sample) 6 - average arkose, Upper Unit, LemitarMountains (average of 3 analyses) 7 - average subarkose, Upper Unit, Lemitar Mountains (average o f 2 analyses) 1 e 2.8 523 2.6 e @ a GRAYWACKE 2.4 520 524 A 8 40 I FIELD Na20 - AVERAGE - AVERAGE GRAYWACKE ARKOSE ARKOSE FIELD 2.2 2.0 I .8 a 3 4 5 6 K20 FIGURE 5 - Na20 - K20 PLOT OF SANDSTONES FROM THE CORKSCREW CANYON SEQUENCE (DIAGRAM AFTER PETTIJOHN, 1963) 0.5 GRAYWACKE C Na20 K2° QUARTZITE 'E ARENITE - 0.5 -I 0.5 2c.5 1 LOG 7 2.5 1.5 5102 A1203 FIGURE 6 -GEOCHEMICALCLASSIFICATIONOFSANDSTONESFROMTHE CANYON SEQUENCE(AFTERPETTIJOHN, 1963) CORKSCREW Page 23 TABLE 2 CHEMICAL CLASSIFICATION OF SANDSTONES ( m o d i f i e df r o mP e t t i j o h n ,P o t t e r ,a n dS i e v e r ,1 9 7 3 ) HIGH Si02/A1203 RATIO - Q u a r t za r e n i t e s( q u a r t z i t e s ) mature, l i t t l e c l a y o r d e t r i t a l Al-silicate (1) a l k a lrii c (hc a r b o n a t ce e m e n t ) ( 2 a) l k a l i ( s i l i c a cement) poor LOW S i 0 2 / A 1 2 0 3 R A T I O ( ( 1 2 ) immature, c l a y p l u s d e t r i t a l A l - s i l i c a t e (1) a l k a l ri i c h (a) iVa20>K20 (b) Na20<K20 ( 2 )a l k a l ip o o r NOTE - - - f e l d s p a t h i cg r a y w a c k e s a r k o s e s ,l i t h i cg r a y w a c k e s l i t h i ca r e n i t e s g r a y w a c k e is d e f i n e d a s a s a n d s t o n e h a v i n g matrix. >15% Page 24 \ A c h e m i c a cl l a s s i f i c a t i o n b, a s e d on t h ec o m p o s i t i o n a l m a t u r i to ytfh .es e d i m e n th, abs e e p nr o p o s e d (1963 a n dP e t t i j o h n P , otter, 6). afni dg . by P e t t i j o h n 1973; and Siever, s e et a b l e 2 f a l l tlihonew TLheem ist ea dr i m e n t s S i 0 2 / A 1 2 0 3g r o u pa n dn e a tr h eb o r d e b r e t w e e nt h eh i g ha n d i s c h a r a c t e r i s t ioc f l o awl k a sl iu b g r o u p sT. h igsr o u p i n g y o u n g e ra r k o s e s and lithicarenites. One m u s tu s ec a u t i o n when u s i n gt h e s ed i a g r a m sb e c a u s e t haef f e cortfe g i o n aml e t a m o r p h i s o m sne d i m e n t s i s not (1966) c l e a rul y n d e r s t o oSdc. h w a r c z s t u d i ea d n ro e af r e g i o n a lm e t a m o r p h o s e da r k o s i cq u a r t z i t e sa n df o u n dt h a tn o a p p r e c i a b lceh a n g e i n modal or m a j oerl e m e nc to m p o s i t i o n Shaw ( 1 9 5 4 , i n m e t a m o r p h igcr a d e . o c c u r r ew d i tihn c r e a s e 1 9 5 6 1 , B a r t h( 1 9 3 6 ) a, n d Mason ( 1 9 6 2 a) l s of o u n da l m o snt o s i g n i f i c a n tc o m p o s i t i o n a lc h a n g e si ns e d i m e n t sm e t a m o r p h o s e d u tptoh ue p p ear m p h i b o l i t fea c i e s . It is p r o b a b lteh a t m e t a m o r p h i s mh a sn o ts i g n i f i c a n t l yc h a n g e dt h em a j o re l e m e n t c h e m i s t r yo ft h eL e m i t a rs e d i m e n t sb e c a u s et h e i rc h e m i s t r i e s a r en o ts i g n i f i c a n t l yd i f f e r e n tf r o mc h e m i s t r i e so fy o u n g e r 1963), a rskuaobnsadersk(oPseetst i j o h n , m e t a m o r p h i ca f f e c t s may a c c o u n t f o r s o m eo ft h ed i f f e r e n c e s th ex abti es t w etLehenem i st ea d r i m e anr ntesdc e n t sediments. although Page25 PROVENANCE AND SEDIMENTATION Some c o on rstithgrseaio enid nnai tlms e n t a r y c a n dbeed u cf er od m e n v i r o n m eantnetdc t o ns iect t i n g m i n e r a l o g ti ec x a glt ,uae rn oad clh, e mviacrai la t i o n s . i s c o n t r o l l e d by a number o f f a c t o r s S a n d s t o n ec o m p o s i t i o n (Potter, 1978): (1) c o m p o s i t i o n a n d v o l u m eo ft h es o u r c e (2) relief (3) weathering (4) climate (5) m e t h o da n dd i s t a n c eo ft r a n s p o r t . T h ea b u n d a n c eo fq u a r t za n df e l d s p a ri n d i c a t e s a source acr oe n a s i sgtroi ag nf nn goiert ies s . By applying 19791, D i c k i n s o n ' cs r i t e r i a( 1 9 7 0D , i c k i n s o na n dS u c z e k , a i s i n d i c a t e fdotrh L e emitar g n e i s s io c gr r a n i t i sc o u r c e M o u n t a i nbstyhhei gqhu a n t i t i eoqsfu a r taznfde l d s p a r ( > 2 5 % )a n dt h e 7). low q u a n t i t i e s of l i t h i cf r a g m e n t s (O%, fig. R o u n d e d st ou b r o u n d et ed x t u r es u s g g e isnt t e r m e d i a t e t r a n s p o rdt i s t a n c e s , f r o mt h er e w o r k i n g if t h e stee x t u r easrne oi tn h e r i t e d o f a q u a r t zs a n d s t o n e T h er e l a t i v ea b u n d a n c eo ff e l d s p a r i n d i c a t i v eo f i n t h es o u r c ea r e a . i n t h es e d i m e n t s is a n e n v i r o n m e n t i n w h i c hi n t e n s ew e a t h e r i n gd i d n oetx i s S t .u cshe d i m e n t s may h a vf o e rmed in a variable Q F LQ CONTINENTALBLOCKPROVENANCE CRATONINTERIOR C O N T I N E N T A LR I F T T O T A LQ U A R T Z O S EG R A I N S RECYCLED OROGEN PROVENANCE SUBDUCTION COMPLEX COLLISIONOROGEN FORELANDUPLIFT T O T A LF E L D S P A RG R A I N S TOTALLITHICGRAINS MAGMATIC ARC PROVENANCE UNDISSECTED ARC DISSECTED ARC PROVENANCE MAGMATICARC PROVENANCE 25 L F FIGURE 7 - T E C T O N I C PROVENANCEOFPROTEROZOICSANDSTONES (DIAGRAM PROPOSED BY DICK I NSON ANDSUCZEK, 1979) L FROMTHELEMITAR MOUNTAINS c l i m a t ei nw h i c he r o s i o na n db u r i a w l e r er e l a t i v e l yr a p i d (Folk, 1974; P o t t e r , 1978; Condie a n d Budding, 1 9 7 9 ) . may r e f l e c t a l o c a l m a s s i v eq u a r t z i t eb e d si nt h es u c c e s s i o n t e c t o n i c a sl lt y a bs o l eul roccr ea l i zr ee dw o r k i n g q u a r t z o - f e l d s p a t h i cs e d i m e n t s The of i n a high energy environment ( s u c h as ainn t e r t i d az lo n e T ) .hseu b r o u n d esdh a p easn d small stqio hzufeea g r trza if na svr oe rw o r k ionfg q u a r t z o - f e l d s p a t h i cs e d i m e n t s . T h em i n e r a l o g i c a la n dt e x t u r a le v i d e n c ea r ec o n s i s t e n t w i t hd e p o s i t i o n a nSd i n g h , i n a f l u v i a l or d e l t a i ce n v i r o n m e n t( R e i n e c k 1973). H o w e v e rt ,heev i d e n c e t od i f f e r e n t i a t eb e t w e e n n o st u f f i c i e n t is a l a c u s t r i n e or a m a r i n es e t t i n g . T h eR . inconadF a ormation (Precambrian) in and M e x iccoon s i o sn tft se r b e d dqeuda r t z i t e s s c h i s t s similar t o thC e orkscrew a n dK i r s c h n e r , 1979). northern New pelitic C a n y oSn e q u e n c(eB a r r e t t T h e s ed e p o s i t h s a v eb e e ni n t e r p r e t e d t o r e p r e s e n dt e l t a i c f, l u v i a l , and s h a l l o w - m a r i n de e p o s i t s b a s eodtnhper e s e n coecfr o s s b e d d i n gr ,i p p l e marks, and g r a d e db e d d i n ga n do nt h es i m i l a r i t yb e t w e e nt h eR i n c o n a d a s e d i m e n tasnH d o l o c e nsee d i m e n tfsr o m t hDe o n j e cRk i v e r , Yukon ( f l u v i adl e p o s i t s )a, n d N i g e dr e l t a syst,ems a nK dirschner, 1979). T hCeo r k s c r eC wa n y osne d i m e n t s r e p r e s e n t a s i m i l a r d e p o s i t i o n a le n v i r o n m e n tb e c a u s eo f s i m i l a r i t yi np r i m a r yb e d d i n gs t r u c t u r e sa n dl i t h o l o g y . (Barrett may the Page 28 S e v e r a la t t e m p t sh a v eb e e n made t oa p p l ym i n e r a l o g i c a l c o m p o s i t i op to nl a t e - t e c t o n si ce t t i n g( D s i c k i n s o1 n9 , 70; Dickinson a n d Suczek, 1979; Dickinson and V a l l o n i1, 9 8 0 ) . 7 ) clearly Td ho e m i n a nfocefel d s paan qr d u a r(tfzi g . i n t h eL e m i t a rM o u n t a i n s i n d i c a t e st h a tt h es e d i m e n t sf o u n d i n a c o n t i n e n t a bl l o c kp r o v e n a n c e a, s s u m i n g w e r ed e p o s i t e d i s a p p l i c a b l tetoh L e e m i t aM r ountain D i c k i n s o n 'tsh e o r y P r e c a m b r i asne d i m e n t s . Two s p e c i f i tce c t o n i sc e t t i n g as r e ( 1 9 7 9 ) a so c c u r r i n gi n r e c o g n i z e d b yD i c k i n s o na n dS u c z e k - c o n t i n e n t a lb l o c kp r o v e n a n c e u p l i f t e d, b a s e m e n t a t h ec r a t o ni n t e r i o ra n dt h e (rift zone). C h e m i s thbray eu sedsn tieofdf e r e n t i abteet w e e n 1975). a n c iteenctt osnei tct i n ( Sg cs h w a b , s a n d s t o n(ecsh a r a c t e r i s toi fc rift and valleys rising, a h i g hS i 0 2c o n t e n ta n d s t a b l ec o n t i n e n t a l -m a r g i n s )h a v e K20/Na2O r a t i oe q u a tl o Quartz-rich a o r g r e a t etrh a on n eT. hL eemitar s a m p l e s ,w i t ho n ee x c e p t i o n , f i t t h e s ec r i t e r i a( t a b l e 3). B l o c kf a u l t i n ga s s o c i a t e dw i t hr i f t i n gc o u l du p l i f t g r a n i t ibca s e m e n at ;nrda p iedr o s i oanl o nsgt e espl o p e s c o u l dp r o d u c ea l l u v i a l - f a nd e p o s i t s ,r e s u l t i n g and i n t h eg r a d e d c r o s s b e d d e dp ,o o r ltm yo o d e r a t e lsyo r t efde l d s p a t h i c s e d i m e n tssu c h as t h o se x p o s e d in t hL e e m i t aM r ountains. P r o l o n g e da b r a s i o no af n yq u a r t z - r i c hs o u r c ec o u l dp r o d u c e quartzitesD . e l t a i ce n v i r o n m e n t sc o u l dd e v e l o pf u r t h e rf r o m a P a g e 29 TABLE 3 GEOCHEMISTRY OF THE LEMITAR SEDIMENTS 76.5 69.6 62.0 77.8 73.8 S i 0 2 / A 1 2 0 3 3.8 6.2 4.8 3.3 7.0 5.3 K ~ O / N ~ ~ 1.6 O 0.8 1.6 3.2 1.2 1.5 S6 i50. 2 P a g e 30 theupliftedterrain. more A envisioned t e c t o n i c a sl lt y a be lnev i r o n m ec no tubled as well, (Schwab, 1975) or 1979). A s u cahs a r i s i ncgo n t i n e n t a l - m a r g i n a c r a t o ni n t e r i o (r D i c k i n s o na n dS u c z e k , g r a n i t i cs o u r c ec o u l de x i s t c o n d i t i o n sf o r a l o n gt i m e ;a n d ,u n d e rd r y a t r e l a t i v e l ys t a b l e or c o l dc l i m a t i c Over a c o n d i t i o ntfhse,el d s p awr o s undlodetc o m p o s e . l e n g t h o f t i m et,h ae b r a s i v ae c t i o n produced wind may c o u l pd r o d u caer k o s isca n d(sF o l k , dbeer i vfer d o l omc a rl el yw o r kseedd i m e n t i n t e r t i d azl o n eF. l u v i aol dr e l t a i ec n v i r o n m e n t s c o n s i s t e n tw i t hs u c h a setting. by 1974). water or Quartzites in wou.ld be an Page 31 IGNEOUS ROCKS INTRODUCTION T h eP r e c a m b r i a ni g n e o u sr o c k s i n t h eL e m i t a rM o u n t a i n s a m a f i ci n t r u s i v eb o d y( L e m i t a rd i o r i t e / g a b b r o ) , c o n s i s to f a g r a n i t i cc o m p l e x m , a f i cd i k e s a, n dc a r b o n a t i t ed i k e sa n d a a gr er o u p ea dc c o r d i nt og c l a s s i f i c a t i omno d i f i eb dy (1967, Hyndman ( 1 9 7a2f )tSet rr e c k e i s e n 8). fig. The i g n e o u sr o c k sh a v eb e e nm e t a m o r p h o s e da n ds h o u l db ep r e f i x e d w i t ht h et e r mm e t a ,b u tf o rt h ep u r p o s e so ft h i sr e p o r tt h e o r i g i n a ln o m e n c l a t u r e Lemitar P r e c a m b r i agnr a n i t irco c kistnh e compose meta. is u s e d , l e a v i n g o f f t h e t e r m Mountains 7 5 % o f t h et o t a le x p o s e dP r e c a m b r i a nt e r r a i n ,w h i l e t h e L e m i t a r d i o r i t e / g a b b r oc o m p o s e 2 0 % o ft h et o t a le x p o s e d N e w M e x i c oP,r e c a m b r i agnr a n i t i c P r e c a m b r i atne r r a i nI .n r o cckosm p oaspep r o x i m a t etlw tyhoi rto eh dx fes p o s e d 1979) P r e c a m b r i taenr r a(iC n o n dai n B e du d d i n g , as w e l l ( D e n i s o n a n d m a j o r i t yo ft h eb a s e m e n t 1969; al., M u e h l b e r g eer t, n o t a s common, Mexico. A 1966). a nt hde Hetherington, M a fri oc c kasl,t h o u g h a r ep r e s e n tt h r o u g h o u tt h eP r e c a m b r i a ni n 1 . 5 - b . (yW . hite, 1 9 7 8 ) g a b b rcor o posu t New i n the M a g dM a loeunna( tLaK oi n uoasgnchdhl1im 9n4a 2n ;, Blakestad, 1976; S u m n e r1, 9 8 0t)h a t may b er e l a t e dt ot h e X GNEISSIC GRANITE 0 POLVADERA GRANITE + M U S C O V I T E - B I O T I TGER A N I T E A B I O T I TGER A N I T E CB MAFIC DIKES QUARTZ 0 DlORITE/GABBRO DIKE + OIAEASE TRONOHJEMITE QUARTZ-BEARING GRANODIORITE QUARTZ-MONZOGABBRO MONZONITE NORITE, DIORITE, MONZONITE ALKALI 'ELDSPAR FIGURE 8 - 10 , 35 GABBRO 65 90 PLAGIOCLASE CLASSIFICATIONOF SAMPLESFROMTH IGNEOUSROCKS(AFTER STRECKEISEN, I967 AND HYNDMAN, 1972) SHOWING E LEMITAR MOUNTAINS BASED ON ESTIMATEDMODALANALYSIS P.age 33 L e m i t a rd i o r i t e l g a b b r o . 1978; R e c e ngte o c h r o n o l o g isct u d i e(sW h i t e , et al., 1978; 1979) o tf h eP r e c a m b r i a n Condie a n d Budding, r o c k isn c e n t r aal n d southern New Brookins, most M e x i ciom p ltyh a t 1 . 5 a n d 1.1 b . yT. h e s e g r a n i t i cp l u t o n i s mo c c u r r e db e t w e e n s t u d i e ss u g g e s tt h a tp e r h a p st h eP r e c a m b r i a ng r a n i t i cr o c k s i n t h eL e m i t a rM o u n t a i n sw e r ee m p l a c e dd u r i n gt h i sp e r i o d . LEMITAR D I O R I T E / G A B B R O Introduction The Lemitar out d i o r i t e l g a b b rc or o p s C o r k s c r eC wa n y osne d i m e n (t sf i g . 2), n o r tohf e f o r m i n g many o f t h e l o w ehr i l l as n rdi d g e as l o n tgh ee a s t e r p no r t i oo ntfh e mapped area. a s f a u l bt l o c k s T h de i o r i t e l g a b b r co o n t i n u e s a n dw i n d o w sf a r t h e rn o r t ho ft h e mapped a r e a . forms T shoe u t h ebr n o u n d atorb hy fo edy a nearly v e r t i c a ol ,f t em n i g m i t i z e di n, t r u s i vceo n t a c w t , h e rt eh e d i o r i t e l g a b b r o i s i nc o n t a c tw i t hm u s c o v i t e - b i o t i t eg r a n i t e . T hw e e s t e rb no u n d a r y i s f o r m e bduy n c o n f o r m a b l oy v e r l y i n g bP eod hfsa n e r o z os iecd i m e nT t esha. es t ecronn t a c t formed by a series P h a n e r o z o i cs e d i m e n t s of f a u lat n u sd n c o n f o r m i t iw e si t h and volcanics. is P a g e 34 of t hneo r t h w e s t e rcno n t a c t T hnea t u r e in is doubt b e c a utlohsagfeocofkeoxdp o s u r eTsPh. oe l v a d e r a G r a n i t e i s i n f a u l t or i n t r u s i v ec o n t a c w t i t ht h e diorite/gabbro on a northeast-striking t h ne o r t hf,o r m i n g and c o n t a c tE. v i d e n c eosbfr e c c i a t i o n Lemitar s l i c k e n s l i d eos c c u r a l o np gatorhnft eo r t h e a settoa- s t - t r e n d i nc go n t a c t and b e t w e e tnhde i o r i t e / g a b b r o indicate as 3 2 , Map 1). f a u cl to n t a c ( st e c . a c o u l d form t h e r e m a i n d e r of units t hPe o l v a d e rG a r a n i taen d (1978) Chamberlin T h fi sa u l t t hceo n t a cbt e t w e e tnhtew o mapped b r e c c i a t i oannsdl i c k e n s l i d easr e it, more bu t htl e a cokf s u g g e s t i voef an i n t r u s icvoen t a cNt e.tcaho ren t af cotl i a t it io hnn e diorite/gabbro t hP eo l v a d e G r ar a n i pt ea r a l l etlhs e and c o n t a c ts u g g e s t i n g a n i n t r u s i v er e l a t i o n s h i p . Th mea fbi c ody is intruded by b i o t i tger a n i taen d l e u c o g r a n i t ed i k e sa n dp l u g s ,a n dp o r t i o n so fp e g m a t i t e sa n d q u a rvt ze i anfrsoe u ns cd a t t e r et hdr o u g h o uM t .a fai n cd c a r b o n a t i dt ei k ae ls si no t r u dt hd e ei o r i t e / g a b b r o . m a f idci k e s may b e a l a tset a goet fhdei o r i t e / g a b b r o ; o t h e r si n t r u d et h i sg r a n i t ea n da r ep o s t - g r a n i t e . Some P a g e 35 Description Td h ieo r i t e j g a b bm r oa i n t a i n s a mm. p r o dluab(crsyegedev e r a l phenocrysts of plagioclase. It s p e c k laepdp e a r a n c e i n d i a m ew t ehr i)t e a is lithologically h e t e r o g e n e o u su n i tr a n g i n gf r o mg a b b r oa n dd i o r i t et oq u a r t z 4). g a b b raonqdu a r tdzi o r i t( et a b l e varies i n m i n e r a l o g i c a lc o m p o s i t i o n ,b u tp r i m a r i l yc o n s i s t s o f p l a g i o c l a s e , An40-60 hornblende (30-40%), 10-20%), T hdei o r i t e j g a b b r o (30-40%), and d a r kb l u e - g r e e n brown b i o t i t e( p a r t i a l l ya l t e r e dt oc h l o r i t e , at rnadm c eoguaonrftnasepta, t iatned, m a g n e t i t eA. u g i t eo, l i v i n ea, n d / opr y r o x e n e o r i g i n a l l yp r e s e n tb u th a v e may h a vbee e n now b e e na l t e r e dt oh o r n b l e n d e . Thp e l a g i o c l a s ce o m p o s i t i o n c o n t r i b u t e tso t h lei t h o l o g i c i s often d i f f e r e n c e sb e t w e e nt h ed i o r i t ea n dg a b b r o .Q u a r t z p r e s aeim nn to u ntuotps O p h i stt u iocb o p h i t i c 10%. is t e x t u r e si, nw h i c hp l a g i o c l a s e partially or completely e n c l o s e db yh o r n b l e n d e ,a r eo f t e np r e s e r v e d ,s u g g e s t i n gt h e o r i g i n arlo c k may h a vbee e n a g a b b r (ot a b l e 4). However and h y p i d i o m o r p h i c - g r a n u lt ae rx t u raoerfsetperne s e n t s u g g e s tt h a tt h er o c k may h a v e b e e n i n p a r t T dh i oer i t e / g a buhbnar d o s ergo dn e feo r m a t i o n shearing near t h ec o n t a c w t i t ht h ea l t e r e df a c i e s P o l v a d e r a , G r a n i tw e ,h e lraer g ae m r o u ncot hsf l o r i t e - a diorite. and of t h e and .. P a g e 36 TABLE 4 D i f f e r e n c eB e t w e e nG a b b r oa n dD i o r i t e ( m o d i f i e d a f t e r Hyndman, 1 9 7 2 ) CRITERIA DIORITE GABBRO plagioclase An>50 An<50 composition (laboradiorite, (andesine, bytownit e ) oligoclase) Other a u g i t e ,o l i v i n e , hornblende, Minerals hornblende, pyroxenes, clinopyroxenes biotite Associated pyroxenites, granodiorites, R o c kT y p e s anorthosites q u a r t zd i o r i t e s C o l o ro ft h e graytogreenish white Plagioclase gray Texture subophitic, cumulus, or hypidiomorphic granular ophitic NOTE: M e t a m o r p h i s m may c h a n g e some of t h e s ev a r i a b l e s . P a g e 37 biotite are f o u n df o , r m i nsgc h i s t o szeo n e sT.h icso n t a c t a p p e agr rs a d a t i o naanl d is p o o relxyp o s eQd u. a ratnzd in K - f e l d s( p raor b ambilcyr o c l oi n ifnteec) nr e a s e s a b u n d a n c en e a tr h ec o n t a c w t i t ht h eP o l v a d e r aG r a n i t ea n d o t h e rg r a n i t e s . I n c l u s i o n s a r e f o u n dt h r o u g h o u tt h ed i o r i t e l g a b b r oa n d e s p e c i a l l yi nt h es o u t h e r np o r t i o no ft h eo u t c r o pa r e a .T h e to i n c l u s i o n sa r eg e n e r a l l yf i n eg r a i n e d d , ark m a f i c r o c k( p l . e x h i b i t i n gs h a r pc o n t a c t sw i t ht h ee n c l o s i n g 6). some in L i g h t - c o l o r e lde u c o s o m ew s i tm h a f isce l v a g eos c c u r a n 0 r i g i . n by. p a r t s o ft h ed i o r i t e l g a b b r os u g g e s t i v eo f (Pl. m e t a m o r dp ihf ifce r e n t i a t i o n f o l i a t e ad r k o s oe c c u r (P1. l i g h tg r a y , 8). a n dh a v e as 7). i n c l u s i o n us tpo Q u a r t. za intde 50 cm. across Dark f i, n e - g r a i n eadm p h i b o l i ti en c l u s i o nosc c u r a n a p p e a r a n c ea n dc o m p o s i t i o n similar t o t h e m a f i c d i k e sH. o r n b l e n daenbdi o t i t ep,o s s i b ldye r i v efdr o m the d i o r i t e / g a b b r o ,o f t e n - r e p l a c e so r i g i n a lm i n e r a l sw i t h i nt h e inclusions. Large b l o c k so fs e d i m e n t s Lemitar Some diorite/gabbro t oh febsleo cam krsea p p a b l e F o l i a t i o na n d a r e s c a t t e r e dt h r o u g h o u tt h e ( a f e w m e t e r s t o 1 0 meters a c r o s s ) . (sec. r e l i c t b e d d i n g a r e o f t e np r e s e r v e d M . ost, n o t a l l , of t h e s eb l o c k sa r ep r o b a b l yr o t a t e dx e n o l i t h s opposed 7, t o r o o fp e n d a n t s ,b e c a u s et h ea t t i t u d e Map 1). if as of f o l i a t i o n PL. 6: Photomicrograph (lox, c r o s s - p o l a r s ) d i o r i t e / g a b b r ow i t h of a f i n e - g r a i n e ds e d i m e n t inclusion. PL. 7: D i o r i t e / g a b b . r ow i t h a s e d i m e n ti n c l u s i o n . c---"--l 0.35 mm PL. 8: Amphibolite inclusion in the diorite/gabbro. Page 40 v a r i e s f r o mt h a t o f t h eg e n e r a la t t i t u d es e e ni nC o r k s c r e w Canyon. Migmitization M i g m i t i z a t i toL hn fee m i tda iro r i t e t g a b b or o ccurs s oatuh litoen hnteg rru cno st h w invetieat hc t m u s c o v i t e - b i o t i t eg r a n i t e .T h eg r a n i t e is s t r o n g l yf o l i a t e d 9 1 , f o r m i ni rgr e g u l a r , n e at hri n e t r u s i vc eo n t a (c Pt l . f o l d e db a n d so fq u a r t za n df e l d s p a r .F o l d e dv e i n so fq u a r t z mafic r o c k s o f t h e a n df e l d s p a cr r o s s c u t h em e l a n o c r a t i c L e m i t a r d i o r i t e / g a b b r o (Pl. 11 and 12) 1 0 )A . g m a t i t i sc t r u c t u r e (sP 1 . a n dl e u c o c r a t i cp t y g m a t i cf o l d so c c u lr o c a l l y . a r e s u g g e s t i v e o f t h ei n t e n s e B o u d i n a g es t r u c t u r e s( P l .1 3 ) s h e a r i n ga n ds t r e t c h i n g . of F o upro s s i b lme e c h a n i s m s m i g m i t i z a t i ohna vbee e n p r o p o s ebY dya r d l e( y1 9 7 8 i)g: n e o ui n s jection an , atexis, external metasom maeattniasdm mo, srepghriecg a t i o n . of i n d i v i d u a x l enoliths, A g m a t i z a t i o na n dr o t a t i o n i nt h e as s e e n Lemitar m i g m i t i t e sa,rlei k e l w y h e r e v eerx t e n s i v e m e l t i n gh a so c c u r r e d ,w h e t h e rp r o d u c e d a noar t e cmt ei cl t s . It is b yi g n e o u si n j e c t i o n u n l i ktehx laytte r n a l m e t a s o m a t i s m o r m e t a m o r p h i cs e g r e g a t i o nc o u l dp r o d u c ee n o u g h f l u i d t o c a u s er o t a t i o n s of l a r g e x e n o l i t h (sK i n g , 1965). PL. 9 : PL. 10: Strongly foliated muscovite-biotite granite. Migmititic layers in t h e dioritejgabbro of t h e Lemitar diorite/gabbro. PL. 11: Agmatitic structures in dioritefgabbro. PL. $2: Agmatitic structures in dioritefgabbro. PL. 13: Boudinage structures in diorite/gabbro. 44 Page i n the T h ea p p e a r a n c ea n dc o m p o s i t i o no ft h el e u c o s o m e ss e e n L e mm i tiagrm i triet seaestdm hj eaotbchfl eae nts t m u s c o v i t e - b i o t i t eg r a n i t e .L e u c o s o m e sc a nb el o c a l l yt r a c e d im n t htuo es c o v i t e - b i o tgi rt ea n(iPt e1 . indicating that clearly 101, of t h em u s c o v i t e - b i o t i t e i g n e o u si n j e c t i o n g r a n i t ei n t ot h eL e m i t a rd i o r i t e / g a b b r op r o d u c e dt h eL e m i t a r migmitites. Geochemistry A a n d f o u tr r a c ee l e m e n t s( A p p e n d i x . a n a l y z e df o re i g h m t ajor C). was r e p r e s e n t a t i svaem ptod lhfeieo r i t e / g a b b r o T shaem plloec a t i o anprsleo t t o fe id n2g.. Norms w e r e c a l c u l a t e d u s i n g CIPW a c o m p u t e rp r o g r a m( A p p e n d i x T h ed i o r i t e / g a b b r of r o mt h eL e m i t a rM o u n t a i n s S i 0 2 ,T i 0 2 ,F e 2 0 3 ,a n d K20 a n dl o w e r t h a no t h e P r r e c a m b r i a nm a f i cr o c k sf r o m is New (1954) a v e rdai g o er i t e . Mexico and 5). is A l l h i g h e ri n i n A1203, MgO, a n d C a O a v e r a gA e r c h e a bn a s a l t iacn d e s i t(et a b l e Si02 c o n t e n tt,h d eiorite/gabbro C). I n t e r mosf h i g h etrh a N n ockolds' sfatihm veeopfl e s d i o r i t e / g a b b r oc o n t a i nn o r m a t i v eq u a r t z( A p p e n d i x C). an TABLE 5 C h e m i s t r y of t h e M a f i c ' Si02 1 2 52.5 48.2 1.53 3 ' 4 1.41 Ti02 14.2 A1203 13.0 Fe203* 1 2 . 1 14.5 8.20 5.49 MgO CaO 9.00 9.50 2.05 2.57 Na20 0.56 0.53 K20 TOTALS 9 7 . 3 19 8 . 0 3 5 6 48.4 53.1 0.96 1.32 16.8 . 14.2 10.4 11.2 8.06 7.77 9.35 2.26 2.47 0.56 0.36 9 8 - 9 0 99 * 4 1 11.1 7 356 55 109 108 - 8 9 47.5 53.4 4 6 . 4 1 . 8 9 2.16 1 . 6 3 11.4 11.0 13.4 1 6 . 8 18.3 1 5 . 5 7.36 2.15 8 . 4 3 8.58 6 . 8 9 9.16 1 . 9 4 2.39 3.14 1 . 5 8 1 . 7 2 0.35 9 7 - 0 5 9 8 . 0 19 8 . 0 1 25 205 Ba Rb Sr 1 Rocks 366 47 150 108 11 . 191 t y p i c a la m p h i b o l i t eo fL a sT a b l a sQ u a d r a n g l e ,B a r k e r , 1958 2 3 - a v e r a g e of 6 a r e a so fP r e c a m b r i a nm a f i cr o c k s s o u t h - c e n t r a l New M e x i c o ,C o n d i e a n d Budding, - and metabasaltic a v e r a g e of 1 0 a n a l y s e s o f m e t a t h o l e i i t e 1974 a n d e s i t e f r o m t h e T u s a s Mts., B a r k e ra n dF r i e d m a n , ' 4 - 5 - 6 , 7 8 9 * - a v e r a g ed i o r i t e ,N o c k o l d s , a v e r a g eg a b b r o ,N o c k o l d s , 1954 1954 a l , 1977 a v e r a g eA r c h e a nb a s a l t i ca n d e s i t e ,P e a r c e ,e t a v e r a g eL e m i t a rm a f i cd i k e( a v e r a g eo f a v e r a g eL e m i t a rd i o r i t e l g a b b r o( a v e r a g e M a g d a l e n ag a b b r o ,C o n d i ea n dB u d d i n g , T o t a li r o ne x p r e s s e d in 1979 as Fe203. 5 samples) of 5 s a m p l e s ) 1979 Page G a b b r o o f Garcia Canyon T hLe e m i t adri o r i t e l g a b b raontdhgea b b rooGf a r c i a similar t e x t u r e s a n d C a n y o'n( M a g d a l e ngaa b b r oh)a vvee r y m i n e r a l o gai letsh, othudhagievfhyfee cr eh ne tm i c a l c o m p o s i t i o n( sL o u g h l iannKdo s c h m a n 1 ,9 4 2S;u m n e1r ,9 8 0 ) . Both mafic are u inni t rsoulsddeeedri m ea nn tds s u b s e q u e n it n l yt r u dybeoydu n gPerro t e r o z ogirca n i t e s , i m p l y i n gt h a tt h et w om a f i cu n i t s the at s a mtei m eT. hge a b b r oG f a r c iC a a n y oh n abs e e d na t e d (1.5 b . y . ,W h i t e , by Rb-Sr may h a v eb e e ne m p l a c e d 1 9 7 8 ) a n df o u n dt ob eo fm a n t l ed e r i v a t i o n i n i t i a l Sr86/Sr87 i s o t o p set u d i e sa, l t h o u g thh e i s o t o p er a t i oo 0 f . 7 0 4( W h i t e , 1 9 7 8 ) i s s u g g e s t i v eo f some c r uc sotnatla m i n adtTiifh ofenec.rheeinn m c ei cs a l c o m p o s i t i o nc o u l db ed u et od i f f e r e n c e si n h e r i t e df r o mt h e s o cutorocnret a m i n a t i o n e m p l a c e m e n tD . ifferences of granitic magmas after i n t h ed e g r e eo fc o n t a m i n a t i o na n d metamorphism c o u ladl saoc c o u nf tot rhdei s s i m i l a r i t y c h e m i c a lc o m p o s i t i o n sb e t w e e nt h et w om a f i cu n i t s . in Page 47 Origin of l iTt hh oe lhoegt iecr o g e n e i t y L etm h ei t a r a magma of o r i g i n a l d i o r i t e / g a b b r oc o u l db ea c c o u n t e df o rb y d i o r igttoae b b cr o m p o s i t i oH n .o w e v e r , t hLee m i t a r if a d i o r i t et og a b b r o d i o r i t e / g a b b r ow e r ed e r i v e df r o m magma f r otm huep p m e ra n t l oe t, h d e ri o r i t e / g a b b r os h s oub l de i n t h eP r e c a m b r i a nt e r r a i n exposed d o m i n a n t l yg a b b r o s or b a s a l t s a r e s e e n . C o n t a m i n a t i o nb yg r a n i t i c a gabbroic o f New M e x i c oI. n s t e a d , magma magmas o r c r u s t a l m a t e r i a l c oauclcdo u n t for h e t e r o g e n e i t y o f t h eL e m i t a rd i o r i t e / g a b b r o . magma lt ihteh o l o g i c As a c o n t a m i n a t e da,l t e r i npga r tost fhgea b b r o i c magma a n d q u a r t dz i o r i t e from t hceo n t a m i n a t i o ontfhde i o r i t e / g a b b r o magma or as a gabbroic it coulb decome a s c e n d st o w a r d st h ee a r t h ' ss u r f a c e , d i o r i t eT. hqeu a r tgza b b r o of t o a may r e s u l t by granitic l a st te a gd ei f f e r e n t i a fot ref a c t i o n a l c r y s t a l l i z a t i o no ft h ed i o r i t e / g a b b r oo rb o t h .T h ep r e s e n c e o fq u a r t zd i o r i t e sn e a rt h ei n t r u s i v ec o n t a c t ss u g g e s t st h a t t hmea fbi co dpyr o b a b l y was c o n t a m i n a t ewdi g t hr a n i t i c magma. TLheem idt ai or r i t e / g a b bc rooua h ld saboveee n e m p l a c e d a s a g a b b r o ,a n ds u b s e q u e n ti n j e c t i o na n dm i x i n g g r a n i t i c magmas w o u l da l t e rt h eg a b b r o t o a d i o r i t eo re v e n of P a g e 48 to a as q u a rdtizo r i S t eu.fceha t u r e s Lemitar d i o r i t e / g a b b r o w , o u l db ec o n s i s t e n t p r e s e n ti nt h e w i tshu c h a modeL l . a tdei f f e r e n t i a t i oon t fhgea b b r o i c magma c o u l d c r y s t a l l i z e f o rt h e migmitization, a s a d i o r i t e ,a n dc o u l da l s oa c c o u n t L e m i t a r m a f ibc o d y . A c o m b i n a t i o no bf o t hi g n e o u s a i n j e c t iam onn idx ionf g granitic magma in differentiac t ioarouelnsls d ou l t alna dt e L et hmei t a r diorite/gabbro. T hper e s e n coseef d i m e n an tmd a f d i ci ki n eclusions i s y o u n g etrh a n Y n d i c a t e tsh atth L e e m i t a dr i o r i t e / g a b b r o t h es e d i m e n t sa n d a t , l e a s to n ee a r l ys t a g eo fm a f i cd i k e s . B e c a u fsoe l i a t i o n inclusions, is preserved in some of th a rek o s e a p e r i oodmf e t a m o r p h i s m o c c u r r ebde f o rteh e i n t r u s i o no ft h eL e m i t a rd i o r i t e / g a b b r o . MAFIC DIKES Distribution M a f idci k ei n s trude all ot hfeex p o s ePdr e c a m b r i a n r o c kesx, c etph ctae r b o n a t i t eCs a. r e fm u la p p i tn ohg fe m a f i cd i k e si n d i c a t e s a c o m p l i c a t e dh i s t o r yo ft w oo rm o r e p e r i o d so fi n t r u s i o nt h a tc a nb er e c o g n i z e db a s e d r e l a t i o n s h i p sT . h ed i k e s t r i k ed o m i n a n t l y on f i e l d in a northernly P a g e 49 d i r e c t i o nw i t ha l m o s tv e r t i c a ld i p s . A s e r i e so fu n m e t a m o r p h o s e dd i a b a s ed i k e sa l s oi n t r u d e t hP e r e c a m b r i a sn e c t i o n . Tertiary in M o sottfh e sde i k easrpe r o b a b l y a bg ee c a utoh s fel aim roc fek t a m o r p h i c similar c h a r a c at enrd P h a n e r o z osi ec d i m e n t s . (appendix B) d i kaferoseuinndt r u d itnhge One s a m p l e 56) (Lem is described and included with t h ae n a l y s e ostfh m e afic i s similar t ot h em a f i c d i k e s .C h e m i c a l l y ,t h ed i a b a s ed i k e dikes. Description a n d f i n e - g r a i n e da n d T h em a f i cd i k e sa r eg r e e n i s h - b l a c k may i n c l u d ei n c l u s i o n so sf e d i m e n t a r yr o c k s . a v e i n sa n dc a r b o n a t i t ed i k e so f t e nc r o s s c u t m a fdi ci k e s . f o l i a t e da n d In Thin granitic t h is ne c t i o m n ,a f d i ci k e s f e wo tf h e s e are s l i g h t l y may e x h i b i st u b o p h i t i ct e x t u r e s T . h e yc o n s i s t o fg r e e nh o r n b l e n d e( 3 5 - 4 0 2 1 a, l t e r e dp l a g i o c l a s e( 3 0 - 3 5 % ) , g r e e n a n d brown b i o t i t e (10-20$), m a g n e t i t( e5 - 1 0 $ ) , and v a r y i anm g ouq nou tfsa r tczh,l o r i thee,m a t i tgea,r n e t , f l u o r i t ae n , cda r b o n a t M e . o r t at er x t u r eosf t eanc c o m p a n y s e c o n d a r yc a r b o n a t e ,w h i l ec a r b o n a t ef l u i d sa s s o c i a t e dw i t h t h ei n t r u s i o n o f t h ec a r b o n a t i t ed i k e o s f t e nf o l l o w e d partiallyreplacedthese and e a r l i e rd i k e s . and P a g e 50 A s e r i e s offo ut rh isne c t i o nasl o n g a i n t r u d e bd y a mafic dike c a r b o n a t i t de i k w e e r set u d i e dA. d j a c e ntto t hcea r b o n a t i tde i k et ,hm e a f idc i keex h i b i t e edx t e n s i v e a l t e r a twi ohcneorrer om d ea dg n e thi toer,n b l e nadned, feldspar are (1-3b) was r e p l a cbeayd r b o n a( p t el . Apatite 14). i n t r o d u c iendttm hoea fdi ickSeu. b o p h i t i c t e x t u r e s were p r e s e n it n a l l f o utrh i sn e c t i o n sF. u r t h e r i s o b s e r v e da l o n g f r o mt h ec a r b o n a t i t ed i k e ,l e s sa l t e r a t i o n In w i t thh de i s a p p e a r a n c oeaf p a t i t e . t h se a m p l leo c a t e d f a r t h e s tf r o mt h ec a r b o n a t i t ed i k e ,o n l ys l i g h ta l t e r a t i o n was o b s e r v e M d . a g n e t i ct eo r ehs o, r n b l e n daenf, ed l d s p a r w e r eo n l ys l i g h t l yr e p l a c e d b yc a r b o n a t e . T h ef i e l de v i d e n c es u g g e s t st h r e ep e r i o d s - bm y a f idci k e s Stage of I, 11, a n d 111. intrusion T hper e s e n c e of m a f i c d i kien c l u s i o nws i t h itnhdei o r i t e / g a b b rsou g g e s t s that mafic dikes from S t a g e I w e r ee m p l a c e dp r i o rt ot h e intrusion otfh L e e m i t adr i o r i t e / g a b b r oM . a f id c i k e fsr o m Stage I1 i n tL r uteh dmedid itoarri t e / g a b an bd ro s u b s e q u e n t l y were c r o s s c u tb yg r a n i t i ca n dp e g m a t i t ed i k e s a n dv e i n s ,i n d i c a t i n gi n t r u s i o na f t e rt h ee m p l a c e m e n t of t h e d i o r i t e / g a b bbrbuoetf oerm e p l a c e m teg ohnrfeta n i t i c complex. Mafic d i k ferso m the final s t a g Se t, a g e i n t r u d e d a l l o f t h eo l d e rP r e c a m b r i a nr o c k s ,i n c l u d i n gt h e g r a n i t icco m p l e xb;udtindoi n t t r u dt ehcea r b o n a t i t e s . 111, PL. 14: P h o t o m i c r o g r a p (h2 5 xc, r o s s - p o l a r ss) h o w i n g , here e x t e n s i f e c a r b o n a t i z a t i o n o f a m a f i cd i k e , w c a r b o n a t e h a sr e p l a c e df e l d s p a rc r y s t a l s . H 0.3m m Page 53 Geochemistry A r e p r e s e n t a t i v es u i t eo fs a m p l e sf r o mt h em a f i cd i k e s was a n a l y z efdoeri g h t e x p o s eitdnhLe e m i t aM r ountains m a j o ra n d four t r a c ee l e m e n t s( a p p e n d i x plotted on fig. C). T h es a m p l e sa r e 2. T hmea f di ci ks ea m p l ec sabcneo m p a r ewdi o t ht h e r P r e c a m b r i amna f ri o c c kf rso m New A r c h e a nb a s a l t i ca n d e s i t e( t a b l e 5 ) a n df o u n dt ob eh i g h e r in F e 2 0a3n d K20 a nldo w e r M e x i caonaadnv e r a g e i n A1203, C a O , a n d Na20. In terms ot hfSei 0c2o n t e n t hm t ea f d i ci ks ea m p l e, hs a v e approximately the a v e r a g ge a b b r (ot a b l e as Nockolds' s a maem o u noStfi 0 2 5). Two s a m p l eostfhm e a f idci k e s c o n t a i n e dn o r m a t i v eq u a r t z( a p p e n d i x C). (1954) O R I G I N OF THE MAFIC ROCKS in T h em a f i cr o c k o s tfh eL e m i t a M r o u n t a i np s lot 9 1 , w i t ht h em a f i c o f a n AFM d i a g r a m( f i g . t h o l e i i t ef i e l d the d i k e sf a l l i n gc l o s et ot h el i n eb e t w e e nt h et h o l e i i t i c and c a l c - a l k a l i n ef i e l d s ,( u s i n gI r v i n ea n dB a r a g a rd e f i n i t i o n , 1971). T h e r e i s noob v i o ut rse nbde t w e et n hme a f i c a f e l s ir co c k a s ,l t h o u g h and bimoda p lo p u l a t i oenx i s t s . c h e m i c a li n d i c e sh a v eb e e np r o p o s e d Two a s a m e a s u r eo fm a g m a t i c f r a c t i o n a t i o n o f m i n e r a l s ;t h em a f i ca n dt h ef e l s i ci n d i c e s (Simpson, 1954). similar TLheem i . st a rm p p l el so t t ot h eS k a e r g a a r dt r e n d( f i g . t hme a f ir co c k s may Metamorphism may bdee r i v ef d rom on trend a 101, s u g g e s t i n gt h a t a similar source. bree s p o n s i b lfeotrhsec a t t eordf a t a p o i n t s e e ni nf i g 1. 0 . Two m a f i cb o d i e s three a r e e x p o s e d i n t h eL e m i t a rM o u n t a i n s - s t a g e s o fm a f i cd i k e sa n dt h eL e m i t a rd i o r i t e / g a b b r o . M o s tm a f i c Budding, magmas o r i g i n a t e i n t h eu p p e rm a n t l e( C o n d i ea n d 1 9 7 9 1 , a n d i t i s c o n c e i v a b l et h a tt h em a f i c magmas p r o d u c i ntghm e a f irco c ksse ein tnhLe e m i t aM r ountains c o u l dh a v ee m e r g e df r o mt h eu p p e rm a n t l e as w e l l . A l t h o u g hn od e f i n i t ec h e m i c a lt r e n d sb e t w e e nt h em a f i c it d iLtakheneem ds idtiaorr i t e / g a b ebxr ios t , c o n c e i v a b l teh abt o t ah r de e r i v e fdr o m a similar is source. F A - N a O+K20 2 F - FeO M MqO SKAERGAARD - FOR EXPLANATIONOF ". SYMBOLS S E E FIG.8 DASHED CURVESEPARATES CALCALKALINE FIELD (BOTTOM) FROMTHOLEIITICFIELD(TOP) F R O M I R V I N E AND BARAGAR,1971 \ GROUP 2 GRANITES Y A " v V V v V " v N 100 90 ,SKAERGAARD LEMITAR D I O R I T E / G A B B R ~ TREND - 80 70 r - 60 MI 50 - OKONJEJE THOLEIITIC 40 - SERIES 301 20 F O R EXPLANATION O F SYMBOLS SEEFIG. 8 I 0 0 IO 20 30 40 50 60 70 80 90 100 FI .M I = (FeO+ Fe203) x 100 MAFICINDEX M g O + FeO+Fe203 FI (Na20 + K20) X 100 C aO+ Na20+%0 FIGURE 10: M A F I C - F E L S I CI N D E X ROCKS F E L S I CI N D E X PLOT OF THE LEMITAR IGNEOUS (FROM SIMPSON, 1954) T h ed i f f e r e n c e sb e t w e e nt h et w om a f i cu n i t sa r ee x h i b i t e d - i n q u a r t( zS i 0 2c1o n t e n t s t hde i s s i m i l a r i t y or d i k ehs a v i n lgi t t l e in c o n t a i nqiunagr t z no t hme a f i c q u a r tazntdhdei o r i t e / g a b b r o a m ouupn t s to d i o r i t e / g a b b r ow e r ec o n t a m i n a t e d If 10%. the by g r a n i t i c magma a t some it p o i n t i n i t s e a r l hy i s t o r y , by is w i t h itnhbeo u n dosf p o s s i b i l i ttyh at h tm e a f idci k easntdhdei o r i t e / g a b b r o o r i g i n a t e d f r o m t h e samu e pper of mafic m a n t l e s o u r c eT . h r e es t a g e s d i k ei n t r u s i o nw o u l db ec o n s i s t e n w t ith a unique sourcS e .i m i l ac rh e m i s t r i ebse t w e et n ht e h r es et a g eosf m a f idc i k easn tdhde i o r i t e / g a b b r sou p p o rstu c h a model. H o w e v esre, p a r ast oe u r c fetosh m rea fdi ci k ae nts hde d i o r i t e / g a b b r oc o u l de x i s t . G R A N I T I C COMPLEX Introduction G r a n i t ir co c k s m a kuaepb o tuht r ef o e u r t ho t hsf e in e n tei x r ep o sPu or ref ec a m b r ri ao nc k s M o u n t a i n (sf i g . 2). h a v eb e e nd i s t i n g u i s h e do n b e t w e e nt h e m S i xv a r i a t i o n o so f n eo r more plutons Map 1, a l t h o u g ht h er e l a t i o n s h i p i s u n c e r t a i nb e c a u s eo ft h el a c ko fa n y r e l a t i o n s h i p sT . hese tLheem i t a r map u n i t sa r e : field (1) g n e i s s i gc r a n i t e (2) m u s c o v i t e - b i o t i tge r a n i t e (3) biotitg eranite (4) leucogranite (5) P o l v a d e rG a ranite (6) p e g m a t i t e sa n dq u a r t zv e i n s T h eg n e i s s i cg r a n i t ei n t r u d e st h eb a s eo ft h es e d i m e n t s and is n o ti nc o n t a c tw i t ht h eo t h e rg r a n i t e sn o rw i t ht h e L e m idt ai or r i t e f g a b b r o . g n e i s s igc r a n i t e A (Map 1). fpeewg m a ttcihdut eeot s T hgen e i s s igcr a n i tceo u lbde in o l dtehra th one t hge rr a n i t ee xs p o s e d is M o u n t a i nsst;r o nf o gliation present tL he mitar i n t hgen e i s s i c g r a n i taen adb s e nftr o m from t hoe t h egr r a n i t e s . is g n e i s sgi cr a n i t e g n e i s s i cg r a n i t e sediments. If the o l d et rh, et h fnoe l i a t i o tohnf e is possiblyrelatedtothefoliationofthe I t i s d i f f i c u l tt of o l i a t eo n eg r a n i t e( g n e i s s i c g r a n i t e )w i t h o u ta f f e c t i n gt h eo t h e rg r a n i t e s i n t h e Lemitar M o u n t a i n s ,u n l e s st h eo t h e rg r a n i t e sw e r ee m p l a c e da f t e rt h e f o l i a t i o no c c u r r e d P . e g m a t i t e sa n dq u a r t zv e i n sa r e common t h r o u g h o ut thsee d i m e n t st ,hLe e m i t adri o r i t e f g a b b r oa,n d t h e P o l v a d e rga r a n i t eT. hge r a n i t irco c k s from a similar s o u rbceec a tusohisfem e ilarity c o m p o s i t i o na n dt e x t u r e . may bde e r i v e d in G n e i s s i cG r a n i t e T h eg n e i s s i cg r a n i t ec r o p so u t p o r t i o no ft h e a r e a (Map 1 ) a n d i s b o u n d e d on t h e mapped a b r e c c i a t e df a u l tz o n e( f o r m i n ga na r r o y o )a n d s o u t hb y east the i n t h ee x t r e m es o u t h e r n and west on bu y n c o n f o r m i t i ew s i t thh P ehanerozoic l i m i t o ef x p o s u r e s e d i m e n t sT . h en o r t h e r n an is f o r m ebdy . i n t r u s i vceo n t a cwt i tthhsee d i m e n t sa,ntdh idni k eosf g n e i s s i cg r a n i t ei n t r u d et h es e d i m e n t sa l o n gt h ei n t r u s i v e contact. S ePvreercaalsm e am v dbneirakd irfaei nlsc greenish-blacd k i a b a s de i k e osuf n c e r t a i an g ien t r u d teh e g n e i s s i cg r a n i t e .P h a n e r o z o i cl i m e s t o n ec a p st h eg r a n i t e a on f e wo tfh eh i g h e hr i l l sP. e g m a t i t ed i k e as n dv e i n as r e rare. T h e g n e i s s i c g r a n i t e i s a s t r o n g l yf o l i a t e d( s e e 151, p i n k i s h - g r a yt om e d i u m - g r a y ,c o a r s e -t om e d i u m - g r a i n e d a q u a r t z - m o n z o n i tw e ,e a t h e r i nt o g sand. P1. ' r e d d i s h - o r a n ga er k o s i c T h eg r a n i t ec o n s i s t so q f u a r t z( 3 0 - 3 5 % ) K , -feldspar ( 2 5 - 3 0 % ) p, l a g i o c l a s e (20-25%), b i o t i t e( 1 0 - 1 5 $ ) a, n dt r a c e a m ohueonm ft asm at inat deg n e t i t e (fig. 8). Mortar t e x t u r easroef t edne v e l o p e dT.h igsr a n i tdei f f e rf sr o m o t h ePrr e c a m b r i agnr a n i t eit n sh e Lemitar s t r o fnogl i ' a t i p o rno d u csbety dr o n gal lyi g n be ido t i t e c r y s t a l as n d by t hlea cokm f a f iacnadb u n d a nste d i m e n t M o u n t a ibnys PL. 15: P h o t o m i c r o g r a p h (25x, c r o s s - p o l a r s ) g n e i s s i cg r a n i t e . of U 0.3 mm Page 6 1 i n c l u s i o n sI.n c l u s i o nostfhaer k o saerfeo u n adl o n tgh e 16), i n t r u s icvoen t a( cPtl . bmuat if ni cc l u s i oanr se absent. M u s c o v i t e - b i o t i t eG r a n i t e T hmeu s c o v i t e - b i o t i g t er a n i ct er o po sn uo t rth C o r k s c r e w' C a n y o nw , here ' of i t i s i n i n t r u s i v e or f a u l tc o n t a c t (as previousld y i s c u s s e ds, e S e edimentarR y o c k sw ) i t thh e s e d i m e n t so nt h es o u t ha n dt h eL e m i t a rd i o r i t e / g a b b r oo nt h e north, i t o c c u p i e sl e s st h a n a f o u r t ho f a s q u a r ek i l o m e t e r . M a f idci k ea snsde v e r aTle r t i a rdyi k ei n s t r u dt eh e m u s c o v i t e - b i o t gi trea n i S t em. lael nl s e s of d agrrke e n a s x e n o l i t h s ,s u g g e s t i n g c h l o r i t es c h i s ta n ds e d i m e n t so c c u r a n i n t r u s i v er e l a t i o n s h i pw i t ht h es e d i m e n t s .M i g m i t i z a t i o n Lemitar o c c ua rl sotinhnget r u s icvoen t awcittthhe diorite/gabbro as d i s c ueL sa(sersem leidei tra r diorite/gabbro). T h em u s c o v i t e - b i o t i t eg r a n i t e is a s l i g h t l yf o l i a t e d , p i n k i s h - g r a yt og r a y i s h - p i n k f, i n e - g r a i n e dq u a r t zm o n z o n i t e or g r a n i t e . I t d i f f e rf sr o tmhoet h eg rr a n i t e s in the L e mM i t aoru npttrhab eeislynae(sornog fcfetee n m e g a s cpofrplioam im cfka)uersyc o( vp il t. e P o r p h y r i t i c ,w h i t ea n db l a c kv a r i e t i e sa r ef o u n da l o n gt h e c r e s to ft h ew e s t e r n m o s tr i d g e .T h er o c kc o n s i s t so fq u a r t z 18). PL. 16: A r k o s e i n c l u s i o nw i t h i nt h eg n e i s s i cg r a n i t e . P a g e 63 ( 3 0 - 4K 0% - f )e,l d, s( 1 p0 a r- 3 p0 l% a g) ,i o c l a s e , An40-50 ( 2 0 - 3 5 2b1i,o t i(t5e - 1 0 %m) ,u s c o v i(t3e - 1 0 %a)n t,rda c e a m o umnoatfsg n e t iht ee ,m a t i t e , and 8). c a l c i(t fei g . M o s a i ct e x t u r e sd o m i n a t e . B i o t i t eG r a n i t e The b i o t i t eg r a n i t ei n t r u d e st h ec e n t r a la n dn o r t h e r n It p o r t itLohoenefm s i dt ai or r i t e / g a b b r o . often is g r a d a t i o n aw l i t ht h el e u c o g r a n i t ea n df o r m st h ec r e s t s a s p o d sa n d t h er i d g e sa n da p p e a r bmya frioc c kTs h .g er a n i t e of s m a l l i s l a n d ss u r r o u n d e d may represed n it k ea sn d / o r plugs. The b i o t i t e g r a n i t e i s a g r a y i s h - p i n kt og r a y ,f i n e -t o m e d i u m - g r a i n e d ,q u a r t zm o n z o n i t ea n dd i f f e r sf r o mt h eo t h e r L e m i t aM r o u n t a iP n r e c a m b r i a gn r a n i t e s by n a t u r ea n dg r a n o p h y r i ct e x t u r e( p l . its fine-grained I t i s c o m p o s eo df 17). q u a r t(z3 0 - 4 0 % )K, - f e l d s p a(r3 0 - 4 0 2 1p,l a g i o c l a s e , An40-50 ( 2 0 - 3 0 % ) , b i o t i t( e5 - 1 0 % a) ,nt dr a caem o u n tohsfe m a t i t e , 8). mhaogrnanenb(tdfli eti egn,.d e g r a n o p h y r i tce x t u r e is w e ldl e v e l o p e d i n t h i ns e c t i o n so f it t hb ei o t i gt er a n i t de i, s t i n g u i s h i n g Distinctive f r ot o m h teh e r g r a n i t e si nt h eL e m i t a rM o u n t a i n s G . r a n o p h y r i ct e x t u r e i n d i c a ct er y s t a l l i z a t i o n at a eutectic M o s a i ca n dp o r p h y r i t i ct e x t u r e sa r ea l s o ( H y n d m a1n9,7 2 ) . common. may PL. 17: Photomicrograph (25x, cross-polars) of a muscovite-biotite granite. PL. 18: Photomicrograph (25x, cross-polars) of biotite granite showing granophyric texture. H 0.3mm Page 65 Leucogranite T hl e u c o g r a n i it n e t r u d et hsc ee n t r a n lndo r t h e r n p o r t i o notsh fLee m i t adri o r i t e / g a b b raonddi f f e rf sr o m i t s c o a r s e rg r a i n o t h e rg r a n i t e si nt h eL e m i t a rM o u n t a i n sb y It i s often g r a d a t i o n aw l ith the s i z ae n d whitish color. b i o t i t eg r a n i t ea n df o r m st h ec r e s t so fr i d g e s small a n d .o c c u r s as i s l a n d s u r r o u n d e db ym a f i cr o c k as l o n gt h ea r r o y o s (Map 1). T h el e u c o g r a n i t ep r o b a b l yr e p r e s e n t d s i k e as n d / o r plugs. T h el e u c o g r a n i t e i s a w h i t ea n db l a c k c, o a r s e - g r a i n e d rocT k .hger a n i ct eo n s i s o et sq f ua m l o u no q t sfu a r t z , p e r t h i t i cK - f e l d s p a r , a n d p l a g i o c l a s e ,w i t ht r a c ea m o u n t so f b i o t i t e ( < 5 % ) a n dm a g n e t i t e 8). (<l% f i ,g . P o l v a d e r aG r a n i t e T h eP o l v a d e r aG r a n i t e( W o o d w a r d , mapped a r e a a n de x t e n d sn o r t h w a r df o r n o r t h e r nt h i r do ft h e abouthree km. 1971) c r o p so u ti nt h e T h i s g r a n i t ec o m p r i s e sa b o u t h r e ef o u r t h s o tfh eP r e c a m b r i a nr o c k es x p o s e di nt h eL e m i t a M r ountains ( s efei g . 2). A medium- and tcoo a r s e - g r a i n ef da c i e s f a c i easrdei s t i n g u i s h eodn Map 1, w i tthh e an altered medium- to c o a r s e - g r a i fnaecb diem etiesho nxesgtte n s iTvhee. southern limit o fe x p o s u r eo ft h e medium- t oc o a r s e - g r a i n e d Page 6 6 f a c i e s i s f o r m e d by a n o r t h e a s t - t r e n d i n gi n t r u s i v e contact (as fault p r e v i o udsi lsyc u s sL wteehidm te)hi t a r l i m i t s oef x p o s u r e d i o r i t e j g a b b r oT . h ew e s t e r na n de a s t e r n are or f o r m ebdfya u l t s a n d u n c o n f o r m i t i ews i tPhh a n e r o z o i c s e d i m e n t sa n dv o l c a n i c s . i s l o c a t e ds o u t h w e s to ft h e T h ea l t e r e df a c i e s medium- I t i s b o u n d e d on t h es o u t h ,w e s t , t oc o a r s e - g r a i n e df a c i e s . a nndo r tbh fya u l tasnudn c o n f o r m i t i ews i tPhh a n e r o z o i c s e d i m e n t sT.heea s t e r n i s f o r m ebdy oefx p o s u r e limit a g r a d a ti L inoet n rm ctuahow islen tiiatvtrah ec t dioritejgabbro. are B o t hf a c i e o s tfh eP o l v a d e r aG r a n i t e m a f i ca n dc a r b o n a t i t ed i k e s T . he medium- intruded by t oc o a r s e - g r a i n e d of f a c i e so f t e nc o n t a i n si n c l u s i o n so fm a f i cr o c k sa n d gray a n dg r e e nc h l o r i t es c h i s t . The mediumGranite is t oc o a r s e - g r a i n e df a c i e s a p a l er e d , medium- t oc o a r s e - g r a i n e d s, l i g h t l y a foliated rock t h aw t e a t h e r tso s a n dT.h igsr a n i tceo n s i s t s t h eP o l v a d e r a of m o d e r a toe r a n gaer k o s i c of e q ua m l o u n oq t sfu a r t z , p l a g i o c l a s e a, n dK - f e l d s p a r w , i t hv a r y i n gt r a c ea m o u n t so f biotith e ,o r n b l e n d e , and p o r p h y r i t it ce x t u r easroef t epnr e s e n t G r e e na n dg r a ys c h i s t o , f t e ns e v e r a lm e t e r sl o n g o , ccur i n c l u s i o n sw i t h i nt h eg r a n i t e . 8). m a g n e t i (t fe i g . in Mortar a n d t h isne c t i o n . as P a g e 67 T h ea l t e r e df a c i e so ft h eP o l v a d e r aG r a n i t e is poorly e x p o s e adn bd a d l w y e a t h e r e dP. e g m a t i t e sm, a f idc i k e sa,n d P h a n e r o zm o i cn e r a l i z a toi o cw cn ui g trthrhiaenn i t e . M i n e r a l i z a t i ocno n s i s t s of q u a r t zf ,e l d s p a ra ,nbda r i t e . Some g a l e n a ,c a l c i t e ,a n dc o p p e rm i n e r a l sa r ea l s op r e s e n t . F r e ssha m p l e s of t h ae l t e r e fda c i eas r e c o m p o s i t i o an n tde x t u r tetoh e in similar medium- t co o a r s e - g r a i n e d f a c i eTs h .r oe c akbrsel a ca k nd du s kr eyd , medium- c o a r s e - g r a i n egdr a n i t eTs .hg er a n i ct eo n s i s t s (25-p 3 l0a% g )i o , clase, to of q u a r t z An40-45 ( 2 0 - 2p 5e % r t )h,i t i c K - f e l d s p a r( 3 0 - 3 5 % ) b , i o t i t e( 1 5 . - 2 0 % ) a, n dt r a c ea m o u n t s of h o r n b l e n d em, a g n e t i t ea ,nhde m a t i t eS.u b m o r t at re x t u r e is p r e s e n ta n dg r a n o p h y r i ct e x t u r e i s o f t e np r e s e r v e d . I n c l u s i o n s o f s t r o n g l fyo l i a t e qd u a r t az n fde l d s p a r , s e d i m e n t s g, r a ya n dg r e e ns c h i s t a, n dm a f i ci n c l u s i o n sa r e s c a t t e r e tdh r o u g h o u tD. i o r i t i tcg o a b b r o i icn c l u s i o n as r e f o u nadl o nt g hi n e t r u s i vc eo n t a cItn. c l u s i o na sr e common t h a n i n t h e T h ea l t e r a t i o n r e s u l t sf r o m medium- more t oc o a r s e - g r a i n e df a c i e s . of t h i sf a c i e s s o m ec o m b i n a t i o n of t h eP o l v a d e r aG r a n i t e o f t h ef o l l o w i n g : (1) p a r t i a la s s i m i l a t i o no fs e d i m e n t sa n d d i o r i t e / g a b b r or o c k s (2) s h e a r i n ga n dt e n s i o n a ls t r e s s (3) r e g i o n aml e t a m o r p h i s m P a g e 68 (4) f e n i t i z a t i o na s s o c i a t e dw i t ht h ei n t r u s i o n of t h ec a r b o n a t i t e s (5) h y d r o t h e r m a la l t e r a t i o np r o d u c e d b yP h a n e r o z o i c m i n e r a ls o l u t i o n s . S m ablllo csokefsd i m e n t d i o r i t e / g a b bor c oc u r and w i t h itnhael t e r efda c i eotsfhPe o l v a d e rgar a n i taen d p a r t i a al s s i m i l a t i o no tf h e s es e d i m e n t sa n dd i o r i t e / g a b b r o in b l o c k sa l o n gt h es o u t h e r ni n t r u s i v ec o n t a c tc o u l dr e s u l t t hber i c k - r e db,a d leyr o d eadl t e r efda c i esse eitnnh e s t r e s s h a so f t e n L e m i t aM r o u n t a i n sS. h e a r i n ga n dt e n s i o n a l occurred as e v i d e n cnbeoydr t h e a s t - t r e n d ilnagy eorfs f o l i a t eqdu a r t z and feldspar in some o u t c r o p s (Map 1 ) . F e n i t i z a t i o na s s o c i a t e dw i t ht h ei n t r u s i o no f body at i n t h ea l t e r a t i o no ft h e d e p t hc o u l da l s or e s u l t g r a n i taes, s u m i nt hg a t a carbonatite a I c a r b o n a t ibt eo d y is at depth b e n e a tt hhai lst e r ef ad c itoeh Pfseo l v a d e gr ar a n i t e . H y d r o t h ea rl m t ear la t i o n is s u p eor li d meoprno s e d m e t a m o r p h i s ma n da l t e r a t i o n ,c o m p l i c a t i n ga n yi n t e r p r e t a t i o n w h i c hm i g h th a v eb e e np o s s i b l e . P e g m a t i t e sa n dQ u a r t zV e i n s G r a y i s h - p i n ka n dw h i t ep e g m a t i t e an vd e i innst r u tdP heeo l v a d eG r ar a n i tteg h,n eeissic g r a n i ttehL, ee m i t da ir o r i t e / g a b b r aon,t hd sediments. a n d w h i t eq u a r t zd i k e s P a g e 69 Some pt heoegf m a tviethei n ab v sef oe lndTe h d e. o f t h se i m p l tey p ec, o n s i s t i n g p e g m a t i t e as r e mica, f e l d s p a qr ,u a r t z , and a trace of unzoned a m o ueonpft i d o t e . Thesd e i k e as n d v e i n as r d e i s c o n t i n u o u sw , ith a s t r i k ea n do f t e nf o r mp o d - l i k eb o d i e ss u r r o u n d e d northerly by t h e h o s t in r o c kItn .hger a n i t en ,u m e r o upse g m a t i tdei k er sa n g e a f e w cm. t h i c k n e s sf r o m It i s p o s s i b l e t os e v e r a lm e t e r s . a f i n a l s t a g eo ft h eP o l v a d e r aG r a n i t e . t h a tt h e yr e p r e s e n t Geochemistry T hger a n i t ir co c kasreei t h eqru a r tmz o n z o n i t eosr ( L e m 126) i s a g r a n o d i o r i t e g r a n i t e sh,o w e v eornsea m p l e (fig. 8). Group I both groups G e n e r a l l yt,h ge r a n i t e s and Group I1 (table - f a l l i n t o t wgor o u p s 6 a n df i' g . 9 , 11, a n d 1 2 ) ; 9). f a l l w i t h i nt h ec a l ca l k a l i n ef i e l d( f i g . Theg s er o u p i n g b sr o a d cl yo r r e s p o n C t odo n d i eh' si g h ( G r o u p I ) a n dh i g hS i and 7). More Ca t r a ceel e m e n t d a t a a r ree q u i r e tdfou r t h e r d i f f e r e n t i a t eb e t w e e nC o n d i e ' h s i g hS ai n dh i g h Metamorphisa mnodt h earl t e r a t i o n L e m i t a rg r a n i t e s , t h eg e n e r a l R d iba(-gfSirrga .m 6 or h i g h K ( G r o u p 11) g r o u p s( t a b l e shown by trend K may h a vaef f e c t etdh e t h es c a t t e ro fp o i n t s away from o f New M e x i c o Precambrian g r a n i t e os n 12). groups. D e sapl ti et er a t i o n a and TABLE Summary of t h eC h e m i s t r y 1 6 of t h e Lemitar Mountain Granites 4 3 2 si02 66-70% 73-76% 66-73% 70-77% CaO 1.5-3% (1.5% 1.7-4% 0.9-2% MgO 0.8-1.5% (0.8% 0.6-2.546 (1. K20 (4% 3-6% 2.5-4% 4-5% Mn 550-900 ppm 200-450 ppm 1 - G r o u p I g r a n i t e s ,L e m i t a rM o u n t a i n s G n e i s s i c GraniteandBiotiteGranite 2 - Group I1 g r a n i t e s , L e m i t a r M o u n t a i n s P o l v a d e r aG r a n i t ea n dM u s c o v i t e - b i o t i t e 3 4 - H i g h C a g r a n i t e ,C o n d i e , granite 1978 H i g h K a n dH i g hS ig r a n i t e ,C o n d i e , 1978 4% FIGURE 11: CaO-No20-K20 PLOT OF THE IGNEOUS ROCKS FROM THE LEMITAR MOUNTAINS. A TREND BETWEEN LEMITARSAMPLES.DASHEDLINES BUDDING, 1978). NOTETHE THE LACK \ OF ( S POPULATIONS O L I D LINES ARE A R E FROM CONDIEAND ,- " I \ 300 K ...HIGH .... .. \ I I \ \ \ HIGH c o IO0 R b 50 10 FIGURE 12: Rb-Sr PLOT O F THELEMITARGRANITES.FIELDS SHOWING CRUSTAL THICKNESS ARE FROM CONDIE, 1973. F I E L D S O F HIGH Ca, .HIGH S i , AND HIGH K GRANITES (DASHED LINES) ARE FROM CONDIE, 1978. SOLID LINES R E P R E S E N T F I E L D S OF GROUP I AND 2 FROM THE LEMITAR MOUNTAINS. TABLE 7 CHEMISTRY OF THE GRANITES 1 Si02 Ti02 A1203 Fe203" MgO CaO Na20 K20 TOTAL 2 2 3 4 5 6 7 8 - 4 68.0 0.78 14.3 6.46 1.05 73.5 76.4 74.2 0.46 0.07 0.45 13.6 1 3.2 12.5 3.66 0.95 4.43 0.47 0.05 0.44 1.04 2.03 0.95 1.07 3.03 3.67 3.45 3.69 4.81 4.40 5.20 3.94 9 9 . 4 101.31 1 0 1 . 2 9 100.25 B a517780816 100 820 1155 1279 S2r2 6 77 71 Rb 168 1 3 2183 5 0 1 4105 0 5 ' 6 7 76.1 69.8 69.1 0 . 7 9 0.63 0.19 12.2 1 4 . 4 12.6 8 . 0 5 4.48 1 . 7 2 0.93 1 . 4 1 0.11 1 . 9 8 2 . 6 9 0.70 3.03 3.22 3.48 3 . 8 5 3.53 4.63 1 0 0 . 6 3 99.46 9 9 . 5 3 37 110 147 8 72.3 0.40 14.~3 2.76 0.51 1.35 3.08 4.79 99.49 779 255 242 274 Two mica g r a n i t e ,S t .F r a n c o i s ,M i s s o u r i ,K i s v a r s a n y i , 1 9 8 0 (1 s a m p l e ) A v e r a g em u s c o v i t e - b i o t i t eg r a n i t e ,L e m i t a rM o u n t a i n s ( 3 samples) A v e r a g eP o l v a d e r ag r a n i t e , Lemitar Mountains ( 2 s a m p l e s ) A v e r a g eb i o t i t eg r a n i t e ,L e m i t a rM o u n t a i n s ( 3 samples) A v e r a g eg n e i s s i cg r a n i t e ,L e m i t a rM o u n t a i n s ( 2 samples) A v e r a g eH i g h - C ag r a n i t e , N.M., C o n d i e , 1 9 7 8( 9 samples) A v e r a g eH i g h - S ig r a n i t e , N.M., Condie, 1978 ( 1 2 samples) A v e r a g e High-K g r a n i t e , N . M . , C o n d i e , 1 9 7 8( 1 5 samples) NOTE: 2 a n d 3 c o m p r i s eG r o u p I1 g r a n i t e s a n d I granites. c o m p r i s eG r o u p 4 and 5 Page 74 i t i s a p p a r e n tt h a tt h eg r a n i t i cr o c k s m e t a m o r p h i ce f f e c t s , were e m p l a c eidn t h i(cf ki g . a was c o n t i n e n t ac lr u swt h i c h 1979). C o nB adnuidd eding, 12; >25 km. This i s a s s u m i n gt h a tt h ec r u s t a lt h i c k n e s sg r i dp r o p o s e db yC o n d i e ( 1 9 7 3 ) c a nb ea p p l i e dt os u c hg r a n i t e s . Origin E x p e r i m e n t a l c, h e m i c a l a, n di s o t o p i ce v i d e n c ei n d i c a t e thag t ranitic Mountains, magmas magmas, such Lemitar a s t h o s fe o u n d in the of may f o r mb yf r a c t i o n a c l rystallization or C o n t a m i n a t i oo nf p a r tm i aell t i n g by a granitic magma of lt o hw ec re ur s t . of e i t h eorr i g i n mafic by as c r u s t aml a t e r i aclo u lpdr o d u chee t e r o g e n e o ugsr a n i t e s f o u n di nt h eL e m i t a rM o u n t a i n s . Geochemica ml o d e s tl u d i eosn g r a n i t e si n d i c a t et h a t 30 New - M e x i cPor e c a m b r i a n 50% p a r t i a lm e l t i n g of s i l i c e o u s g r a n u l i t e s i n t h el o w e rc r u s tc o u l dp r o d u c eg r a n i t i c similar i n c o m p o s i t i o n t o g r a n i t e s of C o n d i e ' sh i g h melts C a group ( C o n d i e , 1 9 7 8 1 , w h i cbhr o a d lcyo r r e s p o nttdohG eroup granites in h i g hS ai n dh i g h granites in I t hL e e m i t aM r o u n t a i n sG. r a n i t efsr o m Condie's K, which broadly correspond to t hLe e m i t aM r o u n t a i n sc ,o u lbdper o d u c e d f r a c t i o n a lc r y s t a l l i z a t i o n o f g r a n o d i o r i t e magmas. Group II by T h i s may i m p l yt h a tt h eL e m i t a rg r a n i t e s m e c h a n i s m st h a t may b ed e r i v e df r o m similar may h a v ep r o d u c e do t h e rP r e c a m b r i a ng r a n i t e s i n New M e x i c o . D i f f e r e n c eisd n e p t hosef m p l a c e m e nottfh ge r a n i t i c r o c k se x p o s e di nt h eL e m i t a rM o u n t a i n s may a c c o u n t for t h e h e t e r o g e n e i t sye e nT. h be i o t i t ge r a n i t e is at emplaced a t h o u g httb oe its relative sh l ya l ldoewp dt tu ohe f i n e - g r a i n e da n dp o r p h y r i t i cn a t u r ea n d its s i m i l a r i t yt o i n t h eD i x o n - P e n n a s c o t h eP u n t i g u d og r a n i t ep o r p h y r y a l s o t h o u g h t ob ee m p l a c e d at 2 - 4 km. (Long, 1974). area, The Cine-grainedp , o r p h y r i t i cm u s c o v i t e - b i o t i t eg r a n i t ei s . a l s o t h o u g htbtoeem p l a c e d at shallod we p t hbse c a u soef d i s c o r d a n tr e l a t i o n s h i p -w i t ht h eC o r k s c r e w ( B u d d i n g t o n , 1959). its C a n y o ns e q u e n c e H o w e v e trh,me i g m i t i z a t i oanl o nt gh e is i n t r u s icvoen t w a ctL ih ttehem i dt ai or r i t e / g a b b r o s u g g e s t i v eo fd e e p e rd e p t h so fe m p l a c e m e n t h a nt h eb i o t i t e granite (2 -6 km.). T h e a b u n d a n c eo pf e g r n a t i t e tsh r o u g h o u t t h eP o l v a d e r ag r a n i t es u g g e s dt e e p e d r e p t h so ef m p l a c e m e n t ( > 6 k m . ) .P e g m a t i t e sa r er a r e 6 km.) a n tdh o sfee w pegmatites s h a l l o wd e p t h sa r ec h a r a c t e r i z e d absent i n s a n i d i n ea,nadr e is gneissig cranite d e e pd e p t h s , 6 - i n t h ee p i z o n e( d e p t h so f known h a vfeo r m e d at b yb i - p y r a m i d a lq u a r t za n d t hLee m i t apre g m a t i t e sT.h e t h o u g ht tboeem p l a c e d 1 3 k m .d, u e t o 2 at relatively t o i t s c o n c o r d a n tr e l a t i o n s h i p w i tthhCe o r k s c r e w C a n y osne q u e n c ee,v i d e n coef fo r c e f u l sediments), i n j ied(ncittk thrieiu ton shdnei n g c o a r s e - g r a i n e ds i z e ,a n ds i m i l a r i t yw i t ht h eP e n n a s c oq u a r t z at 8 m o n z o n i t e( a l s oe m p l a c e d and others - (1975) p r o p o s e d 1974). 1 3 km.,Long, Barker a m o d efl o trh eo r i g i no tfh e i s s i m i l a r i n c o m p o s i t i o nt ot h e P i k e sP e a kg r a n i t e w , hich was L e m i t a r g r a n i t e s ,s u g g e s t i n gt h a tt h eP i k e sP e a kg r a n i t e e m p l a c e d a t d e p t hos f 3 - 7 km. well e m p l a c e m ecnot r r e l a t e s T h irsa n g e withe in 2 - d e p t .ho f 8 km. range d e t e r m i n e df o rt h eP r e c a m b r i a ng r a n i t e se x p o s e di nn o r t h e r n N e w M e x i c o( L o n g , 1 9 7 4 ) a n d i n t h e Lemitar M o u n t a i n s . CARBONATITE DIKES Introduction Carbonatites are 1966). c a r b o( nHaet ien r i c h , rauhaugite (>80% >50% i g n e oruoscckosn s i s t i on fg Sovite (>80% c a l c i t e ) , 1, d o l o amnaidtn/eko er r i t e and s i l i c o c a r b o n a t i t e ( 5 0 - 8 0 % c a r b o n a t es p e c i e s )d i k e sa n dv e i n s o c c ut h r r o u g h o ut htm eapped rockstothenorthinthe area and in Lemitar Mountains. the Precambrian Distribution T h ec a r b o n a t i t ed i k e ss t r i k ed o m i n a n t l yn o r t h - s o u t h e a s t - w e s ta n dd i ps t e e p l y (Pl. or 1 9 a n d 2 0 ) a n d c r o s s c u tt h e e n t i rPe r e c a m b r i asne q u e n c eT. hdei k ersa n gietnh i c k n e s s from a few cm. to a d i s c o n t i n u o uds uteeor o s i o nh, o w e v e r m f eewt eMrdsoi.askrtees a few dikes can be TABLE a MINERALS OF CARBONATITE COMPLEXES LOCALITY MINERALS Mountain Pass, California c a l c i t e ,d o l o m i t e ,a n k e r i t e ,s i d e r i t e , b a s t n a e s i t e ,q u a r t z ,p h l o g o p i t e ,b i o t i t e , a l l a n i t e ,m a g n e t i t e ,h e m a t i t e ,g a l e n a , a n d o t h e rm i n e r a l s p y r i t e ,f l u o r i t e , i n c l u d i n gs e v e r a ls u l p h i d e s Iron H i l l , Colorado d o l o m i t e ,c a l c i t e ,a p a t i t e ,l i m o n i t e , a e g i r i n e ,s o d aa m p h i b o l e ,p h l o g o p i t e , m i c r o c l i n e ,q u a r t z ,f l u o r i t e ,s u l p h i d e s , p y r i t e ,a n do t h e rm i n e r a l s MagnetCove, Arkan'sas c a l c i t e ,d o l o m i t e ,a n k e r i t e ,m i c r o c l i n e , a p a t i t e ,m a g n e t i t e ,p h l o g o p i t e ,a n d others AlnoIsland, Sweden c a l c i t e ,d o l o m i t e ,a n k e r i t e ,b i o t i t e , p y r o x e n e ,q u a r t z ,p y r i t e ,a l b i t e , g a r n e t ,c h l o r i t e ,b a r i t e ,a p a t i t e , f l u o r i t e ,a n do t h e r s F e n ,N o r w a y s o v i t e - c a l c i t e ,b i o t i t e ,a p , a t i t e , m a n g a n o p h y l l i t e ,m i c r o l i t e r a u h a u g i t e - c a r b o n a t e s ,a p a t i t e ,b i o t i t e , Wet M o u n t a i n s , Colorado c a l c i t e ,d o l o m i t e ,b a r i t e ,b a s t n a e s i t e , b i o t i t e ,p h l o g o p i t e ,a p a t i t e ,g a r n e t , g a l e n a ,s p h a l e r i t e ,q u a r t z ,z i r c o n , and o t h e rm i n e r a l s Lemitar Mountains, New Mexico c a l c i t ed, o l o m i t ea, n k e r i t eb, a r i t e , b a s t n a e s i t e ,b i o t i t e ,p h l o g o p i t e , f l u o r i t e ,m i c a s ,a p a t i t e ,g a r n e t ,z i r c o n , q u a r t z ,m a g n e t i t e ,a n dm i c r o c l i n e Page 79 TABLE 9 CHEMISTRY OF CARBONATITES Si02 Ti02 A1203 Fe203 FeO MgO CaO Na20 K20 MnO ~ 2 0 5 c02 TOTAL 1 2 3 4 5 6 7 - - - 1 2 3 4 5 6 13.87 0.48 24.16 3.40 0.28 0.50 3.04 10.30 0.73 3.29 14.96 1.10 1.32 20.65 0.47 4.32 3.46 6.53 1.91 11.75 7-05 3.60 3.13 8.92 5.79 7.04 30.4 2.28 9.47 2. 8 8 3.39 4.80 9 - 56 29.9 0.37 0.63 0.64 3.44 26.77 96.73 1.78 4.95 7.68 6.87 6.80 17.2 0.75 1.51 0.35 1.32 17.77 91.14 28.7 0.01 0.10 0.48 0.06 35.80 36.1 2.09 28.52 0.36 2.33 26.81 95-56 91.17 97 70 0.42 1.36 0.68 1.44 - 20.33 0.24 2. 0 8 1.30 1.97 26.25 97-91 a v e r a g ep r i m a r ym a g m a t i cc a r b o n a t i t e ,L e m i t a rM o u n t a i n s a v e r a g er e p l a c e m e n t - t y p ec a r b o n a t i t e ,L e m i t a rM o u n t a i n s a v e r a g ea n k e r i t i cc a r b o n a t i t e , Lemitar Mountains a v e r a g ec a r b o n a t i t e ,H e i n r i c h , 1966 r a u h a u g i t e ,I r o n H i l l , C o l o r a d o ,N a s h , 1971 b i o t i t e ,a n k e r i t i c - d o l o m i t i cc a r b o n a t i t eb r e c c i a , C a s t i g o nL a k e ,C a n a d a ,C u r r i e , 1976 a v e r a g el i m e s t o n e ,P e t t i j o h n , 1957 P a g e 80 TABLE 1 0 TRACE ELEMENT 1 1294 297 44 Ba Sr N i cu co Cr L i Zn 13 36 16 36 133 U 1 2 3 4 5 6 7 8 8.7 - - CHEMISTRY OF CARBONATITES 2 3 4 2 4 9 0 2155 450-1120 130 355 286 59 8 63 13 2.5 64 54 17 2314 8 15 40 7 275 527 8.4 4.7 5 830 3200 6 1000 3000 85 5i nil nil-13 8 109 40 7 8 5300 15000 880 3200 200 51 43 39 110 470 470 110 5 26 a v e r a g e p r i m a r ym a g m a t i cc a r b o n a t i t e ,L e m i t a rM o u n t a i n s a v e r a g e r e p l a c e m e n t - t y p ec a r b o n a t i t e ,L e m i t a rM o u n t a i n s a v e r a g e a n k e r i t i cc a r b o n a t i t e ,L e m i t a rM o u n t a i n s a v e r a g e c a r b o n a t i t e ,H e i n r i c h , 1966 a v e r a g e of 4 s o v i t e s ,S o k l i ,F i n l a n d ,V a r t i a i n e na n d Woolley, 1976 c a r b o n a t i t e ,M a g n e tC o v e ,A r k a n s a s ,E r i c k s o n and Blade, 1963 p r i m a r ym a g m a t i c , Wet M o u n t a i n s ,C o l o r a d o , A r m b r u s t m a c h e r , 1979 r e p l a c e m e n t , Wet M o u n t a i n s ,C o l o r a d o ,A r m b r u s t m a c h e r , 1979 TABLE 11 SIMILARITIES AND DIFFERENCES BETWEEN THE LEMITAR C A R B O N A T I T E AND OTHER CARBONATITES SIMILARITIES A. Occurrence N o n a l k ai gl incecooum s p leexxa,m p R l easv: C a lolui n t y , M o n t a nVae; r i B t yr,i t iCs o h l u m bC i aa,n a dSaa;l mB o any , A l a s k aT; u rPi e n i n s u l a , U.S.S.R.; (Heinrich, 1966). Transvaal M a af iscs o c i a t i oenx,a m p l e s : M a g nHeet i g h t s , 1 9 6 6 ) , V e r w o e r d , ( g a b b rmo a, g n e t i tael ,b i t i t e , Stjernoy, Norway ( g aV b be r o w,o e r d , 1966); Sokli, Finland, ( a m p h i b o l i t eV , artiainen and Woolley, 1 9 7 6 1 , M e s s u mS,o u t h 1966). West A f r i c a( b a s a l t ,d o l e r i t e ,g a b b r o ,V e r w o e r d , S t r u c t u r ea n dT e x t u r e R e p l a c e m ecnatr b o n a t i t e s common, example: Wet M o u n t a i n s , C o l o(rAa rdm o brustmacher, 1979); S i i l i n j a er v a si ,t e r n F i n l a n d( P u u s t i n e n , 1969). P o r p h y r i tt iecx t u r e s common, example: 1979). C o l o r a d o( A r m b r u s t m a c h e r , x e n o l i tw h is t htcihnaer b o n a t idtiek e s , O c c u r r e n c e of examples : M o u nP t aC aisansl ,i f o r M n i aa t; o p o n N y a s a l a n dP; a n d a Hill, T a n g a n y i k a( H e i n r i c h , Sligh f ot l i a t i opna r a l l te o hl e walls e x a m p l e sM : o u n t a iPn a s sC, a l i f o r n i(aO l s o ne,t Wet M o u n t a i n s ,C o l o r a d o( H e i n r i c h , 1966). P r e s e n c e o f z o n i n gw i t h i n M o u n t a i nP a s s ,C a l i f o r n i a C. Wet Hill, 1966). toh dfe ikes, al. tchaer b o n a t idtiekeex,a m p l e : (Heinrich, 1966). Mineralogy Common m i n e r a l o g y( t a b l e Mountains, 8 L a c ko f e l d s p a t h o i d sa n ds o d aa m p h i b o l e s e, x a m p l e M : ountain P a s s ,C a l i f o r n i a( O l s o n ,e t al., 1954). 1954); P a g e8 2 TABLE 11 D. - continued Alteration (10) F e n i t i z a t i o n , i f p r e s e n t , i s p o o rdl ye v e l o p eedx, a m p l e s : Magnet H e i g h t s , T r a n s v a a l ( V e r w o e r d1, 9 6 6 )S; o k l iF, i n l a n d ( V a r t i a i n e n a n dW o o l l e y , 1 9 7 6 ) . DIFFERENCES A. Occurrence (1) A b s e n cor ef l a t eadl k a l ri o c c k es x, a m p l e F s :e n , ( H e i n r i c h , 1966); Norway A l n oS, w e d e n (von Eckermann, 1948). (L 2 )a cao k sf s o c i a t el ad r g e mass o p rl u g of carbonatite, e x a m p l e sM : ountain P a s s , C a l i f o r n i (a O l s o ne, t . a l . , 1954); A l n oS , weden (vori Eckermann, 1 9 4 8 ) . ( 3 ) No a s s o c i a t e dk i m b e r l i t e sw h i c ha r eo f t e n b, u nt o at l w a y s , a s s o c i aw tceiad t rhb o n a ct iot m e p l e xeexsa, m p lFeesn: , N o r w a syo; u t h w eTs ta n g a n y i kG a ;i b e opnr o v i n cSe o , uth-West Africa ( H e i n r i c h , 1966). B. Mineralogy ( 4 ) A p p a r e n tl a c k o f s u l p h i d em i n e r a l s common t oo t h e rc o m p l e x e s (table 2). ( 5 ) L a c k of f e l d s p a t h o i d s a n d s o daam p h i b o l e se ,x a m p l e sF:e n , Norway (Heinrich, 1966); A lSnw o ,e (dE veocnn kermann, 1948). C. Alteration ( 6 ) Absence of l a r gh ea l o Sweden ( v o nE c k e r m a n n , foef n i t i z a t i o n , Alno, examples: F e n , Norway ( H e i n r i c h , 1 9 6 6 ) . 1948); P a g e 83 TABLE 1 2 X-RAY FROM THE LEMITAR MOUNTAINS DIFFRACTION LINES OF BASTNAESITE hkl Lem 5 0 0 d d I 4.84 40 4.88 40 110 3.54 60 3.56 70 112 2.89 100 2.88 100 114 2.02 60 2.02 40 202 2.62 40 2.61 20 300 2.09 60 40 2.06 302 1.90 60 - 1-90 40 h e a v ym i n e r a ls e p a r a t ef r o mt h eL e m i t a rM o u n t a i n s (see f i g . - I 002 L e m 500 PDF PDF 2 f o rs a m p l el o c a t i o n ) P o w d e rD i f f r a c t i o nF i l e( 1 9 7 2 1 ,c a r d C h e m i c a lf o r m u l ao fb a s t n a e s i t e i s CeC03F 11-340 PL. 19: B r e c c i as i l i c o c a r b o n a t i t ed i k ec r o s s c u t t i n g s e d i m e n t s i n C o r k s c r e wC a n y o n( l o o k i n gn o r t h ) . PL. 2 0 : S t e e p l yd i p p i n gc a r b o n a t i t ed i k ei n t r u d i n gt h e L e m i t a rd i o r i t e / g a b b r o( l o o k i n gn o r t h , i n sec. 7). P a g e 85 t r a cfseoedrv e rhauln d rm e de t earl sosntgr i kFel .o w s t r u c t u r e s o r b a n d i n go f t e np a r a l l e l ts h ec o n t a c t o s tf h e d i k (ePs211. ) . Some d i k ef o s l l opwr e - e x i s t i nf gr a c t u r e z o n e sF. e e d e sr y s t e m o s ften main f i l l f r a c t u r e sa d j a c e n t ot h e d i kT e .hr ea n d oomr i e n t a t i o n o f t hdei k e s (Map 1) s u g g e s t st h a t h ec a r b o n a t i t ef l u i d sf o l l o w e dp r e - e x i s t i n g f r a c t u r ez o n e s i n t h ed i o r i t e / g a b b r o ,t h es e d i m e n t s ,a n dt h e P o l v a d e rGa r a n i t eO. f t etnhcea r b o n a t i tfel u i df so l l o w e d e a r l i e rm a f i cd i k e s ,p a r t i a l l y o r c o m p l e t e l yr e p l a c i n gt h e m , a s d i s c u s s e d e a r l i e r ( s e eM a f i cD i k e s ) . A p p a r e n t l y ,f r a c t u r e sw e r er a r ei nt h eg r a n i t i cr . o c k s , a s a b u n d a nw t ithin b e c a u s et h i c kc a r b o n a t i t ed i k e sa r en o t tghrea n i t e as t hw a eriy et d h t hi o n erite/gabbro. C a r b o n a t i t ed i k e sa r en o ot f t e nf o u n dw i t h i nt h eb i o t i t e , muscovite-biotite, o r g n e i s s i cg r a n i t e s ,e x c e p to c c a s i o n a l l y a l oti nh n get r u s icvoen t a cTtcsha.er b o n a tfi lt ue i d s a g e n e r asl hl ya t t e rP th eod el v a d G e rraa n iftoer, m i n g s t o c k w o r kp a t t e r n . C a r b o n a t i t ed i k e sa r er a r e a r e aT . his i n t h es o u t h e r nt h i r d may s u g g e s t h a t h es o u r c e t h ea r e an o r t ho fC o r k s c r e w 71, w h e r et h ef r e q u e n c y of t h e may b ec e n t e r e d Canyon ( n o r t h e r n p o r t i o n o f s e c . of c a r b o n a t i t ed i k e s is greater. in PL. 21: B a n d e ds i l i c o c a r b o n a t i t ed i k e . Page 87 Description One of in t hc eh a r a c t e r i s t i co c sa f rbonatites the L e m i t a r Mountains i s t h ep e t r o l o g i cv a r i a t i o n st h e ye x h i b i t . T hdei k evsa r y i n m i n e r a l o g(yf i g . s i z e ,t e x t u r e , a n d c h e m i s t r y( A p p e n d i x i n the t h e c a r b o n a t i t ees x p o s e d can Mountains be a s ptroi m amr ya g m a at rinecdp l a c e m e n t differentiated 1979). c a r b o n a t i t e s( A r m b r u s t m a c h e r , (table grain I nt h i ns e c t i o n , C). Lemitar 131, table 13, 1 31 are T e x t u r ea n dm i n e r a l o g y criteria p tr h im e ary tfhoi rs d i f f e r e n t i a t iPorni .mcaarryb o n a t ei txehs i ibgi nt .e o u s poor r pp rhi ymr aietriiytch ex e rt u r e s , h y p i d i o m o r p h i c - g r a n(uplla. r carbonatites are 22). characterized by and a p a tm i taeg, n e tfiet led, s p a r , are R e p l a c e m ecnatr b o n a t i t e s P r i mp ao rr yp h y r i t i c l a rp gh e e n o c r y sot fs biotite/phlogopite. characterized or c o a r s e - g r a i n e dc a r b o n a t ep a r t i a l l y by fine- or completely replacing r e l i c t p h e n o c r y s t so ff e l d s p a ra n d / o rh o r n b l e n d e ,p r e s e r v i n g t h oe r i g i n atle x t u r e s o f t hreo c(kp l . were o r irgoi cnka sl in and 24). The d m girakafen ioscir,t e s , d i o r i t e / g a b b r o , a s i n d i c a t e db y m o raeb u n d a n t 23 r e l i c t t e x t u r e s .A p a t i t e is t h e primarm y a g m a t i c a r b o n a t i t e sw , hile m a g n e t i t e i s m o r ea b u n d a n t a l t h o u gbho at hp a t i at enmda g n e t i t e i n t h er e p l a c e m e n tc a r b o n a t i t e s , may bp er e s e n t in CARBONATES 50 APATITE 50 MAGNETITE LEMITAR MOUNTAINS 0 P R I M A R YC A R B O N A T I T ED I K E S X R E P L A C E M E N TC A R B O N A T I T ED I K E S ALNO, SWEDEN (von ECKERMANN,1948) 0 SOVITES S O K L I , F I N L A N D ( V A R T I A I N E NAND WOOLLEY, 1976) A AVERAGESOVITE A A V E R A G ER A U H A U G I T E FI GURE 13: CARBONATE-APATITE-MAGNETITE PLOT OF THELEM ITAR CARBONATITES TABLE 13 MINERALOGY OF CARBONATITES OF THE LEMITAR MOUNTAINS MINERAL ABUNDANCE PRIMARY MAGMATIC Ankerite Apat i.te Barite Bastnaesite Biotite/phlogopite Calcite Chlorite Dolomite Fluorite Garnet Hematitelgoethite Hornblende Ilmenite K-feldspar Magnetite Muscovite/sericite Plagioclase Pyrite Pyrochlore Sphene/leucoxene Quartz Zircon E R - - essential to all samples, C present in a few samples, - REPLACEMENT c ,E E R R C E R E C R R C E R C C C R C R - - present in most samples, not present PL. 2 2 : P h o t o m i c r o g r a p h (25x, c r o s s - p o l a r s o )f p o r p h y r i t icca r b o n a t i t e . a A t t hbeo t t o m a r o c kf r a g m e n t . of t h e photograph is p a r to f . H 0.3 mm PL. 23: Photomicrograph ( 2 5 xp, l a n lei g h t ) of a r e p l a c e m e n tc a r b o n a t i t e ,p r e s e r v i n gt h eo r i g i n a l p o r p h y r i t ti ec x t u r e . PL. 24: Photomicrograph ( 2 5 xp, l a n lei g h t ) of a r e p l a c e m e n tc a r b o n a t i t ep r e s e r v i n gt h eo r i g i n a l ophitictexture. P a g e9 2 i s i n a d e q u a t ei nt h ef i e l da n d e i t h e r .T h i sc l a s s i f i c a t i o n furtheg r r o u p i n g sa c c o r d i n gt om i n e r a l o g ya n dt e x t u r ea r e necessary. T h ec a r b o n a t i t ed i k e s b r o a d l yc h a r a c t e r i z e d i n t h e L e m i t a r M o u n t a i n sc a nb e as d i k e sc o n t a i n i n gx e n o l i t h s( b r e c c i a a n dm i c r o b r e c c i as i l i c o c a r b o n a t i t ed i k e s )a n dt h o s ew i t h o u t x e n o l i t h sT. hber e c c iaanm d i c r o b r e c c isai l i c o c a r b o n a t i t e d i k e s are l i g h t t o m e d i u m - g r a y ,w e a t h e r i n g magmatic. a n dg e n e r a l l yp r i m a r y t o a d i r t yb r o w n , 10 T h ed i k e sc o n s i s ot f 40% x e n o l i t h s( r o c kf r a g m e n t s a) n d> 6 0 %c a r b o n a t i t e matrix (up ( p l2.a5n2d6 )L. a r gpeh e n o c r y s t so,f t em n egascopic ts oe v e r a l mm. - a c r o sm so)fa, g n e t i t e (5-10%), apatite (5-10$)b , i o t i t e / p h l o g o p i t e( 5 - 1 5 $ ) a, n df e l d s p a r( < 2 $ )a r e a f o u n ds c a t t e r e dt h r o u g h o u t f, o r m i n g p o r p h y r i t i ct e x t u r e . Othem r i n e r a l so c c u tr h r o u g h o u tt h ef i n e - g r a i n e dc a r b o n a t e m a t r i x ( t a b l e 13). O f t etnh e sm e i n e r a lasrceo r r o d e d of c r raeaccpn kald erbab dy coenR daetseo. r p t i o n phenocrysts is common. On a w e a t h e rs eudr f at h cese p h e n o c r y s t so f t e ns t a n do u tw h e r et h ec a r b o n a t e d i s s o l v e d away. t hdei k e (pl. or S o v i t ea n dr a u h a u g i t ev e i n so f t e nc r o s s c u t 2 6T ) .hcea r b o n a t i tdei k eosf t ecnr o s s c u t e a r l i e r -mafic d i k e s (pl. 27). matrix has PL. 25: Breccia silicocarbonatite d i k e (sample Lem 5 0 0 ) . P e n c i l is a p p r o x i m a t e l y 20 cm. long. PL. 26: P h o t o m i c r o g r a p h ( 2 5 x , cross-polars) of a s o v i t e o r rauhaugite vein crosscutting a replacement carbonatite. The vein PL. 27: is 0.7mm thick. Breccia silicocarbonatite dike (brown) crosscutting diorite/gabbro (lighter gray) and mafic dike (darker gray, fine-grained). a I”--) 0.3mm X e n o l i t hvsa r y i n s i zf er o m a mm. few to a meter a c r oXs es n o l i tihnsc l ufdr ea g m etn hohtofreso s tc k , f o l i a t e gd r a n i t e sf ,o l i a t e adr k o s e sq, u a r t z i t e sg, r a ayn d g r e esnc h i s pt ,h y l l i t e sa ,nrdegdr a n i t if ce n i t e s . g r a n i t i cx e n o l i t h sh a v e texture as Some s i m i l a r a p p e a r a n c e ,c o m p o s i t i o n ,a n d t hPeo l v a d e rG a r a n . i t ew, h i loet h e rhsa v e , b e e n completely o r p a r t i a l l y altered to a f e n i tceo m p o s eodf l i t t l e qnouora ra tnzd K - f e l d s paabnrido t iwt ei t h as a p l a g i o c l a s e .T h ex e n o l i t h sa r eo f t e nr o u n d e d ,p o s s i b l y r e s u lotcf h e m i c arle a c t i o nw s i t thh ce a r b o n a t i t fel u i d s a n d / o r a s a r e s u lot cf o l l u s i . o n w s ith each o t h e ar n d the s u r r o u n d i n g wall rock. C a r b o n a t i dt ei k w e si t h o xu et n o l i t h c asbf n ue r t h e r g r o u p e da c c o r d i n gt om i n e r a l o g i c a lc o m p o s i t i o n : ( 1 )f i n e - g r a i n e dd o l o m i t i ct oc a l c i t i c s i l i c o c a r b o n a t i t ed i k e s (2) a n k e r i t i rc a u h a u g i t d eikes (3) s o v i t ea n dr a u h a u g i t ev e i n s ( < 5 cm. t h i c k ) B o t hp r i m a r ym a g m a t i ca n dr e p l a c e m e n tt y p e sa r ef o u n dw i t h i n t h i ns e c t i o n so ft h ev a r i o u sg r o u p i n g s . F i n e - g r a i n eddo l o m i t itccoa l c i t isci l i c o c a r b o n a t i t e dikes are lighto g r a yB . o t hp r i m a r ym a g m a t i c in m e d i u m - g r a yw, e a t h e r i ntgo a brownish a n d r e p l a c e m e n tv a r i e t i e so c c u r b o t thy p e sO. f t e fni n e - g r a i n e sdi l i c o c a r b o n a t i tde i k e s Page 96 g r a di n e tmoa f d i ci k e s . One of occurrence d o l o m i t it co '7) c o n t a i n e d small c a l c i t isci l i c o c a r b o n a t i tde i k e(ss e c . v e i n so fm e g a s c o p i cp u r p l ef l u o r i t ea n ds u l f i d em i n e r a l s . A n k e rriat u i ch a u d g ick treeo ss sf ci nu et - g r a i n e d 28 a n d 2 9 ) . s i l i c o c a r b o n a t i t de i k e(sp l . l i gbhrto w n and consist of These d i k e s a r e a n k e r i t ce a, l c i t be a, r i t e , d o l o m i thee,m a t i taem n,da g n e t i tTeh. edsiekceosm m o n l y 6. o c c u r i n a n d n o r t ho fs e c . T sh oi nvari n .t aedu h a u gvi et cei n r os s s o c tuht e r c a r b o n a t i t ed i k e sL. a r g e sr o v i t ev e i n (s u pt os e v e r a l t h i c k )o f t e nf o l l o wp r e - e x i s t i n gf r a c t u r e s d i k ea snsdo m e are mm. or e a r l i e r. m a f i c h i g h lrya d i o a c t i v(eutp 1o0t0i m e s backgroM u nidc )r .o s c o p ircasaao ulnv hl dy iat,ueg i t e v e i n l e tcsr o s s c ut h t cea r b o n a t i t e m a t r i x , x e n o l i t h as n , d p h e n o c r y s t s .C l e a r l yt h e s ev e i n l e t sr e p r e s e n t a l a t e rs t a g e o fc a r b o n a t i t ei n t r u s i o n . T h i n l, i g h b t r o w nd i k e l e t so rv e i n s fill s y s t e tm iP hnso e l v a d eG r ar a n i tfeo,r m i n g p a t t e r n (Map 1 ) . the fracture a stockwork C a r b o n a t i t ef l u i d sa p p a r e n t l yi n t r u d e dt h e g r a n i t ea n df o l l o w e dp r e - e x i s t i n gf r a c t u r eo rs h a t t e rz o n e s . T h e s ev e i n sc o n s i s to fb a r i t e ,c a l c i t e ,d o l o m i t e ,a n k e r i t e , and h e m a t i t eO . r i g i n a gl r a n i t i ct e x t u r e as n dm i n e r a l as r e o pf tr ee ns e r v F ee dl d. s p hbpaearversent ioa rl l y c o m p l e t e rl y e p l a c ebcdya r b o n a tT e .h e smei c ah sa vbee e n 8 PL. 28: F i n e - g r a i n e dd o l o m i t i cs i l i c o c a r b o n a t i t ed i k e (sample Lem 5 3 0 ) c u t b y a n k e r i t i c r a u h a u g i t e d i k e s( s a m p l e Lem 531A a n d B ) . approximately thirty PL. 29: Pistol is cm. . l o n g . F i n e - g r a i n e d o l o m i t i sc i l i c o c a r b o n a t i t de i k e c u tb ya n k e r i t i cr a u h a u g i t ed i k e s .P e n c i l . a p p r o x i m a t e l y 20 cm. long. is l e f t i n t a c st ,u g g e s t i nlgo twe m p e r a t u r e s at t htei moef is difficulto replacement. T haegoetfhL e e m i t acra r b o n a t i t e s d e t e r m i n eT. e r t i a r fya u l ttsr u n c a t teh ce a r b o n a t i t de i k e s 6 (Map 1) i n d i c a t i n tgh at thcea r b o n a t i t ews e r e isne c . e mTpelrptaftorciaiaeuordlryF t iunrgt .h e r m o r e , c a r b o n a t i t e sh a v en o b t e e nf o u n d i n a n yr o c k sy o u n g e rt h a n P r tehcea m b( pr iear nsr oe n co a ln n a i s saanndc e R.M. Chamberlin p ,e r s o n ac lo m m u n i c a t i o nT ) .hcea r b o n a t i t e s a P e n n s y l v a n i a nf a u l t( s e c . h a v eb e e nf a u l t e db y may 7 , Map l), s u g g e s t i n g a p r e - P e n n s l y v a n i a na g e . Geochemistry A r e p r e s e n t a t i vseu i tosefa m p l ef sr o tmhvea r i o u s c a r b o n a t i t ed i k e s (Appendix C ) . was a n a l y z e df o rm a j o ra n dm i n o re l e m e n t s A s c i n t i l l a t i ocno u n t e r was n oa tv a i l a b l e d u r i nt ghsea m p l i npge r i o dt h; e r e f o r et h,sea m p l ews e r e c o l l e c twe idt h oakunntyo w l e td ro hagfede i o a c t i v i t y content. A f e w o f t h ec a r b o n a t i t e sh a v em a j o re l e m e n to x i d e sums l e s st h a n 100%. T h ed i f f e r e n c ec a nb ea c c o u n t e df o rb y n u m e r o u so t h e re l e m e n t st h a tw e r en o td e t e r m i n e d . T h ec a r b o n a t i t ed i k e s on f a l l i n t ot w op o p u l a t i o n sb a s e d 9). i r o nc o n t e n (t t a b l e i s due The h i g h e irr o n content t tohpe r e s e n coeafn k e r i taen hd e m a t i t eT. hhe i g ihr o n in c a r b o n a t i tdei k easrneo t c a r b o n a t i t ed i k e s , c o n t a cwt i tthhl eo iwr o n s o t h ee x a c ta g er e l a t i o n s h i p i s unknown. H o w e v eerv, i d e n fcreoom t hleorc a l i t iiensd i c a ttehsa t a n k e r i t e i s o n oetfh e l a s t c a r b o n a t e ts of o r m( e x a m p l e s : E a s t eSr na y M a no u n t a i n s , Iron H i l l , U.S.S.R.; 1966). M o u n tPa aiCnsas l, i f o r nHi ae ;i n r i c h , c a l c i ucm ontent of L e m i t aP r r e c a m b r i a nr o c k s c a r b o n a t i t e sh a v e Colorado; h Tihgeh t hc ea r b o n a t i t er es l a t i vtoo et h e r 13.. The as w e l l ( t a b l e 9). i s q u i t eo b v i o u si nf i g . a h i g hv o l a t i l ec o n t e n t Iannpya r t i c u l ao rc c u r r e n c tehc, ea r b o n a t i t ea sr e q u i t eh e t e r o g e n e o u m s i n e r a l o g i c a l l ya n dc h e m i c a l l y . t h i sh e t e r o g e n e i t y ,n o r m a lv a r i a t i o nd i a g r a m s Due t o commonly used it nhset u doiyg f n e o ur so c kasrneov te ruys e f u l . v a r i a t i o nd i a g r a mh a sb e e n ' u s e db y A Dawson ( 1 9 6 7 ) t o show t h e c h e m i c a lr e l a t i o n s h i pb e t w e e nc a r b o n a t i t e sa n dk i m b e r l i t e s . A plot of n u m e r ocuhse m i ca anla l ycsoaefrsb o n a t i t e s t h r o u g h o utth e world (misc. d a t a c o m p i l e db yt h ea u t h o r ) , d e f i n e s a c a r b o n a t i t ef i e l d ,w h i c ho v e r l i e st h ea r e ab e t w e e n a n dw i t h i nt h ek i m b e r l i t ea n dm a f i cc a r b o n a t i t ef i e l d s . Lemitar s a m p l e sf a l ln i c e l yw i t h i nt h i sf i e l d( f i g . The 14). FIGURE 14: CHEMICAL PLOTSHOWlNO RELATIMISHIPBETWEEN \ AND GRANITES SOLID CARBONATITES, KIMBERLITES, LINESREPRESENTFIELDSDETERUINED BY DAWSON, 1967 DASHED LINE REPRESENTS FIELD DETERMINED BY AUTHOR FROM MISC. ANALYSES 0 5 0 ) OF CARBONATITES FROU THRCUOHOUT THE WRLD 0 Page 1 0 1 L T ehm e ci at ar rb o ncaotbcm ietaepnsawr ietdh 9 H e i n r i c ha 'vse r acgaer b o n a t i( tt ea b l e similar L e m i t a cr a r b o n a t i t e as r eg r o s s l y as 10). The t ot h i sa v e r a g e . a n a v e r a g e of a n a l y s e s T h ae v e r a g ce a r b o n a t i t re e p r e s e n t s w i t hrao eng uyat r d and l otcoa t im on i n, e r a l oogry , h e t e r o g e n e i t yo tf h ec a r b o n a t i t e sT . h ea v e r a g ec a r b o n a t i t e reflect dn oo e st in et hxet r ehmeet e r o g e n efi ot yu n d general c a r b o n a t i t iens a aenvdw en ithin particular locality. Tdhies t r i b u t m iooafnjaom nrdi neol re m e n t s in c a r b o n a t it e s h a v e b e e ne x a m i n e db ys e v e r a al u t h o r s( t a b l e 1 4 , O l s o ne,t . 1954; a1 1963; aB n lda d e , d i f f e r e n c e si n 1966; Heinrich, it e s a m o u n t s of c a l c i t e , 1954; Barber, C a O , MgO, a n d t o t a il r o n M o u n t acianr b o n a t 15). al., R u s s eel t, among Erickson 1974). the The Lemitar p r o b a b l yr e f l e c dt i f f e r e n c e si nt h e d o l o m i t e ,a n k e r i t e ,a n dm a g n e t i t e( t a b l e K20 e x c e e d s Na20 i n a l l b u to n es a m p l e ,r e f l e c t i n gt h e d o m i n a nm o c efi ac n aKd- f e l d s poa vr pe lra g i o c l a sTe h .e i s r e f l e c t e db yt h ea m o u n o t fP 2 0 5a n d p r e s e n c eo fa p a t i t e H20 ( i n c l u d e s F a n d C1). carbonate minerals and (Heinrich, c o n s t i t u e n t o f b a r i t e( t a b l e 550a36n0, d, Ba 531a). a c c o u n tf o rt h ed i f f e r e n c e s Sarrfeo u nid ena r l y 1966). Ba i s a l s o a major 15, samples Differences in Lem 4 2 7aanbd, m i n e r a l owgoyu l d i n c h e m i c a cl o m p o s i t i o nb e t w e e n P a g e1 0 2 TABLE 14 DISTRIBUTION OF ELEMENTS I N CARBONATITES OXIDEIELEMENT DISTRIBUTION Si02 Ti02 A1203 F e 2 0 3 , FeO MgO, C a O Na20, IC20 MnO Sr Ba U P205 H20, F , C 1 C r , N i , Co cu q u a r t z f, e l d s p a r m a g n e t i t e ,s p h e n e ,g a r n e t ,p y r o c h l o r e , micas feldspar m a g n e t i t e ,a n k e r i t e ,h . e m a t i t e c a r b o n a t e s ,m a g n e t i t e (MgO) m i c a s ,f e l d s p a r c a r b o n a t e s ,a p a t i t e c a r b o n a t e s ,a p a t i t e c a r b o n a t e s ,a p a t i t e ,b a r i t e a p a t i t e ,z i r c o n ,p y r o c h l o r e ,s p h e n e ,f l u o r i t e apatite m i c a ,a p a t i t e ,f l u o r i t e ,b a s t n a e s i t e p y r i t e ,m a g n e t i t e ,a p a t i t e p y r i t e ,c a l c i t e ,n i a g n e t i t e m a g n e t i t e ,c a l c i t e phlogopite Zn Li R e f e r e n c e s :O l s o n e, t E r i c k s o na n dB l a d e , a l . , 1 9 5 4 ; R u s s e l l ,e t 1963; R e i n r i c h , 1966 al., 1954; TABLE 1 5 MINERALOGY OF THE LEMITAR CARBONATITES BY X-ray 427a 3M 0 5i n e r a l 531a 4 255 75 00 b3 060 Biotite X X X Chlorite X X X quartz X X X fluorite X X calcite X X dolomite X X X X X X X X X X X X .x X X X X X X X X X X X X X X apatite X X X X X X magnetite X X X X X X X' X bastnaesite x - present 531b X ankerite barite DIFFRACTION X X X X Page 104 Mountain t hLe e m i t a r c a r b o n a t i t easnodt h ecra r b o n a t i t e s t h r o u g h o u tt h ew o r l d . Fenitization F e n i t i z a t i o n i s t h ea l k a l im e t a s o m a t i c 'r e p l a c e m e n t 'o f c o u n t r ryo c kgs e n e r a l l ays s o c i a t e w d i t thhien t r u s i o on f c a r b o n aatlioktreac sloi m c p l e xReosw c. khhsi ac vh e u n d e r cgoom n epml e t ae s o mr ea pt ilca caeram enedn t a s s o c i a t e dw i t ha l k a l i n t r u s i o n sh a v eb e e nt e r m e df e n i t e s (Heinrich, 1966). r e c o g n i z e d( t a b l e 16). a n dp o t a s s i u m( n o r m a l Two p r o c efseosnfeist i z a t ai or en One i n v o l v e st h ea d d i t i o n of sodium or s o d i cf e n i t i z a t i o n ) ,a n dt h eo t h e r i n v oaltdvhdeeist i o n of p o t a s so(i u n pm loyt a s s i c fenitization). is Norm sooardfl iecn i t i z a t i o n tm ho est common alterap t iroonca es s so c icaw tathrieetbdho n a t i t e as i n t r u s i v e is nt h eL e m i t a M r ountains, later. b ed i s c u s s e d w i l l Some p o t a s s i u mh a sb e e na d d e dt ot h ed i o r i t e l g a b b r o i nt h ef o r mo fK - f e l d s p a r ,b u tt h i sa d d i t i o n i s minor. Some r e dg r a n i t i cf e n i t e s ,c o n s i s t i n go fm i c r o c l i n ea n db i o t i t e w i t hl i t t l eo rn oq u a r t z ,o c c u r m a ni dc r o b r e csci il ai c o c a r b o n a d t iiteakex ne h ds i b i t p o t a s s i cf e n i t i z a t i o n . a s x e n o l i t h sw i t h i nb r e c c i a Page 105 TABLE 1 6 CLASSIFICATION OF FENITES ( a f t e r V a r t i a i na n dW o o l l e y , 1976) EXAMPLE FENITE TYPE FEATURES NORMAL or SODIC FENITIZATION Na a n d K a d d e d , a l k a l ip y r o x e n e s a n d amphiboles s t r o n g l ys o d i c S o k l i ,F i n l a n d I n t e r m e d i a t eT y p e m a j o r Na a n d K A l n oS , weden P o t a s s i ct y p e major K , Amba D o n g a r ,I n d i a Sodic .Type - K a d d e d ,n o alkali pyroxenes o r a m p h i b o l e s ,o f t e n phlogopite POTASSIC FENITIZATION Ptoytpaes s i c m i n o r Na UB g aKk nu dosau n ,l y Late Stage F e n i t iszuaptei roinm on posed K fenitization n o r m a lf e n i t i z a t i o n C h i l w aI s l a n d , Nyasaland (Africa) S o k l i ,F i n l a n d P a g e1 0 6 A t h i nz o n eo sf o d i cf e n i t i z a t i o n some is developea dl o n g c a r b o n a t i t ed i k e si nt h ed i o r i t e l g a b b r o T . h i sz o n e is n ost e e n e v e r y w h e r eb, uat p p e a r tso b re e s t r i c t e d to the w e s t e r ns i d e so ft h et h i c k e r T hzeo n e i s t w o t o t e n cm. l a r g( u et o p 60 mm. characterized by di ina m e t e ro)r,a n g e - p i an lkb i t e is is and is t h i c ka n d c r y s t a lTs .hr e d d i sc ho l o r occurrences m e t e r c) a r b o n a t i t ed i k e s . ((1 to common o t h ef er n i t e t h o u g hthtoa vbee epnr o d u c ebdtyh e of i r o n m o l e c u l e s o r i g i n a l l y w i t h i n o x i d a t i o na n de x s o l u t i o n 1948, p. t hf e l d s p al ar t t i c( ev oEnc k e r m a n n , o x i d a t i o n i s b e l i e v e dt ob e 2 9T)h. e a r e s u l ot tf h ed e g a s s i n g of c a r b o nd i o x i d ef r o mt h ec a r b o n a t i t ei n t r u s i v e . an T hpel a g i o c l a sceo m p o s i t i orne f l e c t s s o d i u mb yt h ec h a n g ef r o m An40 - increase An50 t o A n 5 - in An15. The f e n i t i z e dd i o r i t e / g a b b r oa p p e a r sa l s ot oi n c r e a s es l i g h t l y i nq u a r t za n dp e r t h i t i cK - f e l d s p a rc o n t e n t . o ff e n i t i z a t i o n i nS o u t h i s r e p o r t e df r o mt h e A similar t y p e Messum c a r b o n a t i t e v e i n W e sA t f r i c aF. o usr t a g e osffe n i t i z a t i o n can be distinguished at t h il so c a l i t( yionr d eoi rn f creasing f e n i t i z a t i o n ,V e r w o e r d , (1) 1966): i n c r e a s e i n a l b i t ec o n t e n t ( 2 )i n t r o d u c t i o no fp e r t h i t i cK - f e l d s p a r (3) i n t r o d u c t i o no fn e p h e l i n er e p l a c i n gp l a g i o c l a s e w i t ha c c e s s o r ys o d a l i t ea n da n a l c i t e P a g e1 0 7 (4) i n c r e a s eo fo r t h o c l a s e n , e p h e l i n e a, n d ferrohastingsite F e n i t i z a t i o no ft h eL e m i t a rd i o r i t e l g a b b r oa p p e a r st oh a v e p r o g r e s s e d as f a r as s t a g e 2 of t h i s s e q u e n c e . Two s a m p l e s o f t h fee n i t i z e d i o r i t e / g a b b r (os a m p l e s Lem 5 3 3 , A p p e n d i x B ) w e r ea n a l y z e d 5 3 2a n d for e i g h tm a j o r e l e m eatm nw ntid soenloerm e(nAt sp p e n d i x p r e l i m i n a r ys t u d i e s a C). show a s i g n i f i c a n ti n c r e a s e s i g n i f i c a dn et c r e a s e in 15). s a m p l e( sf i g . i n t a b l e 17. CaO compared u t on f e n i t i z e d T h e sceh e m i c ac lh a n g easrceo n s i s t e nwt i t h as seen at S o kFl i n , land 1976). ( V a r t i a i na n dW o o l l e y , i n Na20 i s r e f l e c t e db yt h ec o n v e r s i o no f T h ei n c r e a s e a n d e s i n ae n d l a b o r a d i o r i t teo a l b i t ae n d increase i n Na20 a n d O t h ec rh e m i c ca h l a n g ea srs eu m m a r i z e d n o r ms o a ldf ei cn i t i z a t i o n r e l a t e dt o may b d eirectly l o s s of s o d i u mb yt h ea d j a c e n ct a r b o n a t i t e T . he in Na20 is a l sr oe f l e c t ebdy n o r m a t i v ea l b i t e( A p p e n d i x of t toh feo r m a t i o n C). an i n c r e a si e n The l o s s o f C a O may t h i cn a l c i t ve e i n cs r o s s c u t t i n tgh e d i o r i t e / g a b b r iotnh ve i c i n i t oytfh ce a r b o n a t i t de i k e s . Some CaO F e 2 0 3 may Similar These may be m i g r a ttteohcea r b o n a t i tdei k eT. i 0a2n d loss chemical t ohcer o s s c u t t i nhge m a t i tvee i n s . trends t h r o u g h o u tt h ew o r l d( t a b l e are 16). r e p o r t ef rdocm arbonatites bde u e FIGURE 15: C&-Na20-K20 FENIT1ZATION PLOT OF THEEFFECT ON OF THE LEYITARDIWITWGAQBRO,TRENDS REPORTED BY VERWOERD, IS66 FROM BASALT AND OAEBRO NEAR THE MESSUM CbRBONATITE,SOUTHWESTAFRICA TABLE 17 SUMMARY OF CHEMICAL CHANGES OF THE LEMITAR DIORITEIGABBRO D U E TO FENITIZATION Significant increase Na20 Significant decrease CaO Slight increase A1203, MgO Slight decrease Ti02, Fe203 No significant trend Si02, K20, Rb, S r P a g e1 1 0 TABLE 18 CHEMICAL TRENDS OF , FENITIZED MAFIC ROCKS COMPLEX FENITIZED ROCKS REF. LOSSES GAINS Messum, b a s a ldt o, l e r i t e , gabbro S.W. Africa Na, A l , K B r emi v F e itek a, g b ao bt nb,r o Norway Mu K h i b i n a ; - K odl iaa b a s e S o v i e tU n i o n M b o z i , S.W. Tanzania gabbro Blu Meo u n t a ianm , phibolite Ontario Callander Bay, a m p h iOb no tl ai tr ei o 2 3 4 - Na, K, Si K, V e r w o e r d , 1966 R o b i n sa n dT y s s e l a n d , 1979 C u r r i e a n dF e r g u s o n ,1 9 7 2 T h i s report Al, Na, A 1 g a r nSei t, L e m i t da ir o, r i t e / g a b b r o New Mexico 1 K , Na, Mg, Fe, A l , T i f o l l o w e db y K , Na, A l , Si Al, S i , Ca, 1 A1 2 Ca, S i 2 Ca, Mg, F e Ti Ca, Mg, F e , 2 . . Ti Ca, Na, Fe Mg, F e 2 T i , Mg, C a 3 K Na, Al, Mg Ca, T i , Fe ' 4 P a g e 111 , F e n i tan earsoel tw apyrso d u ctL ih ened m i t a r diorite/gabbro when a d j a c cetanort b o n a t idtiek e s . At a s o v i t de i k ien t r u d e gs a b b r o , M a g n eHt e i g h t sT, r a n s v a a l , m a g n e t i taean,ldb i t iwt eiantpohp a r efne tn i t i z a t i o n (Verwoerd, 1966). a l t e r e dt o a n h o r n b l e n d i t e b yg a s e o u s Fenitization is also a t S o k l i ,F i n l a n d( V a r t i a i n e n a b s e n tw i t h i nt h ea m p h i b o l i t e 1976). g a b b rhoabse e n H20 a n d C02 e r u p t i n g 1966). f r o mt h ec a r b o n a t i t e( V e r w o e r d , a nW doolley, a A t S t j e r n o yN, o r w a y , Fenitization in p o o r ldye v e l o p e d is c o u n rt or ycs k u sr r o u n d iS tn hi g ei l i n j a cr av ri b o n a t i t e is c o m p l eFxi ,n l a nadn,d c h a r a c t e r i z lbeiy dgghrte e n 1969). a l k a l i - a m p h i b o l e sa n db l u i s hq u a r t z( P u u s t i n e n , T h ea p p a r e n tl a c ko fe v i d e n c ef o rf e n i t i z a t i o no ft h e Lemitar diorite/gabbro c o m b i n a t i o no ft h e s e is probably a reso u fl t some factors: s t a b i l i t y of h o r n b l e n d e (resists f e n i t i z a t i o n ) l a c ko fc o n d u i t sf o rf e n i t i z i n gf l u i d s i n s u f f i c i e n tv o l a t i l ec o n t e n t (H20, C02) o ft h e carbonatitetoinitiatefenitization i n s u f f i c i e n tp r e s s u r e sa n dt e m p e r a t u r e so ft h e c a r b o n a t i t e st oi n i t i a t ef e n i t i z a t i o n c o m p o s i t i o no ft h e Lemitar d i o r i t e / g a b b r o i s incompatiblewithfenitization q u i c kc o o l i n g a n d c r y s t a l l i z a t i o n of t h e P a g e 112 c a r b o n a t i t ed i k e s ,a l l o w i n gi n s u f f i c i e n tt i m e forfenitizationtooccur (7) d i s t a n c e f r o m t h es o u r c eo ft h ec a r b o n a t i t e dikes is great. V a r t i a i n e na n dW o o l l e y( 1 9 7 6 )s u g g e s t fenltes at resists a l t e r a t i oanntdhlea cokf as f r a c t u r ae n sv de i n l e tw s ,h i ca hc t f e n i t i z i n gf l u i d s T . his of may b e a r e s u l to ft h es t a b i l i t y S o k l i ,F i n l a n d o h fo r n b l e n dweh i c h t h a t t h el a c k a p a ft h o t hr e may p a r t i a l l ye x p l a i nt h el a c ko f f e n i ttieh L nsee m i t M a ro u n t a i nFs e. n i t i z a t i tohnf e c o u n t r yr o c k i s d e p e n d e n to nv o l a t i l ec o n t e n t ,p r e s s u r e ,a n d t e m p e r a t u r oetfh ce a r b o n a t i t e ; g r e a te n o u g h ,f e n i t i z a t i o n i f t h e s fea c t o r as r ne o t , may n o to c c u r , a s i nt h eL e m i t a r M o u n t a i n sU. n f o r t u n a t e l ye,x p e r i m e n t aelv i d e n c e t os u b s t a n t i a t et h i st h e o r y . rock is lacking T h ec o m p o s i t i o no ft h ec o u n t r y a f f e c t s t h ef e n i t i z a t i o np r o c e s s .T h el a c ko f alkalis effects w o u l dp a r t i a l l ye x p l a i nt h ea b s e n c eo ff e n i t i z a t i o n ( V e r w o e r d , 19661, a n d it h a s a l r e a d y b e e n m e n t i o n e d t h a t t h e s t a b i l i t y o f h o r n b l e n d e i s s u c h a s t or e s i s tf e n i t i z a t i o n . If t h ec a r b o n a t i t ed i k e sc o o la n dc r y s t a l l i z eq u i c k l y ,t h e t e m p e r a t u r ea n dp r e s s u r ew o u l dd r o p time off, n o ta l l o w i n ge n o u g h f ofre n i t i z a t i o tntoa k pe l a c eF. u r t h e r m o r e , as t h e d i s t a nf cr tcoehamer b o n a tsi ot eu rbceec o ml ae rs g e r , f e n i t i z a t i o nb e c o m e sl e s sp r o n o u n c e d T . his was o b s e r v e d a t P a g e 113 19481, a n d A l n oS,w e d e(nv oEnc k e r m a n n , may be a primary r e a s o nf o rt h el a c ko ff e n i t e si nt h eL e m i t a rM o u n t a i n s . in T heef f e c tofsfe n i t i z a t i ohna vbee em n inor P o l v a d eG r ar a n i t e and t hs e d i m e n t s . c a r b o n a t ev e i n sa r ep r e s e n ta n d stages of the Some h e m a t iat en d may b e r e l a t e d t o t h e e a r l y a n i n c r e a siepn l a g i o c l a s e f e n i t i z a t i o nO. f t e n a n dK - f e l d s p a rc a nb ed e t e c t e di nt h er o c k sa d j a c e n tt ot h e c a r b o n a t idtiek eTsPh. oe l v a d eGr ar a n iotfetbe enc o m e s b r e c c i a t ea dnf d r a c t u r e fdo, r m i nogn v l ye i n l e o tt hsf e * c a r b o n a t i t e a n d c r e a t e s a s t o c k w o r kp a t t e r n . at o f ef n i t i z a t i oonc c u r s Callander Bay., C a n a dwah, e r e a s f o l l o w s( C u r r i e f e n i t i z a t i o no fg r a n i t i cr o c k sp r o g r e s s e s a n dF e r g u s o n , A similar t y p e 1971): (1) h e m a t i t ev e i n s (first stage) (2) i n c r e a s e i n t h eo r d e r i n go fK - f e l d s p a r (3) p l a g i o c l a s ec o n v e r t e dt oa l b i t e (4) K - f e l d s p a rc o n v e r t e dt o p y r o x e n e sb e c o m ea b u n d a n t plus c a l c i t e maximum m i c r o c l i n e , (final stage). T h ep r e s e n c eo fh e m a t i t e - c a r b o n a t ev e i n sa n dt h ei n c r e a s e p l a g i o c l a s ea n dK - f e l d s p a rc o n t e n t s i n t h eL e m i t a rg r a n i t e s a n ds e d i m e n t si n d i c a t e st h a tf e n i t i z a t i o nh a so c c u r r e d ,b u t h a sp r o g r e s s e do n l yt o first stage. in Page m i l l i m e t e r s ) h e m a t i t ev e i n so c c u rw i t h i n T h i n( s e v e r a l as c o a t i n g as l o n fgr a c t u r ae n d t hP e r e c a m b r i a rno c k as n d j o i n st u r f a c e s . 114 a r e o f t e dn i s c o n t i n u o uw s ith T hvee i n s l a t e r a le x t e n to fa b o u t a meter. a I n t h i ns e c t i o n ,h e m a t i t e o f t e n o c c u r sa r o u n dc o r r o d e dm a g n e t i t ea n db i o t i t ec r y s t a l s . T h em a j o r i t yo ft h i st y p eo fa l t e r a t i o n i s a r e s u l t of t h e w e a t h e r i no i rgfo n - r i cmhi n e r a las l, t h o u g h some may be r e l a t eo to dx i d a t i opnr o d u c ebtdh ydee g a s s i no tg hf e c a r b o n a t i t ei n t r u s i v e . Origin T h ec a r b o n a t i t ed i k e sw e r ep r o b a b l ye m p l a c e d a t a great as d i s t a n c( el a t e r a l lovyre r t i c a l l yf r) o tm hs eo u r c e , e v i d e n c e db y : ( 1 )t h el a c k o f a n yr a d i a l o r c o n i c a lp a t t e r n si n t h ed i k eo u t c r o p , (2) t h el a c ko ff e n i t i z e dh a l o e sa b o u tt h ed i k e s (3) t h e common o c c u r r e n c eo fr e p l a c e m e n t - t y p e c a r b o n a t i t ed i k e s (4) t h el a c k o f c a r b o n a t i t ed i k e si nt h es o u t h e r n p o r t i o no ft h ea r e a . .Page 115 is O n l yo n eo t h e or c c u r r e n c eo cf a r b o n a t i t e s from New 1961). M e x i c o l, o c a t e d T h i sc a r b o n a t i t e i n t h e M o n t eL a r g o reported area (Lambert, i s a m a s s i v ed o l o m i t i c a r b o n a t i t e . d i kw e i t ah p a t i t em , a g n e t i t ea, n m d i c aO . t h eor c c u r r e n c e s co af r b o n a t i t ae frs oe u na ds s o c i a t ewdi t ha el k a l i c 1966). c o m p l e x e s i n s o u t h e r nC o l o r a d o( H e i n r i c h , i s 520 m.y. t h ce a r b o n a t i t eisC n olorado T h ea g eo f et (Olson, al., 1977). are Carbonatites g e n e r a l al ys s o c i a t ewdi at hl k a l i c 1966). i n t r u s(iH v e si n r i c h , i n New Mexico. i n c l u d et h eP a j a r i t oM o u n t a i n P r e c a m b r i a na g e 1 9 6 8 ) a n dt h eF l o r i d aM o u n t a i n s y e n i t e( 1 1 7 0m . y .K , elley, s y e n i t e( 4 2 0 - 7 0 0m . y .B , rookins, Lemitar 1974). T h i se v i d e n c e a n a l k a l i icg n e o u ps r o v i n c o eccurring b se u g g e s t i v o ef C o l o r a da on d A l ki an lt ir cu soi fv e s New M e x i b ce ot w e e n 1100 a4 n2 d0 may in m.y. The M o u n t ac ianr b o n a t i tweosptubo h alerfidst postulatedprovince. C a r b o na n do x y g e ni s o t o p es t u d i e si nt h e Wet Mountain c a r b o n a t i t ec o m p l e x C , o l o r a d o c, l e a r l yi n d i c a t et h a tt h o s e c a r b o n a t i t e sa r ef r o m 1979). a d e e p - s e a t e ds o u r c e( A r m b r u s t m a c h e r , O t h ecr a r b o no, x y g e ns, u l f u ra, n d strontium isotope s t u d i e sa l s oi n d i c a t e a d e e p - s e a t e do ru p p e rm a n t l es o u r c e 1965; f oc ra r b o n a t i t e( H s ayatsu e t, . a l . , 1966; Heinrich, 1966; Taylor, et.al, 1967; P o w e lel t, . a l . , Suwa, et.al., Page 116 1975; 1975). . M i t c h e lal n K d rouse, isotopevidence, in i t i s p r o b a b l et h a tt h ec a r b o n a t i t e s a l s o a r ed e r i v e df r o m t h eL e m i t a rM o u n t a i n s It um p pasenortul re c e . carbonatites W i t thh ias b u n d a n c oe f is a d e e p - s e a t e do r c o n c e i v tat hhbeal et o f t h eL e m i t a rM o u n t a i n s may b ed e r i v e df r o m a m a f isco u r cw e h i c gh a vrei stetohm e a f idc i k easn tdh e d i o r i t e / g a b b r o ,a l t h o u g hp r e l i m i n a r yc h e m i c a ls t u d i e sa p p e a r trends. e xthnocaiohb nteiytm i c a l An extensive g e o c h e m i c a lni ds o t o p isct u dotyh fLee m i t aMr o u n t a i n s c a r b o n a t i t e sw o u l dh a v et ob ec o n d u c t e db e f o r ec o n s t r a i n t s on t h e c o m p o s i t i o n o f t h e s o u r c e c o u l d b e a c h i e v e d . E x p e r i m e n et avli d e nccoen f i r tmhmsaet w l t ist h a in v a r i e toycfo m p o s i t i o ncsapnr o d u ctehw e i dvea r i a n c e in m i n e r a l o gayncdh e m i s t rsye e n carbonatites Lemitar ti h ne t e m p e r a t u r e so f from 1 - 1971). Watk aW n i ndy l l i e , s u g g e s t st h a tc a r b o n a t i t e s , Mountains, 450 - Tehvei d e n c e s i m i l a r i n c o m p o s i t i o nt ot h o s e may 600 degrees 1000 b a r s( H e i n r i c h , to 1966; t h ofsoeutL in hned m i tM a ro u n t a i(nHs e i n r i c h , W y l l i e , 1.966; similar h abveeem np l a c e d C. 1966). a n dp r e s s u r e sr a n g i n g at P a g e 117 STRUCTURE AND METAMORPHISM INTRODUCTION T h eL e m i t a M r o u n t a i n sl i eo nt h ew e s t e r ne d g eo tf h e R iG o r a n dge r a b e nw, h e rne o r m afla u l ths a vue p l i f t e da'n d Perxetpchoam esmerTbto dh arcm iekason.r p h o s e d P r e c a m b r ri ao nc k s are s t r u c t u r a cl loym p l eFxo.l i a t i o n , of f a u l st sh,e a r i nagbn,rde c c i a t i omn o, s t which are L a r a m i d ea n dT e r t i a r ys t r u c t u r e sa, f f e c t e dt h eP r e c a m b r i a n r o c kTd sh.ief f i c ui lintntye r p r e t itn Phg ree c a m b r i a n s t r u c t u r e i s i n d i f f e r e n t i a t i n gy o u n g e rc o m p l e xf a u l t i n ga n d s h e a r i n gf r o mt h a to ft h eP r e c a m b r i a n . T h eP r e c a m b r i a nr o c k sh a v eu n d e r g o n es u c c e s s i v ep e r i o d s mineral mo ef t a m o r p h i sm ma, k itn ihdgee n t i f i c a t ioofn a s s o c i a t i o nd si f f i c u lTt .hr o e c ka sar el sa of f e c t ebdy as r e t r o g r am d e t a m o r p h i s smu,c h b i o t i t ea n dt h es e r i c i t i z a t i o n m e t a s o m a t i s ms, u c h of t hc eh l o r i t i z a t i o n of f e l d s p a r s .T h ee f f e c t so f as c a r b o n a t i z a t i o na n dh e m a t i z a t i o n ,a r e s u p e r i m p o s eodv et rhm e e t a m o r p h ifca b r iicn d i c a t i ntgh a t m e t a m o r p h i s mo c c u r r e dp r i o tr oa l t e r a t i o n T . h ec o m p l i c a t e d s t r u c t u r at rl e n d s in the Lemitar Mountains s e v e r a lp e r i o d so fb u r i a la n du p l i f td u r i n gt h eL a r a m i d e T e r t i a r yo r o g e n i e s .C o n t a c tm e t a m o r p h i ce f f e c t sa r er a r e . may suggest and Page 118 METAMORPHISM Generally, the mineral assemblages of the Precambrian rocks in the Lemitar Mountains can be summarized as follows: quartz-muscovite quartz-muscovite-biotite-plagioclase-(garnet) quartz-biotite-potassium feldsparplagioclase-(garnet) blue-green hornblende-biotite-plagioclase-(garnet) quartz-biotite-muscovite-potassium feldspar- plagioclase These mineral assemblages represent the the greenschist amphibolite facies (low (medium grade grade between metamorphism)and metamorphism, the Winkler, Condie and Budding, 1979). 1976; Regional sediments. metamorphism The are consistent amphibolite of facies transition crystals completely mineral assemblages and gneissic with facies the upper greenschist of metamorphism; may possibly metamorphism. recrystallized The be presence amphibolite zone facies. foliation and lower undulatory extinction related to regional of trace amounts of garnet in some of the thin sections is suggestive of the transitional the. between the Well-preserved metamorphism to greenschist and lower foliated arkose Page 119 i n c l u s i o n sa r ef o u n ds c a t t e r e dt h r o u g h o u tt h ed i o r i t e l g a b b r o s u g g e s t i n gt h a t h i sp e r i o do fm e t a m o r p h i s mo c c u r r e dp r i o r ttehom e p l a c e m etoL hnfet m i tdairo r i t e / g a b b rToh. e f o l i a t i o nw i t h i nt h ea r k o s ei n c l u s i o n s i s r a n d o m l yo r i e n t e d . A t l e a s t o n eo t h e rp e r i o do fm e t a m o r p h i s mt h a ta f f e c t e d Lemitar t hCeo r k s c r e C wa n y osne q u e n cael saof f e c t et dh e d i o r i t e l g a b b r oa n dt h em a f i cd i k e s T . h ep r e s e n c eo fg a r n e t a n dt h et r a n s f o r m a t i o no fp y r o x e n e st oh o r n b l e n d e ,f o u n d in t h e Lemitar d i o r i t e l g a b b r o ,a r ei n d i c a t i v eo ft h et r a n s i t i o n b e t gwtreheeenn s caah mni pd sh t i b ogl ri atoedf e s metamorphio sm c c, u r r i n g after et h mep l a c e m t hoeefn t dioritelgabbro. I t i s d i f f i c u l tt od e t e r m i n ew h e t h e r t h e g r a n i t i cr o c k s h a v eu n d e r g o n em e t a m o r p h i s mF. o l i a t i o nw i t h i nt h eg r a n i t i c rocks is r a n d o molryi e n taelnd odc a l i zaendd may be p a r t i a l rl ey l a t tet h eodm e p l a c e m etonh gfter a n i t e s . M o r t atre x t u r eas r oe f t e pn r e s e n tb, utth e s teo o may be r e l a t e tdtoheem p l a c e m e not fhge r a n i t e sC. r o s s c u t t i n g m a f idci k ehsa vbee em n etamorphosed, as i n d i c a t eb d tyh e transform p yao rt h ofi oo x nrteo nn be lse cn ldeea,r l y indicating t h alto w gradm e etamorphism occurred e m p l a c e m e n to ft h em a f i cd i k e sa n dt h eg r a n i t e s . after the P a g e1 2 0 T chaer b o n a t i tperso b a bhl aybv e ue n a f f e c t be y d m e t a m o r p h i sdm ue ttohlea c k of a m e t a m o r p hfiacb r i c . M o r ttaerx t u r ae n u sd n d u l a t o er y x t i n c t i ofo nefsl d s p a r c r y s t a al sr p e ,r o b a b lr ye l a t et dohi en t r u s i o n of t h e c a r b o n a t i t ed i k e . FOLIATION Foliation i n C o rt hk C es casre ned ywiom nents a p p r o x i m a t e lp y a r a l l e lrse l i cbt e d d i n gR. e l i cbt e d d i n g d i s t i n g u i s fhrfeoodm liation by is c otalenoxdrt u r a l c o n t r a s t sT. hter e nodffo l i a t i oanl o nC gorkscrew Canyon 40 N40W t o N 4 0 E , w i t he a s t e r l yd i p os f r a n g efsr o m - 70 d e g r e e sR. e l i cct r o s s b e d d i n ag n gd r a d e bd e d d i n ign d i c a t e s t h a tt h es e q u e n c e i s p r e s e n t l yu p r i g h t ,y o u n g i n gt o w a r d st h e east. are V efreo yw utcrops exposed in foun bd etwee th snee d i m e n t s C o r k s c r e wC a n y o na n dt h ea r k o s ef r o mt h el o w e s t e x p o s e du n i it nt h es o u t h e r np o r t i o no ft h e 1). map area (Map If the T hfeo l i a t i oont fhaer k o spea r a l l e ltsheea s t - w e s t t r efon ofd l i a t tigihonene i s sgirca n i t e . sediments are s t i l l i n a n u p r i g h tp o s i t i o ni nt h es o u t h e r n p o r t i o n o f t h es t u d ya r e a t, h e nt h ea r k o s e sedimen x tp o s eTda hr.g iesel a t i o n s h i p is is t h eo l d e s t uncertain, P a g e1 2 1 well b e c a u spe r i m a r tye x t u r easrne o t may a r k o s ae n d faulting may this from t h e o f f s e t t h ae r k o s e i n C o r k s c r e wC a n y o n .T h ef o l i a t i o no ft h e s e d i m e n t se x p o s e d arkose have in preserved also be due to the intrusion o tf h e gneissic granite. A Tertiaryfaultcutsthegneissicgranitesouthofthe i n t r u s i v ce o n t a cw t ith t h ae r k o s e f a u l t , f o l i a t i o nt r e n d s North of t h i s (Map 1). to east-west a n dd i p s t h ne o r t h . i s s t i l l i an n Souto h tfh i fs a u l tf, o l i a t i o n east-west directionb , ud t i p st ot h es o u t h w , h i l ef u r t h e rs o u t ht h e t o t h en o r t h T . h i sf o l i a t i o n d i pd i r e c t i o nc h a n g e s may b e of t h e g r a n i t e . p a r t i a l l yi n h e r i t e df r o mt h ee m p l a c e m e n t F o l i a t i o n i s a b s e n tt op o o r l yd e v e l o p e di nt h en o r t h e r n g r a n i t i rc o c k st,h L e e m i t a dr i o r i t e . j g a b b r oa, n d thm e afic dikes. Some f o l i a t i o n , p a r a l l e l t ot h ee d g e so ft h ed i k e s , i s p r o b a b l yr e l a t e dt o o c c u r si nt h ec a r b o n a t i t ed i k e sa n d t heem p l a c e m e notth fdei k e sF.o l i a t i oinnt h,Lee m i t a r diorite/gabbro is restricted to s h e a zr o n e as n d n e a trh e westernandnortherncontactswiththealteredfaciesofthe P o l v a d e r aG r a n i t eF. o l i a t i o ni nt h eb i o t i t ea n dP o l v a d e r a G r a n i t e i s p o o r ld ye v e l o p e d to a b s e n ta, n d is r e l amt eiogd m i t i z a t i o n may represent prim sf ltao rruw yc t uwrfh eositllh ,ieaeitni o n m u s c o v i t e - b i o tgi tr ea n i t e o c c u r r i nagl o n g the i n t r u s i vceo n t a cwt i tt hh e Lemitar Page 1 2 2 diorite/gabbro. FAULTS F a u l t i nhgaosc c u r r e d determination on a l a r gsec a lme a k i ntgh e o f t h i c k n e s sa n do r i e n t a t i o n d i f f i c u l tt od e t e r m i n eT. h e of t h es e d i m e n t s L a r a m i d e o r o g e n ay n T d ertiary B a s i n - a n d - R a n g e - t yf pa eu l t i( nr igf t i no gv )e r p r i n t eh de P r e c a m b r i af na b r i rc e, i n f o r c i nt g hneo r t h e r lsyt r u c t u r a l trends of tPh ree c a m b r itaenr r a iLna. r a m isdter u c t u r e s c o n s i s t of b r o a d f o l d s a n d r e v e r s e f a u l t s woodw ward,^ 1 9 7 3 ) ~ a n dr o t a t i o n a le f f e c t sd u r i n gt h eL a r a m i d ea r em i n o r( a b o u t 1 5 d e g r e ews e s t , Woodward, 19731, w h i lT e e r t i a r fya u l t s , r e l a t e dt or i f t i n g ,t i l t e dt h eP r e c a m b r i a nr o c k se v e nm o r e ( a p p r o x i m a t e l y 4 0 d e g r e e sw e s t , Woodward, 1973). N o r t h - t r e n d i n gf a u l t sw i t hs i l i c i f i e dc a r b o n a t e dg o u g e z o n e sc u tt h er o c k sa l o n gC o r k s c r e wC a n y o na n da l s oc u tt h e P o l v a d e r aG r a n i t ea l o n gt h e Not m a i n a r r o y oi ns e c . a l l o f t h e s ef a u l t sc a nb e mapped. Widths b r e c c i az o n e sr a n g ei nt h i c k n e s sf r o m o f t h ef a u l t a few cm. f a u l at sl scout htPeo l v a d e rGa r a n i t e d i o ; i t e / g a bT b er or Pt.airanerdcya m bfraiaaurnlet s t o a meter. of C o r k s c r e w S e v e r a le a s t - w e s tf a u l t sc u tt h es e q u e n c es o u t h C a n y o n f, o r m i n ga r r o y o ss u c h 3 1 (Map 1). a s C o r k s c r e wC a n y o n . and East-west t hLee m i t a r P a g e1 2 3 t o d i s t i n g u i s ho u t s i d eo fC o r k s c r e wC a n y o nd u et o difficult o f g o o edx p o s u r e s . t h el a c k A few s h e a zr o n e w s ithin the s e d i m e n t sa n da l t e r e df a c i e so ft h eP o l v a d e r aG r a n i t e for i n d i c a t i vopefr e - L a r a m i dfea u l t s , affect may b e t h e szeo n eosn l y t hPer e c a m b r i ar no c k F s .ot hrpeu r p o s e s report, breccia of t h i s as nh d ze o an rh eabsvedeeens c r i b e d separately. A n o r t h w e s t - t r e n d i n gT e r t i a r yf a u l (t C h a m b e r l i n 1 , 9.78) 6 a n d 7 (Map 1). c u t st h eP r e c a m b r i a nr o c k si ns e c . b r e c c i a t i o na l o n gt h en o r t h e r np a r t 7 o c c u r as n d t h ef a u l at n dt h e central part mafic d i k e s i n i n t h e d i s c o n t i n u i t yo fs e v e r a l o sf e c . of is s u g g e s t i v o ef Local a f a u l tG . enerally, a r e t o o poor t o t heex p o s u r eitsnhPe r e c a m b r i arno c k s e x t e n dL a r a m i d ea n dT e r t i a r yf a u l t st h a tc u t h ea d j a c e n t P h a n e r o z o i cr o c k s . SHEAR ZONES A n o r t h e a s t - t r e n d i n gs h e a rz o n ec u t sa c r o s st h ew e s t e r n quarter of t h es e c t i o na l o n gC o r k s c r e wC a n y o n B . e d d i n gh a s b e e no b l i t e r a t e da n d u n d u l a t o reyx t i n c t i o n i n t h i ns e c t i o n ,c a t a c l a s t i ct e x t u r e s , of t hger a i n as n ,s du t u r egdr a i n b o u n d a r i e s a r e p r e s e n tB. o u d i n a gset r u c t u r e(ss e v e r a l across) subparallel t ht re e n d of the original cm. bedding P a g e1 2 4 B o u d i n a g ei n d i c a t e st h es t r e t c h i n ga n ds h e a r i n go fl a y e r e d i s formb ed y competen an ti d ncompeten r ot c k Fs .o l i a t i o n s m a l l - s c a l e( w a v e l e n g t h of s e v e r a l cm.) h i g h l yf o l d e dq u a r t z a n df e l d s p a rb a n d sa n db yt i g h t p , t y g m a t i cf o l d sw h i c ha r e i n p l a c e( s ef ei g . o f t es n heared Woodward, s e e sn o u t h 1973). T h e1 2 0 - 18-A and B, 150 m e t e rw i d es h e a rz o n e of Corkscrew C a n y oannedn d s at 54, p. i s not t h ei n t r u s i v e c o n t a c tw i t ht h em u s c o v i t e - b i o t i t eg r a n i t e . T h i s s h e a rz o n e i s P r e c a m b r i a ni na g ea n dp r o b a b l yo c c u r r e db e f o r eo rd u r i n g t h ei n t r u s i o n o f t h em u s c o v i t e - b i o t i t eg r a n i t e , zone a f f e c t so n l yt h es e d i m e n t s . as t h e s h e a r I t may e v e nb er e l a t e dt o t h ei n t r u s i o no ft h em u s c o v i t e - b i o t i t eg r a n i t e . S h e a r i n gh a sa l s oa f f e c t e dt h ea l t e r e df a c i e s of P o l v a d eGr raa n w i th e ezroen e s of f o l i a t qe u dartz the and f e l d s p a lr a y e r o s c c u ri, n d i c a t i v eo if n t e n s es h e a r i n gT . he t r e n do ft h i sf o l i a t i o n i s n o r t h e a s tw i t h a b o u6dt2e g r e e T s .h si sh e a r i n g may P r e c a m b r i a nf a u l t i n g ,b e c a u s ef a u l t i n g a western d i p of a l s boree l a t e tdo a n d s h e a r i n gd o e sn o t a p p e a rt oh a v ea f f e c t e dt h eP a l e o z o i cs e d i m e n t s . S h e a r i n go c c u r sw i t h i nt h eL e m i t a rd i o r i t e j g a b b r on e a r t h ec o n t a c tw i t ht h eP o l v a d e r aG r a n i t e .T h i ss h e a r i n gc o u l d bdeu e t o a P e n n s y l v a n i a nr e v e r s ef a u l (t C h a m b e r l i n , 1978) ottrohi en t r u s i ootnfhPeo l v a d e rgar a n i t eF.o l i a t e d c h l o r i t e -a n db i o t i t e - r i c hz o n e s ,s e v e r a l meters a c r o s s , a r e Page 1 2 5 I l o c a l l yp r e s e n ta l o n gt h ei n t r u s i v ec o n t a c t T . h ef o l i a t i o n i s a b s e n tw i t h i nt h e s u b p a r a l l e l st h ei n t r u s i v ec o n t a c ta n d a P o l v a dG e r a n si tueg, g e s t i n g r e l a t i o n st ht oie p e m p l a c e m e n to ft h eP o l v a d e r aG r a n i t e . BRECCIATION S e v e r a l s m a l l ( s e v e r a lm e t e r sa c r o s s )h e t e r o l i t h o l o g i c within b r e c c i za o n eos c c u r g e n e r aclel m y ented by t h se e d i m e n t s w hc iatreb o n aAt ne g . ur loacrk f r a g m e n t sa r ec o m p o s e do fP r e c a m b r i a ng n e i s s i c and granitic w i t h a l i g h t - c o l o r e dr e a c . t i o n r o c k sa n da r eo f t e ns u r r o u n d e d rim. (Map 1) a n a dr e as B r e c c i a to hi o ca cd n u rar fm etde rt a m o r p h i s m i n d i c a t e d by t h e r a n d o m l y o r i e n t e d f o l i a t e d r o c k f r a g m e n t s . I nc o n t r a s t ,s e v e r a lm o n o l i t h o l o g i cb r e c c i az o n e so c c u r w i t h i nt h em u s c o v i t e - b i o t i t eg r a n i t e (Map 1) w h e r et h er o c k f r a g m e n ct so n s i es nt t i r e o lmyfu s c o v i t e - b i o t i gt er a n i t e . The matrix is i s b l a c ka n dv e r yf i n e - g r a i n e da n dc a r b o n a t e a b s e n ft r o mt h em a t r i x T . h er o c kf r a g m e n t sa r ea n g u l a ra n d u n s u p p o r t e(ds u r r o u n d e d by m a t r i x ) a n d r a n d o m layr r a n g e d , s i m i l a r t or o c kf r a g m e n t sf o u n di nt h eb r e c c i a t e ds e d i m e n t s . T h i bs r e c c i za o n ree p r e s e n t ps a rottfh leo w angle f a u l t f o r m i nt gheea s t e rcno n t a cb te t w e et nhPer e c a m b r i aann d P h a n e r o z o i cs e d i m e n t sa n dv o l c a n i c s( C h a m b e r l i n , 1978). P a g e1 2 6 in A b r e c c i a t e d a n d s h e a r e zdo noe c c u r s portion of t hL e e m i t adr i o r i t e / g a b b r o t h ec e n t r a l (Map 1, s e c . 6 and 71, w h e r ef r a g m e n t so fd i o r i t e / g a b b r oh a v eb e e nc e m e n t e da n d forms an a n g u lbarre c c iTadh. ieo r i t e / g a b bhrbaoes e n a s l i g hftol lyi a at enl tde tr oe d c h l o r ai tned- biotite-ricg h o u g eF. o l i a t i o w n i t h i tnh i ss h e azr o n de i p s t totohne o r t h w e satb o u t 44 h a v eb e e no b l i t e r a t e da n ds h e a r e d . d e g r e e sO. r i g i n at el x t u r e s Some o ft h e s ez o n e s may r e p r e s e nl et n s eossfe d i m e n t a ri yn c l u s i o n T s .h si sh e a r e d b r e c c izao n e (1978 may h a vree s u l t efdr o m f a u l t i n gC; h a m b e r l i n s h o w st h ea r e at ob et r a n s e c t e db yt w of a u l t s e a r l y O l i g o c e n et r a n s v e r s ef a u l t fault - an a n d a P e n n s y l v a n i a nr e v e r s e Page 127 MINERALIZATION Five periods ofmineralization affected the Precambrian rocks in the Lemitar Mountains (in order of decreasing age): (1) Precambrian pegmatite and quartz veins (2) Carbonatite dikes (iate Precambrian) (3) Phanerozoic barite-galena-copper veins (4) Phanerozoic barite-galena-sphalerite veins (5) Barite veins Mining claims cover much of the eastern portions of the area ( sec. map 5, 6, and ~ 7 , Socurro -County-eourthouse "Records Precambrian pegmatites are of the simple type, consisting of unzoned feldspar, quartz, and mica as previouslydiscussed(seeGranitic appear to be Rocks). Quartzveins barren of any other mineralization. Both are discontinuous, forming poorly exposed outcrops. The carbonatite dikes are composed bearing minerals, radioactive minerals, of rare-e?rth and fluorite. High areas of radioactivity (100 times background) occur in sec. 6 and 7. Two samples of high radioactivity were analyzed and found to contain 0.08 (190 ppm U ) and 0.06% U308(ChristopherRautman,personal communication). eight-samples analyzed by the author ranged from 0.0045% U308 (Appendix B). (143 ppm 0.0011 Megascopic fluorite U) The to is found P a g e1 2 8 walls of s e v e r a l p r o s p e cpt i t isn a l o n tgh e concentration 7. sec. The o f r a r e - e a r t h e l e m e n t s may b er e l a t i v e l yh i g h b e c a u s eb a s t n a e s i t e i s present. P h a n e r o z o i cb a r i t e - g a l e n a - c o p p e rv e i n so c c u ra l o n g the w e s t e rcno n t a cwt i tthhPeh a n e r o z o isce d i m e n t P s .r o s p e c t a shaft p i tasn d 18) (sec. e x p o st h em i si n e r a l i z a t i o n . C o p p e rm i n e r a l sc o a tt h ef r a c t u r ea n dj o i n ts u r f a c e s of t h e P r e c a m b r i a nr o c k si nt h ev i c i n i t yo ft h em i n e r a l i z a t i o n . At o f t hPe o l v a d e r a o n leo c a l i t w y i t h i tnh ae l t e r e fda c i e s G r a n i t e , a v e i n o f g a l e n a s, p h a l e r i t e c, h a c o l c i t e q, u a r t z , minerals crosscuts a f l u o r i t e ,b a r i t e ,a n ds e c o n d a r yc o p p e r Some s i l v e r a nzdi nhca vbee erne p o r t e d p e g m a t i tdei k e . f r o mt h e s ev e i n s( L a s k y , 1 9 3 2 ) . P h a n e r o z o i cb a r i t e - g a l e n a - s p h a l e r i t ev e i n so c c u rw i t h i n P h a n e r o z o ilci m e s t o nael o n tgh e T h ims i n e r a l i z a t i o n small is l o c a l i z eadnrde s t r i c t etdo of vwe tii h tnhesi n some of o u t c r olopi fm s e s t o nTesh.teu d y sections three thin limestone c o a r s e - g r a i n e dl i m e s t o n ec r o s s c u tb yt h i n reveals v e i n l e t s o fb a r i t e and c a l c i t e c o n t a i n i n g a l e n a n d s p h a l e r i t eT. h e lack a p a t i t e ,m a g n e t i t e ,a n db i o t i t ec l e a r l yd i s t i n g u i s h e s v e i nfsr o m c a r b o n a t i tdei k e sS. m a lqlu a n t i t i e s were s h i p p ef rdoomntohlefae r g ze or n w e si t h ti hn e l i m e s t o n e( s e c . 5). eastern c o n t a c t (sec. 5 , Map 1). of these of barite Page 129 B a r i t e v e i n s , a l s o P h a n e r o z o i c ,o c c u ra l o n gt h ee a s t e r n east-west. B a r i t ve e i nos f t e n i n t r u d teh ce a r b o n a t i t d e i k e sT. h i m s ineralization may c o n t a c tg, e n e r a l l sy t r i k i n g related t o otherbaritemineralization T h eP h a n e r o z o i cm i n e r a l i z a t i o n be i n thearea. i s n o at s s o c i a t e dw i t h tcha er b o n a tdi ti ek T emsh.ien e r a l o g aitenesd xtures or d i f f e rT . h ec a r b o n a t i t ed i k e sd on o ct o n t a i ns p h a l e r i t e g a l e n a a, n db a r i t e i s r a r e i n t h ec a r b o n a t i t e s T . h eb a r i t e mineralizatid oo nneiosntc l u ad pe a t i tme a, g n e t i toer, b i o t i t eF . i e l dr e l a t i o n s h i p s u g g e s t h a t are o l d et rh.talhniem e s t o tnhehaot st tb hsae r i t e mineralization. the carbonatites P a g e1 3 0 G E O L O G I C HISTORY, TECTONIC SETTING, AND CONCLUSIONS A summary of t h eP r e c a m b r i a ng e o l o g i ch i s t o r yo ft h e L e m i t a r M o u n t a i n s i s p r e s e n t e d i n t a b l e 19. r e c o r d e di nt h e The f i r s t e v e n t L e m i t a r M o u n t a i n s i s t h ed e p o s i t i o no ft h e o f t w ou n i t s C o r k s c r e wC a n y o ns e q u e n c ec o n s i s t i n g c h a r a c t e r i z e db ym a s s i v ea r k o s ea n dU n i t - Un'it I I1 c h a r a c t e r i z e d b y i n t e r b e d d e df, o l i a t e d a r k o s e ss, u b a r k o s e sa, n d quartzites. is T h isse q u e n coesfe d i m e n t s similar t ot h ef e l d s p a t h i c New q u a r t z i t e - a r k o s ea s s o c i a t i o ne x p o s e dt h r o u g h o u tc e n t r a l . . 19791, a l t h o u g hc o r r e l a t i o nt o M e x i c o( C o n d i ea n dB u d d i n g , p a r t i c u l abr a s i n is h a v be e e en m p l a c e d a f t e r t h ed e p o s i t i o n although I m a f i c d i k ef so l l o w e dM. e t a m o r p h i s m , of t h es e d i m e n t so c c u r r e db e f o r e faultinga , n ds h e a r i n go f .. I m a f di ci k eTs .h e . d ou r r i ne gm p l a c e m e tonhSft et a g e e m p l a c e m e not tfh e of may h a v e a t t h e same t i m e a s t h ey o u n g e rg r a n i t e s .T h e i n t r u s i oonSf t a g e intrusion t h es e d i m e n t s , it i s p o s s i b l e t h a t t h i s f o l i a t e d , g r a n i t e b e e ne m p l a c e d may u n c e r t a i nT.hgen e i s s Tgcr a n i t e of a L e m i t a r d i o r i t e l g a b b r o f. o l l o w e db y Stage I1 mafic the d t koecsc u r rne edxTth. e similarity im n i n e r a l o g ay n tde x t u r be e t w e e tnh L e emitar d i o r i t e / g a b b r oa n dt h e' g a b b r oo f Garcia C a n y o(nM a g d a l e n a g a b b r o ) s u g g e s t s t h a t t h e t w o mafic u n i t s may b e r e l a t e d t o a s i m i l a r s o u r c et h a tc r y s t a l l i z e da b o u t 1.5 b.y. according TABLE 19 SUMMARY OF THE G E O L O G I C HISTORY OF THE PRECAMBRIAN ROCKS (1) D e p o s i t i oon t fhCe o r k s c r e w C a n y osne d i m e n tdse r i v e d f r o m a g r a n i t i c or g n e i s s i c s o u r c e . ( 2 ) P o s s i b l ee m p l a c e m e n o t tf h eg n e i s s i cg r a n i t e a, l t h o u g h thisfoliatedgranite may h a v eb e e ne m p l a c e da l o n gw i t h t h eo t h e rg r a n i t i cr o c k sl a t e r on. ( 3 ) I n t r u s i ooSnft a g e I m a fdi ci k ae n smde t a m o r p h i s m , f o l d i n g ,f a u l t i n g ,a n ds h e a r i n g o f t h es e d i m e n t s . ( 4 ) E m p l a c e m e n to ft h e Lemitar d i o r i t e l g a b b r o . ( 5 ) I n t r u s i o n of S t a g e I1 m a f i cd i k e s . ( 6 ) E m p l a c e m e n to ft h eg r a n i t i cr o c k s ,o f t e na s s o c i a t e dw i t h m i g m i t i z aatL nisd eoh tm h /neoeaiortrfai n rg diorite/gabbro. ( 7 ) I n t r u s i o no fp e g m a t i t e sa n dq u a r t zv e i n sa n dd i k e sa n d i n t r u s i o no fS t a g e 111 m a f i cd i k e s ,f o l l o w e d p e r i o do fm e t a m o r p h i s m . by a f i n a l ( 8 ) I n t r u s i o no fc a r b o n a t i t e sa n da s s o c i a t e df e n i t i z a t i o n t hLee m i t d a ri o r i t e j g a b b ra ongdr a n i t ri o ccks. i n c l u d eb r e c c i a t i o n c, a r b o n a t i z a t i o n a, n dh e m a t i z a t i o n o ft h ec o u n t r yr o c k s . of May P a g e 132. t o R b / Si rs o c h r odna t i nogt fhgea b b rooGf a r c iCa a n y o n the Lemitar ( W h i t1e9, 7 8T)gh. rea n i triocciknst r u d e d i o r i t e / g a b b r oa n do f t e na r ea s s o c i a t e dw i t hm i g m i t i z a t i o n a n ds h e a r i n go ft h ed i o r i t e / g a b b r o .M o s tg r a n i t i cp l u t o n i s m i n c e n t r a l New - M e x i cooc c u r r ebde t w e e1n. 2 1.4 bay. 1 9 7 9 ) a n dp e r h a p st h eL e m i t a rg r a n i t e s ( C o n d i ea n dB u d d i n g , w e r ee m p l a c e dd u r i n gt h i sp e r i o dd u et ot h es i m i l a r i t y in m i n e r a l o g yt,e x t u r ea, n d chemistry between these granites. a Simplu e ,n z o n epde g m a t i t ea snqdu a r tvze i nr se p r e s e n t f i n a ls t a g eo fg r a n i t i cm a g m a t i s m i n t h eL e m i t a rM o u n t a i n s . S t a g e I11 m a f i cd i k e si n t r u d e dt h eg r a n i t i cr o c k s ,f o l l o w e d by a perioo dm f e t a m o r p h i s mT. h ien t r u s i o o ncf a r b o n a t i t e d i k easnvde i nasl o npgr e - e x i s t i nfga u l tasnfdr a c t u r e s was f o l l o waendd o f taesns o c i a tw ed ith normal sodic L e m i t a r d i o r i t e / g a b b r oa n dt h eg r a n i t i c f e n i t i z a t i o no ft h e r o c kB s .r e c c i a t i o cna, r b o n a t i z a t i o ann,hde m a t i z a t i oonf t h ec o u n t r yr o c k s may a l s ob ea s s o c i a t e dw i t ht h ei n t r u s i o n otfh ce a r b o n a t i t e sL. a r a m i d e a n d T e r t i a r ys t r u c t u r e s are s u p e r i m p o s e do v e rt h eP r e c a m b r i a nf a b r i c . T hme a f ir co c kasrper o b a b lmy a n t l e - d e r i v efdr o m similar s o u r cT e .hl iet h o l o g i c a l hl ye t e r o g e n e o u Lse m i t a r diorite/gabbro may d i f f e r e n t i a t i o no f hav bee dn erive f rdoem i t hleart e a g a b b r o i c magma o ri n j e c t i o na n dm i x i n g of g r a n i t i c magmas w i t h a g a b b r o i bc o d yT. h m e a f i dc i k e s , a P a g e 133 may r e p r e s e n t a f r a c t i o n s o m eo fw h i c hi n t r u d et h eg r a n i t e , of t h e s a m eg a b b r o i cs o u r c e . T h eg r a n i t e cs a nb ed i v i d e di n t ot w og r o u p b s a s e do n similar - compositions G r o u p I ( g n e i s s i cg r a n i t e b, i o t i t e I1 g r a n i t e s( m u s c o v i t e - b i o t i t eg r a n i t e , g r a n i t e a) n d Group in K20 a nhdi g h e r CaO i n S i 0 2a n d I g r a n i t e sa r el o w e r P o l v a d e r ag r a n i t e ) G . roup and MgO granites. similar i n c o m p o s i t i o n G e o c h e m i c a lm o d e ls t u d i e so ng r a n i t e s 1978) t o G r o u p I g r a n i t e( sC o n d i e , I1 t h aGnr o u p s u g g e st th apta r t i a l meltino gsf i l i c e o u gs r a n u l i t e istnh leo w ecr r u sct o u l d Group I1 I similar i nc o m p o s i t i o nt oG r o u p producm e elts granites a rsei m i l a r in c o m p o s i t i om t one l t s p r o d u cfberyd a c t i o ncar ly s t a l l i z a t i o n 1978). magmas ( C o n d i e , e m p l a c e d a t d e p t h s of 2 granites. of granodiorite T h eg r a n i t i cr o c k sa r et h o u g h tt ob e - 1 3 km. a s e v i d e n c e db yf i e l da n d e x p e r i m e n t a ls t u d i e s . A carbonatite rocks as d i k e sa n d u p p em r antle carbonatites magma i n t r u d et d hoel d eP rr e c a m b r i a n v e i n s a n d was p r o b a b l yd e r i v e df r o mt h e a s e v i d e n c e d by e x p e r i m e n t adl a t af r o mo t h e r similar in c o m p o sLti hettiem oo int a r c a r b o n a t i t eTs .hr ae n d oomr i e n t a t i o n d i k e ss u g g e s tt h a t of t hcea r b o n a t i t e a c a r b o n a t i t e magma p e n e t r a t e dt h ec r u s t b e n e a tt hhper e s e ne tr o s i osnu r f a caent dhcea r b o n a t i t e magma f o l l o w e dp r e - e x i s t i n gf r a c t u r e sa n dz o n e so fw e a k n e s s P a g e 134 i tnhPe r e c a m b r i a rno c k sP. r e l i m i n a r gy e o c h e m i c aslt u d i e s do n o te x h i b i ta n yc h e m i c a lt r e n d sb e t w e e nt h ec a r b o n a t i t e s a n d t h e mafic d i k e s( f i g . 11). of T theex t u r ems ,i n e r a l o gayg n, e do c h e m i s t r y the in C o r k s c r e wC a n y o ns e d i m e n t sa r ec o n s i s t e n tw i t hd e p o s i t i o n a fluvial continental-rift or a r a p i d rl iys i nc g ontinental-margin 9) and settinB g .i m o d (afl i g . thd eeposition a d eel nt aviicre oi tnhim n e er n t or of m a g m a t i sf m ollowed alkali a i s c o n s i s t e nw t ith t h see d i m e n tas n d c o n t i n e n t a l - r isf et t t i n T g .h e sc eo n c l u s i o ns u s g g e tsht a t Lemitar Mountains i s t h teh P e r o t e r o z o i .ct e r r a i n o tfh e a consisten wti t h as c o n t i n e n t a l - r i sf et t t i nsgu c h (1979). m u l t i p l e - r i f ts y s t e mp r o p o s e db yC o n d i ea n dB u d d i n g T h ec a r b o n a t i t e s i n t h eL e m i t a rM o u n t a i n s M o u n t a i n s a) n d may b eo f i n C o l o r a d(oW eM t o u n t a i n sI ,r o n New M e x i c o (MontL e a r g oF, l o r i d M a ountains, P a j a r i tM o o u n t a i nT ) .h e Wet M o u n t a i na snI d r oM nountain com C po llieoncxroa e nd s soi s t of syenm i t ea sf i, c of n e p h e l i n e - b e a r i nr g o c k as n,cda r b o n a t i t ea snadr e similar age - a b o u t 520 m.y. M o n t eL a r g oc a r b o n a t i t e thebasis ( O l s o ne,t al., 1977). a The (New M e x i c o )h a sb e e ni d e n t i f i e do n of c a r b o n a t i t e f l o a t i n L a r g oa r e aa n d a i f s o may b er e l a t e dt o l a t eP r o t e r o z o i c - C a m b r i a na g ea n d o t h e ar l k a l ri o c k fs o u n d the a n a r r o wz o n ei nt h eM o n t e i s t h o u g h t ob eP r e c a m b r i a ni na g e on the P a g e 135 basis of f i e l dr e l a t i o n s h i p s( L a m b e r t , 1961). I t i s similar i anp p e a r a n caen m d i n e r a l o g tytohcea r b o n a t i t eostfh e Lemitar MountaR i nasd. i o m e dt reitce r m i n atthioe ofn s s y e n i t e s of F l o r i d M a o u n t a i n rs a n g fe r o m 420 to a n da r e m.y. a t h e r m a l (magmatic o r v e r y u n c e r t a i nd u et oe i t h e r m e t a s o m a t i c e) v e n t 700 or mixino gyf o u n g esr y e n i t i c material w i tohl d egrr a n i t irco c k(sB r o o k i n s1,9 7 4 )T. hael k a l i n e r o c k s a t P a j a r i t oM o u n t a i n , New M e x i c o ,c o n s i s t of t o be n e a r a n dg n e i s s e s ;r a d i o m e t r i cd a t i n gs h o w st h er o c k s 1 . 1 7 , b . y( .K e l l e y , 1968). syenites T h oe c c u r r e n c oetfh e s ae l k a l i c r o c k sa n dt h ec a r b o n a t i t e si nt h eL e m i t a rM o u n t a i n s may b e s u g g e s t i v e .of.a n a l k a l i . p r o v . i n c e . i n C o l o r a d o a n d 0.4 r a n g i n igan g fer o m 1 . a2 n d bey. 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APPENDIX A A N A L Y T I C A L PROCEDURES S a m p l eP r e p a r a t i o n a r o c kc r u s ' h e tr os i l t - s i z e Samplew s e r ef i r s ct r u s h e di n i n an automatic grams o f e a c hs a m p l ew e r eg r o u n d f r a g m e n t sT . en m o r t aarn pd e s t lw e i t ahc e t o nfeotrh i r t m y i n u t e sD. u p l i c a t e b r i q u e t t e sw e r e made o f e a c hs a m p l ea n ds t a n d a r df o rs u b s e q u e n t X - r a yf l u o r e s c e n c e . of E i g shat m p l e s as t hcea r b o n a t i tdei kwe e rper e p a r e d a b o v e ,x c e pt ht at ht i r tgyr a moesfa csha m p lwe e rues e d . singb l er i q u e t t e was made of A eac s ah m pflfoeur t uX r e- r a y was d r i e d a t 110 d i f f r a c t i oT n .hr e m a i n d o e arf cs ha m p l e d e g r e e s C. f o r w e tc h e m i c a la n a l y s e s . f o ro n eh o u ra n dt h e nu s e d X - r a yF l u o r e s c e n c e X-ray a fluorescen dw ca o eteabr et a i no end 8 - p o s i t i os n p e c t r o g r a p( tha b l e c o l l e c t e df o re a c hb r i q u e t t e . 1). Ten Norelco thousac no d u nwt se r e A s t a n d a r dd r i f tp e l l e t was ipno s i t i ofno uotrfhsep e c t r o g r a pahncdo u n t eeda cthi m e . C o u nrta t efsoera c sha m p laen sdt a n d a r w d e rde i v i d e bdtyh e count r a t e s f o rt h e d r i f t p e l l e tt oc o r r e c tf o ra n yi n s t r u m e n t a l kept Page 150 drift. A c o m p u t e rp r o g r a m (J.R. f o er a c h briquette Renaulp t ,e r s o n aclo m m u n i c a t i o n )T. h e all c o u n t i n gs t a t i s t i c sa r eb e t t e rt h a n2 %f o r Na20 and MgO, ratio was e m p l o y e df o rd e t e r m i n i n gt h e 4%. w h i c ha r eb e t t e rt h a n e l e m e n t es x c e p t C a l i b r a t i o nc u r v e sw e r e a s e c o n dc o m p u t e rp r o g r a m u, s i n g c o n s t r u c t e d ,e m p l o y i n g U.S.G.S. a n di n t r a l a br o c ks t a n d a r d s( t a b l e2 ) .T h ee r r o r sa r es u m m a r i z e d in table 3. C h e m i c a lP r o c e d u r e Mm a jnieondlroe rm ewn deterstee r me iongnehdt c a r b o n as at im t uepasltieoansm bg si oc r p tt ii ot rna, t i o n , 4). c o l o r i m e t r i ca, n d gravimetrim c e t h o d (s t a b l e was ( h y d r o f l u o r i cd)i s s o l u t i opnr o c e s s Two (L. Fe, Mg, Ca, Na, f o trh d eetermination made; one for t h ed e t e c t i o no f Al, K , Mn, a n d Zn a n dt h eo t h e rc o n t a i n e dt w og r a m s of C r , Co, Cu, 5). Xi, Ba, Sr, and Li. The a P e r k i n E l m e r 303 o r a V a r i a n 1 2 5 0 s a m p l e sw e r ea n a l y z e du s i n g s p e c t r o m e t e r( t a b l e Brandvold, d i s s o l u t iw o ne sr e c o n t a i n e do n eh a l ft oo n eg r a mo fs a m p l e HF u s etddoe c o m p o st eh e s a m p l e sf o rs u b s e q u e n ta t o m i ca b s o r p t i o na n a l y s i s p e r s ocnoaml m u n i c a t i o n ) . standard A S t a n d a r d sw e r ep r e p a r e df r o ma n a l y t i c a l grad r eea g e n tCs a . l i b r a t i oc n u r vw e sedr e t e r m i n ef eodar c h e l e m e nat n a l y z e dT. h ree l a t i v e r r o r the elements. are w i t h i n 3%; is within Some e l e m e n t as n a l y z e d (such w h i loet h eerl e m e n t(ss u c h as 5 % f omr o sotf as N a , K, Cu and and ect.) Ba) are Page 1 5 1 w i t h i n1 0 % (L. B r a n d v o l dp, e r s o n a cl o m m u n i c a t i o n ) . M o d i f i e d t i t r a t i o n p r o c e d u r e s were e m p l o y e d t o d e t e r m i n e a n d C02 ( t a b l e 41, gram a nodnhea l f analyzed for u s i n go n eg r a m of e a c hs a m p l e tdoe t e r m i n e C02. approximately analyzed 1%. Two for C02 a r e p r o d u c i b i l i t yo f The r e l a t i v ee r r o r' f o r is FeO were s t a n d a r d( sl i m e s t o naenddo l o m i t e ) 3% t oh fe awnew driet h i n known C02 from t o t a l was f o u n d by subtracting Fe203 c o n c e n t r a t i o nF. e 2 0 3 F ed e t e r m i n e db y t o d e t e r m i n e FeO D u p l i c a st ea m p l ewse r e each s a m p l ae n d resulted in 0.3% f o r FeO a n d 1 . 5 % f o r C02. FeO atomic a b s o r p t i o n . V a r i o u sc o l o r i m e t r i cp r o c e d u r e sw e r e m p l o y e dt od e t e r m i n e U308 T i 0P 22 , 0 a5n, d 4). f oera csha m p l(et a b l e 4 ) a n dt h e d e t e r m i n e d by t h ec l a s s i c a lg r a v i m e t r i cm e t h o d( t a b l e filtrate w a s u s e tddo e t e r m i n e from t h sei l i c da e t e r m i n a t i o n w a s d e t e r m i n e du s i n g T i 0 2P.2 0 5 dissolutio s anm p l e . One to 1 - 5 ml. five d e c o m p o s e du s i n gn i t r i ca n dp e r c h l o r i ca c i d s u308 (table 4). while the of t h e relative e r r o rf o r p e r s o n a lc o m m u n i c a t i o n ) . 0.5 gram BF sample w a s g r aem oafcs h f o r t h ea n a l y s i so f A b s o r b a n c e w a s m e a s u r e du s i n g S p e 2c 0T. h ree l a t i v e r r ofroTr i 0 a2 n P d205 S i l i c a was a B a u s c ha n d was U308 i s w i t h i n 5% ( L . within Lomb 1%, Brandvold, Page 1 5 2 TABLE 1 INSTRUMENTAL PARAMETERS FOR X-RAY FLUORESCENCE ELE TUBE CRYSTAL Si GYPCr Ti Cr Cr A1 QTZ Cr Fe GYP Cr Mg Ca Cr K Cr Na Cr Mn W Ba w Rb iF Mo L Mo Sr QT Z GYP , FPC QT Z QTz GYP LiF LiF L iF - DETECTOR PATH PEAK PEAK 20 FPC FPC FPC FPC FPC FPC FPC FPC SCIN SCIN SCIN SCIN VAC VA C VA C VAC VAC VA C VAC VA C AIR AIR AIR AIR KA 1 KA KA1 KA KA KA KA KA 1 KA LB KA KA 26.00 48.70 66.65 33.79 81.32 60.42 68.24 1 0 3 * 35 62.82 78 9 2 26.34 24.85 Flow proportion counter SCIN - Scintillation counter VAC Vacuum GYP - Gypsum QTZ - Quartz LiF - Lithium Fluoride - BKGRD 20 65.00 - 80.00 - 102,105 62.2,63.5 78,79-5 25.5,26.8 24,25.5 Page 1 5 3 TABLE 2 ROCK STANDARDS USED FOR X-RAY STD Si02 Ti02 A1203 Fe203* MgO CaO K20 Na20 BCR-1 LOSP BLCR JB-1 GSP-1 AGV-1 F-3 G-2 JG-1 HI-31 54.5 75.9 55.7 2.20 0.20 0.84 13.6 i3.4 1.81 7 -51 3.46 6.92 0.93 1.70 4.83 3.27 58.8 52.6 .3a. 2 Mn BCR-1 LOSP BLCR JB-1 GSP-1 AGV-1 F-3 G-2 JG-1 HI-31 * - 0.66 1.04 0.84 0.50 0.26 0.88 1.07 2.60 72.2 STD BR 1.34 67.4 64.8 69.1 BR W-1 52.1 59.0 w-1 ' FLUORESCENCE Ba 12.3 16.9 14.5 15.3 17.3 0.07 9.04 5.97 7-70 4.33 0.96 9.21 2.02 4.90 0.22 6.76 6.36 1.53 2.65 2.21 16.7 6.47 15.0 10.2 11.1 12.9 0.76 0.73 4.21 6.62 1.94 14.2 13.3 13.8 20.7 15.4 Rb - Sr 1080 - 331 763 . 8.11 - 260 - 1280 - T o t a l i r o n c a l c u l a t e d as F e 2 0 3 . 2.18 6.50 11.0 1.52 1.42 3.49 3.51 2 - 79 5.53 2.80 4.26 2.89 2.63 - 4.51 3.96 4.07 2.88 0.64 1.40 3.11 2.15 3.05 3.39 Page 154 TABLE 3 ERRORS ELEMENT S Si02 Ti02 A1203 Fe203 MgO CaO Na20 K20 0.59 0.4370 0.0206 0.1162 0.2336 9.92 0.0230 00. 6. 090 9 6 20 . 2. 1 40 7 9 0 '.00.27338 B a 2.04 Rb Sr Mn C RMS$ ERROR 4.66 1.86 4.59 0.80 0.70 5.17 1.77 1.96 3.25 2.81 3.47 11.8 25.49 0.82 ;0.58 1.15 7.4 0.85 7 - 25 17-19 7.39 4.45 - s t a n d a r dd e v i a t i o n c o e f f i c i e n t o fv a r i a t i o n RMS$ ERROR - r e l a t i v e e r r o r S C - = S / m e a nc o m p o s i t i o n = x 100 Page 1 5 5 TABLE SUMMARY OF ELEMENT CHEMICAL PROCEDURES FOR ANALYSIS OF CARBONATITES METHOD REFERENCE Jeffery, 1 9 6 8 , 323 p. 1 9 7 5 , p. 35 Jeffery, 1 9 6 8 , p . 379 1 9 7 5 , p . 470 S i 0g2r a v i m e t r M i ca x w e l l , T i 0c2o l o r i m e t r iM c axwell, FeO 4 - - 332; 39, 470 - '471' 381; 471 1 9 7 5 , 2 P8p 1r. a; t t , t i t r a t i Joenf f e r y , c 0t i2t r a t i oJ en f f e r y , , - 1894 1 9 7 5 , p. 64 - 6 6 ; S h a p i r o , 1 9 7 5 ; G r i m a l d i ,S h a p i r o ,a n d 1966 Schnepfe, ~ 2 50 c o l o r i m e t r i Jc e f f e r y , 1 9 7 5 , p. LO1 NOTE: g r a v i m e t r iJce f f e r y1,9 7 2p2,.7 0 L O 1 = l o s s o ni g n i t i o n - U308 c o l o r i m e t r imc o d i f i efdr o Y m o eF ,r i t za ,nBdl a c k , 382 - 385 CO2 1953 A l , t o t a l F e , Mg, Ca, Mg, K , Mn, C r , Co, N i , a n d Cu w e r ed e t e r m i n e db ya t o m i ca b s o r p t i o n . S r , B a , L i , Zn, TABLE 5 ATOMIC ABSORPTION INSTRUMENTAL PARAMETERS ELEMENT WAVELEIiGTH A1 Fe Mg Ca Na K Mn C r co ' N i Sr Ba L i Zn cu * - 3100 2494 2862 2122 2950 3838 2805 3584 2412 2369 2350 5542 3394 2152 3254 STANDARDS, ppm 10 2 .1 0-5 0.5 0.5 0.5 1 0.5 1 0.5 10 0.5 0.5 0.5 - - -- - 200 15 2.0 5 5 5 10 10 15 15 10 50 10 2.0 5 a - N 2 0 a: c e t y l e n e - n i t r o u so x i d e a-a: a i r - a c e t y l e n e flame FLAME INSTRUMENT a-N20 a-a a-a a-a a-a a-a a-a a-a a-a a-a a-a a-N20 a-a a-a a-a V a r i a n 1250 P e r k i n E l m e r3 0 3 P e r k i n E l m e r3 0 3 P e r k i n E l m e r3 0 3 P e r k i n E l m e r 303 P e r k i n E l m e r 303 P e r k i n E l m e r3 0 3 V a r i a n 1250 P e r k i n E l m e r3 0 3 P e r k i n E l m e r 303 P e r k i n E l m e r 303 V a r i a n 1250 P e r k i nE l m e r3 0 3 P e r k i n E l m e r 303 Varian1250 flame, APPENDIX B BRIEF PETROLOGIC DESCRIPTIONS OF THE ANALYZED R O C K SAMPLES SEDIMENTS Lem 4 0 1 A , r k o s eL , o w e rU n i t : a d a r k - g r a y ,v e r yf i n e - g r a i n e dr o c k w i tm h i n ofro l i a t i o (nr e l i cbt e d d i n g )R. e l i csta n gd r a i nas r e v e r yp o o r l ys o r t e d v , e r yf i n es a n d - s i z e ' dw i t ha v e r a g er o u n d n e s s a n sdp h e r e c i t yP. o s s i b l ge r a d e b dedding may e x i slto c a l l yT. h e r o c cko n s i s tos f a fine-grained m a t r i x ( p r o b a b l sye r i c i t ae n d (lO-l5%), q u a r t z3 ,5 - 4 0 % q) ,u a r t( z3 0 - 3 5 2 1u ,n t w i n n efde l d s p a r g r e e nb i o t i t e( 5 - 1 0 % ) ,m a g n e t i t e ( < 5 % ) , a n dm u s c o v i t e( 5 - 1 0 % ) . L e m 5 2 4M , e d i u m - g r a i n eA d r k o s eU, p p eUr n i t : a pinkish-gray to d a r k - g r am y ,e d i u m - g r a i n er o d cwki st h t r o nf o g l i a t i oR n .e l i c t sand grains a r e p o o r l ys o r t e d f, i n e t- o medium-sand s i z ew i t h m o d e r a t er o u n d n e s sa n dv a r i a b l es p h . e r e c i t y .T h er o c kc o n s i s t so f q u(a3r0t -z 3a5l$t p e) ,lr ae g di o c l a s e , An50 (20-25%), fine-grained matrix ( p r o b a sbel ryi c i1t0e -, 1 5 % mu ) ,s c o v i t e (10-20%d ) ,a rgkr e etbnor o wbni o t i t(ep a r t i a l layl t e r etdo c h l o r i t e s ,5 - 1 0 % ) ,m a g n e t i t e ( 5 % ) a n d a t r a c ea m o u n to fg a r n e t . Lem 5F2 i5n, e - g r a i nAerdk oUs ep ,U p enri t : a dark-gray f i n e - g r a i n e dr o c kw i t hs t r o n gf o l i a t i o n .R e l i c ts a n dg r a i n sa r e p o o rsl oy r t efdi ,n e - s a sn idz w e divt a h r i a brloeu n d n easns d T hr eo ccko n s i s otqsfu a r (t z2 5 - 3 0 %u) ,n t w i n n e d spherecity. f e l d s(p2a5r - 3 0 f%i n) ,e - g r a i n e d matrix (probab s el yr i c i t e , 2 0 - 2 5 b$ i) o, t (i pt ea r t i a al l yt ecrtheoldo r i1t e5 ,- 2 0 % ) , m u s c o v i t e ( 5 % ) , a n dm a g n e t i t e ((1%). a , Lem 5 2 3M, e d i u m - g r a i n eA d r k o s eU, p p e r Unit: a pinkish-gray to d a r k - g r afyi ,n e - g r a i n se ldi g h tfloyl i a t reodcRk e. l iscatn d graina s r ep o o r -l ys o r t e d f. i n e t- om e d i u m - s a n ds i z e dw i t h fair r o u n d n e S s a n ds p h e r e c i t y .G r a d e db e d d i n gc a nb ed e t e c t e di nt h i n o f q u a r t z( 5 0 - 6 0 $ ) ,p l a g i o c l a s e , An70 T h er o c kc o n s i s t s section , g r e e n b i o t i t ( e 1 0 1 5 % ) p , e r t h i t i K c f e l d s p a ( r 5 1 0 % ) , (20-25$ 1 (<5%). m a g n e t i t e ( 4 5 % ) , a n dm u s c o v i t e Lem 526 S u b a r k o U a m e d i u m - g r faiyn,e - g r a i n e d , s ep, pUenr i t : g r a i n s a r ew e l l - s o r t e d ,m e d i u m - s a n d m a s s i v e r o cRke. l iscatn d k o n s i s tosf s i z e w i t h g o ordo u n d n e sasnsdp h e r e c i t yT. hreo cC (70-80%), p e r t h i tKi c- f e l d s p(a5r- 1 0 %p)l,a g i o c l a s e , quartz ( 5 - 1 0b% i o)(t,5i -t e1 0m%u)s, c o (v5i -t e1 0a% n d) , An20-40 magnetite (<5%). a p i n k i s h - g r atm yo e d i u m - g r a y , Lem 5 2 0 ,S u b a r k o s e ,U p p e rU n i t : R e l i c t s a ngdr a i nasrf ea i r l y f i n e - g r a i n efdo,l i a treodc k . s i z ewdi ft ahrior u n d n e as ns d t o medium-sand sorted, fines p h e r e c i t y .T h i nl a m i n a t i o n s of a r k o s i ct os u b a r k o s i cl e n s e sc a n bd e t e c t e ti hndsi n e c t i o nTs .hr oe c ko n s i s t s of q u a r t z ( 7 0 - 8 0 % ) , g r e ebni o t i (t 5 e - 1 0 $p) e, r t h i t K i c- f e l d s p a r (lo%), ( < 5 % ) , a nfdi n e - g r a i n e d u n t w i n n epdl a g i o c l a s(e< 5 % m ),uscovite m a t r i x ( p r o b a b l ys e r i c i t e , <%5). MAFIC DIKES a p o r p h y r i t i c ,g r e e n i s h - g r a y ,f i n e - g r a i n e d Lem 5 6 , D i a b a s ed i k e : u n m e t a m o r p h o sreodccokn s i s t p ionl fag g i o c l a(sael t e rteod (<5%), chlorite c a l c i t e( 4 , 0 - 4 5 %h ) ,o r n b l e n d(e3 5 - 4 0 1b ,i o t i t e ( < 5 % ) , m a g n e t i t e( 5 - 1 0 % ) a, n d a t r a c e a m o u not qf u a r t zO . phitic t e x t u r e is w e l l preserved. d1 a, d f iick e : a dark-gb rtaloay cvke,r y Lem 1 5 a5n2M f i n e - g r a i nm e da,s s ri o vc ceokn s i sgt o ir neh fg eonr n b l e n d e ( 3 5 - 4 0 %f e) ,l d s p a r , An50 ( 3 0 - 3 5 2g1r ,eaebnnrdo w b ino t i t e ( p a r t i a l l ya l t e r e dt oc h l o r i t e ,1 0 - 2 0 $ ) ,m a g n e t i t e( 5 - 1 0 % ) ,a n d t r a c ea m o u n t o f q u a r t z .S l i g h tf o l i a t i o nc a nb ed e t e c t e d section. a i n thin Lem 4 0 7a n d5 0 2M , a f i cd i k e : a b l a c k ,a p h a n i t i cr o c kc o n s i s t i n g of grh e eo nr n b l e n ( 4d0e - 4 5 % p l )a,g i o c l a s e , An50 (40-4521, m a g n e t i t e( 5 - 1 0 % ) ) ,b r o w nb i o t i t e( p a r t i a l l ya l t e r e dt oc h l o r i t e , <b%), a n d a t r aa cmeo u n t of q u a rO t zp. h i t ei cx t u r e is preserved. Some o t hp f el a g i o c l a s e i s s l i g h t rl y e p l a c ebdy c a r b o n a t ea n ds e r i c i t e . L E M I T A RD I O R I T E / G A B B R O Lem 1 4 8 , 4 3 9 , 5 0 1a, n 5 d 0 3D , iorite/gabbro: a w h i t ea n db l a c k , s p e c k l ecdo, a r s e - g r a i n reodcc ok n s i s t ido nafgbr lku e - g r e e n h o r n b l e n d e( 3 0 - 4 0 % ) ,a l t e r e dp l a g i o c l a s e , An40-55 ( 3 0 - 4 0 % ) b , rown a ngdr e ebni o t i t(e1 5 - 2 0 % )m, a g n e t i t e ( 5 % ) , quartz ( < 5 % ) ,and a n d g a r n eSt .u b o p h i t it co t r a ca em o u n o at sp f a t i t se p, h e n e , o p h ti et ixct u r e is p r e s e rF cvaoienadd er. s- e - g r a i n e d i n c l u s i o n sc a nb ef o u n dw i t h i nt h ec e n t r a lp a r to ft h ep l u t o n . Q u adr it oz r i t e : a b lw aa nchd ksi tpee,c k l e d , Lern 4 4 9 , m e d i u m - g r a i n reodc o k n s i s t i gn org fe h en o r n b l e n (d2e5 - 3 0 % ) , b r o wa nngdr e ebni o t i (t 2 e 5 - 3 0 %a) l, t e r epdl a g i o c l a s e , An50 K f e l d s p a r ( 5 7%), c r u s h e d quartz (7-10%), p e r t h i t i c (2O-25%), of a p a t i at en d t rda ac m e ounts corroded magnetite (5-7%), an garnet. T hqeu a r at zngda r n oe ft t ef n orm inclusions i n t h e b i o t i t e .T h eK - f e l d s p a r i s o f t e nz o n e da n da l t e r e dt o sericite. Subophitictexture i s preserved. Lem 5 3 2 F, e n i t i z e dd i o r i t e l g a b b r o : a p i n ka n db l a c ks, p e c k l e d , c o a r s e - g r a i n e dr o c kc o n s i s t i n g of d a r k g r e e n a n d b r o w nh o r n b l e n d e ( 3 5 - 4 0 2 1 ,a l t e r e dp l a g i o c l a s e , An5-15 ( 4 0 - 4 5 2 1 ,m a g n e t i t e( 2 - 3 2 1 , h e m a t i t e( 1 - 2 % ) ,a n dq u a r t z( 5 - 1 0 2 ) . L e m 533, F e n i t i z e dd i o r i t e l g a b b r o : a p i n ka n db l a c ks, p e c k l e d , o f g r e eannbdr o whno r n b l e n d e c o a r s e - g r a i n erdo ccko n s i s t i n g ( 4 0 - 4 5p2l1a,g i o c l a s e , An15 ( 4 0 - 4 5p$e)r,t h iKt i- cf e l d s p a r ( 5 - 1 0 2 1q ,u a r t(z5 - 1 0 2 1a ,n d a t r a c e amount o f m a g n e t i taen d zircon. G R A N I T I C ROCKS Lem 5 0 , G n e i s s i c g r a n i t e : a p i n k i s h - g r a y t o medium-gray,mediumto c o a r s e - g r a i n e df,o l i a t e d r o c kM . o r t atre x t u r e i s developed. Th r oe c k o n s i s tqosuf, a r(t3z 0 - 3 5 %K) ,- f e l d s p(a2r 5 - 3 0 2 1 , p l a g i o c l a s e( 2 0 - 2 5 2 1 ,g r e e nb i o t i t e( 1 0 - 1 5 $ ) ,a n dh e m a t i t e (<5%). a pinkish-gray to medium-gray, Lern 55, G n e i s s gi cr a n i t e : c o n s i s t s qouf a r t z m e d i u m - g r a i n ef d o ,l i a treodcTkrho . ec k ( 3 0 - 3 5 % ) , ' K - f e l d s p( a2 r5 - 3 0 % p )l a, g i o c l a s~en,6 0 -(7205 - 3 0 2 1 , g r e e na n db r o w nb i o t i t e( p a r t i a l l ya l t e r e d t o c h l o r i t e ,l 0 - 1 5 % ) , a n d a t r a c e a m o u not hf e m a t i t e , m a g n e t i t e a, n d disseminated fluorite. ' ~ aranite: a p a l e - r eadnbdl a c k , mediumt o Lern 8 4 , P o l v a d e rG c o a r s e - g r a i n e rdo c k c o n s i s t i no gqf u a r t (z3 0 - 3 5 2 1p, e r t h i t i c K - f e l d s p a r( 3 0 - 3 5 2 1 ,p l a g i o c l a s e( 2 5 - 3 0 2 1 ,b r o w nb i o t i t e( 5 - 1 0 % ) , A mortar a n d t r a c e a m o u n t s of h o r n b l e n d e ,g a r n e t ,a n dm a g n e t i t e . texture is oftenpreserved. ~ Polvadera Granite: a m o d e r aotrea nagbnelda c k , Lern 511, c o a r s e - g r a i n er d o cc ko n s i s t i no qgfu a r (t 3 z 0 - 3 5 %p) e, r t h i t i c (partially K - f e l d s p(a3r0 - 3 5 2p1l,a g i o c l a(s2e5 - 3 0 $b)i,o t i t e a l t e r e dt oc h l o r i t e ,5 - 1 0 2 1 ,a n d t r a c e a m o u n t s of m a g n e t i t ea n d A s u b m o r t a rt e x t u r e i s preserved. garnet. Lern 447A, L e u c o g r a n i t e : a w h i t ea n db l a c kc, o a r s e - g r a i n e dr o c k - "of--equal-a-mou.nts--of- ~quar-t-z ,-perthitic-K-f e l d s p a r ,--and cons-is-t-%nx plagioclase, An40, and t r a c e a m o u nbotifso t i(t<e5a$n) d m a g n e t i t e( < X % ) . a g r a y i s h - pt oi n k L e m 1M 0 8u,s c o v i t e - b i o g t irtaen i t e : medium-gray, f i n e - g r a i n e d ,s l i g h t l yf o l i a t e dr o c k ,c o n s i s t i n go f ' P a g e1 6 0 , q u a r t z( 3 0 - 3 5 % ) ,p e r t h i t i cK - f e l d s p a r( 2 5 - 3 0 % ) ,p l a g i o c l a s e , An40 ( 2 0 - 2 5 %g) ,r e ebni o t i t e (lo%), m u s c o v i t e ( 5 % ) , a nmda g n e t i t e (<3%). L e m 1 2M 6 , u s c o v i t e - b i o t i gt er a n i t e : a g r a y i s h - p i ntl k o ight g r a yf,i n e - g r a i n e dp, o r p h y r i t i rco c ck o n s i s t i n ogpf l a g i o c l a s e (30-35 q2 u(1 a2r,5t z- 3 0K%- f) e, l d (s2p0a -r 2 5m%a )g,n e t i t e 3 - 5 % ) , brown b i o t i t(e2 - 3 % )m, u s c o v i t e ( a l t e r e tdloe u c o x e n e , a t r a c e a m o u noztfi r c o nG. r a n o p h y r itce x t u r e ( 2 - 3 % )a,n d preserved. Lem 4 2 3 P , o r p h y r i t i cm u s c o v i t e - b i o t i t eg r a n i t e : b r o w n i s h - g r apyo, r p h y r i tm i ce d i u m - g r a i n er od ccko, n s i s t i n g q u a r( t3z5 - 4 0 %p)e,r t h i tKi c- f e l d s p(a2r5 - 3 0 %p)l ,a g i o c l a s e , A n 4 0 - 6( 20 0 - 2 5 %b)i,o t i(t5e - 1 0 %m ) ,u s c o v i t e of m a g n eht ei tm eg,ahratoeni retdn en,b l e n d e . amounts G r a n o p h y r i ct e x t u r e i s p r e s e r v e d . a yellowish- is to of ( 5 % ) , a nt dr a c e L e m 2 0 3 ,B i o t i t eg r a n i t e : a light-graym , e d i u m - g r a i n e d s, l i g h t l y f o l i a t e dr o c k c, o n s i s t i n go q f u a r t z( 2 5 - 3 0 % ) p, l a g i o c l a s e , An50 (lo%), a n dm a g n e t i t e ( 3 0 - , 3 5 % ) ,K - f e l d s p a r( 2 5 - 3 0 % ) ,b r o w nb i o t i t e (<5%). L e m 3 0 2B, i o t i tge r a n i t e : a g r a y i s h - r e dm, e d i u m - g r a i n erdo c k , of p e r t h i t iKc - f e l d s p a( 2 r 5 - 3 0 % q) ,u a r t z (25-30461, consisting p l a g i o c l a s e , An40 ( 2 5 - 3 0 % ) b, r o w nb i o t i t e( 5 - 1 0 % ) a, n dm a g n e t i t e (5%)G . r a n o p h y r i ct e x t u r e i s preserved. a m e d i u m -m g readyi ,u m - g r a i n e d , Lem 438, B i o t i gt er a n i t e : b i o t i t e - r i crho c kT. h irso ccko n s i s tospfl a g i o c l a s e , An40-50 ( 4 5 - 5 0 %q)u, a r(t 2z 0 - 2 5 5b1r, o wbni o t i(t 1e 0 - 1 5 %K) ,- f e l d s p a r was taken ( 1 0 - 1 5 % ) a, n dm a g n e t i t ea n dh e m a t i t e( < 2 % ) T . h i sr o c k n e at rhbeo u n d a rbye t w e etnh e Lemitar d i o r i t e j g a b b r ao n tdh e a l t e r e d f a c i e s o ft h eP o l v a d e r aG r a n i t e . CARBONATITES Lem 34024 572 ,5aP 70 n , rb0 di,m , sai rl y icocarbonates: m e d i u m - g r a i n e dg,r aty bor o w np,o r p h y r i t irco ccko n s i s t i nogf c a r b o n a t e m a t r i x ( d o l o m i t ce a, l c i 6t e0 - 8 0 %a) p, a t i (t 5 e-10%), o p a q u e(sm a g n e t i t5e - 1 0 % )r ,o c fkr a g m e n t(s0 - 1 5 % )d, i s s e m i n a t e d f l u o r i t e( < 5 $ ) , brown b i o t i t ea n dp h l o g o p i t e( 5 - 1 5 % ) a, n dt r a c e of q u a r t fze, l d s p ahr e, m a t i t ae n,hdo r n b l e n d O e .f t e n amounts l a r greo c k f r a g m e n t s ( 1 -i 2n c h e s in d i a m e t e ra)rter a p p e d t h e s ed i k e s T . h e s er o c k sa r ev e r yh e t e r o g e n e o u s o , f t e nl a y e r e d , s h o w i n g r e l i c t c r y s t a l sr e p l a c e db yc a r b o n a t ef l u i d s .I n d i v i d u a l c r y s t a l s a rceo r r o d eadncdr a c k ew d i tcha r b o n a t e ' r e p l a c e m e n t . in Page 1 6 1 Igneou t es x t u r essu, c h as a b s o r p t i o n , a r e p r e v e l a nSt o. v i t e v e i nosf t ecnr o s s c upth e n o c r y s tasnxde n o l i t h s( S . a m p l e4s2 7 a 5-6 f e eat p a rat l o n g a n4d2 7 b come f r o m t hsea mdei k ea,b o u t strike.) Lern 5 0 6 R , e p l a c e m e n st i l i c o c a r b o n a t i t e l: a y e r e d m , edium-grained, g r a y t o b r o w np, o r p h y r i t i c rock consisting o cf a r b o n a t e matrix a trace (70-75561, m a g n e t i (t 1 e 0 - 1 5 %s) e, r i c i (t 1 e 0 - 1 5 %a) n, d a m o u notbf i o t i t eS. u b o p h i t i tce x t u r e i s p r e s e r v e dS. o v i t ae n d h e m a t i t ev e i n l e t sc r o s s c u tt h er o c k . Lem 5 3 R0e,p l a c e m es inlti c o c a r b o n a t ift ien: e - g r a i n e gd r a, y , p o r p h y r i t i cr o c kc o n s i s t i n go cf a r b o n a t e m a t r i x ( 5 0 - 6 0 % )g, r e e n (10-15%), a nbdr o wbni o t i at encdh l o r i (t 2 e 0 - 2 5 %m ) ,a g n e t i t e hematite ( 5 % ) , q u a r t(z1 - 2 % )a,n d a t r a caem o u n t of f e l d s p a r . R e l i c ts u b o p h i t i ca n dp o r p h y r i t i ct e x t u r e sa r ep r e s e r v e d . L e m 531a a n 5 d 3 1 bA, n k e r i t i rca u h a u g i t e : a f i n e - g r a i n e db, r o w n r o c kc o n s i s t i n g o f c o a r s ec a r b o n a t e ( 8 0 - 9 0 % ) , m a g n e t i t e( 2 - 1 0 % ) , h e m a t i t (e5 - 1 0 % )a, n d a t r a c e amount of b i o t i t ea n dc h l o r i t e . . ( B o t hs a m p l e s a r e f r o mt h es a m ed i k e ,a b o u t s i x f e e ta p a r ta l o n g strike. DESCRIPTION OF R O C K SAMPLES NOT ANALYSED F O R CHEMISTRY Quartzite: Lem 3 , f i n e - g r a i nreodc k . fine-sandsizedwith consisto s qf u a r t z a tnrdaacm e ounts f i n e - g r a i n e dm a t r i x . a p i n k im s he-d tgoiruam y - gvrearyy, R e l i cs ta ngdr a i nasrw e e l l - s o r t e dv,e r y g oroodu n d n eassnspdh e r e c i tTyrh.oec k (>so%), K-feldspar ( < 5 % ) ,p l a g i o c l a s e of b i o t i tme a, g n e t i tme u , s c o v i taen, d (<5%), Lem 5 2 2 ,G r e e nc h l o r i t es c h i s t : a f o l i a t e d ,g r a y i s ho l i v eg r e e n , f i n e - g r a i n e dm , i c a e o urso c kT. h reo c ck o n s i s toscf h l o r i t e b i o t i t e( 4 0 - 5 0 % ) p, l a g i o c l a s e , An40-50 ( 2 5 - 3 0 % )q, u a r t (z5 - 1 0 % ) , a n dm a g n e t i t e( 5 - 1 0 % ) . a and Page APPENDIX C CHEMICAL ANALYSES* SEDIMENTS Lem 401 Lem 524 Si02 77- 8 0.54 Ti02 A1203 11.1 4.57 Fe203* MgO 0.94 1.39 CaO 2.45 Na20 2.91 K20 0.07 MnO TOTAL101.77 512 1172 Mn Ba Rb Sr * - 69.6 0.72 14.6 6.09 1.54 1.05 2-53 4.03 62.0 0.72 18.6 7-52 1.54 0.20 65.2 0-75 17-3 76.5 73.8 0.65 13.9 5-05 1.37 1.39 2.54 3.79 4.48 0.59 12.4 4.42 1.03 2.65 2.86 2.22 100.24 0.06 98.03 0.07 99.73 102.75 102.56 490 892 303 577 .139 600 1140 203 78 144 87 592 1534 164 237 1376 161 162 0.08 1.76 5.63 6.66 1.38 1.06 2.83 995 244 163 0.07 0.08 548 Total iron expressedas Fe203. $, elements expressed inppm. Oxides expressed in weight . . 162 MAFIC DIKES 120 Lem 56 Lem 1 5 Lem 407 Lem 5 0 2 Lem 5 2 1 Si02 Ti02 A1203 Fe203* MgO CaO Na20 K20 MnO TOTAL 49.8 1.58 11.7 14.7 5.78 47.8 1-77 46.9 1.85 45.0 12.0 12.1 15-9 15.7 9.37 9.44 10.2 20.9 6.32 4.52 48.0 2.38 11.2 0.26 0.25 96.95 98.11 Mn Ba Rb Sr 2011 1936 333 334 1549 375 45 35 99 24 122 9.27 2.28 1.58 8.00 10.0 1.68 0.71 1.85 2.05 0.60 0.19 98.20 1.75 4.37 0.35 95 * 2 6 2677 397 119 98 16.9 7.31 9-69 1.92 0.67 0.22 98.29 1698 341 56 108 CIPW Norms or ab an di hY 01 4.2 9.3 14.2 19.3 1 7 . 1 2 2 . 02 3 . 1 mt 4.9 il 3.0 0.3 2 4 . 0 20.421.9 19.7 25-5 0.9 Q or ab an c di - 5.3 3.4 orthoclase albite anorthite corundum diopside - 3.5 25.8 4.0 17-3 14.8 7.1 16.2 23.3 24.4 13.3 12.8 0.1 24.2 5.3 3.5 7.0 3.5 5.6 4.5 14.2 - il mt 01 Q hy - - - ilmenite magnetite olivine quartz hypersthene 19.8 - 0.6 LEMITAR D I O R I T E / G A B B R O Lem 1 4 8 54.5 51.2 Si02 2.88 Ti02 A1203 11.1 Fe203" 18.2 3.08 MgO CaO 7.63 1.73 Na20 2.83 2.43 K20 1.50 Lem 449 Lem 501 Lem 5 0 3 59.1 12.1 51.0 2.29 9.26 17.7 21.1 51.0 2.99 10.6 18.6 3.12 7.43 Lern 439 1.46 2.58 7.97 1.01 6.10 1.17 11.8 15.9 0.98 5.34 2.53 2.43 1.50 2.03 0.32 97 * 7 6 99 * 17 1.65 0.27 98.09 2538 404 44 86 2448 329 52 185 2063 366 49 89 Q 9.7 17.3 or 12.0 21.4 14.7 6.2 9.8 20.6 13.2 10.3 20.2 16.7 5.3 17.0 6.2 5.7 Mn 0 TOTAL 1.90 0.19 0.33 0.31 9 8 . 92 71 *91 1502 386 35 176 Mn Ba Rb Sr 2395 346 55 214 . CIPW Norms 9.1 ab an di hy mt il 6.4 8.9 20.6 14.6 14.7 15.0 19-5 17.4 6.1 5.5 11.2 8.9 23.9 13.7 17.0 5.9 2.8 13.1 22.8 18.5 7.0 4.3 2.2 LEMITAR DIORITE/GABBRO - continued Lem 532 Lem 533 Si02 54.2 Ti02 1.17 13.1 A1203 11.8 Fe203* 17.0 MgO 2.94 CaO 4.30 Ma20 3.75 K20 TOTAL Rb Sr 1.19 96.35 58.9 1.30 12.2 2.06 4.42 3.16 2.00 97-14 82 41 745 211 . CIPW Norms Q or ab an di hy mt il 8.8 7.0 31.7 11.9 8.0 19-77 5.7 2.2 16.6 11.8 26.7 15.6 5.4 13.4 4.1 2.5 . Page 166 G R A N I T I C ROCKS f f Si02 Ti02 A1203 Fe203" Lem 5 0 L e m 55 L e m 84 Lem 5 1 1 70.1 0.73 69s.5 0.85 12.2 12.1 73.3 0.43 13.0 5.00 73.8 0.48 13.3 3.86 0.49 0.93 3.05 5.35 0.06 CaO Na20 K20 7.06 0.94 1.90 3.06 4 ..17 MnO 0.10 MgO TOTAL Mn Ba Rb Sr 100.26 806 946 173 105 9.04 0.91 2.06 0.40 1.14 3.01 3.01 3.52 5.05 0. og 0.11 101.10 848 686 101.32 L e m 447A 74.1 0.50 13.8 3.86 0.60 1.51 3.89 3.72 0.06 102.04 445 1378 242 78 434 1415 - 31.9 32.1 0.8 20.8 31.6 25.8 4.6 0.7 22.0 120 115 208 154 Lern 108 73.1 0.56 14.6 3.57 0.79 0.99 2.74 4.59 0.06 101.00 422 1248 191 85 CIPW Norms Q C or ab an di hY mt il 29.4 - 24.6 25-9 7.2 1.8 5.5 3.8 1.4 30.6 25.5 9-2 0.9 7.2 4.9 1.6 35.5 3.3 27.1 32.9 7.5 23.2 - 4.9 3.3 3.5 2.1 2.1 3.0 3.7 1.9 - 0.9 - 1.1 G R A N I T I C ROCKS si02 Rb. Sr continued Lem 1 2 6 Lem 4 2 3 Lem 203 Lem 302 L e m 438 74.0 75.6 0.39 70.6 0.94 2.89 66.5 0.77 13.9 6.46 66.9 0.64 16.0 5.54 0.40 1.20 0.44 Ti02 A1203 13.1 Fe203* 4 . 5 2 0.22 MgO CaO 1.38 Na20 4.83 K20 3.25 0.03 MnO TOTAL 1 0 1 . 7 7 Mn Ba - 228 1248 70 68 13.2 0.83 2.78 5.37 0.05 101.51 98.44 349 1342 244 59 808 892 139 190 35.8 1.3 31.7 23.5 21.6 0.3 24.2 32.7 7.7 1-55 3.86 4.10 0.10 13.1 7.39 0.66 1.62 3.39 4.10 0.08 101.88 589 1.30 2.91 3.81 3.63 0.09 100.82 108 107 693 880 174 382 28.9 21.3 690 CIPW Norms Q C or ab 4.5 29.5 - 19.2 40.9 4.1 an di hy 2.1 2.1 mt 2.5 - 2.5 1-5 - 6.6 3.5 0.1 24.2 28.7 8.0 5:6 4.0 - 21.5 32.2 14.0 0.3 6.2 3.0 P a g e 168 CARBONATITE DIKES Lem 305 Si02 Ti02 A1203 Fe203 FeO MgO CaO .Na20 K20 MnO c02 P20 5 Lem 427a 21.45 2-75 5.44 8.92 24.5 0 .:70 1.45 0.53 22.66 3.26 4.19 LO1 TOTAL CARBONATITE DIKES Lem 5 3 0 Si02 Ti02 A1203 Fe203 FeO MgO CaO Na20 K20 MnO c02 P205 LO1 TOTAL - 27.93 1-79 5.54 9.58 6.36 3.70 17.5 0.02 0.83 0.40 17.40 1.59 .3.47 96.11 - 10.89 0.28 2.61 19.11 0.13 2.14 3.57 3.73 4.28 5.27 9.67 9.53 31.6 30.9 0.19 0.47 0.67 29.01 3.47 1.46 99.77 101.30 Lem 506 11.57 11.20 0.40 2.44 3.50 4.22 10.10 32.5 0.19 0.22 0.72 29.10 3.72 1.13 4.32 L e m 500 Lem 427b 1.05 97-12 0.20 4.35 5-78 7.38 9.90 17.8 1.13 0.41 0.37 0.65 26.31 18.14 3.33 3.95 98.93 1.47 88.81 2.20 0.30 1.05 continued L e m 531a 3.20 L e m 531b 3.59 <o. 1 0 0.46 0.49 0.51 2.23 12.0 7.64 3.86 11.51 6.47 30.2 0.01 0.10 0.47 27.1 0.01 0.10 0.49 36.65 34.85 0.06 0.07 4.67 97.84 4.11 - 93 11 - L o s s on i g n i t i o n C02; i n c l u d e s H20,F, C 1 , and othervolatiles. NOTE: S e eA p p e n d i x A f o r a n a l y t i c a lp r o c e d u r e s . LO1 . . CARBONATITE DIKES ..?. Lem r - Mn Cr co Ni Sr Ba Li Zn cu U ~30846 410 560 520 500 20 10 24 10 42 30 51 38 33 298 1262 84 158 1170 244 18 116 20 7.2 0.0023 Lem L i Zn cu U U308% continued 305 Lern 427a Lern 427b Lem 500 Lem 506 10 10.3 . CARBONATITE DIKES Mn Cr co Ni Sr Ba - 0.0033 - 60 322 1516 20 133 9.8 5.9 0.0019 continued 530 L e m 531a Lem 531b 400 398 97 390 177 1779 19 397 26 3.4 0.0011 470 25 56 48 136 3658 7.4 436 24 5.0 0.0016 490 5 52 70 123 652 6-5 619 2-5 4.4 0.0014 230 64 34 31 31 183 534 3200 61 323 1226 20 125 13 11.2 0.0036 154 100 13.4 0.0045 This thesis is accepted on behalf of the facultyof the Institute by the following committee: ." - 'IGURE 2- PRECAMBRIAN GEOLOGY OF THE LEMITAR MOUNTAINS A \ +4-+ ++4-++r+ + + + ++ c+ iiii + +++++ i+ + + + + + i + +++ + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + +++ 4- +++ i c + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + 3 0 + + + + + + + + + + + + 2 9 + + + + + + + + + + + + + + + + + + + + + + + + + + - I - + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + + f + + + + + + + + + + + + + + + + + + + + + i+ f + ++ + + + + + + + + + + + + + + + + + tiif + + + + + + + + + + + c + + + _ . . . . . . . T T M I - C R O W A V ET O W E R I I T T T + + + + + + + + + + + + t34 07 + + + + + + + + + + + + I + c + i + +/+" + + + + + + + + + + +,0449 + + + + + + + + +,/0447A + + + + + + + +A i+ + + + + , + + + + + + + + / i + + + + + + i ,c + + + + + / ' + + + + + + i f .MAP A R E A + I P O L V A D E RGAR A N I T E ALTEREDPOLVADERAGRANITE B I O T I T EG R A N I T E MUSCOVITE T I S T2 - BIOTITE GRANITE G N E I S S I CG R A N I T E $ +."i LOWER UNIT 0 LOCATION - CORKSCREWCANYON 520-5 a OF SAMPLES ROADS f 5 8 401 N T + RIW + GEOLOGY B Y T M C L E M O R E . 1980. T WOODWARD. 1973