Minerals Composition of the Sun What are Planets Made of? • Same material as Sun • Minus the elements that remain mostly in gases • We find this pattern in a certain class of meteorites Chondrites The Earth’s Crust looks Very Different Composition of the Crust Minerals are the Chemicals that make up the Earth • NATURALLY-OCCURRING • INORGANIC • CHEMICAL COMPOUNDS • ABOUT 3000 KNOWN • 200 COMMON • 20 ROCK-FORMING Atomic Bonding 1. Atoms Gain or Lose Electrons 2. Electrical Neutrality • (+) and (-) Cancel Out 3. Bonding (Satisfy 1 & 2) • Ionic (NaCl) • Covalent (O2) • Metallic (Cu, Al, Fe) • Hydrogen (in water) Ionic and Covalent Bonding Metallic Bonding Hydrogen Bonding Summary of Bonding • Ionic bonding holds rocks and minerals together • Covalent bonding holds people and other organisms together • Metallic bonding holds civilization together • Hydrogen bonding gives water its heatretaining and solvent properties 4. Lattices • Atoms in crystals form a repeating pattern called a Lattice 5. Radicals • Many minerals contain groups of atoms that behave as single units IDENTIFYING MINERALS COLOR -Sometimes Distinctive • Often Unreliable • Affected By: – – – – Chemical Impurities Surface Coating Grain Size Weathering IDENTIFYING MINERALS (Continued) We Need Properties Directly Linked to Atomic Structure: • Hardness • Density • Luster • Cleavage • Crystal Form Hardness • Resistance to Scratching • Directly related to relative strength of atomic bonds • Scratch Test (Mohs) 1. 2. 3. 4. 5. 6. 7. 8. 9. 10. Talc Gypsum Calcite Fluorite Apatite Feldspar Quartz Topaz Corundum Diamond: Density • Directly related to masses of component atoms and their spacing • Usually very consistent Ice: 0.92 Water: 1.00 Halite: 2.18 Quartz: 2.65 Pyrite, Hematite, Magnetite: 5.0 Galena: 7.5 Gold: 19.3 Platinum: 21.4 Iridium: 22.4 (densest material on Earth) Luster Metallic or Nonmetallic is the most important distinction. Cleavage • Tendency to split along smooth planes between atoms in crystal • Thus directly related to atomic structure • Related to Crystal Form Crystal Form • Takes Luck & Practice • Well-formed crystals are uncommon • Crystal Classification is somewhat subtle IDENTIFYING MINERALS Geologic Setting Special Properties • Taste, Magnetism, Etc. Experience and Reading Professional Methods • Chemical Analysis • X-Ray Studies • Thin Section MAJOR MINERAL SUITES Elements Metallic:Au, Ag, Cu • Not Al, Pb, Zn, Fe, etc. Nonmetallic: C - Diamond, Graphite • Sulfur Sulfides: Dense, Usually Metallic Many Major Ores • Major Cause of Acid Rain Halide: Halite Carbonates • Principal Components of limestone and dolostone • Storehouse for CO2 Oxide: Hematite Hydroxide: Bauxite MOST IMPORTANT MINERAL SUITE: The Silicate Minerals • • • • Si + O = 75% of Crust Silicates make up 95% + of all Rocks SiO4: -4 charge Link Corner-To-Corner by Sharing Oxygen atoms Silica Structures Inosilicates - Chains Asbestos Phyllosilicates - Sheets Silicates Tectosilicates - ThreeDimensional Networks • Quartz Feldspars Quartz Minerals in Granite Making Sense of Crystals Unit Cells All repeating patterns can be described in terms of repeating boxes (unit cells) The problem in Crystallography is to reason from the outward shape to the unit cell Which Shape Makes Each Stack? Stacking Cubes Some shapes that result from stacking cubes Symmetry – the rules behind the shapes The Crystal Classes