Third sound and stability of 3 He-4 He mixture films Eckhard Krotschecka , Roger Andersonb , and Michael Millerb a b Institut für Theoretische Physik, Johannes Kepler Universität, A 4040 Linz, Austria Department of Physics, Washington State University, Pullman, WA 99164-2814, USA We study third sound and the interaction between 3 He adatoms in thin 3 He-4 He mixture films from both a first-principles, microscopic theory. Utilizing the variational, hypernetted chain/Euler-Lagarange (HNC– EL) theory as applied to inhomogeneous boson systems, we calculate chemical potentials for both the 4 He superfluid film and the physisorbed 3 He. Numerical density derivatives of the chemical potentials lead to the sought-after third sound speeds that clearly reflect a layered structure of at least seven oscillations. In this paper, we report third sound on four model substrates: Nuclepore, glass, lithium, and sodium. We find, that the effect of the 3 He depends sensitively on the particular 4 He film coverage. The third sound speed can either increase or decrease. In fact, in some regimes, the added 3 He destabilizes the film and can drive “layering transitions” leading to fairly complicated geometric structures of the film in which the outermost layer actually consists of phase–separated regimes of 3 He and 4 He. We also study the dimerization of 3 He in Andreev states due to ripplon exchange. Sorting category: Ac Quantum gases, fluids and solids Keywords: Helium films, third sound, correlated basis functions LT1662