ERTEN ESER Institute of Energy Conversion University of Delaware Newark, DE 19716-3820 Tel: 302-831-3315 Fax: 302-831-6226 e-mail: eser@udel.edu EDUCATION Ph.D., Materials Science, Massachusetts Institute of Technology, June 1978 Thesis under Professor R. E. Ogilvie on “Plasma Characterization in Sputtering Processes and the Deposition of Tungsten Carbide-Cobalt Coatings”. S.M., Metallurgy (Solid State Physics), Massachusetts Institute of Technology, June 1972 Thesis under Professor A.F. Witt on “Thermoelectric Power of Indium Antimonide”. Engineer ECS (Ceramics), Physics, chemistry and technology of non-metallic solids, École Nationale Superieure De Ceramique Industrielle, Sèvres, France, June 1970. Thesis on “Sintering of Calcium Stabilized Zirconium Oxide”. EXPERIENCE 1998-Present Associate Scientist Institute of Energy Conversion, University of Delaware, Newark, DE Managed the NREL sponsored program for the development of copper indium selenide based photovoltaics on polymer web substrates. Directed a number of projects on flexible copper indium selenide photovoltaics funded by DuPont and by other companies through SBIR contracts from various agencies. Coordinating Institute’s participation, as subcontractor, in Global Solar Energy LLC’s TFP and PVMat programs for the Development of Copper Indium Selenide based photovoltaics on flexible substrates. Managed amorphous silicon research program focusing on the development of crystalline p-layers. 1995-1998 Visiting Research Scientist Institute of Energy Conversion, University of Delaware, Newark DE Managed amorphous silicon research program achieving 25% improvement in efficiency in two years. Coordinated Institute’s participation in a DARPA sponsored consortium for the Development of Copper Indium Selenide based Photovoltaics on flexible substrates. Designed, constructed and put in service pumping, gas flow, and control systems of a Hot Wire Chemical Vapor Deposition Reactor for Silicon film deposition. 1992-1995 Consultant Erten Eser Prepared the business plan for an amorphous silicon photovoltaic module manufacturing operation with detailed analysis of the technology, economics, marketing and investment attractiveness. Conducted negotiations for the implementation of this project in Turkey with the Turkish government, investment bankers, and private investors. Prepared a critical analysis of the manufacturing potential of Copper Indium Selenide and Cadmium Telluride based photovoltaic modules. Consulted for a research organization in the optimization of the amorphous silicon solar cell deposition system. Consulted for DOE’s office of Program Analysis as a peer reviewer in amorphous silicon and polycrystalline thin-film devices and materials. 1990-1992 Director, Technology Advanced Photovoltaic Systems, Inc., Princeton, NJ Directed the operations of the Manufacturing, Process Engineering, Design an Development, and Quality Assurance/Quality Control divisions. Prepared and implemented Company’s 1992 strategic technology plan which included the procurement, installation, testing and start-up of the Company’s 10 MWP/year manufacturing facility at Fairfield, CA. Organized the Design and Development division, hired 6 mechanical engineers and 5 draft-persons, defined the division’s mission and objectives. Introduced two new products: 25 WP, 12V and 50 WP, 12 V amorphous silicon PV modules. Developed and implemented processes to improve throughput and yield of module encapsulation line. 1990-1991 Manager, Amorphous Silicon Development Advanced Photovoltaic Systems, Inc., Princeton, NJ Managed the development of the amorphous silicon photovoltaic panel manufacturing line. Demonstrated the commercial manufacturability of amorphous silicon photovoltaic modules at 75 Wp per plate level with 95% yield. 1982-1990 Senior Scientist Chronar Corporation, Princeton, NJ (Chronar Corp. was reorganized as APS, Inc. on December 1990). Managed the “Analysis and Testing” division. Project coordinator of the development of an automated amorphous silicon photovoltaic module manufacturing facility having a capacity of 10 Mwp/ year. Designed the amorphous silicon deposition systems for this project and oversaw their fabrication, assembly, and testing. Manager of a research program on the Copper Indium Selenide based solar cells and modules. Developed high speed and high quality aluminum laser scribing process. Principal investigator of a three year research contract awarded by the Solar Energy Research Institute. Investigated Fe based redox battery systems for possible application in photovoltaics. Studied the Erten Eser “Light Induced Instabilities” in amorphous silicon thin films. Investigated interfacial instabilities in the amorphous silicon photovoltaic modules. Worked on the design and construction of 1 Mwp/year amorphous silicon module manufacturing facility. Principal investigator of a three year research contract awarded by the Solar Energy Research Institute. Set-up and managed the materials analysis laboratory with capabilities such as X-ray diffraction, SEM/EDAX, SAM/SIMS, UV-VIS-IR spectroscopy and optical microscopy. 1981-1982 Research Scientist Arco Solar, Inc., Chatsworth, CA (Presently Siemens Solar, Inc.) Worked on the development of Copper Indium Selenide/Cadmium Sulfide solar cells in the areas of materials characterization, Cadmium Sulfide evaporation, cell design and analysis. 1978-1981 Associate Scientist Institute of Energy Conversion, University of Delaware, Newark, DE Investigation of stability related problems in Copper sulfide/Cadmium Sulfide Solar cells such as grain structure of Cadmium Sulfide films, optical properties of Copper Sulfide films, interdiffusion phenomena and junction morphology in micro-scale. Protection of Copper Sulfide surfaces against oxidation by e-beam evaporated glass layers. Setting-up and operating a materials analysis laboratory with capabilities such as x-ray diffraction, SEM/EDAX, and SAM/SIMS. 1976-1978 Intern C.S. Draper Laboratory, Cambridge, MA. Worked in a program to develop coatings to improve friction and wear characteristics of gas bearing surfaces in inertial guidance instruments where the structural material was beryllium. 1976-1978 Teaching Assistant Massachusetts Institute of Technology Teaching Assistant in “Electron Optics” and “Materials Laboratory” courses. 1969 Summer Intern Société Le Carbon Lorraine, Gennevilliers, France Prepared a feasibility study of the automation of “Riedhammer” furnaces used in the graphitization of carbon. Erten Eser PUBLICATIONS 1. “Surface Coating Technology”, K.A. Taylor and E. Eser, The Charles Stark Draper Laboratory, Inc., Report No. C-4926, Cambridge (1977). 2. “Measurement of Plasma Discharge Characteristics for Sputtering Applications,” E. Eser, R.E. Ogilvie and K.A. Taylor, J. Vac. Sci. Technol. 15(2), 199 (1978). 3. “Friction and Wear Results from WC-Co Coatings by (-) DC Biased RF Sputtering in a Helium Atmosphere,” E. Eser, R.E. Ogilvie and K.A. Taylor, J. Vac. Sci. Technol. 15(2), 396 (1978). 4. “Structural and Compositional Characterization of Sputter Deposited WC-Co Films,” E. Eser, R.E. Ogilvie and K.A. Taylor, J. Vac. Sci. Technol. 15(2), 401 (1978). 5. “Plasma Characterization in Sputtering Processes Using the Langmuir Probe Technique,” E. Eser, R. E. Ogilvie and K.A. Taylor, Thin Solid Films 68, 381 (1980). 6. “The Effect of Bias on DC and RF Sputtered WC-Co Coatings,” E. Eser, R. E. Ogilvie and K.A. Taylor, Thin Solid Films 67, 265 (1980). 7. “Growth and Evaluation of CdS and (CdZn)S Films for the Fabrication of High Performance Photovoltaic Devices,” R.B. Hall, R.W. Birkmire, E. Eser, T.L. Hench and J.D. Meakin, Proc. 14th IEEE PVSC, 706 (1980). 8. “F-Etched a-Si Films,” Tetrahedrally Bonded Amorphous Semiconductors, V.L. Dalal, C.M. Fortmann and E. Eser, AIP Conf. Proc.73, American Institute of Physics, 15 (1981). 9. “Grain Structure of CdS and (CdZn)S Films,” E. Eser, and R.B. Hall, Thin Solid Films 86, 31 (1981). 10. “Effects of Oxidation-Reduction Heat Treatments on the Optical Absorption in Cu 2-x S,” E. Eser and J. Cambridge, Solar Cells 5, 343 (1982). 11. “Junction Geometry in Cu2S/CdS or Cu2S/Cd 1-x Znx Solar Cells Prepared by the Solution Reaction Method,” E. Eser, Solar Cells 8, 157 (1983). 12. “Manufacturing Process for Interconnected Submodules of Hydrogenated Amorphous Silicon Photovoltaic Panels,” S.C. Gau, H. Volltrauer, F. Faras, A.E. Delahoy, E. Eser and Z. Kiss, Appl. Phys. Lett. 47, 1317 (1985). 13. “Single Chamber Manufacturing Process for Amorphous Silicon Solar Cells,” M. Bohm, A.E. Delahoy, F.B. Ellis, Jr., E. Eser, S.C. Gau, F.J. Kampas, Z. Kiss, K.R. Ramaprasad, H. Volltrauer and H. Weakliem, Proc. 18th IEEE PVSC, 888 (1985). 14. “Light-Induced Degradation and Thermal Recovery of the Photoconductivity in Hydrogenated Amorphous Silicon Films,” E. Eser, J. Appl. Phys. 59, 3508 (1986). 15. “Long-Term Stability of Amorphous Silicon Solar Cells and Modules,” E. Eser, K.R. Ramaprasad, H. Volltrauer, F. Ramos, S. C. Gau and R. Vos, Solar Cells 21, 25 (1987). 16. “Interface Chemistry of Tim Oxide and Glow Discharge Deposited Amorphous Silicon Thin Film Couples,” E. Eser and F. Ramos, Proc. 7th EC PVSEC, 560 (1987). 17. “Photo-Degradation in Hydrogenated Amorphous Silicon Films at a High Level of Illumination,” E. Eser and E. Urbanski, Appl. Phys. Lett. 51, 2124 (1987). 18. “Thermal Stability of Aluminum-Tin Oxide Thin-Film Interface,” E. Eser, F. Ramos, and J. Grez, J. Appl. Phys. 64, 1238 (1988). 19. “Accelerated Photo-Degradation of Undoped Amorphous Silicon Films at Low Temperatures: an Experimental Study”, E. Eser and E. Urbanski, Proc. 8th EC PVSEC, 886, (1988). 20. “A 10 Mwp a-Si:H Module Processing Line”, E. Sabisky, Z. Kiss, F. Ellis, E. Eser, S. Gau, F. Kampas, J. Van Dine, H. Weakliem and T. Varvar, Proc. 1989 Amorphous Silicon Subcontractors Review Mtg. 297 (1989). 21. “Recent Improvement in Very Large Area a-Si PV Module Manufacturing,” J. Mac Neil, E. Eser, F. Kampas, J. Xi, A. Delahoy and C.H. Liu, Proc. 9th EC PVSEC (1990). 22. “Transparent Conductive Oxide Contacts for n-i-p and p-i-n Amorphous Silicon Solar Cells,” S. Hegedus, W. Buchanan, E. Eser, J. Phillips and W. Shafarman, AIP Conf Proc., 394, 547 (1996). 23. “Improving Performance of Superstrate p-i-n a-Si Solar Cells by Optimization of n/TCO/Metal Back Contacts,” S. Hegedus, W. Buchanan, E. Eser, Proc. 27th IEEE PVSC, 603 (1997). 24. “Polycrystalline Thin Film Solar Cells: Present Status and Future Potential,” R.W. Birkmire and E. Eser, Ann. Rev. Mater. Sci., 27, 625 (1997). 25. “Preparation and Characterization of Micro-Crystalline Hydrogenated Silicon Carbide p-Layers,” E. Eser, S.S. Hegedus, W.A. Buchanan, Proc. 15th NCPV Prog. Rev. Mtg., 254 (1988). 26. “Thin Si P-layers Containing boron Doped Micro-Crystalline Si and a-SiO Phases,”, E. Eser, W. Buchanan, S. Hegedus, Proc. NCPV Prog. Rev. Mtg., 183 (2001). 27. “Fabrication of Graded Cu(InGa)Se2 Films by Inline Evaporation,” G.M. Hanket, P.D. Paulson, U. Singh, S.T. Junker, R.W. Birkmire, F.J.Doyle III, E. Eser, and W.N. Shafarman, Proc. 28th IEEE PVSC, 499 (2000). 28. “Thin Si p-Layers Containing Boron Doped Micro-Crystalline Si and a-SiOx Phases,” E. Eser, W. Buchanan and S. Hegedus, NCPV Prog. Rev. Mtg. (2001). 29. “Pilot-Scale Manufacture of Cu(InGa)Se2 Films on a Flexible Polymer Substrate,” G.M. Hanket, U.P. Singh, E. Eser, W.N. Shafarman, R.W. Birkmire, Proc. 29th IEEE PVSC, 567 (2002). 30. “Advances in CuInSe2-based Solar Cells: From Fundamentals to Processing,” W. Shafarman, J. Titus, M. Haimbodi, M. Gossla, G. Hanket, S. Marsillac, T. Minemoto, P. Paulson, B. Sang, U. Singh, E. Eser, R. Birkmire, Proc. NCPV Prog. Rev. Mtg., 525 (2003). 31. Determination of Activation Barriers for the Diffusion of Sodium Through CIGS ThinFilm Solar Cells, M.B. Zellner, R.W. Birkmire, E. Eser, W.N. Shafarman, J.G. Chen, Prog. In Photovolt:Res, Appl. 11(8), 54 (2003). 32. Processing Improvements for Roll-to-Roll Deposition of Cu(InGa)Se2, E. Eser, S. Fields, G. Hanket, R.W. Birkmire, W.N. Shafarman, Solar Energy Tech. Prog. Rev. Mtg., (2004). 33. Critical Issues in Vapor Deposition of Cu(InGa)Se2 on Polymer Web: Source spitting and back contact,” E. Eser, S. Fields, G. Hanket, R.W. Birkmire, J. Doody, 31st IEEE PVSC (2005). 34. “Critical Issues for Cu(InGa)Se2 Solar Cells on Flexible Polymer Web,” Erten Eser, Shannon Fields, William Shafarman, Robert Birkmire, submitted to the 19th Space Photovoltaic Research and Technology Conference (SPRAT XIX), Sept. 2005. 35. “Cu(InGa)Se2 Solar Cells on a Flexible Polymer Web”, R. W. Birkmire, E. Eser, S. Fields, W.N. Shafarman, Prog. Photovolt:Res. Appl. 13(2), 141 (2005). 36. “Design Strategy for Scale-Up of Physical Vapor Deposition of Cu(InGa)Se2 on Flexible Substrates,” Kapil Mukati, Babatunde A. Ogunnaike, Erten Eser, Shannon Fields, Robert W. Birkmire, Proc. 32nd IEEE PVSC and WCPEC-4, 1842 (2006). 37. “Scaleup of Cu(InGa)Se2 Thin Film Coevaporative Physical Vapor Deposition Process, 1. Evaporation Source Model Development,” Kapil Mukati, Babatunde A. Ogunnaike, Erten Eser, Shannon Fields, and Robert W. Birkmire, Ind. Eng. Chem. Res. 48, 5975-5991 (2009). 38. “Commercial-Scale Sources for the Evaporation of Elemental Cu, Ga, and In: Modeling, Design and Validation,” Gregory M. Hanket, Robert W. Birkmire, Shannon Fields, and Erten Eser, Proc. 35th IEEE PVSC, Waikiki, Hawaii, June 21-25, 2010. 39. “Cu(InGa)Se2 Photovoltaics on Insulated Stainless Steel Web Substrate,” Erten Eser, Shannon Fields, Woo K. Kim, Elizabeth McQuiston, Kihwan Kim, and William N. Shafarman, Proc. 35th IEEE PVSC, Waikiki, Hawaii, June 21-25, 2010. PATENTS 1. U.S. Patent 4,592,558 dated 1987, “Counteraction of Semiconductor Impurity Effects,” Inventors: A.E. Delahoy, V.L. Dalal, E. Eser. 2. U.S. Patent 6,562,405 dated 2003, “Multiple-Nozzle Thermal Evaporation Source,” Inventors: E. Eser, G.M. Hanket. 3. U.S. Patent 6,676,994 dated 2004, “Method for Producing Thin Films,” Inventors: R.W. Birkmire, E. Eser, G.M. Hanket, B.E. McCandless. Erten Eser 4. PCT Application 60/620,352 dated 2004, “Formation of Selenide, Sulfide or Mixed Selenide-Sulfide Films on Metal or Metal Coated Substrates,” Inventors: E. Eser, S. Fields. AFFILIATION American Vacuum Society American Society for Metals LANGUAGES English, French, Turkish