BIOFUELS IN THE FUEL INJECTION SYSTEM OF A SINGLE-CYLINDER MEDIUM-SPEED DIESEL ENGINE Aki Tilli Ossi Kaario Martti Larmi BIOFUELS IN THE FUEL INJECTION SYSTEM OF A SINGLE-CYLINDER MEDIUM-SPEED DIESEL ENGINE Introduction - Objective: Evaluate renewable diesel compatibilities with EVE research engine - Literature study: renewable diesel fuels - Trad. biodiesel (FAME), HVO (NExBTL), Fischer-Tropsch (BTL), ref: EN 590 - Production, environmental impact, properties - Simulation model: EVE fuel injection system - software: GT-FUEL - Simulations: - Comparison with reference measurements - Physical behavior of the biofuels in the fuel injection system => boundary conditions for CFD calculations Page 2 BIOFUELS IN THE FUEL INJECTION SYSTEM OF A SINGLE-CYLINDER MEDIUM-SPEED DIESEL ENGINE FAME = fatty acid methyl esters - Competition with food industry; LCA: no CO2 reduction! Page 3 BIOFUELS IN THE FUEL INJECTION SYSTEM OF A SINGLE-CYLINDER MEDIUM-SPEED DIESEL ENGINE FAME = fatty acid methyl esters - Non-toxic; biodegradable; HC, CO, particle emissions reduce - Thermodynamics: ~ trad. diesel - Higher density, viscosity, compressibility => faster p- pulsations, higher max. pressures, earlier injection (Yamane et al., 2001) - Chemical properties problematic => engine oil deterioration, corrosion, rubber part deterioration, storage problems - High NOx emissions, cold smoking, carbon build-up, cold operation... - => max. 5 % blends recommended Page 4 BIOFUELS IN THE FUEL INJECTION SYSTEM OF A SINGLE-CYLINDER MEDIUM-SPEED DIESEL ENGINE HVO = Hydrotreated vegetable oil - From oils and fats: Competition with food industry - Palm oil: deforestration of rain forests? Picture: Neste Oil - Isoparaffinic hydrocarbons => nontoxic, no aromatics, no sulphur - LCA: CO reduction considerable 2 Page 5 BIOFUELS IN THE FUEL INJECTION SYSTEM OF A SINGLE-CYLINDER MEDIUM-SPEED DIESEL ENGINE HVO = Hydrotreated vegetable oil - High quality: high cetane number, boiling range, adjustable cold operation properties (process T and p) - Thermodynamically ~ fossil diesel - Low density, lubricity - Emission measurements (VTT, Scania, truck engine optimized for traditional diesel): Regulated emissions Other emissions • NOx - 0 ... - 20 % • Aldehydes - 40 ... - 45 % • Particles • Benzene - 40 ... - 45 % - 17 ... - 30 % • CO - 45 ... - 55 % • PAH decrease • HC - 45 ... -55 % • Mutagens decrease Page 6 BIOFUELS IN THE FUEL INJECTION SYSTEM OF A SINGLE-CYLINDER MEDIUM-SPEED DIESEL ENGINE Fischer-Tropsch-diesel - Biomass to liquids BTL, (and GTL, CTL) - BTL: Biomass gasification => CO ja H (Syngas) => gas cleaning => FT-synthesis => isoparaffinic hydrocarbons 2 - End product properties adjustable (process p, T) Page 7 BIOFUELS IN THE FUEL INJECTION SYSTEM OF A SINGLE-CYLINDER MEDIUM-SPEED DIESEL ENGINE Fischer-Tropsch-diesel - High quality (~ same end-product as HVO, same properties!) - Production costs high - Technology still under development - BTL: Small volumes, stranded feedstocks, expensive technology Page 8 BIOFUELS IN THE FUEL INJECTION SYSTEM OF A SINGLE-CYLINDER MEDIUM-SPEED DIESEL ENGINE Fuel comparison and properties FAME HVO BTL Process route Transesterification Hydrotreatment Gasification, FT Feed Product Vegetable oils Oils, fats Biomass Product (type) Fatty acid methyl esters Isomerized paraffinic hydrocarbons Isomerized paraffinic hydrocarbons Product quality Consistency and stability issues High High CO2 emissions (LCA) 1.6-2.3 kg CO2/kg oil equivalent 0.5-1.5 kg CO2/kg oil equivalent 0.3-1.5 kg CO2/kg oil equivalent Note: Fossil diesel fuel value reported as 3.8 kg CO2 / kg oil equivalent (Bown D. 2007) Page 9 - Compressibility: only small differences => ”only” injection and spray optimation challenge - Cold operation: in research engine not an issue - Vapour pressure: very similar to trad. diesel - => Density and Viscosity most important! BIOFUELS IN THE FUEL INJECTION SYSTEM OF A SINGLE-CYLINDER MEDIUM-SPEED DIESEL ENGINE Fuel comparison and properties NExBTL GTL FT FAME (RME) Diesel Typical Typical fuel EN 590 Density at +15°C (kg/m3) 780 - 785 770- 785 885 835 820-845 Viscosity at +40°C(mm2/s) 3.0 - 3.5 3.2- 4.5 4.5 3.5 2.0-4.5 Cetane number 98 - 99 73 - 81 51 53 >51 10 % distillation (°C) 260- 270 260 340 200 90 % distillation (°C) 295 – 300 325 - 330 355 350 Cloud point (°C) - 15 0 ... +3 0 ... - 5 -5 Heating value (MJ/kg) 44 43 38 43 Heating value (MJ/l) 34,5 33,8 34 36 Polyaromatics (wt-%) 0 0 0 4 Oxygen content (wt-%) 0 0 11 0 Sulfur content (mg/kg) < 10 < 10 < 10 < 10 Values: Neste Oil Page 10 Typical diesel <11 <50 BIOFUELS IN THE FUEL INJECTION SYSTEM OF A SINGLE-CYLINDER MEDIUM-SPEED DIESEL ENGINE Page 11 BIOFUELS IN THE FUEL INJECTION SYSTEM OF A SINGLE-CYLINDER MEDIUM-SPEED DIESEL ENGINE (Polynomial form) GTI (Improved power form) Page 12 BIOFUELS IN THE FUEL INJECTION SYSTEM OF A SINGLE-CYLINDER MEDIUM-SPEED DIESEL ENGINE Page 13 BIOFUELS IN THE FUEL INJECTION SYSTEM OF A SINGLE-CYLINDER MEDIUM-SPEED DIESEL ENGINE Simulations: comparison with measurements Rail pressure (bar) SOI (deg) Injection duration (ms) Injection duration, CA (deg) EOI (deg) Injected mass (g) Simulation: injected mass (g) simulated inj. mass/real inj. mass Page 14 1400 bar 357.5 5.5 29.7 387.2 1.4778 1.40379 94.99 % 1300 bar 352.6 1.8 9.72 362.32 0.4111 0.441385 107.37 % 1200 bar 350.5 4.25 22.95 373.45 1.0185 0.977956 96.02 % 1100 bar 351.5 3.25 17.55 369.05 0.7037 0.721532 102.53 % BIOFUELS IN THE FUEL INJECTION SYSTEM OF A SINGLE-CYLINDER MEDIUM-SPEED DIESEL ENGINE Simulated mass flow rates with different biofuels Page 15 BIOFUELS IN THE FUEL INJECTION SYSTEM OF A SINGLE-CYLINDER MEDIUM-SPEED DIESEL ENGINE Simulated pressures in fuel gallery Page 16 BIOFUELS IN THE FUEL INJECTION SYSTEM OF A SINGLE-CYLINDER MEDIUM-SPEED DIESEL ENGINE Simulated pressure difference between the fuel gallery and the volume behind the needle Page 17 BIOFUELS IN THE FUEL INJECTION SYSTEM OF A SINGLE-CYLINDER MEDIUM-SPEED DIESEL ENGINE Conclusions - Physical property differences cause only slight deviation from traditional diesel behavior in the fuel injection system => no EVE modifications needed - Chemical properties may cause problems, if FAME is used - Lubricity of HVO and FT –fuels must be corrected with additives (as usual) ...or FAME? - Next step: fuel spray and combustion optimization, modern combustion techniques: ReFuel Page 18 BIOFUELS IN THE FUEL INJECTION SYSTEM OF A SINGLE-CYLINDER MEDIUM-SPEED DIESEL ENGINE Thank you for your attention! 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