1 2.02 Atomic Parts 8.17.09 What is an atom? What are the parts of an atom? How are these part put together? 2 2.02 Atomic Parts 8.17.09 The parts: Electrons - Thomson (1904), Millikan (1909) Protons - Goldstein (1886) Rutherford (1911) Neutrons - Sir James Chadwick (1932) 2.02 Atomic Parts 3 8.17.09 Faraday Electrolysis ~1832 Balmer Discharge Tubes ~ 1830 - 90 Thomson e/m ~1897 Millikan e ~1909 Mendeleev Periodic Table ~1870 Michelson C ~1885 Becquerel, Curie Radioactivity a,b g ~1897 Planck Quantum ~1900 Rutherford Nucleus ~1911 Einstein E=hv, E=mc ~1905 2 Bohr Shell Model ~1913 Aston Isotopes ~1909 Stern, Gerlach Electron Spin ~1921 Schrodinger Wave Model, Pauli Exclusion, Hund's Rules ~1926 deBroglie Matter Waves ~1924 Heisenberg Uncertainty Principle ~1927 Chadwick Neutron ~1932 4 2.02 Atomic Parts 8.17.09 Matter contains negative charge particles; electrons. Later cathode rays were discovered and into the late 1800's question of cathode rays identity were put forth. An electroscope demonstrates electric charge. (a) With no electrical influence, the foil leaf hangs straight down. (b) A rubber rod that had been rubbed with fur was touched to the bulb of the electroscope. (The rod was withdrawn slightly before this photograph was made.) The electric charge that had built up on the rod flowed onto the electroscope, and the movable leaf diverged from the stationary leaf. The reason for this observation is that the same charge has flowed onto both leaves. Because like charges repel, the leaves repel each other. (C. D. Winters) 5 2.02 Atomic Parts Cathode rays were electrically charge particles. • Cathode Ray tube with electron stream where deflected by positive and negative plate. • e/m = -1.76•108 C/g 6 2.02 Atomic Parts 8.17.09 Proposed the "plum pudding model" theory of the atom; Coulomb's Law: F = k Q1 Q2 / r2. Atoms contains protons and electrons. 8.17.09 Oil drop experiment to determine the charge value of the electron e = -1.60•10-19 V m = 9.11 •10-31 kg 7 2.02 Atomic Parts 8.17.09 Gold thin foil experiment with alpha radiation through gold foil proved that the atom consisted with a very dense nucleus. Based on the particles deflection pattern, Rutherford calculated the fraction of the atomic volume occupied by the positive nuclei, that is 1 part in 1014. The mass is so dense that a nucleus the size of a pea would have mass greater that 250 million tons. This led to the modern view of the atom (nucelar atom) 8 2.02 Atomic Parts 8.17.09 Scientific Method development of the atomic theory. 2.02 Atomic Parts 9 8.17.09 The parts: Subatomic particles and their properties Particle Mass *Rel Mass Rel Charge (amu) e-; electron p+; proton n; 10 neutron -31 9.109•10 -27 1.673•10 -27 1.675•10 Kg 1/1837 Kg 1 Kg 1 2.02 Atomic Parts -19 - 1.602•10 C -19 + 1.602•10 C 0 8.17.09 These were the experiments which leading to the discovery of the parts of the atom. The picture of the atomic architecture is now complete. (Or is it?) Three particles - electron, protons, and neutrons combine in various numbers to make the 118 (and counting) elements of the periodic table. 11 2.02 Atomic Parts 8.17.09