COMPONENTS OF OPTICAL INSTRUMENTS Chapter 7_II UV, Visible and IR Instruments Topics A. B. C. D. E. F. G. H. I. GENERAL DESIGNS SOURCES WAVELENGTH SELECTORS SAMPLE CONTAINERS RADIATION TRANSDUCERS SIGNAL PROCESSORS AND READOUT FIBER OPTICS TYPES OF OPTICAL INSTRUMENTS PRINCIPLES OF FOURIER TRANSFORM OPTICAL MEASUREMENTS 1 Semiconductor Diodes Lasers Semiconductor diode • A device that has greater conductivity in one direction than in the other Chap.2 p. 45 Forward biased current Reverse biased Resistance to current 2 Semiconductor diodes • Made by forming n-type and p-type region within a single silicon (Si) or germanium (Ge) crystal • Interface between the regions: pn junction • Si : group IV element, semiconductor • n-type: doped with group V element – Arsenic (As) or Antimony (Sb) introduces one unpaired (non bonding) electron in the lattice – negative charges are the majority charge carriers • p-type: doped with group III element – Gallium (Ga) or Indium (In) introduces a “hole” in the Si lattice – Movement of holes from silicon atom to silicon atom constitute a current. – positive charges are the majority charge carriers • pn junction: add p-type imputrity in minute Si chip doped with an ntype impurity Semiconductor diode lasers • Electrons are excited into the conduction band by application of a forward bias voltage across the semiconductor • Some electrons relax back to the valence band by emitting light of energy equal to the band gap, Eg = hν • LEDs are fabricated so as to enhance their light emitting capacity • Example: – Gallium Arsenic Phosphide: 650 nm – Gallium Aluminum Arsenide: 900 nm • Applications – Indicator lights – Readout devices • Limitation: red and IR ER only. 3 Nonlinear Optical Effects with Lasers • Linear optical phenomena – Relationship between polarization and field strength is linear – P= αE – α: • Non linear phenomena P = αE m sin ωt + β E m2 sin 2 ωt – at high radiation intensities, especially when E 1 sin 2 ωt = (1 − cos 2ωt ) approaches the binding 2 energy of electrons. P = αE + βE 2 + γE 3 + ... α f β fγ P = αE m sin ωt + βE m2 2 (1 − cos 2ωt ) C. Wavelength Selectors • Function: to isolate a narrow band of wavelengths • Why: – To improves selectivity – To insure linear response • Effective bandwidth 4 C-1 Filters • Interference filters: – Based on destructive and constructive interference of radiation – Consists of a dielectric (transparent nonconducting substance:CaF2 or MgF2) sandwiched between two semitransparent metallic films. – Efffective bandwidth: 2- 5 nm λ= 2tη n wavelength of radiation transmitted after internal reflection t: thickness of dielectric n: order of interference η : retfractive index of the material • Absorption filters – Selectively absorb portions of the spectrum of the source. – Colored glass – Dyes suspended in gelatin sandwiched between glass plates – Effective bandwidth: 30 250 nm – Transmittance can be only 10% at the band peak! 5 C-2 Monochromators • Components of Monochromators 1. Dispersing element: Grating or Prism: 2. Slits: narrow rectangular opening 3. Lenses: for collimating and focusing 4. Mirrors: for reflection 5. Windows: for transmission Components of Monochromators Dispersion by Prism and Grating Linear Dispersion is constant for a grating monochromator Linear Dispersion is wavelength dependent for a prism monochromator 6 Prism Monochromators Prism material must have a large dη/dλ Hartman equation for the refractive index of glass c λ − λ0 dη c =− (λ − λ ) dλ η = η0 + 2 0 dη dλ is large for shorter wavelengths • Angular dispersion Angular dispersion = a.d. = dθ dθ dη = × dλ dη dλ dθ : dispersion, depends on geometry of prism dη dn : material dependent dλ 2 sin α 2 −c dθ = × dλ (λ − λ ) (1 − η sin α 2) 2 2 2 θ 12 o The angular dispersion is a function of the prism apex angle and the refractive index 7 •Resolving Power R= λ dη =b× ∆λ dλ b: width at base of prism R changes as dη varies dλ with wavelength 8