Working With Simple Models to Predict Contaminant Migration Matt Small U.S. EPA, Region 9, Underground Storage Tanks Program Office What is a Model? • A systematic method for analyzing realworld data and translating it into a meaningful simulation that can be used for system analysis and future prediction. • A model should not be a “black box.” Modeling Process • Determine modeling objectives • Review site conceptual model • Compare mathematical model capabilities with conceptual model • Model calibration • Model application Site Conceptual Model Source Dissolved Ground Water Flow Direction Sources Primary Tanks Piping Spills Secondary Residual NAPL Pathways Soil Vapors Ground Water Surface Water Receptors People Animals, Fish Ecosystems Resources Mathematical Model • A mathematical Model is a highly idealized approximation of the real-world system involving many simplifying assumptions based on knowledge of the system, experience and professional judgment. Ct C0 e K dh v ne dx ( kt ) Model Assumptions • Common simplifying assumptions – – – – 2-Dimensional flow field (no flux in z direction) Uniform flow field (1-D flow) Uniform properties (homogenous conductivity) Steady state flow (no change in storage) Model Selection • Select the simplest model that will fit the available data Input Parameters • Model input parameter values can be either variable, uncertain, or both. – Variable parameters are those for which a value can be determined, but the value varies spatially or temporally over the model domain. – Uncertain parameters are those for which a value cannot be accurately determined with available data. • To evaluate variability and uncertainty we can use several possible values to describe a given input parameter and bound the model result. Lumped Input parameters • To simplify the mathematics, and quantify poorly understood (complex) natural phenomena, subsurface processes are typically described by five parameters: – source – velocity – retardation – dispersion – decay Input Parameters: Ground Water Flow •Processes Simulated –Ground Water Flow Rate, Seepage Velocity, or Advection •Input Parameters –Hydraulic conductivity Source Plume Migration due to Advection –Gradient –Aquifer thickness –Aquitards/aquicludes Ground Water Flow Direction v K dh ne dx C C v x t Ground Water Flow Rate Example Calculation Ground Water Seepage Velocity (vs ) = hydraulic conductivity x gradient effective porosity vs Ki ne Hydraulic conductivity (K) estimated to be between 10-2 and 10-4 cm/sec. Ground water gradient measured from ground water contour map 0.011 ft/ft. Effective Porosity estimated to be 30% or 0.3. vs Travel Time t1 = Ki ne 104 cm ft 0.011 sec ft ?? 0.3 Distance ft Ground Water Flow Rate ft 1,000 ft ?? years ft X year t2 = year 1,000 ft ?? years ft X year Input Parameters: Retardation •Processes Simulated –Retarded contaminant transport –Adsorption and desorption processes –Interactions between contaminants, soil, and water Source •Input Parameters –Fraction of organic carbon –Organic carbon partitioning coefficient –Soil bulk density –Porosity R = 1.1 For MTBE R = 1.8 For Benzene R = 1 For Advective Front Ground Water Flow Direction K d f oc K oc R 1 K d b Retarded Ground Water Flow Rate Example Calculation Ground Water Flow Rate ft Travel Time = t1 = year Distance ft 1,000 ft 264 years ft 3.45 year t2 = 1,000 ft 2.6 years ft 345 year R = 1.8 for benzene R = 1.1 for MTBE t1, MTBE =1.1 t1, benz =1.8 1,000 ft 290 years ft 3.79 year 1,000 ft 475 years ft 3.79 year t 2, MTBE =1.1 t 2, benz =1.8 1,000 ft 2.9 years ft 379 year 1,000 ft 4.7 years ft 379 year Input Parameters: Dispersion •Processes Simulated –Macroscopic spatial variability of hydraulic conductivity –Microscopic velocity variations Dy Source Dispersed Plume Non-Dispersed Plume Dx •Input Parameters –Ground water seepage velocity –Dispersivity –Molecular diffusion coefficient Dz Ground Water Flow Direction Fick's Law F Dmolecular dC dx Dmechanical v Dtotal Dmolecular Dmechanical Input Parameters: Biodegradation and Decay •Processes Simulated –Chemical transformation and decay Decaying Front –Biodegradation –Volatilization Retarded Front Source •Input Parameters –Initial concentrations –First order decay rate or half life Dissolved Ground Water Flow Direction Advective/Dispersive Front (no decay or retardation) Ct C0 e t1/ 2 ( t ) ln 2 3-D Contaminant Fate and Transport in Ground Water C C 2C 2C 2C R x Dx 2 Dx 2 Dx 2 C t x x y z Numerical Model Example Model Output Making Regulatory Decisions • What models can do: – Predict trends and directions of changes – Improve understanding of the system and phenomena of interest – Improve design of monitoring networks – Estimate a range of possible outcomes or system behavior in the future. Making Regulatory Decisions • What models CANNOT do: – Replace site data – Substitute for site-specific understanding of ground water flow – Simulate phenomena the model wasn’t designed for. – Represent natural phenomena exactly – Predict unpredictable future events – Eliminate uncertainty