The Periodic Table and the Elements Adapted from a Powerpoint by Dr. Fred Omega Garces 1 3.3 Periodic Table 9.17.00 1:37 PM The Periodic Table and the Elements What is the periodic table ? What information is obtained from the table ? How can elemental properties be predicted based on the Periodic Table? 2 3.3 Periodic Table 9.17.00 1:37 PM Dmitri Mendeleev (1869) In 1869 Mendeleev (Russia) and Lothar Meyer (Germany) published nearly identical classification schemes for elements known at the time. The periodic table is based on the similarity of properties and reactivities exhibited by various elements. Later, Henri Moseley ( England,18871915) established that each element has a unique atomic number, which is how the current periodic table is organized. http://www.chem.msu.su/eng/misc/mendeleev/welcome.html 3 3.3 Periodic Table 9.17.00 1:37 PM The Periodic Table A map of the building block of matter. 1 1 IA 1 H Periodic Table 2 IIA 13 IIIA 14 IVA 15 VA 16 VIA 17 VIIA 1.00797 2 3 Li 4 5 Be B 6.939 9.0122 3 4 5 6 7 4 11 Na 12 Mg 22.9898 24.305 19 20 K Ca 3 IIIB 21 Sc 4 IVB 22 Ti 5 VB 23 V 6 VIB 24 Cr 7 VIIB 25 Mn Rb Sr Mo Tc 85.47 55 87.62 88.905 91.22 92.906 95.94 56 57 72 73 74 [99] 75 Ba 7 N 8 O 9 F He 4.0026 10 Ne 10.811 12.0112 14.0067 15.9994 18.9984 20.179 8 26 Fe 9 VIIIB 27 Co 10 28 Ni 39.102 40.08 44.956 47.90 50.942 51.996 54.9380 55.847 58.9332 58.71 37 38 39 40 41 42 43 44 45 46 Cs 6 C 18 VIIIA 2 Y La Zr Hf Nb Ta W Re 132.905 137.34 138.91 178.49 180.948 183.85 186.2 87 88 89 104 105 106 107 Fr Ra Ac Ku [223] [226] [227] [260] Ru Rh Pd 11 IB 29 12 IIB 30 Cu Zn 63.54 47 65.37 48 Ag Cd 13 Al 14 Si 15 P 16 S 17 Cl 18 Ar 26.9815 28.086 30.9738 32.064 35.453 39.948 31 32 33 34 35 36 Ga Ge 65.37 49 72.59 74.9216 78.96 79.909 83.80 50 51 52 53 54 In Sn As Sb Se Te Br I Kr Xe 101.07 102.905 106.4 107.870 112.40 114.82 118.69 121.75 127.60 126.904 131.30 76 77 78 79 80 81 82 83 84 85 86 Os 190.2 108 Ir Pt Au Hg Tl Pb Bi Po At Rn 192.2 195.09 196.967 200.59 204.37 207.19 208.980 [210] [210] [222] 109 http://www.chemsoc.org/viselements/pages/periodic_table.html 3.3 Periodic Table 9.17.00 1:37 PM Periodic Table Expanded View The Periodic Table can be arranged by energy sub levels The s-block is Group IA and & IIA, the p-block is Group IIIA - VIIIA. The d-block is the transition metals, and the fblock are the Lanthanides and Actinide metals The way the periodic table usually shown is a compressed view. The Lanthanides and actinides (F block)are cut out and placed at the bottom of the table. 5 3.3 Periodic Table 9.17.00 1:37 PM Periodic Table: Metallic arrangement Layout of the Periodic Table: Metals vs. nonmetals 1 IA 1 18 VIIIA 2 IIA 13 IIIA 14 IVA 15 VA 16 VIA 17 VIIA 2 3 4 5 3 IIIB 4 IVB 5 VB 6 VIB 7 VIIB 8 9 VIIIB 10 Metals 11 IB 12 IIB Nonmetals 6 7 6 3.3 Periodic Table 9.17.00 1:37 PM Periodic Table: The three broad Classes Main, Transition, Rare Earth Main (Representative), Transition metals, lanthanides and actinides (rare earth) 7 3.3 Periodic Table 9.17.00 1:37 PM Reading the Periodic Table: Classification Nonmetals, Metals, Metalloids, Noble gases 8 3.3 Periodic Table 9.17.00 1:37 PM Across the Periodic Table Periods: Are arranged horizontally across the periodic table (Rows 1-7) These elements have the same number of valence shells. 1 IA 1 2 IIA 13 IIIA 14 IVA 15 VA 18 VIIIA 16 VIA 17 VIIA 2nd Period 2 3 3 IIIB 4 IVB 5 VB 6 VIB 7 VIIB 8 9 VIIIB 10 11 IB 12 IIB 4 5 6th Period 6 7 9 3.3 Periodic Table 9.17.00 1:37 PM Down the Periodic Table Families are arranged vertically down the periodic table (columns or group, 1- 18 or 1-8 A,B) These elements have the same number of electrons in the outer most energy level , known as the valence shell. 1 IA 1 18 VIIIA Alkali Family: 1 e- in the valence shell 2 IIA 13 IIIA 14 IVA 15 VA 16 VIA 17 VIIA 2 3 3 IIIB 4 IVB 5 VB 6 VIB 7 VIIB 8 9 VIIIB 10 11 IB 12 IIB 4 Halogen Family: 7 e- in the valence shell 5 6 7 10 3.3 Periodic Table 9.17.00 1:37 PM Notable Families of the Periodic Table Notable families of the Periodic Table and some important members: Halogen Alkali Noble Gas Alkaline Chalcogens 1 18 (earth) IA VIIIA 1 2 IIA 13 IIIA Transition Metals 14 IVA 15 VA 16 VIA 17 VIIA 2 3 3 IIIB 4 IVB 5 VB 6 VIB 7 VIIB 8 9 VIIIB 10 11 IB 12 IIB 4 5 6 7 11 3.3 Periodic Table 9.17.00 1:37 PM Important Elements of Various Groups Individual members of selected groups & their characteristics 1 IA 1 H 2 Li 3 4 18 VIIIA 2 IIA Na Mg K Ca 13 IIIA 3 IIIB 4 IVB 5 VB 6 VIB 7 VIIB 8 9 VIIIB 10 Fe 5 11 IB 12 IIB Cu Zn Ag 14 IVA 15 VA 16 VIA 17 VIIA C N O F Al Si P S Cl He Br I 6 7 12 3.3 Periodic Table 9.17.00 1:37 PM Periodic Table e- configurations are inherent in the periodic table 1 IA 18 VIIIA 2 IIA 1 H 1s1 2 Li Be 2s1 2s2 Na Mg 3s1 3s2 3 4 5 6 7 13 13 IIIA 3 IIIB 4 IVB Sc 3d1 Rb 5s1 Ca 4s2 Sr 5s2 Y 4d1 V Ti Cr Mn Fe Co 3d2 3d3 4s13d5 3d5 3d6 3d7 Zr Nb Mo Tc Ru Rh 4d2 4d3 5s14d5 4d5 4d6 4d7 Cs 6s1 Ba 6s2 La 5d1 Hf Ta W Re Os 5d2 5d3 6s15d5 5d5 5d6 Fr 7s1 Ra 7s2 Ac Rf 6d1 6d2 K 4s1 5 VB 6 VIB 7 VIIB Db Sg Bh 6d3 7s16d5 6d5 8 9 VIIIB 14 IVA 15 VA 16 VIA 17 VIIA B 2p1 BC N O 1 2 3 2p 2p 2p 2p4 F 2p5 Ne 2p6 Al 3p1 Si 3p2 Cl 3p5 Ar 3p6 He 1s2 10 11 IB 12 IIB Ni 3d8 Cu 4s13d10 Ni 4d8 5s14d10 Zn Ga Ge 3d10 4p1 4p2 Cd In Sn 10 4d 5p1 5p2 As Se Be 4p3 4p4 4p5 I Sb Te 5p3 5p4 5p5 Kr 4p6 Xe 5p6 Hg Tl Pb 5d10 6p1 6p2 Bi Po At 6p3 6p4 6p5 Rn 6p6 Ir Ni 7 5d 5d8 Hs Mt 6d6 6d7 3.3 Periodic Table Ag Au 6s15d10 S P 3 3p 3p4 9.17.00 1:37 PM Periodic Table: Electron behavior The periodic table can be classified by the behavior of their electrons West (South) METALS Alkali Alkaline Transition These elements tend to give up e - and form CATIONS 1 IA 1 Mid-plains METALLOID These elements will give up e- or accept e- East (North) NON-METALS Noble gas Halogens Calcogens These elements tend to accept e - and form ANIONS 2 IIA 13 IIIA 14 IVA 18 VIIIA 15 VA 16 VIA 17 VIIA 2 3 3 IIIB 4 IVB 5 VB 6 VIB 7 VIIB 8 9 VIIIB 10 11 IB 12 IIB 4 5 6 7 14 3.3 Periodic Table 9.17.00 1:37 PM 2. Trend in Atomic Radius Atomic Radius: The size of an atom is determined by the boundaries of the valence e-. Largest atomic species are those found in the lower left corner since these atoms have the largest n, but the smallest Zeff. 15 3.3 Periodic Table 9.17.00 1:37 PM 3. Trends in Ionization Energy Ionization energy: The energy required to remove the valence electron from an atom is known as the ionization energy. Largest toward upper right corner of periodic table since these atoms hold on to their valence e- the tightest. 16 3.3 Periodic Table 9.17.00 1:37 PM 4. Trend in Electron Affinity Electron Affinity: The energy released when an electron is added to an atom. The electron affinity is highest among the elements of the upper right corner of the periodic table (excluding the noble gases) since these atoms have a great affinity for electrons. 17 3.3 Periodic Table 9.17.00 1:37 PM Summary of Trends Periodic Table and Periodic Trends 1. Electron Configuration 3. Ionization Energy: Largest toward upper right 4. Electron Affinity: Most favorable upper right 2. Atomic Radius: Largest toward lower left 18 3.3 Periodic Table 9.17.00 1:37 PM Summary Periodic Table: Map of the Building blocks of matter Types : Blocks: S,P, D, and F Representative or main = S and P Blocks Transition = D Block Lanthanide/Actanides = F Block Families or Groups: Elements in the same column have similar chemical properties because of similar numbers and types of valence electrons Alkali metals, Alkaline Earth Metals, Chalcogens, Halogens, Noble gases Periods : 19 Metal, metalloid and Nonmetal Elements in the same row have valence electrons in the same energy level. 3.3 Periodic Table 9.17.00 1:37 PM