Chapter 1 Matter, Energy, & Change 1.1 What is Chemistry? •the study of matter and its transformations Why study chemistry? •learn fundamental physical models •gain technical perspective on current events •develop problem solving skills •appreciate life's little mysteries •Most of the building materials, clothes, and medicines today are the result of chemistry Branches of Chemistry Organicthe study of the structures, synthesis, and reactions of carbon- compound Inorganicthe study of the properties and reactions of inorganic compounds Physical•dealing with the physical properties of chemical substances Biochemistry•study of the chemistry of living things Analytical- analysis of material samples to gain an understanding of their chemical composition and structure. 1.2 Matter and Energy Matter______________________________ •Matter – anything that has mass and occupies space •Inertia – the tendency of a body to stay at rest or to continue to move at the same velocity, unless acted on by an outside force. A tractor trailer has more inertia than a bicycle. A bowling ball has more inertia than a tennis ball. Mass and weight – used interchangeably, but there is a difference… Mass -a quantity of matter, mass is measured using a balance Weight -a measure of gravity's effect on something; use a scale to measure weight Law of Conservation of Mass -Matter can neither be created nor destroyed in chemical or physical changes. Example – sodium metal + chlorine gas ---> table salt, an edible crystal _____Energy_________________________ Everything that you see or sense is either matter or the interactions of energy and matter. True or False? Example: a book – a chunk of matter – hold it up – potential energy – drop it – kinetic energy Energy – the ability to cause change or the ability to do work. (two types) Kinetic – the energy of motion Ex. baseball in flight, car rolling down a street Potential - stored energy waiting to be released Ex: gasoline, water behind a dam Law of Conservation of Energy Energy can change forms, but it cannot be created or destroyed by ordinary chemical or physical changes 1.3 States of Matter Gas •low density •easy to expand/compress •shape - fills container •quick diffusion •volume – container Liquid •high density •hard to expand/compress •takes shape of container •middle diffusion •definite volume Solid •high density •hard to expand/compress •rigid shape •low diffusion •definite volume Plasma – A highly ionized gas. The fourth state of matter (it does matter). 99% of all matter in the universe is in a plasma state. Lightning, neon lights and fire are natural examples of plasma on Earth. Plasma tv’s? What are they all about? Plasma in flat-panel display technology that ignites small pockets of gas to light phosphors. Each plasma panel contains thousands of tiny tubes filled with ionized gas that, when excited by electricity, glow in different colors and intensities to create an image. Properties and Changes of Matter Properties – characteristics that enable us to distinguish one kind of matter from another describe materials by listing their properties Chemical properties vs. physical properties Measurement of a chemical property involves a chemical change. Ex: determining the flammability of gasoline involves burning it, producing CO2 and H2O; wood burning, rusting iron, tarnishing silver, leaves changing colors, baking a cake Measurement of a physical property may change the arrangement but not the structure of the molecules of a material. Ex: density, color, boiling point, volume, temperature, and mass. Intensive properties vs. extensive properties •Extensive properties change when sample size changes; intensive properties don't. Mass of Water 100.0 g 10.0 g Volume of Water 0.100 L 0.010 L Temperature of Water 25 C 25 C Density of Water 1.00 g/ml 1.00g/ml Chemical Change vs. Physical Change •A chemical change occurs when a substance is converted into a different substance Ex. chemical change: sodium metal + chlorine nonmetal --> table salt (crystal, white, edible) Ex. physical change: cutting paper, chopping wood, freezing water Signs of a chemical change • evolution of heat and light •production of a gas • formation of a precipitate Energy and Changes in Matter Chemical reactions involve energy Exothermic releases energy reactants --> products + heat water(l) → ice(s) + heat Graph: Endothermic absorbs energy reactants + heat ---> products ice(s) + heat → wate(l) Graph: Water (products) Water (reactants) heat ergy Energy heat Ice (products) ice (reactants) Examples of Exothermic Processes making ice cubes formation of snow in clouds condensation of rain from water vapor a candle flame mixing sodium sulfite and bleach rusting iron burning sugar forming ion pairs combining atoms to make a gas molecule mixing strong acids and water nuclear fission Examples of Endothermic Processes melting ice cubes conversion of frost to water vapor evaporation of water forming a cation from an atom in the gas phase baking bread cooking an egg producing sugar by photosynthesis separating ion pairs splitting a gas molecule apart mixing water and ammonium nitrate melting solid salts 1.4 Classification of Matter Matter Separate physically Mixtures Heterogeneous Pure Substances Homogeneous Compounds Separate chemically Suspension Solution Colloid Elements Mixture combination of two or more kinds of matter, but each retains its own physical properties Heterogeneous composition is not uniform where samples are different Pure Substance homogeneous sample of matter that always has the same composition Compound substance that can be decomposed into 2 or more substances by chemical change Ex: NaCl, H2O, C6H12O6, CO2 Homogeneous Uniform composition; every sample is the same Suspension Solid in liquid muddy water, granite Solution small particles that won’t scatter light ex: air, salt water Colloid particles larger than molecules, scatterlight Shaving cream, starch water Element substance that cannot be broken down by ordinary chemical change Ex: Au, Cu, Ni, Na 1.5 The chemical elements The periodic table compactly shows relationships between elements, and features are: Periods are horizontal rows on the table. - Have the same number of electron shells Groups (or families) are columns on the table. - Have similar chemical properties. Blocks are regions on the periodic table www.periodictable.com Types of Metals Alkali Metals (Group IA, first column ) soft, extremely reactive metals react with cold water to form hydrogen gas form +1 ions Li, Na, K, Rb, Cs, Fr Lithium Potassium Sodium Types of Metals alkaline earth metals (Group IIA, second column): soft, reactive metals compounds are a major component of earth's crust form +2 ions Be, Mg, Ca, Sr, Ba, Ra Magnesium Barium Beryllium Types of Metals Transition Metals (columns 3-12) hard, dense metals less reactive than Group IA and IIA Nickel Gold Chromium Types of Metals Rare earth metals are the elements at the bottom of the table. lanthanides (top row) actinides (bottom row) Lanthanide Uranium Nonmetals halogens (Group VIIA, next-to-last column): poisonous and extremely reactive nonmetals fluorine and chlorine are yellow-green gases bromine is a volatile red-brown liquid iodine is a volatile blue black solid all form -1 ions noble gases (Group 0, last column) all are monatomic gases a. k. a. inert gases; almost completely unreactive Properties of Metals - Macro malleable: can be hammered into thin sheets ductile: can be drawn into wire conduct heat and electricity well lustrous Properties of Metals - Micro Appear different colors when metals are in tiny clusters (nanoparticles)– up to 30 atoms Stained glass Lycurgus cup How Small is a Nanoparticle? Nano 1 billionth of a meter Properties of Nonmetals • Not Malleable or ductile – brittle • Poor conductors of electricity • dull Properties of Metalloids • Properties of metals and nonmetals