- Sit with, or near, your group & take out your sig figs worksheet - Talk to group members to see where you want to sit - Remember your number! # Group A Group B Group C Group D Group E Group F Group G 1 ANNA G. NICOLA BERNICE JASMINE KOMAL MANISHA BEN 2 IVAN VIVI ANNA Z. IVY NICOLE TIAN WING 3 TOMMY ECKHAM SIMRAN ANGELA KIANA DOM NANCY 4 DEBORAH HUSN RAFAY AUTUMN VERONICA JONATHAN FELIPE & AMY • Hand in Course Outline, Safety Agreement, Contact Lens Letter on the overhead please • New students: measurement lab at lunch today, safety quiz tomorrow at lunch • Was it helpful to post up the notes a day beforehand? • I will try to do this every class so you can print, take notes or read it over before class Today’s Groups • When I ask you to go into groups to try questions today, discuss the solution in your group • Make sure everyone understands the steps • I pick a number, that number from every group stands up, I pick one (or more) to write answers on the board • No notes allowed when you come up to write • Get into your groups and remember your numbers Mixed Operations with Sig Figs • Follow the rules for each operation • Do NOT round off after every step • Do keep track of the decimal places and sig figs every calculation you make • Try: 9.34 x 0.07146 – 6.88 x 0.08115 Mixed Operations with Sig Figs 9.34 x 0.07146 – 6.88 x 0.08115 = 0.6674364 – 0.558312 Mixed Operations with Sig Figs 9.34 x 0.07146 – 6.88 x 0.08115 = 0.6674364 – 0.558312 = 0.1091244 Mixed Operations with Sig Figs 9.34 x 0.07146 – 6.88 x 0.08115 = 0.6674364 – 0.558312 = 0.1091244 = 0.109 Try Hebden p.40 #59 c, f, g Work with your groups! Dimensional Analysis (Unit Conversions) Conversion Factors • A conversion factor is a fraction relating 2 units without changing the actual quantity • E.g. 1 min = 60 s can be written as the conversion factor 1 min 60 s of or 60 s 1 min • Note the quantity (amount of time) in 1 min and 60s are the same, they are just expressed using different units Same Quantity, Different Units Sig Figs in Conversion Factors • How many sig figs in the numbers of 1 min 60 s ? Sig Figs in Conversion Factors • How many sig figs in the numbers of • (1 sig fig)/(1 sig fig) you say? 1 min 60 s ? Sig Figs in Conversion Factors • How many sig figs in the numbers of 1 min 60 s • (1 sig fig)/(1 sig fig) you say? Nope! • Recall: sig figs are all the certain digits of a measurement plus the 1st uncertain digit ? Sig Figs in Conversion Factors • How many sig figs in the numbers of 1 min 60 s ? • (1 sig fig)/(1 sig fig) you say? Nope! • Recall: sig figs are all the certain digits of a measurement plus the 1st uncertain digit • How certain are we that there are 60 s in 1 min? Exact/Defined/Counting Numbers • Exact/defined/counting numbers have infinite sig figs and are not considered when doing calculations • 1 min 60 s is an exact conversion factor because there are exactly 60 s in 1 min (not 60.000001 or 59.999999999 but 60.00000000000000000000…) • There is no rounding and there is no uncertainty • Other examples: 12/dozen, 2/pair, 1 m = 100 cm, 1 ft = 12 in Exact/Defined/Counting Numbers • Warning: not all conversion factors are exact • Can you think of an example of an inexact conversion factor? Exact/Defined/Counting Numbers • Warning: not all conversion factors are exact • Can you think of an example of an inexact conversion factor? • Conversions between metric & imperial units • E.g. 1 m = 3.2808 ft • This number is rounded to 5 sig figs but goes on forever • There is uncertainty so the number of sig figs matter Exact/Counting or Measured (Inexact)? • 29 students in the classroom • $20.48 in my pocket • 100,000 hairs on my head Exact/Counting or Measured (Inexact)? • 29 students in the classroom - exact • $20.48 in my pocket • 100,000 hairs on my head Exact/Counting or Measured (Inexact)? • 29 students in the classroom - exact • $20.48 in my pocket - exact • 100,000 hairs on my head Exact/Counting or Measured (Inexact)? • 29 students in the classroom - exact • $20.48 in my pocket - exact • 100,000 hairs on my head - exact Solving Unit Conversion Problems • Step 1: identify the initial amount – what info are you given? • Step 2: identify the unknown amount – what are you looking for? • Step 3: identify the conversion factor – how are 1 & 2 related? • Overall: unknown amount = initial amount x conversion factor Example 1 • How many min are there in 3480 s? • Step 1: • Step 2: • Step 3: Example 1 • How many min are there in 3480 s? • Step 1: initial = 3480 s • Step 2: • Step 3: Example 1 • How many min are there in 3480 s? • Step 1: initial = 3480 s • Step 2: unknown = min • Step 3: Example 1 • How many min are there in 3480 s? • Step 1: initial = 3480 s • Step 2: unknown = min • Step 3: conversion factor between min & s = or 60 s 1 min (which one do we use?) 1 min 60 s Example 1 • How many min are there in 3480 s? • Step 1: initial = 3480 s • Step 2: unknown = min • Step 3: conversion factor between min & s = 1 min 60 s • Use the one with the unit you want on top (numerator) Example 1 • How many min are there in 3480 s? • Overall: unknown = initial x conversion factor Example 1 • How many min are there in 3480 s? • Overall: unknown = initial x conversion factor • ? min = 3480 s x conversion factor • Want to leave min and cancel s so use the c.f. with min on top (numerator) and s below (denominator) Example 1 • How many min are there in 3480 s? • Overall: unknown = initial x conversion factor • ? min = 3480 s x 1 min 60 s • Want to leave min and cancel s so use the c.f. with min on top (numerator) and s below (denominator) Example 1 • How many min are there in 3480 s? • Overall: unknown = initial x conversion factor • ? min = 3480 s x 1 min 60 s • Want to leave min and cancel s so use the c.f. with min on top (numerator) and s below (denominator) Example 1 • How many min are there in 3480 s? • Overall: unknown = initial x conversion factor • ? min = 3480 s x 1 min 60 s • Want to leave min and cancel s so use the c.f. with min on top (numerator) and s below (denominator) Example 1 • How many min are there in 3480 s? • Overall: unknown = initial x conversion factor • 58 min = 3480 s x • Done? 1 min 60 s Example 1 • How many min are there in 3480 s? • Overall: unknown = initial x conversion factor • 58 min = 3480 s x 1 min 60 s • Done? NO! Sig figs! Example 1 • How many min are there in 3480 s? • Overall: unknown = initial x conversion factor • 58 min = 3480 s x 1 min 60 s • ? sig figs = ? sig figs x ? sig figs Example 1 • How many min are there in 3480 s? • Overall: unknown = initial x conversion factor • 58 min = 3480 s x 1 min 60 s • ? sig figs = 3 sig figs x ? sig figs Example 1 • How many min are there in 3480 s? • Overall: unknown = initial x conversion factor • 58 min = 3480 s x 1 min 60 s • ? sig figs = 3 sig figs x ∞ sig figs Example 1 • How many min are there in 3480 s? • Overall: unknown = initial x conversion factor • 58 min = 3480 s x 1 min 60 s • 3 sig figs = 3 sig figs x ∞ sig figs Example 1 • How many min are there in 3480 s? • Overall: unknown = initial x conversion factor • 58.0 min = 3480 s x 1 min 60 s • 3 sig figs = 3 sig figs x ∞ sig figs Example 1 • How many min are there in 3480 s? • Overall: unknown = initial x conversion factor • 58.0 min = 3480 s x • Now are we done? 1 min 60 s Example 2 (don’t copy, just try) The automobile gas tank of a Canadian tourist holds 39.50 L of gas. If 1 L of gas is equal to 0.264 gal in the US (“gal” is the symbol for “gallon”), and gas is $1.26/gal in Dallas, Texas, how much will it cost the tourist to fill his gas tank in Dallas? Example 2 Initial = Unknown = Conversion factors: Example 2 Initial = 39.50 L Unknown = Conversion factors: Example 2 Initial = 39.50 L Unknown = $ (cost) Conversion factors: Example 2 Initial = 39.50 L Unknown = $ (cost) Conversion factors: L gal: gal $: Example 2 Initial = 39.50 L Unknown = $ (cost) Conversion factors: L gal: gal $: 1L 0.264 gal or 0.264 gal 1L Example 2 Initial = 39.50 L Unknown = $ (cost) Conversion factors: L gal: 1L 0.264 gal gal $: 1 gal $1.26 or or 0.264 gal 1L $1.26 1 gal Example 2 • Unknown = initial x c.f. x c.f. Example 2 • $ ? = 39.50 L x c.f. x c.f. • First c.f. must cancel out litres • Must have L in the denominator (below) Example 2 • $ ? = 39.50 L x 0.264 gal 1L x c.f. • First c.f. must cancel out litres • Must have L in the denominator (below) Example 2 • $ ? = 39.50 L x 0.264 gal 1L x c.f. • First c.f. must cancel out litres • Must have L in the denominator (below) Example 2 • $ ? = 39.50 x 0.264 gal 1 x c.f. • Second c.f. must cancel out gallons • Must have gal in the denominator (below) Example 2 • $ ? = 39.50 x 0.264 gal 1 x $1.26 1 gal • Second c.f. must cancel out gallons • Must have gal in the denominator (below) Example 2 • $ ? = 39.50 x 0.264 gal 1 x $1.26 1 gal • Second c.f. must cancel out gallons • Must have gal in the denominator (below) Example 2 • $ ? = 39.50 x 0.264 1 x $1.26 1 • Do we have the units we want for our unknown? • Yes we don’t need anymore conversion factors • No we need more conversion factors Example 2 • $ ? = 39.50 L x 0.264 gal 1L x $1.26 1 gal • Finally: use calculator and express in correct sig figs • ? s.f. = ? s.f. x ? s.f. x ? s.f. • Are these conversion factors exact? Example 2 • $ ? = 39.50 L x 0.264 gal 1L x $1.26 1 gal • Finally: use calculator and express in correct sig figs • ? s.f. = ? s.f. x ? s.f. x ? s.f. • Are the c.f.’s exact? 1st one no, 2nd one yes Example 2 • $ ? = 39.50 L x 0.264 gal 1L x $1.26 1 gal • Finally: use calculator and express in correct sig figs • ? s.f. = 4 s.f. x 3 s.f. x ∞ s.f. • Are the c.f.’s exact? 1st one no, 2nd one yes Example 2 • $ ? = 39.50 L x 0.264 gal 1L x $1.26 1 gal • Finally: use calculator and express in correct sig figs • 3 s.f. = 4 s.f. x 3 s.f. x ∞ s.f. • Are the c.f.’s exact? 1st one no, 2nd one yes Example 2 • $ ? = 39.50 L x 0.264 gal 1L x $1.26 1 gal • Finally: use calculator and express in correct sig figs • 3 s.f. = 4 s.f. x 3 s.f. x ∞ s.f. • $13.1 = 39.50 L x 0.264 gal 1L x $1.26 1 gal Tips to Avoid Rounding Errors • Write only one equation for the entire question • If you must do more than one equation, do not round before you get to the final answer • Instead, write down as many digits as you can or use the memory function on your calculator (M+) • This is the difference b/t right and wrong answers! SI Units • The International System of Units (Le Système International d’Unités) • Modernized version of the metric system used in science • Any SI prefix can be used with any SI base unit SI Units SI Prefixes Quantity Unit name Unit Symbol Length metre m Mass kilogram kg Volume litre L Time second s Temperature kelvin K Amount of Substance mole mol Electric current ampere A Written Prefix mega Prefix Symbol M Equivalent Exponential 106 kilo hecto k h 103 102 deka deci centi da d c 101 100 10-1 10-2 milli micro m μ 10-3 10-6 SI Prefixes Written Prefix mega Prefix Symbol M Equivalent Exponential 106 kilo hecto k h 103 102 deka deci centi da d c 101 100 10-1 10-2 milli micro m μ 10-3 10-6 • 5 Mm = 5x106 m • 5 m = 5x10-6 Mm • 12 ms = 1.2x10-3 s • 12 s = 1.2x103 ms Other Units & Equivalences • 1 t = 1 tonne = 103 kg • 1 mL = 1 cm3 (cubic centimetres, cc) • 103 L = 1 m3 Derived Units • A unit made by combining two or more other units • Speed = distance/time = km/h • Density = mass/volume = g/L Group Activity • Closed book, open notes • I give questions • 5 min to discuss the solution in your group • Make sure everyone understands the steps • I pick a number, that number from every group stands up, I pick one (or more) to write answers on the board • No notes allowed when you come up to write • Get into your groups and remember your numbers Question 1 • Express 905 in 2 sig figs Question 1 Express 905 in 2 sig figs = 9.0 x 102 Question 2 1.805 x 104 + 5.89 x 102 = ? Question 2 1.805 x 104 + 5.89 x 102 = ? Always convert smaller exponent to the bigger one 1.805 x 104 + 0.0589 x 104 = 1.864 x 104 Question 3 25.00 x 0.1000 – 15.87 x 0.1036 Question 3 25.00 x 0.1000 – 16 x 0.1036 = 2.500 – 1.6576 = 0.8424 = 0.8 Question 4 • If there are 6.02 x 1023 atoms in 1 mol of atoms, how many atoms are there in 5.5 mol of atoms? Question 4 • If there are 6.02 x 1023 atoms in 1 mol of atoms, how many atoms are there in 5.5 mol of atoms? Question 5 • Sugar costs $0.980/kg. 1 t = 1000 kg. How many tonnes (“t”) of sugar can you buy for $350? Guiding Questions for the Video • What are the differences between exact and measured numbers? • What are the two kinds of 0’s and how do we tell them apart? • Are there disagreements between the video and your notes? • Hand in tomorrow: sig figs worksheet, Hebden p. 14 #2-10 • Practice: Hebden p.19-22 #11-18 • Start studying for unit 1 test on Monday • Tomorrow will be a fun review activity