I. OVERVIEW of the VORTEX PHYSICS A. General phenomenological approach to second order phase transitions 1. The order parameter field and spontaneous symmetry breaking A second order phase transition is generally well described phenomenologically if one identifies: a). The order parameter field i (x) b) Symmetry group G and its spontaneous breaking pattern. L.D. Landau ( 1937 ) 1 Rest of degrees of freedom are “irrelevant” sufficiently close to the critical temperature Tc. Later, the “relevant” part, namely the symmetry breaking pattern and dimensionality was termed “the universality class”. An example: XY- (anti) ferromagnet Consider in-plane (planar) classical spins of fixed length S 1 defined on the D-dimensional lattice (the type of lattice and other micriscopic details are also irrelevant). 2 1. T=0 well ordered 2. 0<T<Tc ordered M S 0 large M 0 small 3. T>Tc disordered M S 0 3 a. Order parameter : magnetization. M (M x , M y ) or, using complex numbers, M x iM y b . Symmetry : 2D rotations M x cos M x sin M y M x ' M y sin M x cos M y M y ' 4 Using complex numbers the symmetry transformation becomes U(1): i e Symmetry means that the energy of the rotated state is the same as that of the original (not rotated) one. F (M ) F (M ' ) 5 2. Effective free energy near the phase transition Most general functional symmetric under ei and space rotations, with lowest possible powers of and lowest number of gradients is b(T ) 2 F d x * a (T ) * ( * ) 2 D Higher order terms * , ( * )3 ,.... 2 are expected to be smaller close enough to Tc. 6 The remaining coefficients can be expanded around Tc: a(T ) (T Tc ) ..., b(T ) ... F F T Tc T Tc Now we apply this general considerations to the superconductor – normal metal phase transition. 7 B. Ginzburg – Landau description of the SC-normal transition 1. Symmetry and order parameter in terms of the microscopic degrees of freedom a. Order parameter The complex order parameter is “amplitude of the Cooper pair center of mass”: ( x ) ( x ),(k ) c k c k which is “the gap function” of BCS or any other (no matter how “unconventional”) microscopic theory . 8 We disregard the quantum fluctuations of the “bound” state (Cooper pair) and therefore consider the “Bose condensate” amplitude as a classical field. The symmetry content of this complex field can be better specified via modulus and phase: i ( x ) ( x) ns *( x) e ns ( x) ns *( x) 2 ( x) density of the Cooper pairs, the Bose condensate the superconductor (the Josephson, the global U(1) ) phase 9 b. Symmetry The broken symmetry is charge U(1) mathematically the same symmetry as that of the XY magnet. Without external magnetic field the free energy near transition therefore is: 2 3 2 F [ ] d x * (T Tc ) * ( * ) 2 2m * m* 2me Ginzburg and Landau (1950) postulated a reasonable way togeneralize this to the case of arbitrary magnetic field B (x ) : One is using the “principle” of local gauge invariance of electrodynamics. 10 2. Influence of magnetic field. Electrodynamics is invariant under local gauge transformations: ( x ) ei ( x ) ( x) e* 2e c ( x) A( x) A( x) e* x 11 This invariance although not a symmetry (only the “global” part of it is) dictates the charge fields coupling to magnetic field. To ensure local gauge invariance one makes the “minimal substitution”, namely replaces any derivative by a covariant derivative: e* D ( x ) i A ( x ) c The local gauge invariance of the gradient term follows from linearity of the transformation of the covariant derivative: 12 ie * c i ( x ) D ( x ) A ( x ) ( x ) e c e * ie * i ( x ) i A i e c D ei ( x ) | D( x) |2 | D( x) |2 Magnetic field B A Bi ijk j Ak is also gauge invariant. 13 Ginzburg – Landau equations Minimizing the free energy with covariant derivatives one arrives at the set of GL equations: the nonlinear Schrödinger equation (variation with respect to ) 2 e* 2 A (T Tc ) 0 i 2m * c 2 and the supercurrent equation (variation of A): 2 c ie * e * 2 * * B Js ( ) A 4 2m * m*c 14 3. Two characteristic scales GL equations possess two scales. Coherence length characterizes variations of (x) , while the penetration depth l characterizes variations of B (x ) (T ) 2m * (Tc T ) , c m* l (T ) e * 4 Tc T Both diverge at T=Tc. 15 Ginzburg – Landau parameter The only dimensionless parameter is the ratio of the two lengths which is temperature independent: l (T ) m * c (T ) e * 2 Properties of solutions crucially depend on the GL parameter. When 1 2 (the type II superconductivity ) there exist “topologically nontrivial” solutions – the Abrikosov vortices. Abrikosov (1957) 16 C. Abrikosov Vortices 1. Why look for an asymmetric “singular” solution? Normally one doesn’t look for inhomogeneous solutions in a homogeneous physical situation. Also one prefers to consider smooth regular one rather than singular solutions of field equations. Examples: Maxwell, Schrödinger eqs. etc. However the type II superconductor case is very special. Homogeneous external magnetic field does penetrate a sample as an array. One has to look for these solutions due to combination of four facts. Two crucial and two more technical. 17 a. Interface energy is negative for type II superconductors, while positive for the type I. Mixed state under applied magnetic field H H Type I : Type II: Minimal area of domain walls. Maximal area of domain walls. 18 b. Flux quantization. Division into domains stops due to this. To minimize the potential term far from isolated vortex (where (Tc T ) 0 B=0 ), one has to optimize the modulus of the order parameter: The phase however is free to vary. In order to minimize the (positive) gradient term, one demands: D x 0 De i ( x ) e * i ( x ) 0 i A e 0 c e* A c Fgrad 0 19 c ds A e* C C ds n 0 C ninteger hc hc 0 e * 2e c. n=1 is energetically favored over n>2 d. The normal core 0 region shrinks to a point. 20 2. Shape of the vortex solution B 0 l J Vortex – a linear topological defect. The “singularity” line 0 r core l 21 Abrikosov vortices in type II superconductors as seen by electron beam tomography. KT pair Tonomura et al PRL66,2519 (1993) Tonomura et al PRB43,7631 (1991) 22 D. Overview of properties of vortices and systems of vortices (vortex matter) 1. Inter-vortex repulsion and the Abrikosov flux line lattice Line energy To create a vortex, one has to provide energy per unit length ( line tension ) l 0 log 4l Therefore vortices enter an infinite sample only when field exceeds certain value 2 23 Interactions between vortices They interact with each other via a complicated vectorvector force. Parallel straight vortices repel each other forming highly ordered structures like flux line lattice (as seen by STM and neutron scattering). S.R.Park et al (2000) Pan et al (2002) 24 Two critical fields As a result the phase diagram of type II SC is richer than that of the two-phase type I H c1 H Hc2 Normal 0 4l 2 first vortex penetrates. 0 cores overlap Hc2 2 2 Mixed Hc1 T Meissner H c 2 2l 2 2 2 2 1 H c1 Tc 25 Two theoretical approaches to the mixed state Just below H c 2 vortex cores almost overlap. Instead of lines one just sees array of superconducting “islands” Hc2 Mixed Lowest Landau level appr. for constant B Hc1 Meissner Just above H c1vortices are well separated and have very thin cores Tc London appr. for infinitely thin lines 26 2. Thermal fluctuations and the vortex liquid In high Tc SC due to higher Tc, smaller and high anisotropy thermal fluctuations are not negligible. Thermally induced vibrations of the flux lattice can melt it into a “vortex liquid”. The phase diagram becomes more complicated. H Hc2 FLL Normal Vortex liquid H c1 Meissner Tc T 27 First order melting of the Abrikosov lattice Magnetization Zeldov et al Nature (1995) Specific heat Schilling et al Nature (1996,2001) 28 Metastable states: zero field cooled and field cooled protocols result in different states. Neutron scatering in Nb Ling et al (2000) 29 Vortex “cutting” and entanglement Vortices can entangle around each other like polymers, however due to vectorial nature of their interaction they can also “disentangle” or “cut each other”. There are therefore profound differences compared to the physics of polymers 30 3. Disorder and the vortex glass point Columnar Vortices are typically pinned by disorder. For vortex systems pinning create a glassy state or viscous entangled liquid. In the glass phase material becomes superconducting (zero resistance) below certain critical current Jc. 31 Imperfections act as pinning centers of vortices STM of both the pinning centers (top) and vortices (bottom) Pan e al PRL (2000) Disappearance of Bragg peaks as the disorder increases Gammel et al PRL (1998) 32 4. Vortex dynamics Vortices move under influence of external current (due to the Lorentz force). Field driven flux motion probed by STM on NbSe2 A.M.Troianovski (2004) The motion is generally friction dominated. Energy is dissipated in the vortex core which is just a normal metal. The resistivity of the flux flow is no longer zero. 33 Vortex loops, KT pairs and avalanches Current produces expanding vortex loops even in the Meissner phase leading to non-ohmic “broadening” of I-V curves J ext V const / T I e I In 2D thermal fluctuations generate a curious Kosterlitz – Thouless vortex plasma exhibiting many unique features well understood theoretically 34 Unstable normal domain under homogeneous quench splits into vortex-antivortex (KT) plasma Kirtley,Tsuei and Tafuri (2003) Polturak, Maniv (2004) Scanning SQUID magnetometer 35 Spontaneous flux in rings Kirtley,Tsuei and Tafuri (2003) 36 Vortex front propagation is normally shock wave like, but occasionally creates avalanches after 50 ns after 10 s Boltz et al (2003) Magneto-optics in YBCO films, 10K, B=30mT, size 2.3x1.5 mm 37 5. Vortex dynamics in the presence of disorder Disorder profoundly affects dynamics leading to the truly superconducting vortex glass state in which exhibits irreversible and memory dependent phenomena (like aging). Magneto-optics in Nb Johansson et al (2004) It became perhaps the most convenient playground to study the glass dynamics 38 Dependence on magnetic history: the field cooled and the field cooled with return protocols result in different states. Transport in Nb Reversible region Voltage (V) 30 B 30 FCW FCW FCW 4.2K 80% 20 20 10 10 4.90 K FC 0 0.01 FC Irreversible region 0.1 Time(ms) 1 FC 0 0.01 0.1 6.30 K T Andrei et al (2004) 1 Time(ms) 39 Summary 1. In extreme type II superconductors the “topological” vortex degrees of freedom dominate most of the macroscopic magnetic and transport properties. 2. One can try to use the GL theory to describe these degrees of freedom. 3. Experiments suggest that in new high Tc SC thermal fluctuations are important as well as disorder. 4. The vortex matter physics is quite unique, well controlled experimentally and may serve as a “laboratory” to test a great variety of theoretical ideas. 40