Unit 6 Student Notes: Properties of Light and Electron Configuration Name____________________________ Hr____ General Chemistry Video 1: Properties of Light Light can behave as a ___________________ or a ___________________. Wavelength - The Electromagnetic Spectrum … Characteristics of Visible Light: 1. Wavelengths between ________ nm and _______ nm. 2. The order of the colors from longest wavelength to shortest wavelength is… 3. We see colors when… 4. If all colors are reflected off of an object, the object appears to be ______________________. 5. If all colors are absorbed, the object appears to be ______________________. Frequency – __________ wavelength __________ frequency __________ energy Speed of Light – __________ wavelength __________ frequency __________ energy Page 1 of 11 Unit 6 Student Notes: Properties of Light and Electron Configuration Name____________________________ Hr____ General Chemistry Properties of Light, continued... 1. Does a longer or a shorter wavelength have the higher frequency? 2. Consider a stoplight. Which of the three colors—red, yellow or green—has the… a. Longest wavelength? b. Highest frequency? Video 1 Stamp c. Highest energy? Video 2: Light Calculations c=fλ Ephoton = h f hc λ Ephoton = c Ephoton f h λ Problem 1: Violet light has a wavelength of 4.10 x 10-12 m. What is the frequency? Problem 2: A particular light has a frequency of 6.01 x 1014 Hz. What is the wavelength in nm? Is it in the visible range? Problem 3: Calculate the energy of a photon of radiation with a frequency of 8.5 x 1014 Hz. Page 2 of 11 Unit 6 Student Notes: Properties of Light and Electron Configuration Name____________________________ Hr____ General Chemistry Problem 4: Calculate the energy of a photon of radiation with a wavelength of 6.4 x 10-7 m. Problem 5: A plastic toy reflects a wavelength with energy of 4.0 x 10-19 J of energy. Given the information below, determine the color of the toy. Red Orange Yellow Green Blue Indigo Violet 700-650 nm 649-580 nm 579-575 nm 574-490 nm 489-455 nm 454-425 nm 424-400 nm Problem 6: An electron gives off electromagnetic radiation with energy of 5.25 x 10-22 J. Calculate the frequency of the radiation emitted by the electron. Video 2 Stamp Video 3: Atomic Spectra and Quantum Numbers Continuous Spectrum: Emission Spectrum: Absorption Spectrum: Every element has a __________________ emission / absorption spectrum. This is one way to identify an element. __________________ __________________ studied the emission spectrum of hydrogen to determine that electrons are on different energy levels. Ground State: All electrons are in the __________________ energy level available. Excited State: When an electron temporarily moves to a __________________ energy level. Page 3 of 11 Unit 6 Student Notes: Properties of Light and Electron Configuration Name____________________________ Hr____ General Chemistry In order to move from one energy level to another, electrons must gain or lose an exact amount of energy known as a __________________. The __________________ of an electron is described by a series of 4 quantum numbers: n, l, ml, and ms. You can think of these as being the “__________________” for an electron’s probably location. (State, city, street, house number – each gets more and more specific.) Electrons contain __________________ amounts of energy. The amount of energy they contain determines where in the electron cloud they are located. ____________________________ : n *Electron clouds are made up of energy levels which are like __________________ of a ladder, but they are not equally spaced. *The higher the value of n… the __________________ away from the nucleus the electron is the __________________ the energy level and the __________________ energy the electron must have to stay there *The maximum number of electrons in any energy level can be found using the following formula: #e- = 2n2 Energy Level (n) Maximum number of electrons n=1 n=2 n=3 n=4 n=5 Energy Level (n) 1 ____________________________ : l *The 4 sublevels you need to know are: __________________ 4 *Each sublevel contains a certain number of orbitals. s p d f Page 4 of 11 Sublevels Present 3 Sublevel *Each orbital can hold a maximum of ______ electrons. n=7 2 *The __________________ of sublevels on an energy level is equal to ______ for that energy level. ____________________________ : ml n=6 # of orbitals Maximum # of electrons on sublevel (= # orbitals x 2) Unit 6 Student Notes: Properties of Light and Electron Configuration Name____________________________ Hr____ General Chemistry ____________________________ : ms *Electrons within the same orbital must have __________________ spins to overcome their repulsion, which we represent with opposite arrows. *Spin is either + ½ (_____) or – ½ (_____) Video 3 Stamp Video 4: Electron Configuration and Orbital Notation There are 2 ways to indicate the location of the electrons in an atom: Electron Configuration a. b. Orbital Notation a. Uses __________________ to indicate each orbital b. Uses __________________ to indicate the spin of the electron in a specific orbital Page 5 of 11 Unit 6 Student Notes: Properties of Light and Electron Configuration Name____________________________ Hr____ General Chemistry After completing, you will cut this out and place in chemistry notebook. Periodic Table of the Elements Group 1 (IA) 1 Group 18 (VIIIA) 1 2 1s1 1s2 Fill in the periodic table to determine 5 ATOMIC NUMBER the electron configuration of each element. Group 2 (IIA) 3 2 4 2s1 11 5 6 2p1 12 13 14 19 20 Group 3 (IIIB) Group 4 (IVB) Group 5 (VB) 21 22 23 8 2p4 9 10 15 16 17 18 33 34 35 36 51 52 2p6 Group 6 (VIB) Group 7 (VIIB) Group 8 (VIIIB) Group 9 (VIIIB) Group 10 (VIIIB) Group 11 (IB) Group 12 (IIB) 24 25 26 27 28 29 30 31 32 2 2 3d 4 37 38 39 40 1 5 7 2p3 3s2 3 Period Group 13 (IIIA) Group 14 (IVA) Group 15 (VA) Group 16 (VIA) Group 17 (VIIA) 41 42 43 3 5s 55 4p 56 71 72 73 44 45 5 4d 74 75 46 47 88 50 76 77 78 79 80 81 82 105 106 107 108 109 110 111 112 4 57 58 59 84 113 114 115 61 62 63 64 65 66 6 116 7p 67 68 69 1 70 4f14 4f 89 90 91 92 93 94 95 96 97 98 99 100 101 5f13 Page 6 of 11 86 6p 4 7p 60 85 6p 1 6d 7 83 3 5d 104 54 5 10 103 53 5p 6s 87 49 4d 2 6 48 8 4d 102 Unit 6 Student Notes: Properties of Light and Electron Configuration Name____________________________ Hr____ Some things to remember: General Chemistry Example: Electron configuration of vanadium (23V) superscript = the _____________________ 2 2 6 2 6 2 3 1s 2s 2p 3s 3p 4s 3d # in front of letter = the _____________________ letter = the _____________________ _______________________________ – electrons must be placed in orbitals of lowest energy first A sublevel is completely filled before placing electrons in a higher sublevel The last sublevel might not be filled The superscripts must add up to the _________________________________ _________________________________ The valence electrons are… always _____ and _____ electrons on the ________________________ energy level How can I remember the Aufbau Principle? 1. Memorize the following: __________________________________________________________ 2. Memorize this diagram: 3. Use the Periodic Table Complete this portion on the next page. You will cut it out to add to your notebook upon completion. Example: Orbital Notation of vanadium (23V) ↑↓ 1s2 ↑↓ 2s2 ↑↓ ↑↓ ↑↓ 2p6 ↑↓ 3s2 ↑↓ ↑↓ ↑↓ ↑↓ 4s2 3p6 ↑__ ↑__ ↑__ ___ ___ 3d3 Some things to remember about orbital notation: Must correspond to the electron configuration Lines = ________________________ Arrows = _________________________ Total number of arrows must equal the total number of electrons in the atom Each sublevel must have the correct number of orbitals drawn, even if they are empty Follow the __________________________________ Principle – an orbital may only hold up to two electrons, and they must have opposite spin This: ↑↓ Not This: ↑↑ Follow ____________________ Rule – one electron enters each orbital of a sublevel separately and with the same spin until all the orbitals have one electron, then they pair up. This: ↑__ ↑__ ↑__ ___ ___ Not This: ↑↓ ↑__ ___ ___ ___ Page 7 of 11 Unit 6 Student Notes: Properties of Light and Electron Configuration Name____________________________ Hr____ General Chemistry How can I remember the Aufbau Principle? Memorize the following: __________________________________________________________ Use the Periodic Table Memorize this diagram: Return to the previous page to complete the “Things to remember about orbital notation” Page 8 of 11 Unit 6 Student Notes: Properties of Light and Electron Configuration Name____________________________ Hr____ General Chemistry Problem 7: Consider the potassium (K) atom. a. Write the electron configuration for a neutral potassium atom. b. Draw the orbital notation for potassium. c. In which sublevel are the valence electrons? d. How many valence electrons does potassium have? e. The electrons with the highest energy are in which sublevel? Problem 8: Consider the bromine (Br) atom. a. Write the electron configuration for a neutral bromine atom. b. Draw the orbital notation for bromine. c. In which sublevel are the valence electrons? d. How many valence electrons does bromine have? e. The electrons with the highest energy are in which sublevel? Problem 9: Write the electron configurations for the following neutral atoms. a. Carbon b. Silicon c. Zinc Problem 10: Determine the neutral element for the configurations below. a. 1s22s22p63s23p64s23d104p65s24d7 b. 1s22s22p63s23p64s23d104p65s24d8 c. 1s22s22p63s23p64s23d6 Page 9 of 11 Unit 6 Student Notes: Properties of Light and Electron Configuration Name____________________________ Hr____ General Chemistry Abbreviated Configurations (or Noble Gas Configurations) To write the abbreviated configuration, look to the ___________________________ in the previous period. Place ___________________________ around the symbol to indicate the element has the same configuration of that noble gas, plus whatever follows. Example: The electron configuration for iron is ________________________________________. The abbreviated configuration is _____________________________. Video 4 Stamp Video 5: Lewis Dot Structures _______________________ Electrons In the outermost energy level (or shell) Most likely to be involved in _______________________ Helpful in predicting _______________________ numbers (charge within a compound) The noble gases are considered to be _______________________, so their outer shell is _______________________. Steps for drawing Lewis Dot Structures: 1. 2. 3. Problem 11: Draw the Lewis Dot Structures for the following elements. K Al P C Cl Kr Problem 12: Complete the following questions. a. How many valence electrons does sulfur have? Video 5 Stamp b. Draw the Lewis Dot Structure for sulfur. c. How many valence electrons does sodium have? d. Draw the Lewis Dot Structure for sodium. Page 10 of 11 Unit 6 Student Notes: Properties of Light and Electron Configuration Name____________________________ Hr____ General Chemistry Unit 6: Properties of Light & Electron Configuration Properties of Light Unit 56: Video 1 (video 56 on YouTube channel- semester 1) 7:02 Light Calculations Unit 6: Video 2 (video 26 on YouTube channel) 17:06 Atomic Spectra & Quantum Numbers Unit 6: Video 3 (video 57 on YouTube channel) 13:32 Electron Configuration and Orbital Notation Unit 6: Video 4 (video 27 on YouTube channel) 16:16 Lewis Dot Structures Unit 6: Video 5 (video 28 on YouTube channel) 5:26 Page 11 of 11