Presentation Slides for Air Pollution and Global Warming: History, Science, and Solutions Chapter 9: Indoor Air Pollution By Mark Z. Jacobson Cambridge University Press (2012) Last update: February 15, 2012 The photographs shown here either appear in the textbook or were obtained from the internet and are provided to facilitate their display during course instruction. Permissions for publication of photographs must be requested from individual copyright holders. The source of each photograph is given below the figure and/or in the back of the textbook. Sources of Indoor Air Pollution Kerosene heater www.chemistryland.com Gas stove www.sispropane.ca Fireplace Gas heater Car exhaust from garage www.homeinteriorszone.com Sims2.puskala.org www.3planesoft.com Sources of Indoor Air Pollution Particle board Plywood www.vgtrading.com.ar Paneling www.cof.orst.edu www.germes-online.com www.californiapaints.com www.vintageagainsoutheast.com Img.epinions.com Dust mites www.buttercuppuppies.com Aura.gaia.com Dust Mite Feces www.sciencephoto.com Enhs.umn.edu Dust Mite S. Kaulitzki/Dreamstime Pollen Fungal spores specialcomment.wordpress.com www.,materials.drexel.edu Bacteria www.scharfphoto.com Viruses www.healthinitiative.org Static.howstuffworks.com Geoscape.nrcan.gc.ca Radioactive Decay Emission First Evidence of Radioactivity From Becquerel's Notes American Institute of Physics Emilio Segrè Visual Archives, William G. Myers Collection Decay of Uranium to Lead Decay sequence produces radon, polonium, and lead 4.5x109 yr 238U 234Th a 234Pa b 3 min b a b 226Ra 22 yr 210Pb 214Po a 1620 yr a 0.00016 s 30 min 214Bi 8x104 yr 230Th 234U b 27 min 214Pb a 1.2 min 2.5x105 yr 24 d 222Rn 218Po a a 5d 138 d 210Bi b 3.8 d 210Po b 206Pb a (9.1) www.epa.gov Zone 1 (red) = high radon Radon Zones Red= high radon Orange=medium radon Yellow=low radon www.epa.gov Mineral Asbestos Pancaketom/Dreamstime Asbestos Chrysotile Chrysotile Amosite Crocidolite www.enviraz.co.uk Robert Grieshaber Asbestos Ship insulation Attic insulation Lamp wicks www.technicaon-asbestos.co.uk Mine Fire blanket Home insulation Pipe insulation Brake pads oraclesolutionsltd.co.uk Locomotive insulation Roofing products Health Effects of Asbestos Lung cancer: 4800 deaths/yr US Mesothelioma: 2500/yr Cancer of mesothelial membrane lining lungs Asbestosis: 1400/yr US: Slow, debilitating lung disease Gastro-intestinal cancer: 1200 deaths/yr Reports.ewg.org Libby, Montana Vermiculite mine, which produced 80% of the world’s vermiculite, opened in 1918. W.R. Grace Co. owned the mine from 1963-1990, during which 192 deaths and 375 lung injuries due asbestos were reported. Closed Libby vermiculite facility www.bitsofnews.com Libby contaminated soil covered www.home-air-purifier-expert.com Environmental Tobacco Smoke Mainstream smoke Exhaled smoke Sidestream smoke Emitted from burning cigarette Environmental tobacco smoke (ETS) = second-hand smoke Combination of mainstream and sidestream smoke. Contains more than 4000 particle components and gases, over 50 of which are known carcinogens. ETS may cause 17% of lung cancers of nonsmokers. Concentrations One pack of cigarettes ≈ 20 mg m-3 of particles in room over 24 hours. Near smoker, concentrations 500-1000 mg m-3 Mainstream/Sidestream Smoke R. Kneschke/Henrischmit/Dreamstime Comparison of Cigarette with Automobile Emissions Avg. cigarette emission (g/cigarette) CO 0.0464 NOx Particles 0.0021 0.058 Avg. automobile emission (g/mi) 4.2 0.07 0.01 Number of cigarettes resulting in same emission as driving one mile 90.5 33.3 0.17 Est. U.S. cigarette emiss. (tonnes/day) 2.7 76 61 Est. mobile-source emiss. (tonnes/day) 193,000 40,600 12,200 Table 9.3 Indoor Cookstove Kacpura/Dreamstime Indoor Workplace Standards www.ipmsafety.com Indoor Workplace Standards NAAQS apply to outdoor pollution only in the U.S. No regulations control air pollution in indoor residences. Standards for indoor workplaces set by Occupational Safety and Health Administration (OSHA). Recommendations for standards made by National Institute for Occupational Safety and Health (NIOSH) and American Conference of Governmental Industrial Hygienists, Inc. (ACGIH). Permissible exposure limits (PELs) - set by NIOSH Maximum allowable indoor workplace concentration over 8-h day Time-weighted average threshold limit value (TWA-TLV) Similar to PELs, but set by ACGIH Comparison of Indoor with Outdoor Standards Gas Indoor 8-h PEL and TWA-TLV (ppmv) Outdoor NAAQS (ppmv) Outdoor California Standard (ppmv) Carbon monoxide 35 9.0 (8-h) 9 (8-h) Nitrogen dioxide 1 (15-m) 0.053 (annual) 0.18 (1-h) Ozone 0.1 0.075 (8-h) 0.07 (8-h) Outdoor standards tougher to protect entire population. Outdoor standards for NO2(g) tougher since ozone forms outdoors, but not indoors, from NO2(g). Table 9.4