Chapter 2(a) Atoms, Molecules, and Ions Figure 2.7: A cathode-ray tube. The fastmoving electrons excite the gas in the tube, causing a glow between the electrodes. Copyright © Houghton Mifflin Company. All rights reserved. 2a–2 Figure 2.8: Deflection of cathode rays by an applied electric field. Copyright © Houghton Mifflin Company. All rights reserved. 2a–3 Figure 2.9: The plum pudding model of the atom. Copyright © Houghton Mifflin Company. All rights reserved. 2a–4 Figure 2.10: A schematic representation of the apparatus Millikan used to determine the charge on the electron. Copyright © Houghton Mifflin Company. All rights reserved. 2a–5 Rutherford Copyright © Houghton Mifflin Company. All rights reserved. 2a–6 Figure 2.12: Rutherford's experiment on -particle bombardment of metal foil. Copyright © Houghton Mifflin Company. All rights reserved. 2a–7 Figure 2.13: (a) The expected results of the metal foil experiment if Thomson's model were correct. (b)Actual results. Copyright © Houghton Mifflin Company. All rights reserved. 2a–8 Figure 2.14: A nuclear atom viewed in cross section. Note that this drawing is not to scale. So how many nucleons (protons or neutrons) in 1 gram? 1 / 1.67 x 10-24 = 6.022 x 1023 Copyright © Houghton Mifflin Company. All rights reserved. = Avogadro’s number = N 2a–10 The molar mass of water is 18 g/mol. How many water molecules are present in 18 cc of water? How much does 1 mole of water weigh? How many hydrogen atoms are present In 9 grams of water? Copyright © Houghton Mifflin Company. All rights reserved. 2a–11 Nitrogen (N2) and hydrogen (H2) react to form ammonia (NH3): N2 + H2 NH3 N2 + 3H2 2NH3 How much hydrogen is need to completely react with 7 grams of nitrogen? How much ammonia will that produce? With 7 gram each of nitrogen and hydrogen, Which is the limiting reagent? Copyright © Houghton Mifflin Company. All rights reserved. 2a–12 Figure 2.15: Two isotopes of sodium. Both have eleven protons and eleven electrons, but they differ in the number of neutrons in their nuclei. Copyright © Houghton Mifflin Company. All rights reserved. 2a–13 Figure 2.21: The Periodic Table. Copyright © Houghton Mifflin Company. All rights reserved. 2a–14 Copyright © Houghton Mifflin Company. All rights reserved. 2a–15 Copyright © Houghton Mifflin Company. All rights reserved. 2a–16 Copyright © Houghton Mifflin Company. All rights reserved. 2a–17 Crystals of copper(II) sulfate. Copyright © Houghton Mifflin Company. All rights reserved. 2a–18 Various chromium compounds dissolved in water. From left to right; CrCl2, K2Cr2O7, Cr(NO3)3, CrCl3, K2CrO4. Copyright © Houghton Mifflin Company. All rights reserved. 2a–19 Figure 2.22: The common cations and anions Copyright © Houghton Mifflin Company. All rights reserved. 2a–20 Copyright © Houghton Mifflin Company. All rights reserved. 2a–21 Copyright © Houghton Mifflin Company. All rights reserved. 2a–22 Figure 2.23: A flowchart for naming binary compounds. Copyright © Houghton Mifflin Company. All rights reserved. 2a–23 Figure 2.24: Overall strategy for naming chemical compounds. Copyright © Houghton Mifflin Company. All rights reserved. 2a–24 Copyright © Houghton Mifflin Company. All rights reserved. 2a–25 Copyright © Houghton Mifflin Company. All rights reserved. 2a–26 Figure 2.25: A flowchart for naming acids. An acid is best considered as one or more H+ ions attached to an anion. Copyright © Houghton Mifflin Company. All rights reserved. 2a–27 Copyright © Houghton Mifflin Company. All rights reserved. 2a–28 Copyright © Houghton Mifflin Company. All rights reserved. 2a–29 Figure 2.4: A representation of some of Gay-Lussac's experimental results on combining gas volumes. Copyright © Houghton Mifflin Company. All rights reserved. 2a–30 Figure 2.5: A representation of combining gases at the molecular level. The spheres represent atoms in the molecules. Copyright © Houghton Mifflin Company. All rights reserved. 2a–31 The molar mass of styrene is 104.14 g/mol. How many styrene molecules are present in 104.14 gram of styrene? The empirical formula of styrene is CH; How many H atoms are present in a 52.07 g sample of styrene? what is the molecular formula of styrene? Copyright © Houghton Mifflin Company. All rights reserved. 2a–32 Figure 2.16: The structural formula for methane. Figure 2.17: Space-filling model of methane. This type of model shows both the relative sizes of the atoms in the molecule and their spatial relationships. Copyright © Houghton Mifflin Company. All rights reserved. 2a–34 Figure 2.18: Ball-and-stick model of methane. Copyright © Houghton Mifflin Company. All rights reserved. 2a–35 Figure 2.19: Sodium metal reacts with chlorine gas to form solid sodium chloride. Figure 2.20: Ball-and-stick models of the ammonium ion and the nitrate ion. Copyright © Houghton Mifflin Company. All rights reserved. 2a–37 Figure 1.13: The three states of water (where red spheres represent oxygen atoms and blue spheres represent hydrogen atoms). Copyright © Houghton Mifflin Company. All rights reserved. 1b–38 Figure 1.14: Simple laboratory distillation apparatus. Copyright © Houghton Mifflin Company. All rights reserved. 1b–39 Figure 1.16: The organization of matter. Copyright © Houghton Mifflin Company. All rights reserved. 1b–40