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Optical Mineralogy

WS 2008/2009

Next week ….

So far ….

Light - properties and behaviour;

Refraction - the refractive index (

n

) of minerals leads to many of their optical properties

Snell’s law

- learn it!;

Double refraction;

Polarization and the polarizing microscope;

Plane polarised light observations (PPL):

• crystal shape/habit

• colour/pleochroism

• cleavage/fracture

• relief, Becke test

 refractive index estimation

Crystal systems and symmetry

The crystal systems are sub-divided by their degree of symmetry….

CUBIC > TETRAGONAL, HEXAGONAL, TRIGONAL >

ORTHORHOMBIC, MONOCLINIC, TRICLINIC

The Optical Indicatrix

The optical indicatrix is a 3-dimensional graphical representation of the mineral; changing refractive index of a

The shape of the indicatrix reflects the crystal system to which the mineral belongs;

The distance from the centre to a point on the surface of the indicatrix is a direct measure of

n

at that point.

The Optical Indicatrix

The simplest case - cubic minerals (e.g. garnet)

Cubic minerals have highest symmetry (a=a=a);

If this symmetry is reflected in the changing refractive index of the mineral, what 3-d shape will the indicatrix be?

Isotropic indicatrix (= cubic)

Sphere

n

is constant is every direction isotropic minerals do not change the vibration direction of the light - no polarisation

Indicatrix = 3-d representation of refractive index

Isotropic indicatrix

Isotropic minerals and polarized light

West (links)

Ost (rechts)

Polarisator z.B. Granat

Süden

(vorne)

Analysator

Norden

(hinten)

Schwarz!!

Beobachtungen unter gekreuzten Polarisatoren

(gekreuzte Nicols)

XPL = crossed nicols (crossed polars)

Anisotropic minerals

– Double refraction

Example: Calcite

The incident ray is split into 2 rays that vibrate perpendicular to each other.

These rays have variable

v

variable

n

)

(and therefore fast and slow rays

One of the rays (the fast ray for calcite) obeys Snell’s Law ordinary ray (

n

o

)

The other ray does not obey Snell’s law extraordinary ray (

n

e

)

Birefringence = Δ

n

=

n

e

n

o

Anisotropic Minerals

– The Uniaxial Indicatrix

c-axis c-axis

Quartz

Calcite

What does the indicatrix for each mineral look like?

Uniaxial indicatrix

– ellipsoid of rotation c=Z optic axis

≡ c-axis c=X

n

e

n

o b=Y=X

n

e

n

o a=X

n

e

>

n

o uniaxial positive (+)

PROLATE or ‘RUGBY BALL‘

NOTE:

n

o

n

e

=

n



n

 a=X

n

e

<

n

o uniaxial negative (-)

OBLATE or ‘SMARTIE‘

b=Y

Quartz

n

e

>

n

o uniaxial positive

Calcite

n

e

<

n

o uniaxial negative

Uniaxial Indicatrix

All minerals belonging to the TRIGO

NAL

, TETRAGO

NAL

and HEXAGO

NAL

indicatrix….

crystal systems have a uniaxial

This reflects the dominance of the axis of symmetry (= c-axis) in each system ( 3-, 4and 6 fold respectively)….

Different slices through the indicatrix (+)

Basal section

Cut perpendicular to the optic axis: only n o

No birefringence

(isotropic section)

Principal section

Parallel to the optic axis: n o

Maximum birefringence

& n e

Random section

 n e' n e' and n o is between n e and n

Intermediate birefringence o

All sections contain n o

!

c=Z b=Y n

 n

 a=X

Basal Section

Cut PERPENDICULAR to the caxis,

Contains only n o

(n

)

Isotropic section

(remains black in XN)

n

> n

Principal Section

Cut PARALLEL to the c-axis, contains n o

(n

) und n e

(n

)

The principal section shows MAXIMUM birefringence and the HIGHEST polarisation colour

DIAGNOSTIC PROPERTY OF

MINERAL

Random Section

Cut at an angle to the c-axis, contains n o

(n

) und n e‘

(n

)

A random section shows an intermediate polarisation colour

 no use for identification purposes

Double Refraction

Privileged Vibration directions

In any random cut through an anistropic indicatrix, the privileged vibration directions are the long and short axis of the ellipse. We know where these are from the extinction positions

….

n e n o n o

Polariser

Parallel position

Polariser parallel to n e

:

 only the extraordinary ray is transmitted inserting the analyser

BLACK

=

EXTINCTION POSITION

Polariser parallel to n o

:

 only the ordinary ray is transmitted inserting the analyser

BLACK

=

EXTINCTION POSITION n e

Diagonal position

n

e

Polariser

n

o

Split into perpendicular two rays (vectors) :

1) ordinary ray where

n = n o

2) extraordinary ray where

n = n e

Each ray has a N-S component, which are able to pass through the analyser.

Maximum brightness is in the diagonal position.

As both rays are forced to vibrate in the N-S direction, they INTERFERE

So why do we see polarisation colours?

Fast wave with v f

(lower n f

) d

Mineral

Retardation (

Gangunterschied

)

Polariser

(E-W)

= retardation

Slow wave with v s

(higher n s

)

Polarised light (E_W)

After time, t, when the slow ray is about to emerge from the mineral:

The slow ray has travelled distance d…..

The fast ray

…..

has travelled the distance d +

Slow wave :

Fast wave:

…and so t = d/v s t = d/v f

+

/v air d/v s

= d/v f

+

/v air

= d(v air

/v s

= d(n s

- n f

)

= d ∙ Δn

- v air

/v f

)

Retardation,

= d ∙ Δn (in nm)

….and we know d (= 30

 m)….

Interference

Analyser forces rays to vibrate in the N-S plane and interfere .

Destructive interference

(extinction):

= k∙

 k = 0, 1, 2, 3, …

Constructive interference

(maximum intensity):

= (2k+1) ∙

/2 k = 0, 1, 2, 3, …

Explanation of interference colours

Example: a mineral with retardation of 550 nm in the diagonal position

Retardation,

Wavelength,

550

400

550

440

550

489

550

550

550

629

550

733

1

3

/

8 l 1

1

/

4 l 1

1

/

8 l 1 l

7

/

8 l

550 nm is lost, other wavelengths will be partly or fully transmitted.

3

/

4 l

Retardation,

Wavelength,

550

400

1

3

/

8 l

550

440

1

1

/

4 l

550

489

1

1

/

8 l

550

550

1 l

550

629

7

/

8 l

550

733

3

/

4 l

No green

(absorbed)

 red + violet

 purple interference colour

Fig 7-7 Bloss, Optical

Crystallography, MSA

Retardation,

Wavelength,

800

400

2 l

800

426

1

7

/

8 l

800

457

1

3

/

4 l

800

550

1

1

/

2 l

800

581

1

3

/

8 l

800 800

711 800

1

1

/

8 l 1 l

No red or violet

(absorbed)

 green interference colour

Fig 7-7 Bloss, Optical

Crystallography, MSA

Michel-

Lévy colour chart

Michel-

Lévy colour chart birefringence ( d

) d

= 0.009

d

= 0.025

30

 m

(0.03 mm) retardation (

) first order second order third order

….orders separated by red colour bands….

Uniaxial indicatrix - summary

Can be positive or negative;

Mierals of the tetragonal, trigonal and hexagonal crystal systems have a uniaxial indicatrix;

All sections apart from the basal section show a polarisation colour;

All sections through the indicatrix contain

n

w

;

The basal section is isotropic and means you are looking down the c-axis of the crystal;

The principal section shows the maximum polarisation colour characteristic for that mineral.

Polarisation colours

Isotropic (cubic) minerals show no birefringence and remain black in XN;

Anisotropic minerals have variable

n

polarisation colours; and therefore show

The larger

 n is, the higher the polarisation colour;

The polarisation colour is due to interference of rays of different velocities;

THE MAXIMUM POLARISATION COLOUR IS THE

CHARACTERISTIC FEATURE OF A MINERAL (i.e., look at lots of grains);

Polarisation colours should be reported with both

ORDER and COLOUR (e.g., second order blue, etc.).

Todays practical…..

Making the PPL observations you made in the previous 2 weeks;

Putting a scale on your sketches to estimate grain sizes;

Distinguishing isotropic from anisotropic minerals;

Calculating retardation;

Calculating and reporting birefringence - fringe counting.

Thinking about vibration directions….

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