PHYSICS 1401 SEMESTER EXAM REVIEW 1.1 Measurements Micrometer Vernier caliper Photogate (millisec) % error theoretica l value - experiment al value theoretica l value (100%) 1.2 Resultant and Equilibrant 2.4 Motion Graphs 2.4 Equations of Kinematics for Constant Acceleration Equations of Kinematics for Constant Acceleration POSITION, VELOCITY & ACCELERATION v vo at x 1 2 vo v t v v 2ax 2 2 o x vot at 1 2 2 3.2 Equations of Kinematics in Two Dimensions vx vox axt x voxt a x t 1 2 x 2 1 2 vox vx t v v 2a x x 2 x 2 ox 3.2 Equations of Kinematics in Two Dimensions v y voy a y t y voyt a yt 1 2 y 1 2 v oy 2 vy t v v 2a y y 2 y 2 oy 3.3 Projectile Motion Under the influence of gravity alone, an object near the surface of the Earth will accelerate downwards at 9.80 m/s2. a y 9.80 m s 2 ax 0 vx vox constant 3.3 Projectile Motion Objects falling in a vacuum will experience the same speed. Galileo started experimenting to test the theories of other scientists such as Aristotle. 3.3 Projectile Motion Properties of Projectile Motion 1. Horizontal velocity stays constant. 2. No vertical velocity when object is thrown horizontally from the top of hill. 3. When object is launched from the ground, velocity has horizontal and vertical components. 4. At the top of the trajectory, no vertical velocity, but there is acceleration due to gravity. 5. The time for a projectile to reach the top is equal to the time for it to go back to the ground. 6. The initial launching velocity is equal to the final lvelocity just before it hits the ground. 3.3 Projectile Motion y ay -1050 m -9.80 m/s2 vy voy t ? 0 m/s 14.6 s 3.3 Projectile Motion y ay vy voy ? -9.80 m/s2 0 14 m/s t 3.3 Projectile Motion Example 7 The Time of Flight of a Kickoff What is the time of flight between kickoff and landing? 3.3 Projectile Motion y ay 0 -9.80 m/s2 vy voy t 14 m/s ? 3.3 Projectile Motion y ay vy 0 -9.80 m/s2 voy t 14 m/s ? y voyt a yt 1 2 0 14 m s t 1 2 2 9.80 m s t 2 2 0 214 m s 9.80 m s t t 2.9 s 2 3.3 Projectile Motion Example 8 The Range of a Kickoff Calculate the range R of the projectile. x voxt axt voxt 1 2 2 17 m s 2.9 s 49 m 4.2 Newton’s First Law of Motion An object continues in a state of rest or in a state of motion at a constant speed along a straight line, unless compelled to change that state by a net force. The net force is the vector sum of all of the forces acting on an object. If the vector sum is equal to zero, then the system is in equilibrium. 4.2 Newton’s First Law of Motion Inertia is the natural tendency of an object to remain at rest in motion at a constant speed along a straight line. The mass of an object is a quantitative measure of inertia. SI Unit of Mass: kilogram (kg) 4.3 Newton’s Second Law of Motion Newton’s Second Law When a net external force acts on an object of mass m, the acceleration that results is directly proportional to the net force and has a magnitude that is inversely proportional to the mass. The direction of the acceleration is the same as the direction of the net force. a F m F ma 4.3 Newton’s Second Law of Motion SI Unit for Force m kg m kg 2 2 s s This combination of units is called a newton (N). 4.4 The Vector Nature of Newton’s Second Law The direction of force and acceleration vectors can be taken into account by using x and y components. F ma is equivalent to F y ma y F x max 4.5 Newton’s Third Law of Motion Newton’s Third Law of Motion Whenever one body exerts a force on a second body, the second body exerts an oppositely directed force of equal magnitude on the first body. It involves TWO objects to form an action-reaction pair. 4.6 Types of Forces: An Overview In nature there are two general types of forces, fundamental and nonfundamental. Fundamental Forces 1. Gravitational force 2. Strong Nuclear force 3. Electroweak force 4.6 Types of Forces: An Overview Examples of nonfundamental forces: friction tension in a rope normal or support forces 4.7 The Gravitational Force Newton’s Law of Universal Gravitation Every particle in the universe exerts an attractive force on every other particle. He said gravity is universal. The force that each exerts on the other is directed along the line joining the particles. 4.7 The Gravitational Force For two particles that have masses m1 and m2 and are separated by a distance r, the force has a magnitude given by m1m2 F G 2 r G 6.673 1011 N m 2 kg 2 4.7 The Gravitational Force m1m2 F G 2 r 6.67 10 8 11 1.4 10 N N m kg 2 2 12 kg 25 kg 2 1.2 m 4.7 The Gravitational Force 4.9 Static and Kinetic Frictional Forces When the two surfaces are not sliding across one another the friction is called static friction. 4.9 Static and Kinetic Frictional Forces The magnitude of the static frictional force can have any value from zero up to a maximum value. fs f f MAX s 0 s 1 MAX s s FN is called the coefficient of static friction. 4.9 Static and Kinetic Frictional Forces Note that the magnitude of the frictional force does NOT depend on the contact area of the surfaces. 4.9 Static and Kinetic Frictional Forces Static friction opposes the impending relative motion between two objects. Kinetic friction opposes the relative sliding motion motions that actually does occur. f k k FN 0 k 1 is called the coefficient of kinetic friction. 4.9 Static and Kinetic Frictional Forces 4.10 The Tension Force Cables and ropes transmit forces through tension. 4.11 Equilibrium Application of Newton’s Laws of Motion Definition of Equilibrium An object is in equilibrium when it has zero acceleration. Fx 0 Fy 0 4.12 Nonequilibrium Application of Newton’s Laws of Motion When an object is accelerating, it is not in equilibrium. F x max Fy may 5.1 Uniform Circular Motion Let T be the time it takes for the object to travel once around the circle. r 2 r v T 5.2 Centripetal Acceleration The direction of the centripetal acceleration is towards the center of the circle; in the same direction as the change in velocity. 2 v ac r 5.3 Centripetal Force Recall Newton’s Second Law When a net external force acts on an object of mass m, the acceleration that results is directly proportional to the net force and has a magnitude that is inversely proportional to the mass. The direction of the acceleration is the same as the direction of the net force. a F m F ma 5.3 Centripetal Force Thus, in uniform circular motion there must be a net force to produce the centripetal acceleration. The centripetal force is the name given to the net force required to keep an object moving on a circular path. The direction of the centripetal force always points toward the center of the circle and continually changes direction as the object moves. 2 v Fc mac m r 5.7 Vertical Circular Motion 2 1 v FN 1 mg m r FN 2 FN 4 2 2 v m r 2 4 v m r 2 3 v FN 3 mg m r 6.1 Work Done by a Constant Force W Fs 1 N m 1 joule J 6.1 Work Done by a Constant Force W F cos s cos 0 1 cos 90 0 cos 180 1 6.1 Work Done by a Constant Force W F cos 0s Fs W F cos180s Fs 6.2 The Work-Energy Theorem and Kinetic Energy THE WORK-ENERGY THEOREM When a net external force does work on and object, the kinetic energy of the object changes according to W KEf KEo mv mv 1 2 2 f 1 2 2 o 6.3 Gravitational Potential Energy W F cos s Wgravity mg ho h f 6.3 Gravitational Potential Energy Wgravity mg ho h f 6.3 Gravitational Potential Energy Wgravity mgho mgh f DEFINITION OF GRAVITATIONAL POTENTIAL ENERGY The gravitational potential energy PE is the energy that an object of mass m has by virtue of its position relative to the surface of the earth. That position is measured by the height h of the object relative to an arbitrary zero level: PE mgh 1 N m 1 joule J 6.3 Gravitational Potential Energy W 12 mvf2 12 mvo2 mgho h f 12 mvo2 Wgravity mg ho h f vo 2 g ho h f vo 2 9.80 m s 2 1.20 m 4.80 m 8.40 m s 6.4 Conservative Versus Nonconservative Forces Version 1 A force is conservative when the work it does on a moving object is independent of the path between the object’s initial and final positions. Wgravity mg ho h f 6.4 Conservative Versus Nonconservative Forces Version 2 A force is conservative when it does no work on an object moving around a closed path, starting and finishing at the same point. Wgravity mg ho h f ho h f 6.5 The Conservation of Mechanical Energy THE PRINCIPLE OF CONSERVATION OF MECHANICAL ENERGY The total mechanical energy (E = KE + PE) of an object remains constant as the object moves, provided that the net work done by external nonconservative forces is zero. 6.5 The Conservation of Mechanical Energy 6.5 The Conservation of Mechanical Energy Ef Eo mghf mv mgho mv 1 2 2 f 1 2 gh f 12 v 2f gho 12 vo2 2 o 6.7 Power DEFINITION OF AVERAGE POWER Average power is the rate at which work is done, and it is obtained by dividing the work by the time required to perform the work. Work W P Time t joule s watt (W) 6.7 Power Change in energy P Time 1 horsepower 550 foot pounds second 745.7 watts P Fv 6.8 Other Forms of Energy and the Conservation of Energy THE PRINCIPLE OF CONSERVATION OF ENERGY Energy can neither be created nor destroyed, but can only be converted from one form to another. 6.9 Work Done by a Variable Force Constant Force W F cos s Variable Force W F cos 1 s1 F cos 2 s2 7.1 The Impulse-Momentum Theorem There are many situations when the force on an object is not constant. 7.1 The Impulse-Momentum Theorem DEFINITION OF IMPULSE The impulse of a force is the product of the average force and the time interval during which the force acts: J F t Impulse is a vector quantity and has the same direction as the average force. newton seconds (N s) 7.1 The Impulse-Momentum Theorem J F t 7.1 The Impulse-Momentum Theorem DEFINITION OF LINEAR MOMENTUM The linear momentum of an object is the product of the object’s mass times its velocity: p mv Linear momentum is a vector quantity and has the same direction as the velocity. kilogram meter/seco nd (kg m/s) 7.1 The Impulse-Momentum Theorem vf vo a t F ma mv f mv o F t F t mvf mvo 7.1 The Impulse-Momentum Theorem IMPULSE-MOMENTUM THEOREM When a net force acts on an object, the impulse of this force is equal to the change in the momentum of the object impulse F t mvf mvo final momentum initial momentum 7.2 The Principle of Conservation of Linear Momentum sum of average external forces t Pf Po If the sum of the external forces is zero, then 0 Pf Po Pf Po PRINCIPLE OF CONSERVATION OF LINEAR MOMENTUM The total linear momentum of an isolated system is constant (conserved). An isolated system is one for which the sum of the average external forces acting on the system is zero. 7.3 Collisions in One Dimension The total linear momentum is conserved when two objects collide, provided they constitute an isolated system. Elastic collision -- One in which the total kinetic energy of the system after the collision is equal to the total kinetic energy before the collision. Momentum and KE are constant. Inelastic collision -- One in which the total kinetic energy of the system after the collision is not equal to the total kinetic energy before the collision; if the objects stick together after colliding, the collision is said to be completely inelastic. Momentum is constant but not KE. 7.2 The Principle of Conservation of Linear Momentum Pf Po m1v f 1 m2 v f 2 0 vf 2 vf 2 m1v f 1 m2 54 kg 2.5 m s 1.5 m s 88 kg 7.3 Perfectly Inelastic Collision Momentum is conserved. Kinetic energy is NOT conserved. 7.5 Center of Mass The center of mass is a point that represents the average location for the total mass of a system. xcm m1 x1 m2 x2 m1 m2 7.5 Center of Mass xcm m1x1 m2 x2 m1 m2 vcm m1v1 m2 v2 m1 m2 7.5 Center of Mass vcm m1v1 m2 v2 m1 m2 In an isolated system, the total linear momentum does not change, therefore the velocity of the center of mass does not change. 7.5 Center of Mass BEFORE vcm m1v1 m2 v2 0 m1 m2 AFTER vcm 88 kg 1.5 m s 54 kg 2.5 m s 0.002 0 88 kg 54 kg 8.1 Rotational Motion and Angular Displacement Arc length s (in radians) Radius r For a full revolution: 2 r 2 rad r 2 rad 360 8.1 Rotational Motion and Angular Displacement Arc length s (in radians) Radius r 2 rad 0.0349 rad 2.00 deg 360 deg s r 4.23 107 m 0.0349 rad 1.48 106 m (920 miles) 8.2 Angular Velocity and Angular Acceleration DEFINITION OF AVERAGE ANGULAR VELOCITY Angular displaceme nt Average angular ve locity Elapsed time o t to t SI Unit of Angular Velocity: radian per second (rad/s) 8.2 Angular Velocity and Angular Acceleration Example 3 Gymnast on a High Bar A gymnast on a high bar swings through two revolutions in a time of 1.90 s. Find the average angular velocity of the gymnast. 8.2 Angular Velocity and Angular Acceleration 2 rad 2.00 rev 12.6 rad 1 rev 12.6 rad 6.63 rad s 1.90 s 8.2 Angular Velocity and Angular Acceleration Changing angular velocity means that an angular acceleration is occurring. DEFINITION OF AVERAGE ANGULAR ACCELERATION Change in angular ve locity Average angular accelerati on Elapsed time o t to t SI Unit of Angular acceleration: radian per second squared (rad/s2) 8.3 The Equations of Rotational Kinematics 8.3 The Equations of Rotational Kinematics Example 5 Blending with a Blender The blades are whirling with an angular velocity of +375 rad/s when the “puree” button is pushed in. When the “blend” button is pushed, the blades accelerate and reach a greater angular velocity after the blades have rotated through an angular displacement of +44.0 rad. The angular acceleration has a constant value of +1740 rad/s2. Find the final angular velocity of the blades. 8.3 The Equations of Rotational Kinematics θ α ω ωo +44.0 rad +1740 rad/s2 ? +375 rad/s t 2 o2 2 o2 2 375 rad s 2 2 1740 rad s 2 44.0rad 542 rad s 8.4 Angular Variables and Tangential Variables vT tangentia l velocity vT tangentia l speed 8.4 Angular Variables and Tangential Variables s r vT r t t t vT r ( in rad/s) t 8.4 Angular Variables and Tangential Variables Total acceleration is the vector sum of centripetal acceleration and tangential acceleration. atotal ac aT 8.4 Angular Variables and Tangential Variables vT vTo r ro 0 aT r t t t aT r ( in rad/s ) 2 o t 8.4 Angular Variables and Tangential Variables Example 6 A Helicopter Blade A helicopter blade has an angular speed of 6.50 rev/s and an angular acceleration of 1.30 rev/s2. For point 1 on the blade, find the magnitude of (a) the tangential speed and (b) the tangential acceleration. 8.4 Angular Variables and Tangential Variables 6.50 rev 2 rad 40.8 rad s s 1 rev vT r 3.00 m40.8 rad s 122 m s 8.4 Angular Variables and Tangential Variables 1.30 rev 2 rad 2 8 . 17 rad s s 2 1 rev aT r 3.00 m 8.17 rad s 2 24.5 m s 2 9.1 The Action of Forces and Torques on Rigid Objects In pure translational motion, all points on an object travel on parallel paths. The most general motion is a combination of translation and rotation. 9.1 The Action of Forces and Torques on Rigid Objects According to Newton’s second law, a net force causes an object to have an acceleration. What causes an object to have an angular acceleration? TORQUE 9.1 The Action of Forces and Torques on Rigid Objects DEFINITION OF TORQUE Magnitude of Torque = (Magnitude of the force) x (Lever arm) F Direction: The torque is positive when the force tends to produce a counterclockwise rotation about the axis. SI Unit of Torque: newton x meter (N·m) 9.1 The Action of Forces and Torques on Rigid Objects F cos 55 3.6 10 2 m 790 N 720 N 3.6 10 2 m cos 55 15 N m 9.2 Rigid Objects in Equilibrium EQUILIBRIUM OF A RIGID BODY A rigid body is in equilibrium if it has zero translational acceleration and zero angular acceleration. In equilibrium, the sum of the externally applied forces is zero, and the sum of the externally applied torques is zero. F x 0 F y 0 0 9.2 Rigid Objects in Equilibrium F 2 2 W W 0 W W F2 2 F2 530 N 3.90 m 1480 N 1.40 m 9.2 Rigid Objects in Equilibrium F y F1 F2 W 0 F1 1480 N 530 N 0 F1 950 N 9.2 Rigid Objects in Equilibrium Example 5 Bodybuilding The arm is horizontal and weighs 31.0 N. The deltoid muscle can supply 1840 N of force. What is the weight of the heaviest dumbbell he can hold? 9.2 Rigid Objects in Equilibrium W a a Wd d M M 0 M 0.150 msin 13.0 9.2 Rigid Objects in Equilibrium Wa a M M Wd d 31.0 N 0.280 m 1840 N 0.150 m sin 13.0 86.1 N 0.620 m 9.3 Center of Gravity When an object has a symmetrical shape and its weight is distributed uniformly, the center of gravity lies at its geometrical center. 9.3 Center of Gravity W1 x1 W2 x2 xcg W1 W2 9.6 Angular Momentum DEFINITION OF ANGULAR MOMENTUM The angular momentum L of a body rotating about a fixed axis is the product of the body’s moment of inertia and its angular velocity with respect to that axis: L I Requirement: The angular speed must be expressed in rad/s. SI Unit of Angular Momentum: kg·m2/s 9.6 Angular Momentum PRINCIPLE OF CONSERVATION OF ANGULAR MOMENTUM The angular momentum of a system remains constant (is conserved) if the net external torque acting on the system is zero. 9.6 Angular Momentum Conceptual Example 14 A Spinning Skater An ice skater is spinning with both arms and a leg outstretched. She pulls her arms and leg inward and her spinning motion changes dramatically. Use the principle of conservation of angular momentum to explain how and why her spinning motion changes. 10.1 The Ideal Spring and Simple Harmonic Motion Applied x F kx spring constant Units: N/m 10.1 The Ideal Spring and Simple Harmonic Motion HOOKE’S LAW: RESTORING FORCE OF AN IDEAL SPRING The restoring force on an ideal spring is Fx k x 10.2 Simple Harmonic Motion and the Reference Circle amplitude A: the maximum displacement period T: the time required to complete one cycle frequency f: the number of cycles per second (measured in Hz) 1 f T 2 2 f T 10.3 Energy and Simple Harmonic Motion DEFINITION OF ELASTIC POTENTIAL ENERGY The elastic potential energy is the energy that a spring has by virtue of being stretched or compressed. For an ideal spring, the elastic potential energy is PEelastic 12 kx2 SI Unit of Elastic Potential Energy: joule (J) 10.3 Energy and Simple Harmonic Motion Example 8 Changing the Mass of a Simple Harmonic Oscillator A 0.20-kg ball is attached to a vertical spring. The spring constant is 28 N/m. When released from rest, how far does the ball fall before being brought to a momentary stop by the spring? 10.3 Energy and Simple Harmonic Motion E f Eo 1 2 mv2f mghf 12 ky2f 12 mvo2 mgho 12 kyo2 1 2 kho2 mgho 2mg ho k 20.20 kg 9.8 m s 2 0.14 m 28 N m 10.4 The Pendulum Example 10 Keeping Time Determine the length of a simple pendulum that will swing back and forth in simple harmonic motion with a period of 1.00 s. 2 2 f T g L T 2g L 4 2 T 2 g 1.00 s 9.80 m s 2 L 0.248 m 2 2 4 4 2 Period of simple pendulum is T 2 2 L g 11.1 Mass Density DEFINITION OF MASS DENSITY The mass density of a substance is CONSTANT and is the mass of a substance divided by its volume: m V SI Unit of Mass Density: kg/m3 11.1 Mass Density 11.2 Pressure F P A SI Unit of Pressure: 1 N/m2 = 1Pa Pascal 11.2 Pressure Atmospheric Pressure at Sea Level: 1.013x105 Pa = 1 atmosphere 11.3 Pressure and Depth in a Static Fluid V Ah P2 A P1 A Vg P2 A P1 A Ahg P2 P1 hg 11.3 Pressure and Depth in a Static Fluid P2 P1 gh atmospheric pressure P2 1.01105 Pa 1.00 103 kg m3 9.80 m s 2 5.50 m 1.55 105 Pa 11.4 Pressure Gauges P2 PB PA PA P1 gh absolute pressure P2 Patm gh gauge pressure 11.5 Pascal’s Principle PASCAL’S PRINCIPLE Any change in the pressure applied to a completely enclosed fluid is transmitted undiminished to all parts of the fluid and enclosing walls. 11.5 Pascal’s Principle P2 P1 g 0 m F2 F1 A2 A1 A2 F2 F1 A1 11.6 Archimedes’ Principle P2 P1 gh FB P2 A P1 A P2 P1 A V hA FB ghA FB V g mass of displaced fluid 11.6 Archimedes’ Principle ARCHIMEDES’ PRINCIPLE Any fluid applies a buoyant force to an object that is partially or completely immersed in it; the magnitude of the buoyant force equals the weight of the fluid that the object displaces: F B Magnitudeof buoyantforce Wfluid Weight of displacedfluid 11.6 Archimedes’ Principle If the object is floating then the magnitude of the buoyant force is equal to the magnitude of its weight. 11.8 The Equation of Continuity Incompressible fluid: Volume flow rate Q: A1v1 A2v2 Q Av 11.9 Bernoulli’s Equation The fluid accelerates toward the lower pressure regions. According to the pressure-depth relationship, the pressure is lower at higher levels, provided the area of the pipe does not change. 11.9 Bernoulli’s Equation W F s F s PAs P2 P1 V Wnc 1 2 mv12 mgy1 1 2 mv22 mgy2 11.9 Bernoulli’s Equation P2 P1 V 12 mv12 mgy1 12 mv22 mgy2 P2 P1 12 v12 gy1 12 v22 gy2 BERNOULLI’S EQUATION In steady flow of a nonviscous, incompressible fluid, the pressure, the fluid speed, and the elevation at two points are related by: P1 12 v12 gy1 P2 12 v22 gy2 11.10 Applications of Bernoulli’s Equation Conceptual Example 14 Tarpaulins and Bernoulli’s Equation When the truck is stationary, the tarpaulin lies flat, but it bulges outward when the truck is speeding down the highway. Account for this behavior. 11.10 Applications of Bernoulli’s Equation 11.10 Applications of Bernoulli’s Equation Example 16 Efflux Speed The tank is open to the atmosphere at the top. Find an expression for the speed of the liquid leaving the pipe at the bottom. 11.10 Applications of Bernoulli’s Equation P1 P2 Patm P1 12 v12 gy1 P2 12 v22 gy2 y2 y1 h 1 2 v12 gh v1 2 gh v2 0 12.1 Common Temperature Scales AT SEA LEVEL Temperatures are reported in degrees Celsius or degrees Fahrenheit. Temperatures changed, on the other hand, are reported in Celsius degrees or Fahrenheit degrees: 1 C 9 F 5 12.2 The Kelvin Temperature Scale AT SEA LEVEL Kelvin temperature T Tc 273.15 12.2 The Kelvin Temperature Scale absolute zero point = -273.15oC 12.4 Linear Thermal Expansion LINEAR THERMAL EXPANSION OF A SOLID The length of an object changes when its temperature changes: L Lo T coefficient of linear expansion Common Unit for the Coefficient of Linear Expansion: 1 C C 1 12.4 Linear Thermal Expansion 12.4 Linear Thermal Expansion THE BIMETALLIC STRIP 12.4 Linear Thermal Expansion 12.5 Volume Thermal Expansion VOLUME THERMAL EXPANSION The volume of an object changes when its temperature changes: V Vo T coefficient of volume expansion 1 C Common Unit for the Coefficient of Volume Expansion: C 1 12.5 Volume Thermal Expansion Expansion of water. The physics of bursting water pipes. 12.6 Heat and Internal Energy DEFINITION OF HEAT Heat is energy that flows from a highertemperature object to a lower-temperature object because of a difference in temperatures. SI Unit of Heat: joule (J) 12.6 Heat and Internal Energy The heat that flows from hot to cold originates in the internal energy of the hot substance. It is not correct to say that a substance contains heat. 13.1 Convection CONVECTION Convection is the process in which heat is carried from one place to another by the bulk movement of a fluid. convection currents 13.2 Conduction CONDUCTION Conduction is the process whereby heat is transferred directly through a material, with any bulk motion of the material playing no role in the transfer. One mechanism for conduction occurs when the atoms or molecules in a hotter part of the material vibrate or move with greater energy than those in a cooler part. By means of collisions, the more energetic molecules pass on some of their energy to their less energetic neighbors. Materials that conduct heat well are called thermal conductors, and those that conduct heat poorly are called thermal insulators. 13.2 Conduction The amount of heat Q that is conducted through the bar depends on a number of factors: 1. 2. 3. 4. The time during which conduction takes place. The temperature difference between the ends of the bar. The cross sectional area of the bar. The length of the bar. 13.3 Radiation RADIATION Radiation is the process in which energy is transferred by means of electromagnetic waves. A material that is a good absorber is also a good emitter. A material that absorbs completely is called a perfect blackbody. 13.4 Applications A thermos bottle minimizes heat transfer via conduction, convection, and radiation. The space between the inner glass walls minimizes heat transfer by conduction and convection. The silvered surfaces reflect radiated heat back to the inside. 13.4 Applications GREENHOUSE EFFECT -Depletion of the ozone layer is harmful to Earth -Harmful effects of technology and urbanization -Most heat transfer is by radiation. 14.1 Molecular Mass, the Mole, and Avogadro’s Number One mole of a substance contains as many particles as there are atoms in 12 grams of the isotope cabron-12. The number of atoms per mole is known as Avogadro’s number, NA. N A 6.022 1023 mol 1 N n NA number of moles number of atoms 14.2 The Ideal Gas Law An ideal gas is an idealized model for real gases that have sufficiently low densities. The condition of low density means that the molecules are so far apart that they do not interact except during collisions, which are effectively ELASTIC. At constant volume, the pressure is directly proportional to the temperature. P T 14.2 The Ideal Gas Law At constant temperature, the pressure is inversely proportional to the volume. P 1 V The pressure is also proportional to the amount of gas. Pn 14.2 The Ideal Gas Law THE IDEAL GAS LAW The absolute pressure of an ideal gas is directly proportional to the Kelvin temperature and the number of moles of the gas and is inversely proportional to the volume of the gas. nRT P V PV nRT R 8.31J mol K 14.2 The Ideal Gas Law Consider a sample of an ideal gas that is taken from an initial to a final state, with the amount of the gas remaining constant. PV nRT PV nR constant T Pf V f Tf PiVi Ti 14.2 The Ideal Gas Law Pf V f Tf Constant T, constant n: Constant P, constant n: Constant V, constant n: PiVi Ti Pf V f PiVi Vf Vi T f Ti Pf Pi T f Ti Boyle’s law Charles’ law Gay Lussac’s law 14.3 Kinetic Theory of Gases The particles are in constant, random motion, colliding with each other and with the walls of the container. Each collision changes the particle’s speed. As a result, the atoms and molecules have different speeds. 14.3 Kinetic Theory of Gases THE INTERNAL ENERGY OF A MONATOMIC IDEAL GAS 2 KE 12 mvrms 32 kBT U N 32 k BT 32 nRT 15.1 Thermodynamic Systems and Their Surroundings Thermodynamics is the branch of physics that is built upon the fundamental laws that heat and work obey. The collection of objects on which attention is being focused is called the system, while everything else in the environment is called the surroundings. Walls that permit heat flow are called diathermal walls, while walls that do not permit heat flow are called adiabatic walls. To understand thermodynamics, it is necessary to describe the state of a system. 15.2 The Zeroth Law of Thermodynamics Two systems are said to be in thermal equilibrium if there is no heat flow between then when they are brought into contact. Temperature is the indicator of thermal equilibrium in the sense that there is no net flow of heat between two systems in thermal contact that have the same temperature. 15.2 The Zeroth Law of Thermodynamics THE ZEROTH LAW OF THERMODYNAMICS Two systems individually in thermal equilibrium with a third system are in thermal equilibrium with each other. 15.3 The First Law of Thermodynamics Suppose that a system gains heat Q and that is the only effect occurring. Consistent with the law of conservation of energy, the internal energy of the system changes: U U f U i Q Heat is positive when the system gains heat and negative when the system loses heat. 15.3 The First Law of Thermodynamics Thermodynamics is a conservation law; i.e. heat added to a system is used by the system to increase its internal energy or to do work in expanding. An increase in internal energy due to heat added to the system (positive) or work done on the system (positive). U Q W Work done on a system, according to this convention, would result in a decrease in volume: W P(V ) 15.3 The First Law of Thermodynamics THE FIRST LAW OF THERMODYNAMICS Process Definition Result Isothermal T 0 U 0 Q W Adiabatic Q0 U W V 0 W 0 U Q Isochoric or Isovolumetric 15.3 The First Law of Thermodynamics Example 1 Positive and Negative Work In part a, the system gains 1500J of heat and 2200J of work is done BY the system on its surroundings. In part b, the system also gains 1500J of heat, but 2200J of work is done ON the system. In each case, determine the change in internal energy of the system. 15.4 Thermal Processes An isobaric process is one that occurs at constant pressure. W Fs P As P(V ) At constant pressure, if volume decreases, ΔV is negative, and work done is positive. Isobaric process: W P(V ) P V f Vi 15.4 Thermal Processes Example 3 Isobaric Expansion of Water One gram of water is placed in the cylinder and the pressure is maintained at 2.0x105Pa. The temperature of the water is raised by 31oC. The water is in the liquid phase and expands by the small amount of 1.0x10-8m3. Find the work done and the change in internal energy. 15.4 Thermal Processes W PV 2.0 105 Pa 1.0 108 m3 0.0020J U Q W 130 J 0.0020 J 130 J Q mcT 0.0010 kg 4186 J kg C 31 C 130 J 15.4 Thermal Processes W P(V ) P V f Vi 15.4 Thermal Processes isochoric: constant volume U Q W Q W 0 15.4 Thermal Processes Example 4 Work and the Area Under a Pressure-Volume Graph Determine the work for the process in which the pressure, volume, and temperature of a gas are changed along the straight line in the figure. The area under a pressure-volume graph is the work for any kind of process. 15.4 Thermal Processes Since the volume increases, the work is negative. Estimate that there are 8.9 colored squares in the drawing. W 8.92.0 105 Pa 1.0 10 4 m 3 180 J 15.5 Thermal Processes Using an Ideal Gas ISOTHERMAL EXPANSION OR COMPRESSION Isothermal expansion or compression of an ideal gas Vf W nRT ln Vi 15.5 Thermal Processes Using an Ideal Gas Example 5 Isothermal Expansion of an Ideal Gas Two moles of the monatomic gas argon expand isothermally at 298K from and initial volume of 0.025m3 to a final volume of 0.050m3. Assuming that argon is an ideal gas, find (a) the work done by the gas, (b) the change in internal energy of the gas, and (c) the heat supplied to the gas. ?? 15.5 Thermal Processes Using an Ideal Gas (a) Vf W nRT ln Vi 0.050 m 3 3400 J 2.0 mol 8.31 J mol K 298 K ln 3 0.025 m (b) (c) U 32 nRT f 32 nRTi 0 U Q W Q W 3400 J 15.3 The First Law of Thermodynamics (a) U Q W 1500 J 2200 J 700 J (b) U Q W 1500 J 2200 J 3700 J 15.3 The First Law of Thermodynamics Example 2 An Ideal Gas The temperature of three moles of a monatomic ideal gas is reduced from 540K to 350K as 5500J of heat flows into the gas. Find (a) the change in internal energy and (b) the work done by the gas. ??? U U f U i Q W U 32 nRT 15.3 The First Law of Thermodynamics (a) U 32 nRT f 32 nRTi (b) 3 2 3.0 mol 8.31 J mol K 350 K 540 K 7100 J W Q U 5500 J 7100 J 12600 J 15.4 Thermal Processes A quasi-static process is one that occurs slowly enough that a uniform temperature and pressure exist throughout all regions of the system at all times. isobaric: constant pressure isochoric: constant volume isothermal: constant temperature adiabatic: no transfer of heat 15.7 The Second Law of Thermodynamics The second law is a statement about the natural tendency of heat to flow from hot to cold, whereas the first law deals with energy conservation and focuses on both heat and work. THE SECOND LAW OF THERMODYNAMICS: THE HEAT FLOW STATEMENT Heat flows spontaneously from a substance at a higher temperature to a substance at a lower temperature and does not flow spontaneously in the reverse direction. 15.8 Heat Engines A heat engine is any device that uses heat to perform work. It has three essential features. 1. Heat is supplied to the engine at a relatively high temperature from a place called the hot reservoir. 2. Part of the input heat is used to perform work by the working substance of the engine. 3. The remainder of the input heat is rejected to a place called the cold reservoir. QH magnitude of input heat QC magnitude of rejected heat W magnitude of the work done 15.8 Heat Engines The efficiency of a heat engine is defined as the ratio of the work done to the input heat: e W QH If there are no other losses, then QH W QC e 1 QC QH 15.8 Heat Engines Example 6 An Automobile Engine An automobile engine has an efficiency of 22.0% and produces 2510 J of work. How much heat is rejected by the engine? e W QH W QC QH QH W e 15.8 Heat Engines QH W QC QH W QC QH W 1 QC W W 1 e e W 1 2510 J 1 8900 J 0.220 e 15.9 Carnot’s Principle and the Carnot Engine A reversible process is one in which both the system and the environment can be returned to exactly the states they were in before the process occurred. CARNOT’S PRINCIPLE: AN ALTERNATIVE STATEMENT OF THE SECOND LAW OF THERMODYNAMICS No irreversible engine operating between two reservoirs at constant temperatures can have a greater efficiency than a reversible engine operating between the same temperatures. Furthermore, all reversible engines operating between the same temperatures have the same efficiency. 15.9 Carnot’s Principle and the Carnot Engine The Carnot engine is useful as an idealized model. All of the heat input originates from a single temperature, and all the rejected heat goes into a cold reservoir at a single temperature. Since the efficiency can only depend on the reservoir temperatures, the ratio of heats can only depend on those temperatures. QC QH e 1 QC QH TC 1 TH TC TH 15.11 Entropy Any irreversible process increases the entropy of the universe. S universe 0 THE SECOND LAW OF THERMODYNAMICS STATED IN TERMS OF ENTROPY The total entropy of the universe does not change when a reversible process occurs and increases when an irreversible process occurs. 15.11 Entropy Example 12 Energy Unavailable for Doing Work Suppose that 1200 J of heat is used as input for an engine under two different conditions (as shown on the right). Determine the maximum amount of work that can be obtained for each case. ecarnot 1 TC TH e W QH 15.11 Entropy The maximum amount of work will be achieved when the engine is a Carnot Engine, where (a) ecarnot 1 TC 150 K 1 0.77 TH 650 K W ecarnot QH 0.771200 J 920 J (b) ecarnot TC 150 K 1 1 0.57 TH 350 K W ecarnot QH 0.571200 J 680 J The irreversible process of heat through the copper rod causes some energy to become unavailable. 15.12 The Third Law of Thermodynamics THE THIRD LAW OF THERMODYNAMICS It is not possible to lower the temperature of any system to absolute zero in a finite number of steps.