General Chemistry Final Review The final will consist of: 100 Multiple choice questions (can cover topics from the entire year) 1 problem sheet front and back (only the second semester topics) You may use a 3”x5” notecard on your exam provided that notecard is turned before to the end of last class day before exams start. No cards will be accepted once your last class period ends. Major topics covered Chapter 1 Chemistry an Introduction Theory Law Scientific Method Lab safety Chapter 2 Measurements and Calculations Sig figs Dimensional analysis (field goals) Metric system Density Chapter 3 Matter Elements Compounds Mixture Homogeneous/heterogeneous Chapter 4 Chemical Foundations Subatomic particles Proton Neutrons Electrons Nucleus Orbitals Rutherford Thomson Periodic Table Periodic trends Metals Nonmetals Metalloids Alkali metals Alkaline Earth Metals Transition metals Halogens Noble gases Chapter 5 Nomeclature Ions Cations Anions Ionic bonding Polyatomic ions Naming ionic compounds Determining ionic formulas Ionic dissociation Molar mass Covalent Naming Covalent Prefixes Naming Acids Chapter 6 Chemical Reactions Products Reactants Energy Exothermic Endothermic Balancing Equations Chapter 7 Reactions in an aqueous solution Preciptiate Redox reaction Combustion Reaction Single Replacement Reaction Double Replacement reaction Synthesis Reaction Double Replacement Reaction Net Ionic Equation Spectator Ions Acid Base Reactions Chapter 8 Chemical Composition Mole Molar Mass Mole gram conversion Mole atom conversion Chapter 9 Chemical Quantities Stoichiometry Limiting reactants Percent Yield Mole atom conversion Chapter 11 Modern Atomic Theory Bohr Heisenberg Orbitals Energy levels Electron configuration Quantum numbers Chapter 12 Chemical Bonding Covalent bonding Electronegativity Polar Covalent Bond Nonpolar covalent bond Determining the type of bond Lewis dot structures VSEPR Shapes of Molecules Chapter 13 Gases Boyle’s Law Charles’ Law Avagadro’s Law Gay Lussac’s Law Pressure Combined Gas Law Ideal Gas Law Diffusion Effusion Graham’s Law of Effusion Chapter 14 Liquids and Solids Kinetic Molecular Theory Solid Liquid Gas Evaporation Volatility Phase Changes Chapter 15 Solutions Suspensions Colloids Tyndall Effect Solutions Solute Solvent Polarity of solvent (like dissolves like) Concentration Molarity Saturated Supersaturated Chapter 16 Acids and Bases Acids Bases Hydronium Hydroxide pH Dilution Neutralization Salts Chapter 17 Equilibrium Equilibrium Le Châtelier’s Principle Shifting of equilibrium Buffers Acidosis/alkanosis Chapter 19 Nuclear Chemistry Radiation Alpha () Radiation Beta () Radiation Gamma () Radiation Showing decay Showing decay Half life Determining the age using half life Fission Fusion Transmutation Meltdown Nuclear Winter Nuclear Medicine X Rays CT Scan/MRI Practice Problems for the Chemistry Final Given the balanced equation Mg + 2 HNO3 Mg(NO3)2 + H2 1. Calculate how many grams of Magnesium nitrate Mg(NO3)2 will be made from 32.1 g of HNO3 and 15.4 g of Mg. 2. Given the balanced equation CH4 + 2 O2 2 H2O + CO2 How many grams of water will be produced from 18 g of CH4 (methane) and 49 g of O2? Balance the equation and do the following problem O2 + C4H10 CO2 + H2O 3. How much carbon dioxide can be produced from 32 g of oxygen and 45 g of butane (C4H10) assuming a 39% yield? Balance the equation and do the following problem CH3COOH + NaHCO3 NaCH3COO + H2O + CO2 4. If 25.1 g of sodium acetate is produced from 43.6 g of CH3COOH and 79.6 g of NaHCO3 what is the percent yield? PV = nRT VP/T = VP/T 5. If you collected 120 mL of gas at 25o C and 711 mm Hg, what volume will it occupy at STP? 6. A chemical reaction will create 17.1 moles of gas, what volume will this occupy at 19o C and 125 kPa? 7. If you have 32 g of CH4 gas, what volume will it occupy at 19o C and a pressure of 1.3 atm? 8. Balance the equation ____ Al + ___ HCl ____ AlCl3 + ____ H2? If you have 29.5 g of aluminum and react it completely, what volume of H2 gas will you have at 15o C, and 124 kPa? M = mol/L MV = MV pH = -log[H3O+] [H3O+] [OH-] = 1 x10-14 9. A solution of vinegar has a [H3O+] of 1.45 x10-5, what is its pH, what is its [OH-]? 10. A solution of milk of magnesia has a pH of 10.6, what is its [H3O+], what is its [OH-]? 11. A solution of ammonia has a [OH-] of 5.87 x10-4, what is its [H3O+], what is its pH? 12. If 27 g of HNO3 are dissolved in 1.2 L, what concentration will the solution be? 13. Show the beta decay C-14 14. Show the alpha decay followed by the beta decay of Ra-230 15. Show the alpha decay followed by another alpha decay of W-186 16. Show the beta decay followed by another beta followed by the alpha decay of decay of K-40. 17. If you originally had 125 g of K-40, you now have 32 g left. How much time has passed? 18. If you originally had 37 g of Na-22 and you now have 14 g left. How much time has passed?