CHEMISTRY July 31st, 2012 Brain Teaser: Dollar Bill 2 What do think will happen if I dip a dollar bill in a 50% ethanol solution and light it on fire? Why? Demo Record Observations Was your prediction correct? Explain the science behind this Agenda 3 Brain Teaser Demo: Dollar Bill Lecture: Introduction to Chemistry SI Units and Base Units Significant Figures Homework Intro to Measurement Worksheet Unit 1 Objectives Introduction to Chemistry 4 Define chemistry and matter Units of measurement SI Units Base Units Accuracy versus Precision Uncertainty in Measurement Significant Figures Introduction to Chemistry 5 Chemistry: The Central Science Chemistry is the science that investigates and explains the structure and properties of matter. Seeks to explain the submicroscopic events that lead to macroscopic observations Branches of Chemistry 6 Branch Area of Emphasis Examples Organic chemistry most carbon-containing chemicals pharmaceuticals, plastics Inorganic chemistry in general, matter that does not contain carbon minerals, metals and nonmetals, semiconductors Physical chemistry the behavior and changes of matter reaction rates, and the related energy changes reaction mechanisms Analytical chemistry components and composition of substances food nutrients, quality control Biochemistry matter and processes of living organisms metabolism, fermentation Units of measurement 7 SI Units (Le Systéme Internationale) Scientists need to report data that can be reproduced by other scientists. They need standard units of measurement. Base Units • A base unit is a defined unit in a system of measurement •There are seven base units in SI. 8 Base Units 9 10 SIGNIFICANT FIGURES Significant Figures 11 Significant Figures Digits in a measurement that have meaning relative to the equipment being used Significant Figures 12 Place What is the increment on the equipment? What you know for sure. 13 Significant Figures Digits with meaning Digits that can be known precisely plus a last digit that must be estimated. 14 Ruler 15 http://www.funbrain.com/measure/ What are the units? Graduated Cylinder 16 http://www.uwplatt.edu/chemep/chem/chemsc ape/labdocs/catofp/measurea/volume/gradcyl/ gradcyl.htm What are the units? Significant Figures 17 What do you notice? Depends on type of equipment being used. Depends on size of equipment used. Significant Figures 18 Raw Data Rules 1. All digits 1-9 are significant. How do you 2. Zeros between significant know how many digits are always significant. sig figs? 3. Trailing 0’s are significant only if the number contains a decimal point 4. Zeros in the beginning of a number with a decimal point are not significant. 5. Zeros following a significant number with a decimal are significant. Significant Figures 19 Pacific to Atlantic Rule Examples Pacific = Decimal Present Start from the Pacific (left hand side), every digit beginning with the first 1-9 integer is significant 20.0 = 3 sig digits 0.00320400 = 6 sig digits 1000. = 4 sig digits Significant Figures 20 Atlantic Rule to Atlantic = Decimal Absent Pacific Start from the Atlantic (right hand side), every digit beginning with the first 1-9 integer is significant Examples 100020 = 5 sig digits 1000 = 1 sig digits Practice 21 1. 2. 3. 4. How many significant figures are in 400.0 4000 4004 0.004 Rally Rows 22 How many significant figures are in 1. 0.02 2. 0.020 3. 501 4. 501.0 5. 5000 6. 5000. 7. 5050 8. 01.0050 9. 50300 10. 5.0300 Review Questions 23 Determine the number of significant figures in the following: 1005000 1.005 0.000125 1000. 0.02002 2002 200.200 Review Questions 24 Determine the number of significant figures in: 72.3 g 60.5 g 6.20 g 0.0253 g 4320 g 0.00040230 g 4.05 x 10^5 g 4500. g Why do we use the metric system? 25 Advantages Simple to use Easy to convert from one unit to another Dimensional Analysis Universal – used worldwide By all scientists to communicate By all industrialized nations Except United States U.S. loses billions of dollars in trade