Chapter 1 The Chemical World

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Chapter 1

The Chemical World

1

What Makes Soda Pop Soda Pop?

Virtually everything around you is composed of chemicals

The three main chemical ingredients of Soda Pop are

Water, Sugar and Carbon dioxide

The properties of Soda Pop are directly related to the properties of these chemicals

Sugar = Sweetness

Water = Liquid

Carbon dioxide = bubbles

2

Structure Determines Properties

Everything is made of tiny pieces called atoms and molecules

Chemists believe that the properties of a substance are determined by the kinds, numbers and relationships between these pieces

3

What is Chemistry?

What chemists try to do is discover the relationships between the particle structure of matter and the properties of matter we observe

Chemistry is the science that seeks to understand what matter does by studying what atoms and molecules do.

4

The Scientific Method

A process for trying to understand nature by observing nature and the way it behaves, and by conducting experiments to test our ideas.

Key Characteristics of the Scientific Method include Observation , formulation of

Hypotheses , Experimentation and formulation of Laws and Theories

5

Observation

A way of acquiring information about nature

Some observations are simple descriptions about the characteristics or behavior of nature

 “The soda pop is a liquid with a brown color and a sweet taste. Bubbles are seen floating up through it.”

Some observations compare a characteristic to a standard numerical scale

 “A 240 mL serving of soda pop contains

27 g of sugar.”

6

Hypothesis

A tentative interpretation or explanation of your observations

 “the sweet taste of soda pop is due to the presence of sugar”

A good hypothesis is one that can be tested to be proved wrong!

Falsifiable

One test may invalidate your hypothesis

7

Experiments

Tests of hypotheses, laws or theories

Can you think of a way to test whether the sweet taste of soda pop is due to the presence of sugar?

Results either Validate (confirm) or Invalidate (deny) your ideas

Invalidate = Discard or Modify

 Many times experiments invalidate only parts of the hypothesis or theory, in which case the idea is modified

Validate ≠ Proof your idea will always hold

8

Laws

Summary of observations that combines all past observations into one general statement

Law of Conservation of Mass –

“In a chemical reaction matter is neither created nor destroyed.”

Allows you to predict future observations

So you can test the Law with experiments

Unlike state laws, you cannot choose to violate a scientific law!

9

Theories

General explanation for the characteristics and behavior of nature

Models of nature

 Dalton’s Atomic Theory

Can be used to predict future observations

So they can be tested by experiments

10

What’s the Difference Between a

Hypothesis and a Theory?

A hypothesis is an explanation of a single or small number of observations

A theory is an explanation that extends beyond individual observations to an understanding of the underlying causes for the way nature is or behaves

11

What’s the Difference Between a

Law and a Theory?

Laws answer the question What will happen.

Theories answer the question Why does something happen.

Which will allow you to predict what will happen!

12

13

Why do some things burn?

Observations

1. Things would stop burning when placed in a closed container

2. Many metals burn to form a white powder called a calx

3. Metals could be recovered from their calx by roasting it with charcoal

14

Why do some things burn?

Phlogiston Theory

• Explanation of combustion in early/mid 1700’s

Combustible substances contained a substance they called phlogiston .

When a substance burned it released all or some of its phlogiston into the air

15

How does Phlogiston Theory

Explain the Observations?

When a substance is burned in the open, all the phlogiston is released.

When a substance is burned in a closed container, the phlogiston is released until it saturates the container, at which point the combustion stops.

• A metal’s calx is what is left after it releases all its phlogiston.

When roasted with charcoal the calx reacquires phlogiston from the charcoal.

 Charcoal is rich in phlogiston, that’s why charcoal burns

16

How was Phlogiston Theory

Put to the Test?

Prediction of Phlogiston Theory – if phlogiston is lost when metals burn, then the metals should lose weight when burned

• Morveau’s Experiments showed that when a piece of metal burned, the resulting calx weighed more than the original metal

• Do Morveau’s observations validate or invalidate the Phlogiston Theory?

17

How was Phlogiston Theory

Put to the Test?

Prediction of Phlogiston Theory – if a calx is heated, it should remove phlogiston from the air as the calx is converted to the metal

Lavoisier roasted many calx with a large lens and observed that material he called

“fixed air” was released into the air

• Do Lavoisier’s observations validate or invalidate the Phlogiston Theory?

18

The Great Burning Lens

19

A Better Theory of Combustion

Lavoisier proposed an alternative theory of combustion

When materials burn, they remove and combine with “fixed air” from the air.

• Does Lavoisier’s idea explain all the previous observations?

• How could you test Lavoisier’s idea?

20

How to Succeed in Chemistry

Be Curious and use your

Imagination

 explore and investigate

Quantify and Calculate

 even small differences can be important!

Commitment

Work Regularly &

Carefully

21

The Best Approach to

Learning Chemistry

Learn the Vocabulary of Chemistry

Definitions of Terms

How Common Vocabulary is Applied to Chemistry

Memorize Important Information

Names, Formulas and Charges of Polyatomic Ions

Solubility Rules

Learn and Practice Processes

Systematic Names and Formulas

Dimensional Analysis

Do the Questions and Exercises in the Chapter to Test your Understanding and help you learn the Patterns

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