Karla's Elliott's and Alex's WS

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Acids and Bases ANSWER SHEET

Name:________________________ PD.__________

Date:_________________

1. Properties of acids and bases: Label the following acid, base, or both.

- taste sour_________ A

- has a pH greater than 7 _________ B

- reacts with hydrogen gas on active metals (e.g.: Mg) _________ A

- conducts electricity _________ A and B

- feels slippery or soapy_________ B

- neutralizes bases_________ A

- neutralizes acids_________ B

- taste bitter ________ B

- turns red litmus paper blue in color_________ B

- turns blue litmus paper red in color _________ A

- has a pH less than 7 _________ A

2. Writing acid-base reactions in aqueous solutions:

Notable points to remember :

-The properties of an acid are neutralized by the addition of a base, and vice versa.

- Arrhenius proposed that an acid is a substance that produces hydrogen ions (H + , also called protons) in aqueous solution, and a base is a substance that produces hydroxide ions (OH

) in aqueous solution

-all acids and bases are electrolytes undergoing dissociation in aqueous solution.

-Arrhenius explained neutralization as the combination of H + ions and OH

ions to form water.

H + (aq) + OH

(aq) H

2

O(l)

In the Brønsted– Lowry theory, an acid donates a proton and the base accepts it.

-. Lewis ' theory used electrons instead of proton transfer and specifically stated that an acid is a species that accepts an electron pair while a base donates an electron pair.

3. Write a balanced net ionic equation for each of the following acid-base reactions in water: i. butyric acid (HC4H7O2, a weak acid) with potassium hydroxide (KOH, a strong base)

HC4H7O2 (aq) + OH(aq) ----->C4H7O2(aq) + HOH ii. ammonia (NH3, a weak base) with hydrobromic acid (HBr, a strong acid)

NH3 (aq) + H 1+ (aq)--------> NH4 1+ (aq) iii. nitric acid (HNO3, a strong acid) with lithium hydroxide (LiOH, a strong base)

H 1+ (aq) + OH1- (aq)-----> HOH

4. Identify which characteristic falls under Arrhenius, bronsted lowry, or lewis theories of acids and bases.

Hint: Arrhenius (producing different ions) Bronsted Lowry (proton) lewis (electrons)

Bronsted lowry : An acid is a proton (hydrogen ion) donor.______________________________

Lewis : An acid is an electron pair acceptor__________________________________________

Arrhenius : Acids are substances which produce hydrogen ions in solution_________________

Bronsted lowry: A base is a proton (hydrogen ion) acceptor._____________________________

-.

Arrhenius : Bases are substances which produce hydroxide ions in solution_________________

Lewis: A base is an electron pair donor._____________________________________________

5. Given that [H

3

O + ] = 4.5 x 10 -5 M, calculate [OH ]. remember [H

3

O + ]·[OH ] = K w

and K w is always equal to 1.0 x 10 -14 calculate [OH ] given that [H

3

O + ] = 4.5 x 10 -5 M. Starting with the water constant equation

[H

3

O + ]·[OH ] = K w

, we can figure that [OH ] = K w

/[H

3

O + ]. Then, substitute the known values for K w and [H

3

O + ] to get that [OH ] is equal to 1.0 x 10 -14 divided by 4.5 x 10 -5 . That comes out to be 2.2 x 10 -10 M for the concentration of hydroxide ion.

6. Calculate PH and POH for each equation (pH = - log [H

3

O + ]) (pOH = - log [OH ])

Find the pH of a 0.0025 M HCl solution

PH = - log (0.0025) = - ( - 2.60) = 2.60 (PH)

PH +POH= 14 so 14-2.6 =11.4 (POH)

7. What is the pOH of a solution that has a hydroxide ion concentration of 4.82 x 10 -5 M pOH = - log [4.82 x 10 -5 ] = 4.32

8. What is the purpose of titration?

The purpose of titrating is to determine the concentration of an unknown acid or base.

9. A 15.0 mL sample of an H

2

SO

4

is titrated with 50.5 mL of 0.200M KOH. What is the concentration of the unknown acid?

0.200M KOH=(x/.0505 L KOH)=.0101 mol KOH

.0101 mol KOH(1 mol H

2

SO

4

/2 mol KOH)=.00505 mol H

2

SO

4

.00505 mol H

2

SO

4

/.015 L H

2

SO

4

=.337M H

2

SO

4

10. What is the concentration of a 10 mL sample of HCl if 30.2 mL of 0.120M NaOH is needed to titrate it?

.120M NaOH=(x/.0302L)=.0036 mol NaOH

.0036 mol NaOH(1 mol HCl/1 mol NaOH)=.0036 mol HCl

.0036 mol HCl/.010 L HCl= .36 M HCl

11. Fill in the blanks:

● Binary acids are made up of two elements. The first element in a binary acid is hydrogen .

○ Naming: hydro__(root word of second element)__ic acid

● Oxyacids are made up of more than two elements.

○ Naming: NO PREFIX. Change the ending of the polyatomic ion’s name and add the word “acid”;

-ate becomes -ic and -ite becomes -ous

12. Name the following acids: hydrofluoric acid HF

H

2

CO

3 carbonic acid

HC

2

H

3

O

2 acetic acid

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