Paperwork • • • • Mastering Physics Course # DRKIDD880131 Assignments should be up Need to be de-enrolled from Physics I Schedule Short Term • Today – Equations for #2? • Monday – Off • Tuesday – Lab #1 – Copyworks – Quiz#1 [Chapter 17] • Wed HMWK due 11pm – Finish Chapter 18 Equation of State • Relationship between – p, pressure – V, volume – T, temperature – m or n (mass or # moles) • Related by Molar Mass (MM) Equation of State • Relationship between – p, pressure – V, volume – T, temperature – m or n (mass or # moles) • Related by Molar Mass (MM) Equation of State for Solid • Volume – Related to mass & density – V = m/r • For a given volume V0: – Relate to changes in temperature & pressure • V = V0 [ 1+b(T-T0) – k(p-p0) ] – Examine this equation for a solid • If T = T0 & p = p0? • What happens if T not T0, p not p0? Equation of State for Gas • pV=nRT • Identify Equation components • Units of pV? • “Better” Version – pV = NkBT • kBT = Thermal Energy, more “Physicsy” • Notice Gas Density at given Parameters • • • • • • • • • pV=nRT r = m/V m = nM (M is Molar Mass) Algebra to isolate m/V n = m/M pV = (m/M)RT pV/(RT) = m/M pM/(RT) = m/V = r Gas density equation. Examine Gas Density at given Parameters • • • • • • • • • • pV=nRT r = m/V m = nM (M is Molar Mass) Algebra to isolate m/V n = m/M pV = (m/M)RT pV/(RT) = m/M pM/(RT) = m/V = r Gas density equation. Examine density is amount of mass per unit volume (dm/dV) Isolated System pV=nRT • Examine a closed system • Mass cannot enter or escape – Balloon? Gas Tank? • Examine at different parameters – p,V,T can change. R & n constant • p1V1/T1 = nR : case 1 • p2V2/T2 = nR : case 2 • Example, what happens to a balloon that gets hot? Isolated System pV=nRT • p1V1/T1 = nR : case 1 • p2V2/T2 = nR : case 2 • Example, what happens to a balloon that gets hot? • What is pressure felt by balloon? • Warm balloon by some method. • Does pressure change? • What happens to balloon? – Approximation for weak rubber casing. Pressure vs. Height • Example 18.4 Force = pA + (dp)A Thin object, mass m dy Force = pA For an object in a fluid Pressure on sides of object is the same, so cancels (Book on desk is stationary) Assume pressure felt by top is slightly different than bottom (p+dp) Pressure vs. Height • Example 18.4 Force = pA + (dp)A Thin object, mass m dy Force = pA For an object in a fluid Pressure on sides of object is the same, so cancels (Book on desk is stationary) Assume pressure felt by top is slightly different than bottom (p+dp) dp can be +, - or even zero. Just much smaller than p for thin object Let’s say this object is stationary – floating in the fluid. What is sum of all forces on object? What are all forces on object? What if “Object” was just a portion of the fluid itself? Pressure vs. Height • Example 18.4 Force = pA + (dp)A mass = rV = rA(dy) Force = pA SF = 0 = pA - [pA + (dp)A] – mg 0 = pA – pA – (dp)A – rVg (dp)A = -rVg (dp)A = -r(Ady)g (dp/dy) = - rg Implications? dy Pressure vs. Height • Example 18.4 Force = pA + (dp)A mass = rV = rA(dy) dy Force = pA SF = 0 = pA - [pA + (dp)A] – mg 0 = pA – pA – (dp)A – rVg (dp)A = -rVg (dp)A = -r(Ady)g For Ideal Gas (dp/dy) = - rg r = m/V = pM/(RT) (dp/dy) = - rg Pressure vs. Height • Example 18.4 Force = pA + (dp)A mass = rV = rA(dy) dy Force = pA Pressure vs. Height Any Fluid (dp/dy) = - rg For Fluid that is an Ideal Gas r = m/V = pM/(RT) (dp/dy) = - pgM/(RT) Pressure vs. Height • (dp/dy) = - pgM/(RT) • Now need to set up equation to solve • (dp/p) = -(gM/RT)(dy) – Assume a constant temperature (?) 1 p 0 p dp pF yF Mg y 0 ( RT )dy Pressure vs. Height • (dp/dy) = - pgM/(RT) • Now need to set up equation to solve • (dp/p) = -(gM/RT)(dy) – Assume a constant temperature (?) 1 p 0 p dp pF yF Mg y 0 ( RT )dy 1 Mg p 0 p dp ( RT ) y0 dy pF yF Pressure vs. Height 1 p 0 p dp pF yF y0 ( Mg )dy RT 1 Mg p 0 p dp ( RT ) y0 dy pF yF Mg ln pF ln( p0) ( ) yF y 0 RT pF Mg ln ) yF y 0 ( RT p0 Pressure vs. Height Let’s say integration was from sea level (p0=p0, y0 = 0) To a point pF = p, yF = y Need to have known endpoints Then can derive equation for air pressure as a function of height above sea level ln pF ln( p0) ( ln ln Mg ) yF y 0 RT pF Mg ( ) yF y 0 p0 RT p Mg ) y ( p0 RT Mg ( ) y p RT e p0 p p0 e ( Mg ) y RT Happy Equation: Should Check Accuracy Implications? Check at sea level. Schedule Short Term • Today – Equations for #2? • Monday – Off • Tuesday – Lab #1 – Copyworks – Quiz#1 [Chapter 17] • Wed HMWK due 11pm – Finish Chapter 18