Speeding up the melting process of ice By: Geert Jaspers and Joris Voorn Ignatius Gymnasium Introduction In daily life, salt is often used for frozen roads. This will then cause the ice, upon the road, to melt. The salt, causes the ice to melt faster than normal, in other words, the melting point of the ice is now lower than normal. Given that, it’s important to know that many salts, such as NaCl, dissolve very well in water. Apparently, the melting and freezing point of water decrease when a salt is dissolved in it. But, what’s the cause of this to happen? One of the factors that makes one salt different to another is the difference in molar mass. We can easily control and regulate that factor by just picking another salt, with a different molar mass each time. That raises the following question: Does the molar mass of one salt, that is dissolved in water, has coherence with the melting and freezing point of that same water. To inquire this we made up an accurate study design. Before we started, we presumed that the salt with a smaller molar mass causes the water, in which that very salt is dissolved, to have a lower melting and freezing point. Experimental design To figure out which chemical will speed up the melting process of ice, we have to take four (plastic) cups filled with water (60 ml). In three of them we put the different kinds of salts, NaCl, NaF and KI, all with the same weight. To mimic the real situation as good as possible it is important to use as much as 10% of the weight of the water, that means we used 5,99 grams of each salt. And after one day left in the freeze, we could start measuring. Drawing of experimental design To measure the speed of the melting process of the different ice cubes as accurate as possible, we took four burettes. On top of those we put funnels with a coffee filter in it, as you can see in the drawing above. Uppermost lays the cube of ice. And now we only have to wait, reading out the burette every two minutes for 40 minutes long. The results are placed beneath and put into a graph. Between the parenthesis is given the molar mass of each salt. Evaluation As usual, there is no inquiry without any mistakes, ours included. But from your mistakes you learn, but we think we didn’t make huge mistakes. The main reason for the mistakes was the lack of really enough time. Most mistakes are made In the measuring process, which is inevitable. Beside that we have measured on two different days, the consequence of that could be that the Photo of the experimental design Results and Conclusion As you can see in the graph, the water with NaF dissolved (red line) melted a lot faster than the water with NaCl dissolved (green line). That is completely what we expected, because the molar mass of NaF is smaller than the molar mass of NaCl. That means there is more mole of NaF than there is of NaCl in the same mass of salt. So, you need a lot less NaF than NaCl to melt the same quantity of ice. On the contrary, the results we measured with KI dissolved in water, are quite unexpected. Reading the results, the ice with KI melted faster than any other, but that is not what we expected. We expected that the melting process of the ice would slow down, instead of speed up. That strange result could have many reasons. One of the reason could be that only that salt has one more variable comparing to the others, and that is potassium instead of sodium. It could be that potassium has more difficulties to dissolve in water than sodium does, in any case the dissolving process could be different than the dissolving process of sodium. Maybe that is a good starting point for a new inquiry. Further questions might also be: are salts with a smaller molecule mass more costefficient. Or are there other advantages or disadvantages such as: does it less affect the environment or does it corrode bikes and cars far far mor than normal salt? Beside the molar Time No salt NaF NaCl KI (min) (0) (41,99) (58,44) (166,0) (ml) (ml) (ml) (ml) 0 0 0 0 0 2 0,01 0,08 0,03 0,18 4 0,01 0,1 0,03 0,2 6 0,01 0,13 0,03 0,21 8 0,01 0,14 0,41 0,62 10 0,01 0,56 0,74 1,01 12 0,01 0,95 1,21 1,32 14 0,01 1,61 1,62 1,88 16 0,01 1,9 2,21 2,19 18 0,01 2,46 2,5 2,52 20 0,33 2,98 2,85 3,26 22 0,88 3,85 3,2 3,77 24 1,48 4,37 3,53 4,4 26 2,03 5,09 3,82 5,02 28 2,63 5,81 3,98 5,58 30 3,24 6,35 4,32 6,63 32 3,64 7,24 4,51 7,6 34 4,3 8,05 4,78 9,18 36 4,7 8,66 5,02 9,79 38 5,33 9,47 5,42 10,73 40 5,96 10,18 5,85 11,88 temperature in the room was different. Table of results Volu 14 me (ml) 12 No salt(0) 10 NaF (41,99) 8 NaCl (58,44) 6 KI (166,0) 4 2 0 -2 0 Time (min) Graph 10 20 30 40