Intermolecular Forces Assignment

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9/29/2009

Chemistry 20 Unit A –

Bonding UA pt B:

Name: __________

Date: __________

Intermolecular Forces

b.

1.

State the intermolecular forces in each of the following groups of molecules and then number them from highest to lowest boiling points. The following abbrivations are allowed: Ionic = I, Dipole-Dipole = DD, London Dispersion = LD, Hydrogen Bonding =

HB (2 marks each) a. Cl H

\ /

C ═ C

/ \

H H

H H O

│ │ ║

H ─ C ─ C ═ C ─ C ─ OH

│ │

H H

CH

4

C

2

H

6

CH

3

Cl CH

3

OCH

3 c. C

6

H

5

OH d. H

2

O

C

6

H

HF

5

F C

6

H

5

CH

3

LD Industries

9/29/2009 e. f.

CO

CH

2

3

CH

3,

CH

3

NH

2

SiO

, CH

3

2

OH, CH

3

F g. CH

3

OCH

3

, CH

3

CH

2

OH, CH

4 e.

c.

a.

2.

Identify the types of intramolecular or intermolecular bonds in the following. You may use the abbreviations from the first question. (0.5 marks each) b.

argon _____________________ water _____________________ f.

Al ___________________ g.

CaCl

2

________________ methane __________________ h.

KClO

3

_______________ d.

carbon monoxide ___________ i.

NaCl _________________

SiC ______________________ j.

HCN _________________

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9/29/2009

3.

Predict the order of increasing melting points of these substances containing chlorine. Explain the basis for your prediction. (2 marks)

HCl Cl

2

NaCl CCl

4

4.

Arrange from highest to lowest boiling point. (2 marks)

LiF, H

2

O, H

2

CNH, HCN, CsCl, Co, C, C

3

H

8,

PH

3

, F

2,

SCl

2

5. You are also responsible for reading the following in the textbook: Nelson pages 119-

129. Define the following terms and concepts: (0.5 marks each)

Crystal lattice: ……………………………………………………………………...............

………………………………………………………………………………………………

Metallic crystal: ……………………………………………………………………………

………………………………………………………………………………………………

Molecular crystal: …………………….……………………………………………………

………………………………………………………………………………………………

Covalent network crystal: ……………………….…………………………………………

………………………………………………………………………………………………

The 4 covalent networks of Carbon: ……….………………………………………………

………………………………………………………………………………………………

Semiconductors: ……………………………………………………………………………

………………………………………………………………………………………………

Bonus Questions: Answer only ONE!!!

Fair Bonus Question: Define the term allotrope.

Unfair Bonus Question: Write yours or someone you love’s name using only chemical symbols for elements.

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