AP Chemistry Pacing Guide Sequence # of Days AP Course

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AP Chemistry Pacing Guide
Seque
nce
# of
Days
1-12
All
1
3
AP Course
Description
ASIM
Lab Activity
IV. Descriptive Chemistry (10–15%)
Knowledge of specific facts of chemistry is essential for an
understanding of principles and concepts. These descriptive
facts, including the chemistry involved in environmental and
societal issues, should not be isolated from the principles being
studied but should be taught throughout the course to
illustrate and illuminate the principles. The following areas
should be covered:
1. Chemical reactivity and products of chemical reactions
2. Relationships in the periodic table: horizontal, vertical,
and diagonal with examples from alkali metals, alkaline
earth metals, halogens, and the first series of transition
elements
3. Introduction to organic chemistry: hydrocarbons and
functional groups (structure,nomenclature, chemical
properties)
Review (nomenclature, safety, etc.)
2
AP College Board
Lab Activities
7
I. Structure of Matter (20%)
A. Atomic theory and atomic structure
1. Evidence for the atomic theory
2. Atomic masses; determination by chemical and physical
means
3. Atomic number and mass number; isotopes
4. Electron energy levels: atomic spectra, quantum numbers,
atomic orbitals
5. Periodic relationships including, for example, atomic radii,
ionization energies,
electron affinities, oxidation states
NMSI Periodic Trends Do’s and Don’t Handout
The AP College Board suggests a
total of 22 labs. NMSI has
provided a protocol for all 22 labs
at their website.
The numbers beside the labs
indicate the AP number.
**Labs#14 (Separation by chromatography use
as first year lab),
#15 (Synthesis of a coordination compound) and
(#22) Synthesis of organic compound are not
included
Below is the website for ASIM labs that are
correlated to AP objectives. These include:
 Labs that are available from
ASIM
 Vernier labs that may not be
available. You may request
Vernier probes from your lead
teacher.
ASIM Web Site
NMSI Atomic Structure and Periodicity Quizzes
NMSI Atomic Structure and Periodicity AP FR Worksheet
NMSI Unit Exam: Atomic Structure
3
10
B. Chemical bonding
1. Binding forces
a. Types: ionic, covalent, metallic, hydrogen bonding, van der
Waals (including London dispersion forces)
b. Relationships to states, structure, and properties of matter
c. Polarity of bonds, electronegativities
2. Molecular models
a. Lewis structures
b. Valence bond: hybridization of orbitals, resonance, sigma
and pi bonds
c. VSEPR
3. Geometry of molecules and ions, structural isomerism of
simple organic molecules and coordination complexes; dipole
moments of molecules; relation of properties to structure
C. Nuclear chemistry: nuclear equations, half-lives,
and radioactivity
NMSI AP FR Bonding Worksheet
NMSI Bonding Quizzes
NMSI Unit Exam: Bonding
4
5
III. Reactions (35–40%)
*Determination of %
Water/Empirical Formulas (01, 02,
16) suggest first year lab
Empirical Formula of a Hydrate,
Bunsen burner
B. Stoichiometry
1. Ionic and molecular species present in chemical systems: net
ionic equations
2. Balancing of equations, including those for redox reactions
3. Mass and volume relations with emphasis on the mole
concept, including empirical formulas and limiting reactants
*Determination of Mass/Mole
Relationship (09) suggest first year lab
Mass/Mole Relationship in a Reaction
NMSI Stoichiometry AP FR Worksheet
NMSI Stoichiometry Quizzes
NMSI Unit Exam Stoichiometry
5
8
Net Ionic Lab
No lab; use NMSI protocol
A.. Reaction types
6
5
1. Acid-base reactions; concepts of Arrhenius, Brønsted-Lowry,
and Lewis; coordination complexes; amphoterism
2. Precipitation reactions
3. Oxidation-reduction reactions
a. Oxidation number
b. The role of the electron in oxidation-reduction
*Determination of
Electrochemical Series (20)
NMSI: Writing Net Ionic Equation Worksheet
NMSI: Reaction Types Quizzes
*Measurements Using Electrolytic
Cells and Electroplating (21)
c. Electrochemistry: electrolytic and galvanic cells; Faraday’s
laws; standard half-cell potentials; Nernst equation; prediction
of the direction of redox reactions
7
7
NMSI Electrochemistry AP FR Worksheet
NMSI Electrochemistry Quizzes
NMSI Unit Exam: Chemical Rxns and Electrochemistry
*Determination of Concentration
by Redox Titration (08)
Corrosion Cell Lab
voltage probes and Lab
Quest usage
No lab; use NMSI protocol
Redox Titration
e
E. Thermodynamics
1. State functions
2. First law: change in enthalpy; heat of formation; heat of
reaction; Hess’s law; heats of vaporization and fusion;
calorimetry
3. Second law: entropy; free energy of formation; free energy of
reaction; dependence of change in free energy on enthalpy and
entropy changes
*Determination of Enthalpy
change associated with a reaction
(13)
Enthalpy of Reaction temperature probe and
Lab Quest
4. Relationship of change in free energy to equilibrium
constants and electrode
8
8
NMSI Thermodynamics FR Worksheet
NMSI Thermodynamics and Thermochemistry Quizzes
NMSI Unit Exam: Thermochemistry and Thernodynamics
D. Kinetics
*Determination of the Rate,
Order, and Activation Energy of a
reaction (12)
Crystal Violet Lab quest and colorimetry probe
used; same procedure as Vernier except activation
energy
1. Concept of rate of reaction
2. Use of experimental data and graphical analysis to
determine reactant order, rate constants, and reaction rate
laws
3. Effect of temperature change on rates
4. Energy of activation; the role of catalysts
5. The relationship between the rate-determining step and a
mechanism
NMSI Kinetics AP FR Worksheets
NMSI Using the Graphing Calculator
NMSI Kinetics Quizzes
NMSI Unit Exam: Kinetics
9
12
*Colorimetric or
spectrophotometric analysis and
determination of Keq (10, 17)
Determination of Keq LabQuest and
colorimetry probe; same procedure as Vernier
C. Equilibrium
1. Concept of dynamic equilibrium, physical and chemical; Le
Chatelier’s principle;equilibrium constants
2. Quantitative treatment
a. Equilibrium constants for gaseous reactions: Kp, Kc
(2) Solubility product constants (Ksp) and their application to
precipitation and the dissolution of slightly soluble compounds
NMSI General Kc, Kp, and Solubility AP FR Worksheets
NMSI General Kc, Kp, Solubility Quizzes
NMSI Unit Exam: General and Solubility Equilibrium
b. Equilibrium constants for reactions in solution
(1) Constants for acids and bases; pK; pH
(3) Common ion effect; buffers; hydrolysis
*Standardization of NaOH and A-B
Titration (06, 07)
Standardization of NaOH
*Determination of Appropriate
Indicators and Buffers (11, 19)
No lab; use NMSI protocol
10
5
NMSI: Buffers Made Easy
NMSI Acid Base Equilibrium Worksheet
NMSI Acid Base Equilibrium Quizzes
NMSI Unit Exam: Acid Base Buffer Equilibrium
*Determining the Molar Volume
of a Gas (05)
II. States of Matter (20%)
*Determination of Molar Mass by
Vapor Density (03) suggest first ;year
1. Laws of ideal gases
a. Equation of state for an ideal gas
b. Partial pressures
2. Kinetic molecular theory
a. Interpretation of ideal gas laws on the basis of this theory
b. Avogadro’s hypothesis and the mole concept
lab
A. Gases
No lab; use NMSI protocol
No lab; use NMSI protocol
NMSI Gases AP FR Worksheet
NMSI Gases Quizzes
NMSI Unit Exam: Gases
11
5
B. Liquids and solids
1. Liquids and solids from the kinetic-molecular viewpoint
2. Phase diagrams of one-component systems
3. Changes of state, including critical points and triple points
4. Structure of solids; lattice energies
NMSI AP FR States of Matter Worksheet
NMSI States of Matter Quizzes
NMSI Unit Exam: States of Matter
C. Solutions
1. Types of solutions and factors affecting solubility
*Determination of Molar Mass by
Freezing Point Depression (04)
Freezing Pt. Depression Mel-Temps
12
5
2. Methods of expressing concentration (use of normalities is
not tested)
3. Raoult’s law and colligative properties (nonvolatile solutes);
osmosis
4. Nonideal behavior (qualitative aspects)
NMSI AP FR Solutions Worksheet
NMSI Solutions Quizzes
NMSI Unit Exam: Solutions
13
4
Review / Mock Exam
V. Laboratory (5–10%)
Suggest first year lab
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