List of questions to be addressed by the IGCP-502 Global VMS teams The aim of this questionnaire is to create a comprehensive database on VMS districts that will enable comparisons among VMS districts, based on the same criteria.. We aim that the database will contain much more geological and interpretative information than a simple database of tonnage, grade and host rocks. Comparisons among VMS districts are one of the main goals of IGCP-502 and will help us ascertain which are the key geological events, common to all major VMS districts, that result in high-value VMS deposits. Specifically we seek answers to the fundamental question: what controls the distribution and timing of major VMS deposits and VMS districts? The database should also be useful for other research and mineral exploration applications. The leaders of IGCP-502 invite each research team to fill in the following questionnaire for the VMS district that the team is working in. Fill in a new questionnaire for each VMS district if you want to include more than one district from the same country. Please contact the regional co-ordinator for IGCP-502 in your country (see list below) if you wish to participate in this questionnaire. Answers to the questions should provide the current state of knowledge in your district; provide evidence and references where possible. It is anticipated that not all questions can be answered for all VMS districts; in some cases the necessary work may not have been carried out yet. Consequently, this questionnaire will also show what work has been done and what work needs to be done in the future in each VMS district. Please look at the GEODE 2000 Global VMS Questionnaire as an example of how this new questionnaire should be completed. The results for the Iberian Pyrite Belt (available as a PDF file from this web site) are particularly good to use as a template for filling in the questionnaire. VMS Districts in the IGCP-502 project and Regional Co-ordinators VMS Districts for which the previous GEODE questionnaire was completed (please also complete the new questionnaire). Iberian Pyrite Belt Skellefte Bergslagen Abitibi Bathurst Mount Read Volcanics Southern Urals Lau and Manus Basins Fernando Tornos Rodney Allen Rodney Allen Harold Gibson Steve McCutcheon Bruce Gemmell, Ross Large Valeriy Maslennikov Sven Petersen VMS Districts for which the earlier GEODE questionnaire was not carried out. Regional coordinators for the IGCP-502 project are listed. Andes (Peru, Equador) Argentina Green Tuff Belt, Japan VMS Questionnaire 2006 Lluis Fontbote, Dick Tosdal Diana Mutti, Ricardo Acevedo Tetsuro Urabe 1 China (1-3 main VMS districts) East Pontide Belt, Turkey Finland (Vihanti-Pyhasalmi) West Greenland Saudi Arabia India Namibia-Damara Orogen Morocco (Variscan Belt) Nunavut (North Slave Province) Cuba-Carribean Belt Central Mexico Western Mexico Venezuela Jun Li Namik Cagatay, Ramazan Dogan Krister Sundblad Peter Appel Mohammed Sahl Ritesh Purohit Fred Kamona, Gregor Borg Abdelhay Belkabir Jan Peter Xiomara Cañazas Carlos Canet Pedro Zarate Simon Rodriguez ______________________________________________________________ 1. Age and tectonic/structural setting 1.1 What is the age of your VMS district? Extent, type and precision of geochronology? (belt scale and deposit scale). Make a table indicating the more relevant data with type of sample (ore, host rock, alteration), method and precision. Palaeontological control 1.2 What are the current interpretations of the tectonic setting of your VMS district? (include a time-sequence diagram if available) 1.3 What is the tectonic interpretation based upon? Provide a summary of main results and/or references: Structural mapping and interpretation? Is there a comprehensive district-scale structural interpretation (quality of mapping?) Regional stratigraphic, facies and paleogeographic interpretation? (quality of mapping?) Gravity and/or magnetic data (has it been used?) Any seismic sections ? Chemistry of volcanic rocks? What geochemical-tectonic classification was used? 1.4 What is the regional structural interpretation for the district? Provide a summary of the main regional structures and/or styles of structures, including folds, thrusts, faults and shear zones. Include a summary structural geology map or 3D sketch/model if available. VMS Questionnaire 2006 2 1.5 Is there a comprehensive and high quality database of volcanic geochemistry to assist with tectonic interpretation? How many whole-rock (with trace element) analyses on least-altered rocks? Type and quality of trace element data? How many analyses include REE data? What isotope data are available? 1.6 Have the district-scale and deposit-scale ore-fluid plumbing structures been identified? Size of structures? How were they defined (mapping? alteration? aeromagnetics? geochemistry? Isotopes?) 1.7 Have detailed structural studies of the deposits been undertaken? Which deposits? 1.8 What further research is needed to improve the tectonic interpretation 1.9 List key references 2. Volcanic architecture 2.1 What are the scales of geological maps available for the district and the deposits? Has the whole district been mapped? 2.2 Has a comprehensive systematic stratigraphy been established for the district? Provide a summary. 2.3 What is the metamorphic grade, and how strongly deformed are the rocks? Is there a penetrative cleavage in most rocks? Can primary volcanic and sedimentary textures/structures be identified? 2.4 Has volcanic facies mapping been carried out on the regional scale, at individual VMS deposits, and/or in specific parts of the district? Summarise the main results. 2.5 How do the VMS deposits relate to volcanic facies? Provide some sketch diagrams if available. Do the VMS deposits occur in proximal or distal volcanic facies? Percentage of volcaniclastic rocks versus coherent flows or intrusions? 2.6 Do the VMS deposits occur at a single stratigraphic level/horizon? If not, how many different stratigraphic levels do VMS ores occur on? What is the evidence for a single or several ore horizons (stratigraphic correlation? fossil control? radiometric dating?). How are the main ore horizon(s) or ore-host stratigraphic unit(s) identified, both close to ore, and 1 km along strike from ore? VMS Questionnaire 2006 3 2.7 What is the stratigraphic or facies sequence from 200 m into the footwall to 200 m into the hanging-wall at the major VMS deposits (for example: rhyolite dome rhyolite pumice deposit VMS siltstone basalt lava)? Is this sequence the same at distances of 1 km and 5 km from ore. Is there a change in volcanic and/or sedimentary facies at, or close to, the ore position? 2.8 What is the composition (rhyolite?, basalt?) of the VMS host package? Is there a change in volcanic composition at, or close to, the ore position? 2.9 Have original volcanic compositions of the altered volcanic rocks around the ore deposits been verified/identified using immobile element chemistry (e.g. ratios of Ti/Zr, Al2O3/TiO2, Zr/Al2O3….)? How many high quality lithogeochemical analyses with immobile trace elements (Zr, Y, Nb…) exist? Do these include REE? 2.10 What is the interpreted range of water depth during deposition of the volcanic succession, and immediate host rocks? What criteria were used to estimate water depth (eg. volcanic facies, sedimentary structures, fossils, fluid inclusions)? 2.11 What further research is needed to define the relationship between ore formation and volcanic architecture? 2.12 List key references 3. Styles of ore deposits 3.1 Provide a table of tonnes and grade for major deposits (>1 million tonnes) (include economic and sub-economic or barren massive sulphides). How many additional deposits of less than 1 million tonnes are known in the district? 3.2 What is the degree of metamorphism, deformation and recrystallization in the ores. Does it vary from deposit to deposit in the district? 3.3 What VMS deposit types occur within the belt (eg polymetallic Zn-Pb-Cu-type, Cu-Zntype, Cu-type, Au-only, barite-only, pyrite-only)? Give a cartoon model of each type present, showing simple geology, morphology of the deposit and metal zones. Do not use genetic classifications such as kuroko type or Cyprus type, but use metal content and ratios – Cu/(Cu+Zn) and Zn/(Zn+Pb). (eg. Large , 1992 : ECON. GEOL. V87, p 473 ). VMS Questionnaire 2006 4 3.4 Are stringer zones present? Are they economic? What is their mineralogy? Are there any deposits that comprise only stringer sulphides? 3.5 Are there deposits that contain large volumes of semi-massive to strong disseminated/impregnation ore types (25-75% sulphides and 10-25% sulphides respectively)? What is their mineralogy? Are these economic? Are these ore types localised in particular volcanic or sedimentary facies? 3.6 What are the major textures in the massive sulphides – massive featureless, banded, brecciated? Are these textures interpreted to be primary or deformation-related. Key evidence? 3.7 Did most deposits form on the seafloor or by replacement below the seafloor or a combination of both? Key evidence (see Doyle and Allen, 2003. Ore Geology Reviews, v. 23, p. 183-222)? If sub-seafloor, how far below the seafloor? Evidence? 3.8 Did the seafloor deposits form in brine pools, or as mounds, or are both types represented, or did they form by some other mechanism? Key evidence? Is there general agreement on the mechanism of formation? 3.9 Relationships between anoxia and exhalative ore deposits; are there studies on the local environment of deposition of the massive sulphides? 3.10 List key references for each deposit 4. Exhalites 4.1 Are “exhalites” (Fe, Si , Mn… units) present at the same stratigraphic level as the ores? Are other styles of ore-equivalent horizons developed, eg; sulphide-bearing clastic facies, pyritic black shales, limestones? Are the exhalites true seafloor precipitates or simply alteration (silicification?) of tuffaceous sediments? Key criteria? 4.2 Are exhalites developed at other stratigraphic levels above or below the ore position? How far above or below? 4.3 Can the exhalites be mapped along strike from the deposit (how far?), and are they useful for exploration? How do you distinguish ore-associated exhalites from barren exhalites. 4.4 Is there a geochemical database for exhalites in your belt (how many samples, REE data, isotope data)? VMS Questionnaire 2006 5 4.5 List key references 5. Alteration facies 5.1 Have hydrothermal, regional diagenetic, and regional metamorphic mineral assemblages and textures been identified? Criteria used for discrimination? 5.2 What (if any) is the immediate footwall alteration mineralogy and zonation? Does the footwall alteration occur as stratabound zones or as pipes? What is the depth extent and surface area of footwall alteration in absolute terms (metres) and relative to the deposit? 5.3 What (if any) is the extent and mineralogy of hangingwall alteration? Give morphology, dimensions and mineral zonation. 5.4 What particular alteration indices (vectors to ore) have been tested or proposed? 5.5 Has a single database of alteration geochemistry been compiled for the district? (number of samples?). By whom? and is it available? 5.6 Is there a database of whole rock oxygen isotopes? (number of samples?) Is data available on H/D, C or Sr-Nd isotopes of the hydrothermal alteration? 5.7 Have deep semi-conformable alteration zones been identified ? What is their dimension, mineralogy, and chemical characteristics? Is there evidence for metal depletion? 5.8 Is alteration geochemistry used to assist exploration in the district? 5.9 List key references 6. Hydrothermal geochemistry 6.1 Are there systematic published studies on the mineralogy, mineral paragenesis and mineral chemistry of the ores and altered host rocks. Which deposits? 6.2 Are the temperature, salinity and chemistry of the ore fluid well constrained from deposit data? What is the quality of primary fluid inclusion data? 6.3 Is there any evidence for fluid boiling, give details? 6.4 What hydrothermal thermodynamic modelling has been attempted? What modelling software was used (if any)? 6.5 What additional information is required to develop robust geochemical models? VMS Questionnaire 2006 6 6.6 List key references 7. Source of fluids, sulfur and metals 7.1 How extensive is the S isotope database on ores, sulfates and host rocks (numbers of analyses)? What is the range of del 34S? Do the massive sulphides and stringer zones have the same mean value and range? What is the interpreted source(s) of sulfur? 7.2 How extensive is the Pb isotope database on ores and host rocks (number of analyses and range of Lead isotope ratios on ores and host rocks?). What is the interpreted source of metals? 7.3 Is there any other isotopic data (Re/Os, Sm/Nd, Rb/Sr) that may assist in determining the source of metals? 7.4 Is there any evidence for magmatic fluid/metal input? If so what is the key evidence? 7.5 What further research is required to determine the source of fluids, sulfur and metals? 7.6 List key references 8. Subvolcanic intrusions 8.1 Have syn-volcanic intrusions been identified and are they associated with VMS deposits? What are their mineralogy, composition and textures? Are they composite intrusions? 8.2 Classify them (according to distance below the VMS horizon, and if possible according to texture) as shallow (<1000 m from the lowest VMS horizon), epizonal (1000-3000 m) or deep (>3000 m). Is there more than one level present? What are their geometry and dimensions. 8.3 Are they hosted by comagmatic volcanics? Or do they occur in underlying basement? 8.4 Are they identified as comagmatic to VMS-hosting strata by: a) geology; b) igneous geochemistry, and/or c) geochronology? 8.5 Are they related to district-scale alteration zones? Key evidence? 8.6 Do they contain extensive areas of alteration? Do they contain base-metal and/or gold occurrences? VMS Questionnaire 2006 7 8.7 List key references 9. Hydrogeological modelling 9.1 Are there any published or unpublished hydrogeological models for the district or for individual deposits? What software package was used? 9.2 Are there any data on the original porosity and permeability of the volcanic and sedimentary facies in the succession? 9.3 Have regional or local hydrothermal fluid pathways been defined? Using what data or criteria? 9.4 Have any heat sources or fluid driving mechanisms been defined 9.5 What research is required to develop robust hydrogeological models? What computer codes are suitable and available? What computer code developments are needed to better constrain 3D heat and fluid flow modelling? 9.6 List key references 10. Exploration criteria 10.1 How were the known deposits found? Provide a list with dates and the key methods. (eg. outcropping gossan, electromagnetic methods (EM), gravity, magnetics, soil geochemistry etc.) 10.2 Currently, what are the key methods used by companies to identify 1) prospect areas, and 2) drill targets? 10.3 What regional exploration data sets are available from the relevant government departments : aeromagnetics?, gravity?, EM?, stream geochemistry?, soil geochemistry?, till geochemistry?, rock-chip geochemistry? Give specifications and degree of coverage. 10.4 What percentage of the volcanic district is under shallow cover? Have any deposits been discovered in the covered areas? 10.5 What exploration methods need to be considered or further researched in your district? 10.6 List key references VMS Questionnaire 2006 8 11. Research strengths for your VMS district 1 2 3 4 5 1. Tectonic and structural setting: 2. Volcanic architecture: 3. Styles of deposits: 4. Exhalites: 5. Alteration facies: 6. Hydrothermal geochemistry: 7. Sources of S, metals, fluids: 8. Hydrogeological modelling: 9. Subvolcanic intrusions 1 = Adequate database and extensive interpretation of data 2 = Adequate database but little interpretation 3 = Extensive interpretation but inadequate database 4 = Moderate database and interpretations (needs improvement) 5 = Inadequate database and little interpretation 12. List of fifteen key references List the major references, even if the interpretations differ from those generally accepted. The key references should include those that have the major geological, geochemical etc data (maps and tables) and also those that contain important discussions and interpretations. Make sure the titles of key maps or map series are included. List key unpublished references (eg. theses) especially if they contain critical data not available elsewhere. VMS Questionnaire 2006 9 Compiled by Ross Large and Derek Blundell for the GEODE project with further modifications by R. Allen, J. Peter, N. Çagatay and F. Tornos (IGCP-502 Global VMS project). This version 4.11.05. VMS Questionnaire 2006 10