Lewis Structures and Resonance

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Homework 7 – Lewis structures and resonance

INSERT SPACES OR ANSWER ON A SEPARATE SHEET OF PAPER!! Follow the model in Question 1 for problems 3 and 4. Again, for exam practice- see/do/work on the optional homework problems!

1.) Practice Drawing the best Lewis structure for: BeCl

2

H

2

O, PBr

5

, SF

4

, ClF

3

(that’s also a chlorine), XeF

2

, SF

6

, SO

, BrF

3

5

, SO

2

, XeF

, CH

4

4

, NH

2

Cl (that’s a chlorine!),

. (please put these on a

SEPARATE sheet of paper from problems 2, 3 ad 4! Problem 1 should be on its own sheet!! I only want ONE structure for each molecule above – the “best” structure)

2.) Draw 4 resonance structures for N

2

O

4

(no O-O bonds, there IS a bond between N-N): use formal charge calculations to determine the “best” resonance structure(s)

Valence electrons:

Formal Charges

N

N

O

O

O

O

1

2

1

2

3

4

Formal Charges

N

1

Formal Charges

N

1

Formal Charges

N

1

N

2

O

1

N

2

O

1

N

2

O

1

O

2

O

3

O

2

O

3

O

2

O

3

O

4

O

4

O

4

3.) Draw 3 resonance structures for HN

3

(NOT NH

3

!!!!) – (skeletal H-N-N-N) use formal charge calculations to determine the “best” resonance structure(s) – model your set-up as question 2 is displayed.

4.) Draw 3 resonance structures for SO

2

(no O-O bonds) – use formal charges to determine the “best” structure(s) – model your set-up as question 2 is displayed.

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