Material Safety Data Sheet
OCEAN ACLOX® FILM
Date of Issue : June 11, 2010
Page 1of 4
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Identification of the Product
1.1. OCEAN ACLOX® FILM
ACX-G-W (Gloss White) / ACX-M-W (Matte White)
1.2. Usage of the Product
Unplasticized Flexible Butyl-Acrylate-Vinyl chloride copolymer Sheet
1.3. Company
Taiyo Chemical Industry Co., Ltd.
Office/Plant
3-4-28, Imazu-minami, Tsurumi-ku, Osaka 538-0043, Japan
Tel. +81-6-6961-0856
Emergency telephone
+81-6-6961-5561
2.
COMPOSITION / INFORMATION ON INGREDIENTS
2.1. Chemical Composition
Component
Butyl-Acrylate-Vinyl chloride copolymer
Ba-Zn Stabilizer
Wt%
55-65
CAS No.
Non-application
1-3
Nothing to mention particularly
UV absorber
0.5-1
Nothing to mention particularly
Titanium dioxide
4-12
13463-67-7
Antimony trioxide
1-3
1309-64-4
Calcium carbonate
2-4
471-34-1
Other additives
3.
20-30
Nothing to mention particularly
HAZARDS IDENTIFICATION
Classified as non-dangerous product.
3.1 Emergency Overview
In case of emergency such as thermal decomposition, general first aid procedures applied for toxic gasses
are suitable. Avoid processing vapors, especially hydrogen chloride, which will cause irritation of eyes
or respiratory tract.
3.2 Repeated or prolonged
Extended exposure to skin can cause slight irritation.
4.
FIRST AID MEASURES
4.1. Skin contact
Rinse with plenty of water (15 minutes), then wash area with mild soap and water. Get medical attention if
irritation should occur or persist.
Material Safety Data Sheet
OCEAN ACLOX® FILM
Date of Issue : June 11, 2010
Page 2of 4
4.2. Eye contact
Rinse immediately with water (15 minutes), occasionally lift upper and lower lids, until no evidence of
product remains. Get medical attention.
4.3. Inhalation
Move affected person to fresh air. Get medical attention.
4.4. Ingestion
Induce vomiting. Get medical attention.
5.
FIRE FIGHTING MEASURES
5.1. Suitable extinguishing media
Form water, dry chemical agent (ABC) type, CO2, foam. At extinction, avoid the scattering of burning
material and avoid creating dust hazard: do not use stick water jets.
5.2. Unsuitable extinguishing media
Avoid spraying with stick water jet due to the danger of potential spreading.
5.3. Exposure hazards
CO and CO2 gas, HCl and chlorinated hydrocarbons (small amounts), and aromatic aliphatic hydrocarbons
may arise in a fire.
5.4. Special protecting equipment for fire-fighters
Wear full protective clothing. Wear self-contained breathing apparatus.
6.
ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions
Do not breathe dust when dust is raised. Avoid ignition source. Avoid contact with eyes and skin. Use dust
mask, gloves made from antistatic material and protecting glasses when dust is raised. Wash hands at the
end of working.
6.2. Environmental precautions
Prevent contamination of soil, drains, foodstuffs, drinks, animal feeds and surface waters.
6.3. Methods for cleaning
Take up mechanically by brush and dustpan or by suction or vacuum equipment. Avoid dust generation
and ignition source.
7.
HANDLING AND STORAGE
7.1. Handling
In high temperature processing, handle with care. Wear personal protective equipment. Handle in
accordance with industrial hygiene and safty practice. Ensure good ventilation. Do not smoke, eat or drink
at the workplace.
7.2. Storage
Store in a dry area, avoiding high temperature, sunlight and exposure to water.
Material Safety Data Sheet
OCEAN ACLOX® FILM
Date of Issue : June 11, 2010
Page 3of 4
8.
EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1. Engineering Controls；Processes which generate vapours, dust or fumes should be performed with
adequate ventilation. If necessary, use NIOSH approved chemical cartridge respirator.
8.2. Exposure controls
8.2.1. Occupational exposure control
8.2.1.1. Respiratory protection: Use dust mask, if necessary.
8.2.1.2. Hand protection: Not necessary in normal use. But use heavy cotton or insulated gloves to handle
hot sheet.
8.2.1.3. Eye protection: Wear suitable safety glasses.
8.2.2.
Environmental exposure controls: Keep emissions to the atmosphere within local authority
prescriptions for dust.
8.3. Exposure limits
Ingredient
Ba-Zn Stabilizer
Percent
ACGIH TLV
OSHA PEL
0.5mg/m3(Ba)
0.5mg/m3(Ba)
10mg/m3
10mg/m3
1-3
Ba rium stearate
Zn stearate
Titanium dioxide
4-12
10mg/m3
-
Antimony trioxide
1-3
0.5mg/m3(Sb)
-
Calcium carbonate
2-4
10mg/m3
-
9.
PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Odor
Melting point
Boiling point
Oxidizing properties
Density
Flashpoint
Ignition temperature
Solubility in water
Vapour pressure
PH value
Partition coefficient
Viscosity
: White sheet/film
: Not available
: Not available
: Not applicable
: Not applicable
: 1.24～1.44 g/cm³
: Not available
: > 250°C
: Not soluble
: Not applicable
: Not applicable
: Not applicable
: Not applicable
10. STABILITY AND REACTIVITY
10.1.
Conditions to avoid: static discharges, dust generation. Please take care not to hold sheet in
machine for a long time at elevated temperatures in order to avoid decomposition. During long
exposures to high temperatures, the degradation temperature decreases.
Avoid to inhale dust and processing vapours, especially hydrogen chloride, which will cause
irritation of eyes or respiratory tract.
Material Safety Data Sheet
OCEAN ACLOX® FILM
Date of Issue : June 11, 2010
Page 4of 4
10.2.
10.3.
Materials to avoid: oxidizers.
Hazardous decomposition products: when burning or during thermal decomposition, combustion
gases may result; eg CO, CO2, HCl and chlorinated hydrocarbons (small amounts), and aromatic
aliphatic hydrocarbons.
11. TOXICOLOGICAL INFORMATION
No data available for Ocean ACLOX White sheet.
12. ECOLOGICAL INFORMATION
No data available for Ocean ACLOX White sheet.
13. DISPOSAL CONSIDERATIONS
Incineration or landfill in accordance with local regulations. The cleaned packaging can be recycled or
treated together with household refuse. Local regulations may impose specific requirements for treatment
and/or reporting of the packaging wastes (e.g. as based upon EU packaging waste directive).
14. TRANSPORT INFORMATION
Carefully load not fall and drop the product when transporting. Take any measures to prevent injury due to
collapse of cargo piles.
15. REGULATORY INFORMATION
＊Japanese Regulations
PRTR(Pollutant Release and Transfer Register) Law
Chemical Substances
：
Antimony and its compounds
(I-No31)
＊European/International Regulations
European Labeling in Accordance with EC Directives (data for Sb2O3)
Hazard Symbols : XN
Risk Phrases : R 40 Limited evidence of a carcinogenic effect.
Safety Phrases : S22 Do not breathe dust.
: S36/37 Wear suitable protective clothing and gloves.
16. OTHER INFORMATION
The information set forth herein has been gathered from standard reference materials and/or Taiyo Chemical
Industry Co., Ltd. test data. The information containing herein is based on the present state of our knowledge
and is intended to describe our product from the view of safety requirements. It should not therefore be
construed as guaranteeing specific properties.
This product should be stored, handled and used in accordance with good industrial hygiene practices and in
conformity with any legal regulation. Safe handling and use remain the responsibility of the customer.