revision date january 2005

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MATERIAL SAFETY DATA SHEET
HORIBA INSTRUMENTS, INC.
17671 Armstrong Avenue, Irvine, CA 92614
(949) 250-4811
REVISION DATE JANUARY 2005
SECTION I:
MATERIAL IDENTIFICATION
IDENTITY: pH reference solution, KCL, #300
P/N 350158, 360647, 9003003200, #300
___________________________________________________________________________
CHEMICAL FORMULA: KCl
___________________________________________________________________________
GENERIC NAME:
Potassium Chloride
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CHEMICAL FAMILY:
Dissolved Salt
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OTHER DESIGNATION: Pot Ash, Internal Solution pH, Reference electrode filling
solution pH
Horiba Instruments, Inc.
17671 Armstrong Avenue
Irvine, CA 92614
(949) 250-4811
___________________________________________________________________________
IN CASE OF EMERGENCY CONTACT YOUR REGIONAL PLANT MANAGER
SECTION II: HAZARDOUS INGREDIENTS
COMPONENT
CONCENTRATION
TLV
CASE #
Potassium chloride
26.1%
none listed
7447-40-7
Water
73.9%
N/A
7732-18-5
___________________________________________________________________________
This product contains the following toxic chemical(s) subject to Section 313
Title III reporting requirements (40 CFR Part 372): NONE
SECTION III: PHYSICAL DATA
BOILING POINT (*): 212 oF (100 oC)
SPECIFIC GRAVITY (H2O = 1): 1.2
VAPOR PRESSURE: 14 mm Hg (water)
PERCENT, VOLATILE BY VOLUME(%): N/A
SOLUBILITY IN WATER v/v @oC: Soluble
MELTING POINT: 14 oF (-10 oC)
EVAPORATION RATE (ETHER = 1): <1
VAPOR DENSITY: 0.7 (water)
APPEARANCE AND ODOR: Colorless liquid containing crystals of potassium chloride.
SECTION IV:
FIRE AND EXPLOSION HAZARD DATA
FLASH POINT AND METHOD:
Non-combustible
FLAMMABLE LIMITS:
EXTINGUISHING MEDIA:
NA
Dry chemical, carbon dioxide, halon, water
spray or standard foam. For larger fires, use
water spray, fog or standard foam.
1
SPECIAL FIRE FIGHTING PROCEDURES:
Move container from fire area if possible. Do
not scatter spilled material with high pressure
water streams. Dike fire control water for later
disposal.
UNUSUAL FIRE AND EXPLOSION HAZARDS:
SECTION V:
Use agents suitable for type of
surrounding fire. Avoid breathing
hazardous vapors, keep upwind.
REACTIVITY DATA
STABILITY:
Stable under normal temperatures and pressures.
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INCOMPATIBILITY (MATERIALS TO AVOID):
Bromine trifluoride (may react violently),
and sulfuric acid and potassium
permanganate (possible explosion).
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HAZARDOUS DECOMPOSITION PRODUCTS:
Thermal decomposition may release
corrosive hydrogen chloride.
HAZARDOUS POLYMERIZATION:
SECTION VI:
Has not been reported to occur under
normal temperatures.
HEALTH HAZARD DATA
THRESHOLD LIMIT VALUE:
N/A
EFFECTS OF OVER EXPOSURE:
Inhalation:
No data is available for acute exposure. For chronic exposure,
inhalation of potassium mines and plants has been reported to
result in lesions of the nasal septum due to potassium chloride and
can cause respiratory tract irritation.
Skin:
No data is available for acute and chronic exposure. Causes skin
irritation.
Eye:
Acute exposure may cause irritation. Tested in rabbit eyes,
application of 500 mg for 24 hours resulted in mild irritation.
Concentration solutions may cause a stinging sensation. There is
not data available for chronic exposures.
Ingestion:
Acute exposure may cause gastrointestinal irritation with nausea,
vomiting, epigastric distress, abdominal discomfort, and diarrhea.
High local concentrations in the gastrointestinal tract may cause
esophageal ulceration, if there is dysphagia; gastric ulderation,
especially if perforation of the small bowel. Acute intoxications
orally are uncommon since large doses usually induce vomiting
and normally functioning kidneys excrete potassium rapidly.
However, if an overdose results in hyperkalemia there may be
paretthesias, anesthesias, generalized weakness, mental
confusion, hypotension, and sluggishness.
2
EMERGENCY AND FIRST AID PROCEDURES:
Inhalation:
Remove from exposure area to fresh air immediately. If breathing
has stopped, perform artificial respiration. Keep person warm and
at rest. Treat symptomatically and supportively. Get medical
attention immediately.
Skin:
Remove contaminated clothing and shoes immediately. Wash
affected area with soap or mild detergent and large amounts of
water until no evidence of chemical remains (approximately 15-20
minutes). Get medical attention immediately.
Eye:
Wash eyes immediately with large amounts of water or normal
saline, occasionally lifting upper and lower lids, until no evidence of
chemical remains (approximately 15-20 minutes). Get medical
attention immediately.
Ingestion:
If victim is conscious, give him large quantities of water, to dilute
the alkali. Do not induce vomiting. Get medical attention
immediately.
SECTION VII:
SPILL OR LEAK PROCEDURES
Highway or railway spills call Chemtrec
(800) 424-9300
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
Soak up spill with vermiculite or other absorbent material and place into suitable containers for
later disposal.
WASTE DISPOSAL METHOD: Put in laboratory chemical waste container for removal by
approved chemical waste disposal company.
SECTION VIII:
SPECIAL PROTECTION INFORMATION
VENTILATION:
Provide general dilution ventilation.
OTHER PROTECTIVE EQUIPMENT: Employees must wear appropriate protective
(impervious) clothing and equipment to prevent repeated or prolonged skin contact with
this substance. They must also wear appropriate protective gloves to prevent contact
with this substance along with splash-proof or dust-resistant safety goggles to prevent
eye contact with substance. Emergency eyewash should also be available where there
is any possibility that an employee's eyes may be exposed to this substance. The
employer should provide an eye wash fountain within the immediate work area for
emergency use.
SECTION IX: SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING:
OTHER PRECAUTIONS:
None
3
N/A
SECTION X: REGULATORY INFORMATION
Chemical Inventory Status – Part 1
Ingredient
Potassium Chloride (7447-40-7)
TSCA
Yes
EC
Yes
Japan
Yes
Australia
Yes
Chemical Inventory Status – Part 2
--CANADA-Ingredient
Potassium Chloride (7447-40-7)
Korea
Yes
DSL
Yes
NDSL
No
Phil.
Yes
Federal, State & International Regulations – Part 1
-SARA 302--------SARA313-----------Ingredient
RQ
TPQ
List
Chemical Cat.
Potassium Chloride (7447-40-7) No
No
No
No
Federal, State & International Regulations – Part 2
-RCRA-TSCAIngredient
CERCLA 261.33
8(d)
Potassium Chloride (7447-40-7) No
No
No
Chemical Weapons Convention: No
TSCA 12(b): No
SARA 311/312: Acute: Yes
Chronic: No
Fire: No
Reactivity: No
(Pure/Solid)
CDTA: No
Pressure: No
Australian Hazchem Code: None allocated.
Poison Schedule:
None allocated
___________________________________________________________________________
* Information herein is given in good faith, but no warranty, expressed or implied, is made.
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