Les Ateliers de Blicquy SAFETY DATA SHEET per European Directive 91/155/EEC Rue du Couvent, 38 B7903 – BLICQUY Tel: +32 (0) 69 66 96 90 Fax: +32 (0) 69 66 96 99 Page 1 Date: 15/01/09 Edition no. BBPE 01 Safety Manager: Arnaud Fréville BLIC READY-TO-USE CONCRETE 1. Identification of the product and of the company Name of the product Ready-to-use concrete Trade Name BLIC Ready-to-use Concrete Manufacturer LES ATELIERS DE BLICQUY Address Rue du Couvent, 38 7903 Blicquy Tel.: 00 32 (0)69 66 96 90 Fax: 00 32 (0)69 66 96 99 Distributor LES ATELIERS DE BLICQUY Rue du Couvent, 38 7903 Blicquy Tel.: 00 32 (0)69 66 96 90 Information in case of emergency Safety Service 00 32 ()69 66 96 90 Anti-poison Centre (Belgium) 070/245 245 2. Information on the ingredients Dangerous ingredients Portland Clinker Cas No.: 65997-15-1 Danger symbol: Xi R Phrases: 37-38-41-43 Additional indications Indication of danger ‘irritant’ is applied to the concrete mixed with water (alkaline reaction) 3. Identification of the dangers Danger symbol: Xi Principal dangers for man and for the environment: Concrete in the form of a powder or paste can cause a grave ocular lesion and an irritation of moist skin. In case of prolonged contact, concrete can cause an irritation of the skin. In case of inhalation, concrete can cause an irritation of the respiratory system. 4. First Aid Measures Contact with the skin Wash abundantly with water Inhalation Give fresh air. Possibly consult a specialist Contact with eyes Rinse immediately and abundantly with water while moving aside the eyelids for several minutes. Consult a specialist. Ingestion Rinse the mouth abundantly with water: drink a lot of water. Do not cause to Vomit. Consult a specialist. Les Ateliers de Blicquy Rue du Couvent, 38 B7903 – BLICQUY Tel: +32 (0) 69 66 96 90 Fax: +32 (0) 69 66 96 99 SAFETY DATA SHEET per European Directive 91/155/EEC Page 2 Date: 15/01/09 Edition no. BBPE 01 Safety Manager: Arnaud Fréville BLIC READY-TO-USE CONCRETE 5. Measures to combat fires Concrete is not flammable. Method of extinguishing fires 6. All firefighting methods are appropriate Measures to take in case of accidental spills Methods of cleaning up/recovery Concrete powder cannot be gathered up and recovered. After hardening, concrete can be eliminated like other construction industry waste. Concrete hardens in 5 to 6 hours after mixing with water. Individual precautions Avoid contact with skin and eyes: in case of contact with eyes, rinse abundantly with water while keeping the eyelids open for several minutes. Consult a specialist. Handle with gloves. In case of flying dust, wear a device suitable for protecting the eyes and respiratory tract. Precautions for protection of the environment 7. Avoid spilling concrete into surface water and into drains. Handling and storage Handling: - Prevention - Condition of storage Store where children cannot reach it 8. Avoid dispersion and inhalation of concrete dust: avoid contact with the skin and eyes; protect from humidity. No risk of fire or explosion. Store in a dry place in the original packaging; avoid contact with water Control of exposure / individual protection Measures of individual protection Protection of respiratory tract: use of a protective mask against dust is recommended when working in a dusty atmosphere. Protection of the hands: avoid contact with skin; wear gloves Protection of the eyes: avoid contact with the eyes; wear glasses General measures of hygienic protection Provide a source of fresh water to rinse the skin and eyes Components and professional maximal readings to monitor Dust: limits to be respected: TLV – TWA: 10 mg/m3 – conc. Average max. over 8 hours 9. Physical and chemical properties Les Ateliers de Blicquy Rue du Couvent, 38 B7903 – BLICQUY Tel: +32 (0) 69 66 96 90 Fax: +32 (0) 69 66 96 99 SAFETY DATA SHEET per European Directive 91/155/EEC Page 3 Date: 15/01/09 Edition no. BBPE 01 Safety Manager: Arnaud Fréville BLIC READY-TO-USE CONCRETE Aspect Powder Colour Grey or beige Highlights Not applicable Flammability (solid, gas) Not applicable Self-ignition Not applicable Explosion danger Gaseous pressure Weight/volume (dry) +/- 1.9 kg/m3 Weight/volume (moist) +/- 2.3 kg/m3 pH value Aqueous solution between 11 and 13.5 Additional data Alkaline reaction 10. Stability and reactivity The product is stable Conditions to be avoided Humidity. The product hardens in contact with water Substances to be avoided Acids Dangerous products from decomposition 11. Toxicological information Acute toxicity None By ingestion Non toxic By inhalation Contact with the skin Inhalation of the dust can cause irritation of the respiratory tract The dust can irritate moist skin. Contact with fresh mortar can cause Irritation of the skin Contact with the eyes Contact with the eyes can cause a grave ocular lesion Ingestion Swallowing dry concrete can irritate the mouth and stomach Chronic toxicity Inhalation of concrete dust during a prolonged period can cause respiratory ailments. Les Ateliers de Blicquy SAFETY DATA SHEET per European Directive 91/155/EEC Rue du Couvent, 38 B7903 – BLICQUY Tel: +32 (0) 69 66 96 90 Fax: +32 (0) 69 66 96 99 Page 4 Date: 15/01/09 Edition no. BBPE 01 Safety Manager: Arnaud Fréville BLIC READY-TO-USE CONCRETE 12. Ecological information Mobility – none Accumulation – none Ecotoxicity - none Degradability - the elements constituting hardened concrete are definitively set and insoluble Miscellaneous harmful effects: in case of accidental spills into water or in a humid milieu, concrete powder causes a slight increase of the basicity of the water or of the humid milieu. 13. Considerations relating to disposal The dry product remains ready for use. After hardening, the concrete can be disposed of like any other construction industry waste. 14. Information relating to transport Not considered dangerous merchandise according to the transport regulations. 15. Regulatory information Danger symbol Xi : the product is an irritant R Phrases R 37/38: irritant for the respiratory tract and the skin R 41: risk of grave ocular lesions R 43: can lead to heightened sensitivity by contact with the skin S Phrases S 2: keep out of the reach of children S 22: do not inhale the dust S 24/25: avoid contact with the skin and the eyes S 26: In case of contact with the eyes, wash immediately and abundantly with water and consult a specialist S 37/39: Wear appropriate gloves and a device to protect the eyes and face 16. Other information This sheet complements the technical data sheet of the product but does not replace it The information which it contains is based on the state of our knowledge relating to cement at the date indicated. It is given in good faith. The attention of users is drawn to the possible risks incurred when the product is used for other applications than those for which it was designed. This sheet in no way exempts the user from knowing and applying all the laws governing his activity. On his sole responsibility he must take the precautions linked to the use he is making of the product.