MATERIAL SAFETY
DATA SHEET
SECTION I. IDENTITY
Date:
January 3, 2014
Identity (As Used on Label and List):
Emergency Telephone Number:
Transparent Clear Aerosol Paint
CHEMTREC: (800) 424-9300 CANUTEC: (613) 996-6666
DOT Proper Shipping Name:
Paint Related Material, 3, UN 1263, PG III
Manufacturer's Name:
Distributor's Name:
Production Car
Care Products
Address: 1000 East Channel
Street
City - State - ZIP - Phone#: Stockton, CA
95205 209/943-7337
Address:
City - State - ZIP - Phone#:
HAZARD RATING
Fire
Health
Reactivity
4=
3 = High
2=
1=
0=
Extreme
4
0
1
N/D =
N/A =
Moderate
Slight
Insignificant
Not determined
Not applicable
Flammable
Special
SECTION II. HAZARDOUS INGREDIENTS
Hazardous Components:
WT.
Toluene
Hazardous
%
a
b
37
x
30
x
ACGIH
c
x
CAS #108-88-3
Methylene Chloride
OSHA PEL
x
TLV
150 ppm
100 ppm
or
or
560 mg/M3
375 mg/M3
500 ppm
50 ppm
or
2000 mg/M3
CAS #75-09-2
Propane/Isobutane
CAS #74-98-6/75-28-5
25
SEE
[01] See Section V for carcinogenic ity infor mation.
LEL
1.2
Vapor
LD 50 of
Pressure*
Ingredient
22/68F
12
420/25C
2.1
SEE NOTE
LC 50 of
Ingredient
(oral-rat)
(inhalation-mouse)
5000 mg/kg
5320 ppm/8H
or
100 mg/M3
NOTE
[02] ACGIH simple asphyxiant, Vapor pressure = 208 PSIG @ 100 °F
Hazardous according to: a-SARA 302/304, b
c-CERCLA 103 (a) *Vapor Pressure =mm Hg
-SARA 313,
SECTION III. PHYSICAL CHARACTERISTICS
Boiling Range:
Pounds per gallon:
42-232°F
Percent volatile by volume:
8.81
3.98 lbs/gal. (water)
VOC:
94.4
Vapor Density:
Evaporation Rate:
Heavier than air
Faster than ether
SECTION IV. FIRE AND EXPLOSION HAZARD DATA
Flash Point:
(Method Used)
Flammability
-156 °F Setaflash
Flammability Classification:
OSHA 29 CFR - 1910.106(a)
Flammable Liquid - Class 1(A)
Limits (LEL):
See Section II
Parts 18-19
Extremely Flammable (FHSA)
Extinguishing Media: Regular
Foam, Carbon Dioxide or Dry Chemical or other NFPA approved method for treating Class B
fire.
Fire Fighting Procedures:
Use full protective equipment including self-contained breathing apparatus. Water spray may be ineffective. If water is used, fog nozzles are preferable.
If exposed to fire or extreme heat, water should be used to cool closed containers and prevent pressure build-up or possible auto-ignition.
Unusual Fire and
Keep container tightly closed. Isolate from heat & flame. Due to pressure build-up, closed containers Explosion
Hazards: exposed to extreme heat may explode. Never use a welding or cutting torch on or near container (even
empty) as product or its residue may ignite. During emergency conditions, overexposure to decomposition products may cause a health
hazard. Symptoms may not be immediately apparent. Obtain medical attention.
Page 1 of 2
SECTION V. REACTIVITY DATA
Stable:
X
Transparent Clear Aerosol Paint
Unstable:
Condition to Avoid:
Hazardous Decomposition or By-products: May cause hazardous fumes when heated to decomposition. Fumes may contain carbon monoxide.
Incompatibility (Materials to Avoid):
Avoid contact with strong oxidizing agents.
Polymerization Hazard:
May Occur
Conditions to Avoid:
Will Not Occur X
SECTION VI. HEALTH HAZARD DATA
Routes of Entry:
Inhalation:
Skin:
Ingestion:
Yes
Health Hazards:
Yes
Eye or skin contact: Causes eye and skin irritation. Inhalation: Irritation of the respiratory; may affect the brain or nervous system causing dizziness,
headache,
(Acute and Chronic) nausea, weakness and fatigue. Extreme exposure can result in unconsciousness and even respiratory arrest. Ingestion: Can cause stomach and/or
intestinal irritation, nausea, vomiting, diarrhea. Aspiration of vomitus can cause chemical pneumonitis, which can be fatal. METHYLENE CHLORIDE is metabolized by the
body to carbon monoxide which reduces the bloods oxygen carrying capacity. Reports have associated repeated and prolonged occupational overexposure to solvents with
permanent brain and nervous system damage. Prolonged and repeated breathing of spray mist and/or sanding dust over a period of years may cause dust disease of the
lungs. NTP has classified METHYLENE CHLORIDE as a carcinogenic in rats and mice at high levels of exposure to vapors throughout their lifetime. The U.S. Consumer
Product Safety Commission considers METHYLENE CHLORIDE to be a probable human carcinogen. ACGIH lists METHYLENE CHLORIDE as a suspect human carcinogen.
METHYLENE CHLORIDE is known to the state of California to cause cancer. Risk depends on duration and level of exposure.
Signs and Symptoms of Exposure:
None when used in accordance with Safe Handling and Use Information (See section IX)
Medical Conditions That May Be Aggravated by Exposure:
None when used in accordance with Section X
Control Measures
Emergency and First Aid
Procedures:1)
Eyes: Flush with water for 15 minutes
2) Ingestion: Do not
induce vomiting.
Aspiration of vomitus can cause chemical pneumonitis which can be fatal. 3) Breathing: Remove to fresh air, if
necessary administer oxygen and/or artificial respiration 4) Skin: Remove contaminated clothing, wash with soap
and water. Get medical attention if irritation persists. Warning: Intentional misuse by deliberately concentrating and
inhaling the contents may be harmful or fatal. (CALL DOCTOR FOR 1, 2, and 3 )
SECTION VII. SPILL OR LEAK PROCEDURES
Remove all sources of ignition (flames, hot surfaces, and
Steps to be taken in case material is released or spilled:
electrical, static or frictional sparks). Do not smoke. Avoid breathing vapors. Before attempting clean-up refer to
hazard caution information in other sections of this material safety data form. Ventilate area. Contain spilled
material and remove with inert absorbent and non-sparking tools. Store in closed containers until properly
disposed of.
Waste Disposal Method:
Dispose of in accordance with local, state and federal regulations. Incinerate
only in approved facility. Do not incinerate closed containers.
SECTION VIII. SPECIAL PRECAUTIONS
Precautions to be Taken in Handling and Storing: Keep away from heat, sparks, and flame. Do not smoke. Extinguish all pilot lights and turn off all
sources of ignition including heaters, fans and other non-explosion-proof electrical equipment, during use and until all vapors are gone. Vapors may
ignite explosively or cause flash fire. Vapors may spread long distances and beyond closed doors. Prevent build-up of vapors by maintaining continuous
flow of fresh air. DANGER: Extremely flammable liquid and vapor. Contents under pressure. Exposure to heat or prolonged exposure to sun may cause
bursting. Do not puncture, incinerate (burn) or store above 120 °F. Do not place in garbage compactors. Do not store above 120 °F or near fire or open
flame. Store large quantities in building designed to comply with OSHA 1910.106. Keep container closed when not in use. Do not transfer contents to
bottles or other unlabelled containers. Do not reuse empty containers. Keep out of reach of children. Pending government agencies review, it is
recommended that individual exposure to Methylene Chloride, including short term concentration peaks, be reduced to the lowest levels feasible by
utilizing good industrial hygiene practices. Warning: This product contains a chemical known to the state of California to cause cancer, birth
defects or other reproductive harm.
SECTION IX. SAFE HANDLING AND USE INFORMATION
Respiratory protection: Do not breathe vapors, spray mist or sanding dust. When spray applied in outdoor or open areas with unrestricted ventilation
and during sanding or grinding operations, use NIOSH/MSHA approved mechanical filter respirator to remove solid airborne particles of overspray and
sanding dust. When used in restricted area, wear NIOSH/MSHA approved chemical/mechanical filters designed to remove a combination of
particulates and vapor. When used in confined areas, wear NIOSH/MSHA approved air supply respirators or hoods. Use NIOSH/MSHA approved
respirators when flame cutting, welding, brazing and sanding material coated with this product. Follow respirator manufacturer's direction for respirator
use. Ventilation: Use only with adequate ventilation. Provide general dilution or local exhaust ventilation in volume and pattern to keep air
contaminant concentration below current applicable safety and health standards in the mixing, application and curing areas, and to remove sanding
dusts of dried coating and decomposition product during welding and flame cutting on surfaces coated with this product. Heavy solvent vapors should
be removed from lower levels of the work area and all ignition sources should be eliminated. Protective Gloves: Do not get on skin. Solvent
impermeable gloves to prevent contact are recommended. Eye Protection: Do not get in eyes. Solvent resistant safety eyewear with splash guards or
sideshields is recommended to prevent contact. Other protective equipment: Do not get on skin. Solvent impermeable clothing and boots to prevent
contact are recommended. Hygienic practices: Remove and wash soiled clothing before reuse. Wash hands before eating, smoking or using the
washroom.
Disclaimer of Liability:
The information contained herein is based on data considered accurate. However, the information is provided
without any warranty, expressed or implied, regarding its correctness. The conditions or methods of handling, storage, use and disposal of the
product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility for personal
injury or property damage to vendees, users or third parties caused by the material. We also do not assume responsibility and expressly
disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product.
Page 2 of 2