Reaction Rates and catalysts assignment

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Science 10
Outcome: CHEM8 - Investigate and collaborate to describe science and technology relationships and their functions
1. Read the chapter opener on page 240 of your Sciencepower10 textbook. Record answers to the
three opening ideas below:
2. Explain what the term reaction rate means. (p. 242)
3. Explain what a catalyst is and exactly how it works.
4. Give an example of a catalyst found in your body. Explain what it does.
5. Read the article on catalytic converters on the back side of this page. Complete a fact-based article
analysis for it and staple it to this sheet.
6. Read about another chemistry innovation for cars on page 246 of your text.
a) Model this chemical equation using colored circles below:
b) Explain how this chemical reaction saves lives and how the timing of it is controlled.
Science 10
Outcome: CHEM8 - Investigate and collaborate to describe science and technology relationships and their functions
Catalytic Converters
Millions of people worldwide who enjoy the benefits provided by cars and
trucks also suffer the miseries of traffic pollution.
But advances in automotive technology are helping to stem the tide of
pollution and recent U.S. research into the effectiveness of one particular
anti-pollution automotive component has uncovered one of the planet’s
greatest environmental success stories which may have far-reaching
global implications for as markets for new cars expand.
The device in question is the catalytic converter, which cleans gases
passing through vehicles’ exhaust systems.
Engineers estimate that during the last 11 years 130 million catalytic converters used in the U.S. have
eliminated automotive pollutants that-if unchecked and unabated-could have covered the country with a
toxic blanket of carbon monoxide more than 500 feet deep.
The carbon monoxide was captured from exhaust streams by catalytic converters and converted into
harmless carbon dioxide.
Engineers say that between 1975 and 1996, emissions control technology cleaned automotive exhaust
streams in the U.S. of about 195 million tons of carbon monoxide; nearly 42 million tons of hydrocarbons;
and at least 37 million tons of oxides of nitrogen. The carbon monoxide, at standard pressure and
temperature (one atmosphere at 32 degrees Fahrenheit) and 100 parts per million concentration (the toxic
level) would pile 512 feet high over the 50 states.
The U.S. Environmental Protection Agency (EPA) data shows that due to emission controls, vehicles now sold
in the U.S. emit 96 per cent less carbon monoxide, 98 per cent less hydrocarbons, and 90 per cent less
oxides of nitrogen than vehicles sold in the early 1970s.
The improvement in air quality is continuing, as new vehicles are equipped with the latest emission control
technology and older cars are scrapped. Currently, 85 per cent of automotive air pollution in the U.S. comes
from the oldest 50 per cent of vehicles on the road.
Catalytic converters typically consist of a ceramic or metal honeycombed monolith substrate that carries
precious metal catalysts. The coated substrate is wrapped in an intumescent mat that expands when heated,
securing and insulating the substrate which is packaged in a stainless steel shell and fitted into the engine
exhaust system.
As exhaust gases pass over the catalysts, they promote chemical reactions that convert pollutants into
harmless gases and water. Hydrocarbons combine with oxygen to become carbon dioxide; oxides of nitrogen
react with carbon monoxide to produce nitrogen and carbon dioxide; and with hydrogen to produce nitrogen
and water vapour.
The catalyst formulation, which promotes a faster chemical reaction at a lower temperature, is usually a
mixture of the noble metals platinum, palladium and rhodium, and sometimes other catalysts such as the
rare earth ceria.
A catalytic converter is not a stand-alone cure-all for emissions control. Unleaded fuel is required. And to
operate properly, a converter is fitted as part of an engine management subsystem - an integrated set of
specific-purpose emission control components.
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