Nanoparticles in facade coatings – a survey of industrial experts on functional and environmental benefits and challenges Authors Ingrid Hincapié1, Tina Künniger2, Roland Hischier1, Dario Cervellati3, Bernd Nowack1, Claudia Som1* 1 EMPA, Swiss Federal Laboratories for Materials Science and Technology. Technology and Society Laboratory, Lerchenfeldstrasse 5, CH-9014 St. Gallen, Switzerland. 2 EMPA, Swiss Federal Laboratories for Materials Science and Technology. Applied Wood Materials Laboratory, Überlandstrasse 129, CH-8600 Dübendorf, Switzerland 3 GFC Chimica S.r.l, Via Guglielmo Marconi 73, I-44122 Ferrara, Italy *Corresponding author: Contact e-mail: claudia.som@empa.ch Tel: +41 58 765 78 43 SUPPLEMENTARY INFORMATION Section 1: Survey questionnaire Section 2: Answers from paint and ENP producers to the survey questionnaire 17 Figures 1 Section 1. Survey questionnaire and answers The specific questions of the survey were: 1. Do you produce nanomaterials? 2. Do you integrate nanomaterials in facade coatings? 3. Would you be willing to provide us information on the energy consumption for the production of nanomaterials or your integration process? 4. Which of the following properties would you like to improve or bring in new façade coatings? (several answers possible) UV protection, protection from mechanical wear, photocatalytic activity (dirt degradation), water and dirt repellent („easy to clean“), antimicrobial, dripping behavior, drying behavior, thermal insulation, extension of product life, substitution of hazardous substances (e.g. biocides), material and energy savings, flame retardant 5. Which facade coatings functions can be improved with the following nanomaterials? Silver (Ag), Ag ions, silicium dioxide (SiO2), titanium dioxide (TiO2), zinc oxide (ZnO), iron oxid (FeO), aluminium(hydr)oxide (z.B. Al2O3), nano clays (e.g. Montmorillonite) 6. What ecological performance potential may be achieved by integrating nanomaterials in facade coatings: Extended life span of the coating, substitution of hazardous substances, saving energy by shorter drying cycles after the application of the facade coatings on the walls, saving materials 7. What nanomaterials are currently used in use in Europe for facade coatings? 8. What is your estimate of the total amounts of nanomaterials used in Europe for facade coatings (tons/year)? 9. What tests have you carried out to analyze the improvement of facade coatings enhanced with the mentioned nanomaterials? Adhesion, air permeability, alkali resistance and resistance to water, durability and color brilliance, fungal resistance, liquid water permeability and crack bridging, release of substances, resistance to impact, resistance to wind load, spreading rate, thermal insulation proof, water vapour permeability, water tightness, weathering. 10. According to the above mentioned tests: Do nanomaterials enhanced facade coatings compared to conventional facade coatings? 2 11. What amount of nanoparticles would you recommend to ensure the facade coating functionality? 12. How long will be the effectiveness of nano facade coatings properties guaranteed after the first use? 13. In what areas of the company you have made experience with the following certifications? ISO 9000, ISO 14000, OHSAS 18000, Ecolabel, TÜV 14. How do you treat nanomaterials leftovers and how do you recommend to treat the leftovers (paint residues) from facade coatings which contain nanomaterials? 15. In which topics would you most likely need more information? 16. What does your company to evaluate and minimize health and environmental risks? (more than one answer possible) 17. Are you constantly following the current developments in the field of nanomaterials? 3 Section 2. Answers from paint and ENP producers to the survey questionnaire The following figures show how every type of industry answered the survey questionnaire Q1. Do you produce nanomaterials? Yes 17% Q2. Do you integrate nanomaterials in facade coatings? Yes 14% Large Paint 33% SME Paint Large Paint SME Paint 14% SME ENP SME ENP 72% Large ENP 50% Q3. Would you be willing to provide us information on the energy consumption for the production of nanomaterials or your integration process? Yes 20% Large Paint 40% 20% 20% Q4. Which of the following properties would you like to improve or bring in new facade coatings? 1% Large Paint 18% 46% SME Paint SME ENP SME Paint SME ENP 35% Large ENP Large ENP Q5. Which facade coatings functions can be improved with the following nanomaterials? Large ENP Q6. What ecological performance potential may be achieved by integratding nanomatials in facade coatings? 8% Large Paint 13% SME Paint 51% 28% 15% 12% SME ENP Large ENP Q7. What nanomaterials are currently used in use in Europe for facade coatings? Large Paint 42% SME Paint SME ENP 31% Large ENP Q8. What is your estimate of the total amounts of nanomaterials used in Europe for facade coatings 7% 14% 52% 27% Large Paint Large Paint SME Paint SME Paint SME ENP Large ENP SME ENP 100% Large ENP 4 Q9. What tests have you carried out to analyze the improvement of facade coatings enhanced with the mentioned nanomaterials? 8% 6% Q10. According to the above-mentioned tests: Do nanomaterials enhanced facade coatings comparedto conventional facade coatings? 17% Large Paint Large Paint SME Paint 24% 62% SME ENP SME Paint Large ENP Q11. What amount of nanoparticles would you recommend to ensure the facade coatings functionality? 50% 17% SME ENP Large ENP 16% Q12. How long will the effectiveness of nanoFacade coatings properties be guaranteed after the first use? 8% 9% Large Paint 18% Large Paint 17% 49% SME Paint 52% 21% SME ENP SME ENP 26% Large ENP Large ENP Q13. In what areas of the company you have made experience with the following certifications? Q14. How do you treat nanomaterials leftovers and how do you recommend to treat the leftovers from facade coatings which contain nanomaterials? 7% 8% 14% Large Paint Large Paint 19% 46% SME Paint 58% 21% SME Paint SME ENP Large ENP Q15. In which topics would you most likely need more information? SME Paint SME ENP 27% Large ENP Q16. What does your company to evaluate and minimize health and environmental risks? 4% 4% Large Paint 20% 44% SME Paint SME Paint SME ENP Large ENP 32% Large Paint 18% 52% 26% SME ENP Large ENP Q17. Are you constantly following the current developments in the field of nanomaterials? 25% Large Paint 50% 10% SME Paint SME ENP 15% Large ENP 5