CHEN 354- Chemical Engineering Thermodynamics
II-Spring 12
CHEN354_Syllabus-Spring 12
Week
Dates
Lectures and Reading
Assignments
1-2
1/18, 1/20,
1/23, 1/25,
1/27
Class 1-Review of some basic concepts
An interesting web site:
Notes
Read
Chapter 10
http://www.chemguide.co.uk/physical/phaseeqiamenu.html#top
Class 2- Raoult’s law and Binary phase diagrams
Please check this power point for nice graphs about binary,
ternary, and quaternary VLE--Phase
The Phase software for Thermo II has
been set to install on the computer labs. It should be available on
all the computers in about 1 or 2 days. (2/5/2011)
Phase INTERACTIVE--
3-4
1/30, 2/1,
2/3, 2/6, 2/8,
2/10, 2/13
Partial molar properties
Ideal-gas mixture model
Read
Chapter 11
Fugacity of gases and liquids
Ideal solutions and excess functions
Ideal solutions and excess functions-Part II
2/15
Review class—
2/16
FIRST EXAM: 7-9 pm, JEB 104 and 102
2/17, 2/20,
2/22, 2/24,
2/27, 2/29,
3/2, 3/5
Solution Thermodynamics Applications: Data reduction
5-6-7
Data Reduction and Thermodynamic Consistency Test
VLE using modified Raoult’s law
Models for GE/RT
UNIQUAC-original paper
Read
Chapter 12
HW
UNIQUAC-parameters
Heats of solution
8
VLE-more complete description
3/7, 3/9, 3/19
9-11
3/21
3/22
3/23, 3/26,
3/28, 3/30,
4/2, 4/4, 4/9,
4/11,
4/13, 4/16
Read
Chapter 14
Review class
SECOND EXAM: 7-9 pm, JEB 104 and 102
VLE-Applications
Read
Chapter 14
Equilibrium and stability
Liquid-liquid equilibrium
Examples LLE
Vapor-Liquid-Liquid equilibrium (VLLE)
VLLE problems
12-13-14
4/18
Review class
4/19
4/20,
4/23,4/25,
4/27, 4/30
THIRD EXAM: 7-9 pm, JEB 104 and 102
Solid-Liquid equilibrium (SLE) and Solid-vapor equilibrium
(SVE)
Chemical Reaction Equilibria- Extent of a reaction
The Equilibrium Constant- Temperature dependence and
relation to reaction extent
The Equilibrium Constant- Dependence on Pressure
Liquid phase reactions- Homogeneous and heterogeneous
reactions
Multireaction equilibria
Other examples of multireaction equilibria
5/1
Review class
Read
Chapter 13
Final exam: May 5th, Saturday, 10:30am-12:30pm, JEB
104 and 102